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[c] Precision and Accuracy.

The term precision refers for the closeness of the set of values obtained form identical measurements
of a quantity.
Accuracy refers to the closeness of a single measurement to its true value.
Let us take an example to illustrute. this. Three students were asked to determine the mass of a piece of
metal where mass is known to be 0.520g. Data obtained by each Student are recorded in table below
mesurements in g.
1 2 3 Average
Student A 0.521 0.515 .0509 0.515
Student B 0.516 0.515 .0514 0.515
Student C 0.521 0.500 .0520 0.520
The data for student A are neither, precise nor accurate. The data for student B are precise but not
accurate. The data for student C are both precise and accurate.

M.C.Q.
1. Identify the wrong statement in the follwing (AIEEE 2008).
(a) CFCs are responsible for ozone layer depletion.
(b) Greenhouse effect is responsible for global warming.
(c) Ozone layer does not permit I.R. radiation from the sun to reach the earth.
(d) Acid rain is mostly because of oxides of ‘N’ and ‘S’.
2. In the reaction
2 Al( s )  6 HCl( aq )   Al 3 ( aq )  6Cl  ( aq )  3H 2( g ) (AIEEE 2007)

(a) 6L HC1 ( aq ) is consumed for every 3L, H 2( g ) produced.

(b) 33.6L H 2( g ) is produced regardless of temperature and pressure for every mole of Al that reacts.

(c) 67.2L H 2( g ) at STP, is produced for every mole Al that reacts.

(d) 11.2L H 2( g ) at STP, is produced for every mole HC1 ( aq ) consumed.

3. Consider a titration of potassium dichromate solution with acidified Mohr’s salt solution using diphenyl
amine as indicator. The number of moles of Mohr’s salt required per mole of dichromate is (IIT JEE
2007)
(a) 3 (b) 4 (c) 5 (d) 6
4. Which has maximum number of atoms ? (IIT JEE 2003)
(a) 24g of C (12) (b) 56g of Fe(56) (c) 27g of Al (27) (d)108g of Ag (108)
5. What volume of hydrogen gas at 273K and 1 atm pressure will be consumed in obtaining 21.6 g of
elemental boron (atomic mass = 10.8) form the reduction of boron trichloride by hydrogen (AIEEE
2003)
(a) 89.6L(b) 67.2L (c) 44.8L (d) 22.4L
6. In an organic compound of molar mass 108g/mol, C,H and N atoms are present in 9:1:3.5 by weight
Molecular formula can be (AIEEE 2002)
(a) C6 H 8 N 2 (b) C6 H10 N
(c) C5 H 6 N 3 (d) C4 H18 N 3

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7. Number of atoms in 560 g of Fe (atomic mass = 56) is (AIEEE 2002)

(a) twice that of 70 g N. (b) half that of 20 g H
(c) both (a) and (b) (d) None of these
8. In the standardization of Na2 S 2O3 using K 2 Cr2 O7 by iodometry, the equivalent weight of K 2 Cr2 O7 is
(IIT JEE 2001)
Molar mass Molar mass
(a) (b)
2 6
Molar mass
(c) (d) same as molar mass
3
9. Mixture X=0.02 mole of [Co(NH3)5SO4] Br and 0.02 mole of[Co(NH3)5Br]SO4 was prepared in 2L of
Solution
1L of mixture X  excess AgNO3  Y

1L of mixture X  excess BaCl2  Z

Number of mole of Y and Z are (IIT JEE 2003)

(a) 0.01, 0.01 (b) 0.02, 0.01
(c) 0.01,0.02 (d) 0.02, 0.02
10. How many moles of electron weight one kilogram ? (IIT JEE 2002)
1
(a) 6.023  10 23 (b)  1031
9.108

6.023 1
(c)  1054 (d)  108
9.108 9.108  6.023
11. An Oxide of metal contains 60% of the metal. What will be the equivalent weight of the metal ?

(a) 12 (b) 40 (c) 24 (d) 48

12. A container is filled with 2L of water. What will be the volume of water in m3?
(a) 2  103 (b) 1  103 (c) 2  103 (d) 1  103
13. The mass of carbon -12 atom considered in the definition of a mole is
(a) 0.012Kg (b) 0.12g (c) 120 mg (d) None of these
14. The drug which is used for treating AIDS victims is
(a) Azidothymidine (b) Cis- platin
(c) Taxol (d) All of these
15. Chose the incorrect statement .
(a) The constituents of a compound cannot be separated into simpler substances by physical meth-
ods.
(b) An element is consists of only one type of particles and these particles may be atoms or molecules.
(c) The properties of a compound are same as its constituent elements.
(d) Atoms of different elements are different in nature.

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16. Which of the following is a pair of physical and chemical property respectively of a substance ?
(a) acidity & combustibility (b) colour & density
(c) basicity & colour (d) density & acidity.
17. What is the symbol of S.I. unit for the amount of substance ?
(a) NA (b) n (c) mole (d) mol
18. What is the symbol of a multiple ‘109’ ?
(a) G (b) E (c) n (d) Z
19. Find the correct relation.
5 o
(a) o F  9 (o C )  32 (b) C  ( F  32)
o

5 9
(c) Both & (a) and (b) (d) Neither (a) nor (b)
20. In chemistry a number is represented in the form N  10n . This method of expressing the number is
called scientific notation. What is the value of ‘N’ here.
(a) 1 to 10 (b) 0.1 to 9.99
(c) 10 to 100 (d) Any value can be taken
21. What is the correct scientific notation for 0.00016 ?
(a) 1.6  10 4 (b) 16  10 5

(c) 0.16  103 (d)cannot be determined.

22. How many significant digits are there in 0.25 ?
(a) 1 (b) 2 (c) 3 (d) cannot be determined.
23. Which of the following number contains there significant digits ?
(a) 0.200 (b) 0.030 (c) 0.0052 (d) 0.002
2+
24. What is the number of neutrons in Zn ion
(Atomic mass namber = 70) (IITJEE 1979)
(a) 34 (b) 36 (c) 38 (d) 40
25. The same amount of Zinc is treated separately with excess of sulphuric acid and excess of sodium
hydroxide.
What will be the ratio of volumes of hydrogen evolved ? (IITJEE 1979)
(a) 1 : 1 (b) 1 : 2 (c) 2 : 1 (d) 9 :4
26. 2.76g of silver carbonate on being strongly heated yields a residue weighing (IITJEE 1979)
(a) 2.16g (b) 2.48 g (c) 2.32 g (d) 2.64 g
27. Find the total number of electrons in one molecule of carbon dioxide.
(a) 22 (b) 44 (c)66 (d) 88
28. A gaseous mixture contains oxygen and nitrogen in the ratio of 1 : 4 by weight. Therefore, the ratio of
their number of molecules is
(a) 1 : 4 (b) 1 : 8 (c) 7 : 32 (d) 3 : 16
29. Identify the incorrect unit conversion factor.

1cm 3 1cm 60s

(a) (b) (c) (d) None of these
1mL 10mm 1min

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30. 90 g KClO3 on heating gives 2.96g KCl and 1.92g oxygen. Which of the follwing laws is illustrated by
this statement ?
(a) Law of definite proportion (b) Law of mass conservation
(c) Law of multiple proporation (d) Avogadro’s law.
31. Match the following property.
A B
(i) Law of Multiple proportions. (p) Richter
(ii) Law of Combining volumes (q) Proust
(iii) Law of Reciprocal proportions. (r) GayLussac
(iv) Law of Constant composition. (s) Dalton
(a) i - s, ii - p, iii - r, iv - q (b) i - s, ii - r, iii - p, iv - q
(c) i - s, ii - r, iii - q, iv - p (d) i - q, ii - r, iii - p, iv - s
32. Two oxides of a metal ‘M’ contain 27.6% and 30.0% of oxygen respectively. If the formula of the first
oxide is M3O4 , find that of the second.
(a) M 2 O3 (b) M 2 O (c) MO2 (d) M 3O2
33. Naturally occuring Boron consists of two isotopes having atomic masses 10.01 and 11.01 respectively.
Calculate the percentage of both the isotopes in natural Boron (Atomic mass of natural Boron = 10.81)
(a) 20% and 80% (b) 80% and 20%
(c) 25% and 75% (d) 75% and 25%
34. Calculate the mass percent of Na and S in sodium sulphate.
(a) Na = 16.2%, S = 22.54% (b) Na = 32.39%, S = 11.26%
(c) Na = 22.54%, S = 32.39% (d) Na = 32.39%, S = 22.54%
35. Determine the empirical formula of an oxide of iron which has 69.9% iron and 30.1% oxygen by mass.
(a) FeO (b) Fe2O3 (c) Fe3O4 (d) Fe3O2
36. Calculate the amount of carbon dioxide that can be produced when 1 mole of carbon is burnt in 16 g of
dioxygen.
(a) 44g (b) 22g (c) 88g (d) 11 g
37. Calculate the concentration of nitric acid in moles per litre which has a density , 1.41 g/mL. %w/w of
nitric acid is
(a) 15.44M (b) 0.064M (c) 0.077M (d) 12.87M

38. In a reaction : N 2( g )  3H 2( g )  2 NH 3( g ) , 2000g N 2 reacts with 1000g H 2

which reactant will left unreacted ? How much ?
(a) N2 , 2428 g (b) H 2 , 428.6 g
(c) N 2 , 571.4 g (d) H 2 , 571.4 g
39. Calculate the number of sulphate ions in 100mL of 0.001M ammonium sulphate solution.
(a) 6.022  1019 (b) 6.022  1019
(c) 6.022  1020 (d) 6.022  1020
40. Calculate the molarity of a solution of ethanol in water in which mole fraction of ethanol is 0.040.
(a) 2.31M (b) 0.213M (c) 0.0213M (d) 23.1M

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41. Some statements are given below based on the pictures. Identify true and false statements.

(P) (Q) (R)

(i) ‘P’ and ‘Q’ both indicates precision and accuracy.
(ii) ‘Q’ indicates precision and accuracy white ‘R’ indicates neither precision nor accuracy.
(iii) ‘P’ indicates precision but not accuracy.
(iv) ‘Q’ indicates both precision and accuracy
(a) FTTT (b) TTTT (c) TTFT (d)FTFT
42. The normality of 0.3M phosphorous acid is (IITJEE 1999)
(a) 0.1 (b) 0.9 (c) 0.3 (d) 0.6
43. An aqueous solution of 6.3g oxalic acid dihydrate is made upto 250 mL. The volume of 0.1 N NaOH
required to completely neutralize 10 mL of this solution is
(a) 40 mL (b) 20 mL (c) 10 mL (d) 4 mL
44. The pair of the compounds in which both the metals are in the highest possible oxidation state is
3 3
(a)  Fe  CN 6  , Co  CN 6  (b) CrO2 Cl2 , MnO4 

3
(c) TiO3 , MnO2 (d) Co  CN 6  , MnO3
45. In the analysis of 0.0500 g sample of feldspar, a mixture of the chiorides of sodium and potassium is
obtained, which weighs 0.1180 g. Subsequent treatment of the mixed chlorides with silver nitrate gives
0.2451g of silver chloride. What is the percentange of a sodium oxide and potassium oxide in
feldspar ?
(a) 10.62% Na2O , 3.58% K 2O (b) 3.58% Na2O , 10.62% K 2O

(c) 10.62% Na2O , 35.8% K 2O (d) 35.8% Na2O , 10.62% K 2O

46. 5.5 g of a mixture of FeSO4.7H2O and Fe2 (SO4)39H2O requires 5.4 mL of 0.1N KMnO4 solution for
complete oxidation. Calculate the number of mole of Fe2 (SO4)39H2O in the mixture.
(a) 0.0095 (b) 0.15 (c) 0.0952 (d) 1.52
47. A compound contains 28% of nitrogen and 72% of a metal by weight. Three atoms of the metal
combine with two atoms of nitrogen. Find the equivalent weight of the metal.
(a) 12 (b) 24 (c) 36 (d) 48
48. The density of a 3M Na2|S2O3 solution is 1.25 g per mL, What is the molalities of Na+ and S2O32-ions ?
(a) 3.865, 7.732 (b) 7.732, 3.865 (c) 1.933, 7.732 (c) 7.732, 1.933

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49. Haemoglobin present in blood contain 3.72% by mass iron. Calculate the number of iron atoms in 2.0g
of haemiglobin.
(a) 4.53 X 1026 (b) 4.53 X 1023 (c) 5.95 X 1019 (d) 8 X 1020
50. How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms (AEEE
2006)
(a) 0.02 (b) 3.125 x 10-2 (c) 1.25 x 10-2 (d) 2.5 x 10-2
51. The unit J Pa -1 is equivalent to
(a) m3 (b) cm3 (c) dm3 (d) none of these
-3
52. The density of Al metal is 2.7 gcm . An irregularly shaped piece of aluminium weighing 40.0g is added
to a 100mL graduated cylinder containing 50.0mL of water. upto what height the water level will rise in
the cylinder ?
(a) 14.8mL (b) 79.6mL (c) 64.8mL (d) 50mL
53. A sample of clay after drying partially was found to contain 50% silica and 7% water.The original
sample of clay had 12% water, What is the percentage of silica in the original sample?
(a) 50% (b) 5% (c) 43% (d) 47%
54. In which of the following pairs percent compostion of element is not same ?
(a) benzene and ethyne (b) But - 2 - ene and Cyclobutane
(c) glucose and fructose (d) phenol and ethanol
55. What weight of CuO will be required to provide 200Kg copper
(a) 200Kg (b) 79.5Kg (c) 250Kg (d) 100Kg
56. Choose the proper option after studying following statement (T = True, F = False)
1. The percent composition of vinyl chloride and its polymer PVC are same.
2. The perecent compostion of phosphorous trioxide (P2O3)is half than that of its dimer phosphorous
hexoxide (P4O6) for each of the elements present in them.
(a) T, F (b)F,T (c) T, T (d) F, F
57. Impure sample of ZnS contains 42.34% Zn. What is the percentage of pure ZnS in the smaple ?
(a) 67% (b) 63% (c) 58% (d) 37%
58. If the atomic mass of carbon were set at 50 amu, what would be the value of Avog adro’s number ?
(a) 5.01 x 1024 (b) 6.022 x 1023 (c) 1.66 x 1024 (d) none of these
59. For which of the following compounds molecular weigh cannot be determined from atomic weights ?

(a) Fe4  Fe  CN 6  (b) TiO2

(c) TiO1.12 (d) none of these

60. Which one of the following contains greatest number of oxygen atoms ?
(a) 1.0g of O atoms (b) 1.0g of O2
(c) 1.0g of O3 (d) All have same number of atoms

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61. Which of the following chemical equation is incorrectly balanced ?

(a) Sb2 S3  12 HCl  2H 3 SbCl6  3H 2 S

(b) 3IBr  4 NH3  NI3  3NH 4 Br

(c) 2 KrF2  2 H 2O  2 Kr  2O2  4 HF

(d) PCl3  3 H 2 O  H 3 PO3  3 HCl

62. Match the following
Column -I Column -II
(i) Cl2O3 (P) basic anhydride
(ii) Li2O (Q) acid anhydride
(iii) CO2 (R) base
(a) (i) - (q) (ii) - (p) (iii) - (q)
(b) (i) - (r) (ii) - (q) (iii) - (p)
(c) (i) - (p) (ii) - (q) (iii) - (r)
(a) (i) - (p) (ii) - (q) (iii) - (p)
63. How many g of NaOH can be obtained by reaction of 1 Kg of Na2CO3 with Ca(OH)2 ?
(a) 106 g (b) 850 g (c) 755g (d) 943 g
64. How much calcium oxide (CaO) can be obtained by heating 200 Kg of lime stone theat is 95% pure
CaCO3 ?
(a) 56Kg (b) 190Kg (c) 170Kg (d) 107Kg
65. Calculate the amount of NaOH required to neutralize 100 mL 0.1M H2SO4.
(a) 40g (b) 0.4 g (c) 80 g (d) 0.8 g
66. 3g of an oxide of a metal is converted into chloride and it yielded 5 g of chloride. Find the equivalent
weight of the metal.
(a) 33.25 (b) 3.325 (c) 12 (d) 20
67. A compound contains two oxygen atoms, four carbon atoms and number of hy drogen atoms is double
of carbon atoms. What is the density of vapour of this compound ?
(a) 88 (b) 44 (c) 132 (d) 72
68. The number of molecules in 100 mL of each of O2,NH3 and CO2 at STP are
(a) CO2  O2  NH 3 (b) NH 3  O2  CO2

(c) NH3 = CO2 < O2 (d) NH 3  O2  CO2

69. Which of the following represents the formula of a compound which contains 26% nitrogen and
74% oxygen ?
(a) N2O (b) NO (c) NO2 (d) N2O5
-1
70. NKg is the unit of
(a) momentum (b) velocity (c) Pressure (d) accelaration

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71. Which one of the following statements is incorrect ?

(a) All elements are homogeneous system
(b) Compounds made up of a number of elements are heterogeneous.
(c) A mixture is not always heterogeneous
(d) Smoke is a heterogeneous mixture.
72. A balanced chemical equation is in accordance with
(a) Avogadro’s law.
(b) Law of constant proportions
(c) Law of conservation of mass
(d) Law of gaseous volumes.
73. The atomic weights of two elements X and Y are 20 and 40 respectively. If ‘a’ gm of X contains ‘b’
atoms, how many atoms are present in ‘2a’ gm of Y ?

a
(a) b (b) a (c) 2b (d) ( )
2
74. If the components of air are N2 ,78%, O2, 21% ; Ar, 0.9% and CO2, 0.1% by volume, what will be the
molecular weight of air ?
(a) 28.9 (b) 32.4 (c) 16.4 (d) 14.5
75. Calculate the molarity of a solution obtained by mixing 50mL of 0.5M H2SO4 and 75 mL of 0.25M
H2SO4.
(a) 0.375M (b) 0.35M (c) 0.045M (d) 0.45M
76. Which of the following has the highest normality ?
(a) 1M H2SO4 (b) 1M H3PO3 (c) 1M H3PO4 (d) 1M HNO3
77. In an experiment, 4 gm of M2Ox oxide was reduced to 2.8 gm of the metal. If the atomic mass of the
metal is 56 gm/mol, the number of oxygen atoms in the oxide is (AFMC 2010)
(a) 1 (b) 2 (c) 3 (d) 4
78. Match the following
Column - I Column - II
(i) femto (P) 109
(ii) yotta (q) 10-15
(iii) giga (r) 10-18
(iv) atto (s) 1024
(a) i - q, ii - p, iii - r, iv - s (b) i - s, ii - q, iii - p, iv - r
(c) i - q, ii - s, iii - p, iv - r (d) i - r, ii - s, iii - p, iv - q
79. The total number of atoms of all elements present in mole of ammonium dichromate is
(a) 19 (b) 6.023 x 1023 (c) 114.47 x 1023 (d) 84 x 1023
80. 0.32 gm of a metal on treatment with an acid gave 112 mL of hydrogen at STP. Calculate the equivalent
weight of the metal
(a) 58 (b) 32 (c) 11.2 (d) 24

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81. For a reaction A + 2B  C, the amount of C formed by starting the reaction with 5 moles of A and 8
moles of B is
(a) 5 moles (b) 8 moles (c) 16 moles (d) 4 moles
82. 100 mL of PH3 on heating forms P and H2 . The volume change in the reaction is
(a) an increase of 50 mL (b) an increase of 100 mL
(c) an increase of 150 ml (d) a decrease of 50 mL
83. An organic compound made of C, H, and N contains 20% nitrogen. Its molecular weight is (WBJEE
2009)
(a) 70 (b) 140 (c) 100 (d) 65
84. Volume occupied by one molecule of water (d = 1 gm cm -3) is
(a) 9 x 10-23cm3 (b) 6.02 x 10-23cm3 (c) 3 x 10-23cm3 (d) 5.5 x 10-23cm3
85. Calculate the number of moles in 1m3 gas at STP.
(a) 4.46 (b) 44.6 (c) 446 (d) 4460
86. An ore contains 1.24% of the mineral argentite Ag2S by mass. How many grams of this ore would have
to be processed in order to obtain 1.0 g of pure solid silver ?
(a) 23.15 g (b) 69.45 g (c) 92.6 g (d) 46.3 g
87. Find the electric charge in couloumb of 9.0 gm of A13+ ions.
(a) 9.6 x 104 (b) 6.9 x 104 (c) 2.9 x 105 (d) 4.80 x 10-19
88. Which of the following is not a homogeneous mixture ?
(a) smoke (b) air (c) Brass (d) Aqueous solution of sugar
89. Which of the following has the largest number of atoms ?
(a) 0.5g atom of Cu (b) 0.635g of Cu
(c) 0.25 moles of Cu atom (d) 1 g of Cu
90. 27 g of A1 (at mass = 27) will react with oxygen equal to (IIT 1978)
(a) 24 g (b) 8 g (c) 40 g (d) 10 g
91. Two containers P and Q of equal volumes contain 6 g of O2 and SO2 respectively at 300K and 1
atmosphere. Then
(a) No. of molecules in P is less than that in Q
(b) No. of molecules in Q is less than that in P
(c) No. of molecules in P and Q are same.
(d) cannot be determined
92. Which of the following pairs of substances illustrates the law of multiple proportions ?
(a) CO and CO2 (b) NaCl and NaBr
(c) H2O and D2O (d) MgO and Mg(OH)2
In each of the follwoing questions, two statements are given, one is Assertion (A) and the other
is Reason (R). Examine the statements carefully and mark the correct answer according to
the instructions given below :
(a) If both A and R are correct and R is the correct explanation of A.
(b) If both A and R are correct and R is not the correct explanation of A.
(c) If A is correct R is wrong.
(d) If both A and R are false.

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