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4.
Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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CALORIMETRY
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CONCEPT - I
CLARITY ACHIEVER - I
1) b 2) c 3) a 4) d 5) a 6) b 7) d 8) b
9) d 10) a 11) b 12) d 13) d

APPLICATION SKILL ACHIEVER - I

SILVER PACKAGE :
1. b
2. b
3. b
S = 0.03 cal / gm°C
S = 0.03 cal / gm°C
0.03 × 4.2 J 0.126
= =
10 −3 kgK 10 −3

S = 126 J kg −1 K −1
4. b
m = 2kg, Δt = 50 – 10 = 40°C
Sw = 4200 J Kg–1°C–1, Q = ?
Q = ms Δt
= 2 × 4200 × 40
= 336000

Q = 336 × 103 J
5. i - c , ii - c , iii - a

GOLD PACKAGE :
6. a
m = 1g = 10–3 kg
Δt = 1°C, S = 4200 J Kg–1°C–1
Q=?
Q = ms Δt
= 10–3 × 1 × 4200 = 4.2 J = 1 cal

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Varsity Education Management Pvt. Ltd. 1
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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∴ Q = 10 −3 kCal
7. a
m = 20g = 20 × 10–3 kg, Q = ?
Δt = 15 – 10 = 5°C, S = 4200 J Kg–1°C–1
Q = ms Δt
= 20 × 10–3 × 4200 × 5
Q = 420 J
8. c
Q = 420 J, m = 10 g = 10–2 kg, S = 4200 J kg–1°C–1, Δt = ?
Q = ms Δt

Q 420
Δt = = −2 = 10°C
ms 10 × 4200

Δt = 10°C

PLATINUM PACKAGE :
9. b
m = 2kg, Q = 3600 J, S = 900 J kg–1°C–1
Δt = ?
Q = ms Δt

Q 3600
Δt = = = 2°C
ms 2 × 900

∴ Δt = 2°C
10. c
Q = 360 J, Δt = 25 – 20 = 5°C, S = 470 J kg–1°C–1, m = ?
Q = ms Δt

Q
m=
sΔt

360
= = 0.15kg
470 × 5

m = 0.15kg

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2 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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CONCEPT - II
Clarity Achiever - II
1) c 2) c 3) c 4) a 5) a 6) a, c, d 7) d 8) b

APPLICATION SKILL ACHIEVER - II

SILVER PACKAGE :
1. a
2. a
3. a
Cp
Cv = 5 mol–1 cal K-1, =?
Cv
R = 2 cal mol–1 K–1
CP – CV = R
⇒ CP = CV + R = 5 + 2 = 7
∴ CP : CV = 7 : 5
4. d
3R 5R
(CV)mono = , (CV)dia =
2 2
(CV)mix = ?

(CV )mono + (CV )dia

(CV)mix =
2

3R 5R
+ 8R
= 2 2 = = 2R
2 4

(CV )mix = 2 R
5. d
CP
= 1.4 , C = 20.8 J / mol K, C = ?
CV V P

CP = 1.4 CV
= 1.4 × 20.8
= 29.12 J mol–1 K–1
29.12
CP = = 6.93 cal mol–1 K–1
4.2
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Varsity Education Management Pvt. Ltd. 3
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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C P = 6.93cal mol −1K −1

6. i - b , ii - d , iii - a

GOLD PACKAGE :
7. a, b
8. b
Q = 70 cal, n = 2 mol, t = 35°C – 30° C
CP = ? r = 2 cal mol–1 K–1
Q 70 Q
CP = = = 7 cal mol–1 K–1 ⇒ CV = ⇒ Q = nCV T
nt 2 × 5 nt
CP – CV = R
CV = CP – R = 7 – 2 = 5 cal mol–1 K–1
∴ Q = nCVT = 2 × 5 × 5 = 50 cal
∴ Q = 50cal
9. c
m = 3g = 3g
But 2g = 1 mol (for hydrogen)
∴ n = 3g = 1.5 mol
7 CP
t = 1°C, r = 5 =
CV
Q=?
Q = nCVT = 1.5 × 5 × 1 = 7.5 cal
(OR)
CP 7
CP – CV = 2, =γ =
CV 5
dQ = nCVdt H2 = 2
m 3
CV dt = × 5 × 1 = 7.5 cal
=
M 2
Platinum Package :
10. c
11. c
5
γm = nmono = 1 mole
3
7
γd = ndia = 3 mole
5
(CV)mix = ?
nm (CV )m + nd (CV )d
(CV)mix =
nm + nd
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4 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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3R 5R
1× +3× 18 R
= 2 2 = = 2.25 R
1+ 3 8

CONCEPT - III
CLARITY ACHIEVER - III
1) a 2) a 3) b 4) d 5) b

APPLICATIN SKILL ACHIEVER - III

SILVER PACKAGE
1. a
2. c
r1 : r2 = 2 : 3, s1 : s2 = 3 :4, d1 : d2 = 4 : 5, w1 : w2 = ?

4 3
w1 m1s1
π r1 d1s1
= = 3
w 2 m 2 s2 4 π r 3 d s
3 2 2 2

4 2
[3 m = vd ] = π r d]
3

w1 ( 2) × 4 × 3
3

∴ =
w 2 (3)3 × 5 × 4

∴ w1 : w2 = 8 : 45
3. d
m = 200 g = 200 × 10–3 kg
Q = 252 J, Δt = 10°C, H = ?

Q 252
Thermal capacity = = = 25.2 JK–1
t 10
4. b
Q = 1000 cal, Δt = 70 – 20 = 50°C , W = ?

Q 1000
W = ms, Q = ms Δt ⇒ ms = = = 20 g
Δt 50

w = ms = 20 g
5. b
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Varsity Education Management Pvt. Ltd. 5
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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Q = 4500 cal, Δt = 80 – 30 = 50°C

Heat capacity = ?
H.C = ms, Q = mst
Q 4500
∴ ms = = = 90 cal/°C
Dt 50
6. i - b , ii - b , iii - d

GOLD PACKAGE :
7. c
m1s1Δt1 = m2 s2 Δt2
s1 Δt2 30 − 26 4 2
⇒ s = Δt = = =
2 1 26 − 20 6 3
∴ s1 : s = 2 : 3
8. c
Vw = 1200 cm3, Vi = ?, Si = 0.1 cal / g°C , di = 7.5 g/cm3
Heat capacity = ms = dvs
Heat capacity of iron = Heat capacity of water
⇒ di Vi Si = dw Vw Sw
dwVw Sw
∴ Vi =
di si
1 × 1200 × 1
= = 1600cm 3 ∴ Vi = 1600cm 3
7.5 × 0.1
9. a
m1 s1 Δt2 ρ1s1 3 × 2 1
⇒ m1s1Δt1 = m2 s2 Δt2 ⇒ m s = Δt = ρ s = 4 × 3 = 2
2 2 1 2 2

PLATINUM PACKAGE :
10. d
dA = 0.5 g/cm3, dB = 0.6 g/cm3, VA = 8 lit, VB = 10 lit, SA : SB = ?
Heat capacity = ms = dVS
dAVASA = dBVBSB
S A d BVB 0.6 × 10 6 3
∴ = = = =
S B d AV A 0.5 × 8 4 2
∴ SA : SB = 3 : 2
11. c
r1 : r2 = 2 : 3, H1 : H2 = ?
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6 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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4 3
H.C. = ms = π r ds ⇒ H α r 3
3

H1 r13 ( 2)
3
8
= 3= 3 =
H 2 r2 (3) 27

H1 : H 2 = 8 : 27

CONCEPT - IV
CLARITY ACHIEVER - IV
1) c 2) c 3) b 4) b 5) c 6) b 7) d

APPLICATION SKILL ACHIEVER - IV

SILVER PACKAGE :
1) a 2) a 3) c 4) a 5) d 6) i - a , ii - a , iii - a

GOLD PACKAGE :
7. d
3 3 3
of the energy is ratined i.e., of potential energy = mgh
4 4 4
ice melted
3
mgh = mL , L = 80 cal / g
4
80 × 4.2 J 3
= −3
= 80 × 4200 J/Kg = m gh = m L
10 kg 4
3
∴ × 10 × h = 80 × 4200
4

80 × 4200 × 4
h= = 44800 m
3 × 10
∴ h = 44.8 km
8. a
m = 0.3kg, t = 1min = 60s
w Q mL 0.3 × 80 × 103
power = = = =
t t t 60

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Varsity Education Management Pvt. Ltd. 7
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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power = 400 cal/g

9. b
m = 5g L = 80 cal/g
= 5 × 10–3 kg , Q = ?
Q = ML = 5 × 80
Q = 400 cal/g
∴ Q = 400 cal/g

PLATINUM PACKAGE :
10. b
m = 10g, L = 540 cal/g
= 540 × 4.2 J/g
Q = ? , Q = ML
= 10 × 540 × 4.2
= 2.26 × 104 J

∴ Q = 2.26 × 10 4 J
11. b,
m
Melted mass, m =
100
L = 80 cal/g = 336 J/g = 336 × 103 J / Kg Q = ?
Q = mgh = mL
m
⇒ mgh = L
100

1 L 336 ´ 10 3
⇒ h= ⇒ h= = 336m
100 g 100 ´ 10

∴ h = 336 m
12. a
v = 20m/s, m1 = 4.2kg,
L = 336 × 103 J/kg
1
Q= m1v 2
2
But Q = ML

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8 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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1
∴ m1v 2 = mL
2

1
∴ × 4.2 × 20 × 20 = m × 336 × 103
2

21 × 40 × 10 −3
∴ m=
336
= 2.5 × 10–3kg
∴ m = 2.5g

CONCEPT -V
CLARITY ACHIEVER- V :
1) d 2) c 3) a 4) b 5) a

APPLICATION SKILL ACHIEVER - V

SILVER PACKAGE :
1. a
m = 200g, t1 = 30 °C, t2 = 60 °C
T=?
QLost = Qgained
mw sw Δt = ms sw Δt
⇒ 200 × 1 × (60 – T) = 200 × 1× (T – 30) ⇒ 60 – T = T – 30
∴ 2T = 90
T = 45 °C
2. b
mw = 400 g, t1 = 100 °C, mw = 200 g
t2 = 40 °C, T = ? (final temp)
Q lost by body = Q gained by body
mw sw Δ = mw sw Δt
⇒ 400 × 1 × (100 – T) = 200 × 1 × (T – 40)
⇒ 2(100 – T) = T – 40 ⇒ 3T = 240 ⇒ T = 80°c
∴ T = 80°C
3. d
TA = 30 °C, TB = 20 °C
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Varsity Education Management Pvt. Ltd. 9
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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mA = mB, T = 26 °C, sA : sb = ?
QA = QB
S A 26 − 20 6 3
⇒ mA sA (TA – T) = mBsB (T – TB) ⇒ = = =
SB 30 − 26 4 2
S A : SB = 3 : 2
4. a
mb = 100g, Tn = 80 °C, ml = 200g Tl = 20 °C, T = ?
Q2 = Qg
⇒ mn s (Tn – T) = mlsl (T – Tl) ⇒ 100 × 1(80 – T) = 200 × 1(T – 20) ⇒ 80 – T = 2T – 40
3T = 120
∴ T = 40 °C
5. d
m1 L + m1sΔt1 = m2 sΔt2
⇒ 10 × 80 + 10 × 1 × (T – 0) = 100 × 1 × (50 – T) ⇒ 110 T = 4200 ⇒ T = 38.2 ºC
6. i - b , ii - d , iii - d

GOLD PACKAGE :
7. a
ml1 = 10 kg , ml2 = 5 kg
Tl1 = 40 °C Tl2 = 10 °C T = ? , Q2 = Qg

ml1 s ( 40 − T ) = ml2 s (T − 10 )
⇒ 10 × 1 (40 – T) = 5 × 1 (T – 10) ⇒ 80 – 2T = T – 10

∴ 3T = 90 T = 30 °C
8. a
mice = 100g, mb = 100g, Tw = 100 °C Ti = 0 °C, T = ?
QLoar = Qgain
m w sw (100 − T ) = mL + msΔt
⇒ 100 × 1 (100 – T) = 100[80 + T] ⇒ 100 – T = 80 + T ⇒ 2T = 20
∴ T = 10°C
9. mw = 20g, mi = 100g, sb = 0.1 cal/ g °C
QLost = Qgain
mw sw Δt = msΔt

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10 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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⇒ 20 × 1 (100 – T) = 100 × 0.1 × T ⇒ (100 – T) 2 = T

2T = 200 , T = 200/3 = 66.66 °C
T = 66.66°C

PLATINUM PACKAGE :
10. a
mb = 100g, mw = 400g, Tw = 10 °C
T = 20 °C, TFurnace = ?
Sb = 0.032 cal/ g °C
Heat lost by body = Heat gained by body
4000
⇒ ms Δ t = (ms Δ t) ⇒ 100 × 0.032 (T – 20) = 400 × 1 (20 – 10) ⇒ T – 20 = = 1250
3.2
∴ T = 1270 °C
11. a
QL = Qg (cavity)
m L sl Δt = mL
16 × Si × 112.5 = 2.5 × 80
2.5 × 80
⇒ Si = = 0.11 cal/g–1 °C–1
16 × 112.5

CONCEPT - VI
CLARITY ACHIEVER - VI
1) d 2) a 3) b 4) a 5) d 6) a 7) a 8) a
9) True 10) True

APPLICATION SKILL ACHIEVER - VI

SILVER PACKAGE :
1. b
Sice = 0.53 cal/ °C, Lf = 80cells
Lvop = 539cal/ °C, m = 1g
Q1 = ms Δ t = 1 × 0.53 (0 + 20) = 10.6 cal
2. b
Q2 = mLf = 1 × 80 = 80cal

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Varsity Education Management Pvt. Ltd. 11
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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3. a
Q3 = ms Δ t = 1 × 1 × 100 = 100cal
4. d
Q4 = mLvop = 1 × 539 = 539cal
5) c 6) a 7) b 8) c 9) b 10) a
Calorimetry
Student Additional Task - I
1. b
m1 = ‘a’g ; m2 = ‘b’g
Δt = t1 °C ; S2 = 1 cal g–1 c–1|
Q1 = ? ; Δt = t2 °C
S1 = ? ; Q2 = ?
Q1 = Q2
a S1t1 = b × 1 × t2

[ m S Δt
1 1 1 = m2 S2 Δt2 ]

bt20
S=
at1

2. a
loss of
Potential energy = Q
m = 10 kg 25m
S = 252 J kg–1 k–1
Δt = ? 0.5 m
10 × 10 × 24.5 = 10 × 252 × Δt __________(1)

10 × 10 × 24.5 245
Δt = =
10 × 252 252

Δt = 0.972 k
3. d
water :
m= 10 kg , Δt = 10 °C in t = 5 min, Sw = 2 S0
‘Q’ produced by heater in water = 10 × 10 × 2 (S0)
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12 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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= 200 (S) cal
Oil :
m = 30 kg
Δt = 10 °C
Soil = So
Q = 30 × 10 × So = 300 (So )
Q = 30 × 10 × So = 300 (So)
For 200 cal = 5 min
100 cal = 2.5 min
1 ton for
300 = 3 × 2.5 min
⇒ t = 7.5 min

Cp
4. =r
Cv

5. b
Q = 270 J
Δt = 10 k
n = 1 mole

270
Cp = = 27 J k–1 mol–1 k–1
10

Q
Q2 =
mΔt
we know Cp – Cv = R
⇒ 27 – Cv = 8.3
∴ Cv = 18.7 ev
∴ Q = Cv × Δt = 10 × 18.7
⇒ Q = 187 J
6. a
m = 0.32 g
⇒ Δt = 10 °C (or) 10 k
Cv = 20 J mol–1 k–1
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Varsity Education Management Pvt. Ltd. 13
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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Q=?

m
Q = Cv m Δt = Cv × × Δt
M

0.32
= 20 × × 10
32
Q = 2J
7. b
Cp – Cv = 5000J kg–1 k–1

Cp
= 1.6
Cv

Cp = ?
Cp = 1.6 Cv
⇒ 1.6 Cv – Cv = 5000

5000
⇒ Cv = .
0.6

5000 8000
⇒ Cp = 1.6 × =
0.6 6
= 1.3333 × 104
⇒ Cp = 13333.3 J kg–1 k–1
8. c
v = 0.2 m3
t1 = 300k
p = 1.0 × 105 Nm–2
Cv = 3 cal mol–1 k–1
t = 400 k
Q=?

PV
Q = Cv n Δt = 3 × 4.18 × × 100
RT

3 × 4.18 × 1 × 10 5 × 0.2 × 100 0.876 × 105 876

= = = × 103
8.3 × 300 8.3 83
= 10.55 × 103 = 2409 cal
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14 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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9. c
n=2
Δt = 10 °C (or) 10 k
at Cp , Q = ?
Q = Cp n Δt

3
given Cv = R
2

3
Cp – R=R
2

5R
⇒ Cp =
2

5R
∴ Q= × 2 × 10
2
⇒ Q = 50 R
10. b
Q = 6 cal
n = 1 mole

3R
Cv =
2

Δt = ?
as we know Q = Cv n Δt

Q 6
= × 10 3
Δt = C v n 3 × 2 × 1
2

⇒ Δt = 2 °C
11. b

CA
=?
CB

CA dA
⇒ = = 1:2
C B dB
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Varsity Education Management Pvt. Ltd. 15
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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γ A 0.5 2
⇒ = =
γB 1 1

SA 1
⇒ S =3
B

C A m A SA v A ρ A SA
∴∴ C = m S = v ρ S
B B B B B B

4
ΔS ⇒ v = π r 3 for the sphere
3

4
π ( 0.5) × 2 × 1
3

3 2
=
= 4
π (1) × 1 × 3
3 8×3
3

CA
∴ = 1 : 12
CB

12. a

SA 2 ρ A 6 VA
= ; = ; = 1
SB 3 ρ B 5 VB

CA mASA ρASA 6 2
= = = × = 4
CB mBSB ρB SB 5 3 5

CA
⇒ C =4:5
B

13. a
Δt = 81 °C
S = 1 cal g–1 C–1
Q = ms Δt = m(1) × 81
∴ Q = 81 m ⇒ 6 min
For steam at 800 m:
Qv = Qm = 540 cal

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16 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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540 × 6
Lsteam = 540 cal/g =
81

540 × 6
For 540 m ⇒ x ; x =
81
x = 40 min
14. a
2kg __________ 8 km
m m
8 × 80 = 8 × 10 × y
y = 8 km x km y=?
y = x km
15. b
consider ‘x’ g of steam condenced into water at 100 °C
Q = Lv
= x × 540 cal __________ (1)
Now ice at 0 °C is converting water at 100 °C by observing heat. required heat is
⇒ 6 × 80 + 6 (100) = x × 540
100 °C 100 °C
⇒ 480 + 600 = x × 540 0 °C 0 °C
steam
1089 water water
⇒ =x L2
540
msΔt Lf
x = 2g
Left mass = 6 – 2 = 4
m = 4g
16. a
steam at = 100 ° C (t1)
m = 1.1 kg = 1100 g
w = 0.02 kg = ms
t2 = 15 °C , t3 = 80 °C
⇒ x × 536 + x (100 – 80) = 1.1 (80 – 15) + 0.02 (80 – 15)
⇒ 556 x = 1.12 × 65

1.12 × 65
⇒ x= = 0.1309 kg ⇒ x = 0.131 kg
556
Student Additional Task - II
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Varsity Education Management Pvt. Ltd. 17
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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1. a
2. b
m = 20 × 10–3 kg ; v = 210 ms–1

1 1
E= mv2 = × 20 × 10–3 × 21 × 21 × 102 = 441 J
2 2

1
1J = cal
4.18

441
441 = cal
4.18
= 105. 50 cal
3. c
S = 0.09 cal g–1 c–1
1 °C = 1.8 °F
Sp = 0.09 cal
4. c
Hydrogen gas is mono atomic

5R
∴ Cp =
2
and Cp ≥ Cv always

Cp 5 ⎛ 3R ⎞
⇒ C =γ = 3 ⎜⎝3 Cv = 2 ⎟⎠
v

1,3 are correct

5. a
diatomic gas

7R 5R
Cp = ; Cv = =7,5
2 2
Cp – Cv should be ‘2’
6. c
s - same
ρ - same for upper

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18 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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3
V1 ⎛ 5 ⎞
=
V2 ⎜⎝ 10 ⎟⎠
C= =1:8

7. a
a – f, Cp – Cv = R

Cp
b–g , =γ
Cv

C – A , Cp = Cv γ
Cp = Cv γ
Cv γ – Cv = R
Cv ( γ – 1) =

R
Cv =
γ −1

γR
d – c , Cp =
γ −1
8. a
9. c
n = 5 mol ; Δt = 20 °C at Cv
Q = 200 J ; S = ?

200
Cv = J mol–1 k–1 = 2 J mol–1 k–1
5 × 20
10. a
11. a

0.1m
12. m=
100
Ice
L = 80 × 4.2 × 103 = 336 × 103 J

0.1 × 336 × 10 3
∴ × m = m × 10 × h
100
∴ 33.6 m
13. c
for substance like wax, copper, volume ↑ ,
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Varsity Education Management Pvt. Ltd. 19
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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By pressure ↑ ; So malting point ↑

For substance like, Antimojy, Bismuth, Pressure
increased melting point decreases as volume decreases.
14. a
15. a
m1 m2
S1 S2
T1 T2
TR = ? and
Let us consider T1 > T2
According to principal of calorimetry
m1S1 (T1 – TR ) = m2S2 (TR – T2)
⇒ m1S1 T1 + m2S2T2 = TR (m1S1 + m2S2)

m1S1T + m2 S2T2
∴ m1S1 + m2 S2 = TR

16. No option
m1 = m, m2 = 2m, m3 = 3m
S.H.C, S1 = s , S2 = 2s ; S3 = 3s
Temp Δt1 = t ; Δt2 = 2t = 3t = 4t .....
we know for mixture .....

m1S1T1 + m2 s2T2 + ......

TR = m1S1 + m2 S2

mSt (2 m )(2 s ) 2 t + (3m )(3s ) 3t + ....

⇒ TR = mS + (2m ) ( 2 s ) + ......

mSt 2 3 mSt + 3 3 mSt + 4 3 mSt + ...

⇒
mS + 4 ms + 9 ms + 16 ms

t (n ( n + 1))
2

(
mSt 1 + 2 2 + 33 + 4 4 + .... )= 4
(
= mS 1 + 2 + 3 + 4
2 2 2
+ ......) n ( n + 1)(2 n + 1)
6
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20 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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⎢ (
⎡ n 2 ( n + 1) 2 )
×
6
⎤ ⎡ 3n n + 1 ⎤
⎥=⎢ ( ) t
⎥
=t ⎢ 4 n ( n + 1)( 2 n + 1) ⎥ ⎣ 2 (2 n + 1) ⎦
⎣ ⎦

3n ( n + 1)
∴T = t
2 ( 2 n + 1)

17. b
Temp constant ( Δt = 0 ⇒ s = 0)
18. c
19. d
Q1 Q2 Q3
ice ; m = 1g ; t1 = 0 °C
steam t2 = 100 °C, Q = ? Ice water water steam
0 °C 0 °C 100 °C at 100°C
Q1 = mLf = 1 × 80 = 80 cal
Q2 = 1 × 1 × 100 = 100 cal
Q3 = 1 × 540 = 540 cal
∴ Q = Q1 + Q2 + Q3 = 80 + 100 + 540 (536) = 720 cal = 716 cal (Near value)
= 0.716 k cal
20. b

ρ1 5 S1 3 C1
= =
ρ2 6 ; S2 5 ; C2 = ?

v1 = v2

m1S1 5 3
= = ×
m 2 S2 6 5

C1 : C2 = 1 : 2
21. a
22. No option
m = 10 kg
Si = 0.11 cal g–1 c–1
t = 80 °C
= 10 × 0.11 × 80 = x × 80
x = 1.1 kg

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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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23. d
1 _____ m , c, T
2 _____ m/2, 2c, 2T
TR = ?

m
mc (TR – T) = × 2c (T – TR)
2

mcT + 2 mcT m (T + 2T )
⇒ = TR = c
mc + mc 2 mc

3T
TR =
2
24. d (same as 19 th solution)
25. No option

20
Q = 20 J = cal
4.2
m = 10g of water ; Δt = ?
20 = ms Δt

20 20
Δt = −3
=
10 × 4.2 × 10 42
= Δt = 0.47 °C
26. a, b, c, d
27. c
m = 1g, ice ; t = 0 °C ; m = 5g ; t = 10 °C of water
Lf = 80 cal kg ; TE = ?
1 × 80 + 1 × 1 × (T – 0) = 5 × (10 – 7)
80 + T = 50 – 5T = 6Ts = – 30
T = – 5 °C
28. a (same as 22nd solution)
29. a
m1 = 1 kg ; t1 = 0 °C ; m2 = 1 kg ; t2 = 10 °C
T = ? ⇒ 1 × 0.5 × (T – 0) = 1 × 0 × ( 10 – T)
⇒ 0.5 T = 10 – T
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22 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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⇒ 1.5 T = 10

20
⇒ T=
3
T = 6. 66 °C
0 < 6.66 < 16°
Lies between 0° and 10 °C
30. a
mA = mB = m

SA
= ? ; TR = 26 °C ; T1 = 30 °C ; T2 = 20 °C
SB

m A S ATA + m B SBTB
TR =
m A S A + mB SB

S A × 30 + SB × 20
26° =
S A + SB

⇒ 26 SA = 26 SB = 30 SA + 20 SB
⇒ – 4 SA = – 6 SB

SA 6
⇒ S =
B 4
⇒ SA : S B = 3 : 2
Student Additional Task - III
Latent Meat
1. d
2. c
Δt constant s = ∞
3. b
4. b,c
5. b, c
6. a
7. b
8. a, b, c, d

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Varsity Education Management Pvt. Ltd. 23
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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9. c
10. c
11. a
a = 400 cal
Q = m 80
400 = m × 80
m = 5g
12. a
m = 80 g of H2O
t = 30 °C
m= ? of ice
t = 0 °C
⇒ 80 × 1 × 30 = m × 80
⇒ m = 30 g
13. a
h = 100g of water
t = 80 °C ; m = 200g ; t = 20°C

100 × 80 + 200 × 20 120

TR = = = 40 °C
100 + 200 3
14. c
15. b
t = 100 °C, steam
m = 3200g of ice ; t = – 10 °C
steam of water 100 °C
Q1 = x × 540
Q2 = 3200 × 0.3 × 10 = 3200 × 5
Q3 = 3200 × 80
x × 540 = 3200 × 85

3200 × 85
x= = 503.7 = 3500g
540
16. a
t = 100 °C of steam ; x = ?
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24 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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m= 1.1 kg of water
ms = 0.02 kg
t = 15 °C , TR = 80 °C
x × 540 + x × (100 – 80) = 1.1 × 103 × 65 × 0.02 × 65 ×103
⇒ 540 x+ x 20 = 103 (1.12 × 65)

10 3 × 1.12 × 65 112 × 65
⇒ x= = = 130 g
560 56
⇒ x = 0.13 kg
17. a
m = 100 g of water ; t = 0 °C
xg ________ freezes
(100 – x) g _________ evoparactice at same pump
⇒ x (3.36 × 108) = ( 100 – x) 2.1 × 106
⇒ (3.36)x = 100 × 21 –12 x.
⇒ 24. 36 x = 100 × 21

100 × 21
⇒ x= = 86. 20 g
24.36
18. d
m=?
Llead =2.5 × 10–4 J/kg
SL = 125 J/kg - k
T = 27°
melts at 327 °C
Δt = 300 °C

50
Q rise = ×k
100

1 1
⇒ mLf + ms Δt = × mv2
2 2

mv 2
(Lf + S Δt ) m =
4
= 4 (2.5 × 104 + 125 × 3 00) = v2
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Varsity Education Management Pvt. Ltd. 25
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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⇒ 4 × (250 × 102 + 125 × 3 × 102) = v2
⇒ 4 × 102 (250 + 375 ) = v2
⇒ 4 × 102 × 625 = v2
⇒ 2 × 10 + 25 = v
⇒ v = 500 ms–1
Student Additional Task - IV
1. b

t = 0 °C, ρice = 0.9

T (Thickness) = 5 cm
t = 10 °C, rain , mw = V ρ
∴ 0.9 × 5 × A × 80 = 1 × 1 × A × h × 10 = 360 A = h × A × 10
h = 36 cm
2. b
t = 100 °C
m = 22 g of water
sec
t = 20 °C
tR = 90 °C 2g lat
⇒ x × 540 + x (100 – 90) = 22 × 1 × 70
⇒ 550x = 22 × 70

22 × 7
⇒ x= = 2.8 g
55
∴ water in beaker = 22 + 2.8 = 24.8g
3. b
m = 10g of ice ; t = – 20 °C
m = 10 g of water ; t = 50 °C
To melt ice heat required is = mL + ms Δt
= 10 × 80 + 10 × 0.5 × 20
= 900 cal
Water releases heat = ms Δt = 10 × 1 × 50 = 500 cal
Ice reaches temp from – 20 °C, Then starts melts . Heat observed from water to became ice of 0 °C is
Q = 10 × 0.5 × 20 = 100 cal , so
remaining 400 cal of energy used to utilise to convert ice to water (melt)
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26 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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∴ Q = mL ⇒ 400 = m × 80 ⇒ m= 5g
∴ 5g of ice melt in to water.
Now , Ice = (10 – 5) g = 5g
water = (10 + 5) = 15 g.
4. c
m = 5 kg of ice
t = – 10 °C
m = 5 kg of water
t = 10 °C

m1 S1t1 + m 2 S 2 t 2 5 × 0.5 × ( − 10 ) + 5 × 1 × 10
∴ TR = =
m1 S1 + m 2 S2 5 × 0.5 + 5 × 1

−25 + 50 250 10
= ⇒ = = 3.33 °C
7.5 75 3
5. a
Q = 25 cal = 3/4 × kinetic energy
t1 = 27 °C ; t2 = 327 °C
S = 0.03 cal g–1C–1 ; L = 6 cal /g

3
∴ × kinetic energy = (m) × 0.03 × 300 + m × 6 )4200
4

3 1
⇒ × mv2 = m (9 + 6) 4200
4 2

15 × 8 × 4200
⇒ v2 = = 120 × 1440
3
⇒ v = 409.87 = 410 m/s
6. a
7. b
m = 5 kg of water ; t = 40 °C
convert ice at 0°C
Energy released Q = ms Δt + mL
= 5 × 4200 × 40 + 5 × 80 × 4200 = 4200 × 5 × 40 × (1 + 2)
= 4200 ×5 × 40 × 3J
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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t = 20 min = 20 × 60 s

4200 × 5 × 40 × 3
p= = 2100 w
20 × 60
8. a
TR = ?
mice = mw = m
t1 = 0 °C ; t2 = 100 °C

m × 1 × 0 + m × 100 × 1 100m
=
TR = m (1) + m 2m = 50 °C

9. d
10. d
11. d
12. b
13. c
14. b
m = 100g ; t = – 20 °C
added heat = 100 × 4 × 60 = 100 × 240 = 24 × 103 cal
TR = ?
i. Heat observed by aluminium container is 100 g 20 °C
Q = 100 × 0.2 (T + 20) = 20 T + 400 cal
ii. Heat observed by ice at – 20 °C is
Q = 200 × 0.5 (20) + 200 × 80 + 200 × (T – 0)
= 2000 + 1600 + 200 T
∴ Total energy observed by system is
⇒ 20T + 400 + 18000 + 200 T = 24 × 103 cal
⇒ 220T + 18400 = 24000
⇒ 220 T = 5600

5600
⇒ T= = 25.45 °C
220
15. c
t1 = 30 °C , n = 6.2 km ; LL = ? ; SL = 126 J
t = 330 °C ; g = 10 m/s2
2
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28 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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Potential energy = mS Δt + mL
m × 10 × 6.2 × 103 = m (126 × 300 + L)
62 × 103 = 378 × 102 + L
⇒ (620 – 378) 102 = L
⇒ 242 × 102 = L
⇒ 2.42 × 104 = L
∴ L = 2.42 × 104 J /kg
16. d
‘Q’ released by 0.2 g of water per second is
Q = mL
Q = 0.2 × 10–4 × 2.27 × 106 = 454 × 102 = 45.45 in 1s
This energy used by water in pitcher to get 5 °C by evoparating heat required to evaparate
Q = 10 × 4200 × 5 = 210 × 103 J
0.2g
210 × 10 3
45.4 J → 1sec
t= = 4.62 × 103 sec 10g
45.4 210 × 10 3 J → t sec
time = 7.7 min
17. a
condition at equilibrium
Iron displace the water i.e.,
i.e., VI = VIce
∴ Resultant temp is
⇒ V × 8000 × 470 × T = 900 × V × 3.36 × 105
⇒ 8 × 47 × 104 T = 9 × 336 × 105

9 × 336 × 10
T= = 80. 4 °C
8 × 47
T = 80.4 °C
18. m = 20 kg
Δt = 25 °C ; p = 1000 w
80 % p = Q/t

80 20 × 4200 × 25
⇒ × 1000 =
100 t

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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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20 × 4200 × 25
t= = 125 × 21 s
800

125 × 21
∴t = min
60
T = 43.75 min
T = 0.72 hr
19. v = 0.5 m3
h = ? ; Δt = 15 °C ; m = 10 kg ; g = 10 m/s2
Heat librarated by water is doing work to lift the body to height ‘h’
So ‘Q’ = mgh
⇒ 0.5 × 1000 × 4200 × 15 = 10 × 10 × h
⇒ 75 × 4200 = h ⇒ = 315000 m = 315 km
20. m = 20 g = 20 × 10–3 kg
v = 40 ms–1

1 2 1
( ΔE ) I = mv = × 20 × 10–3 × 16 × 102 = 16 J
2 2
21. m = 50 kg, v = 18 kmph = 15 m/s
Δt = 10 °C
Kinetic energy = Q

1
⇒ m × 4200 × 10 = × 50 × (15)2
2

50 × 225 50 × 225
⇒ m × 42 × 10–3 = =
2 2 × 42 × 10 −3
= 13.39 × 10–2kg = 134 g
22. m=4
h=1+2=3
g = 9.8 m/s2
thermal energy produced
= mgh × 80 %

80
= 4 × 9.8 × 3 ×
100
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30 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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= 12 × 98 × 8 × 10–2
= 94.08 J
= 94.08 ÷ 4.2
= 22.4 cal.
23. m=1500 kg

5
v = 54 kmph = 54 × = 15 m/s; t = 10 s
18
all (m.E) = Q ⇒ Q/s = ?

1
⇒ M.E = × 1500 ×15 × 15 = 750 × 225 J
2

Q 750 × 225
⇒ = = 4017.85 cal/s
10 10 × 4.2
24. (ii)
Ice at 0 °C ; m = 1g
Requires heat to reach 100 °C
Q = mlf + ms Δt = 1 × 80 + 1 × 1 × 100 = 180 cal
This much heat is given by ‘x’ of steam condensed
x × 540 = 180

180 1
x= = g
540 3

1
x= g
3
25. (ii)

m1s1 Δt + m2 s2 t2 m (0) + m (0)

=
T= m1 s1 + m2 s2 m (1) + m ( 0.5) = 0 °C

T = 0 °C
26. c
steam at = 100 °C ; m1 = 10g
Ice Ice
ice at = 0 °C steam water water Ice
m = 50 g 100 °C 100 °C 10 °C 10 °C
TR = ?
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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mLv + msΔt = mLt + ms msΔt
⇒ 10 × 540 + 10 × (100 – TR) = 50 × 80 + 50 ×1 (TR – 0)
⇒ 5400 + 1000 – 10 TR = 4000 + 50 TR
⇒ 6400 = 4000 + 60 TR
⇒ 60 TR = 2400

2400
⇒ TR = = 40 °C
60
27. b
calorimeter (m) = 100g
water (m) = 50 g
t1 °C = 25 °C
mass of ice = ?
Sc= 0.1 cal g–1 c–1
TR = 20 °C
∴ Heat loss by calorimeter and water is
= 100 × 0.1 × (25 – 20) + 50 × 1 × (25 – 20)
(Q)loss = ( msΔt )cal + ms ( Δt )w = 10 × 5 + 50 × 5 = 300 cal
This much heat gain by ‘m’ ice
⇒ (Q)gain = mLf + msΔt
= m × 80 + m × 1 × (20 – 0) = 80 m + 20 m = 100 m
(Q)g = 100 m cal
According to principal of calorimeter
⇒ (Q)loss = (Q) gain

300
⇒ 300 = 100 m ⇒ m = = 3g
100
m = 3g
28. b
Ice (m) = 5g
t° = 0 °C
mixed with steam (m) = 5g
t° = 100 °C
∴ TR = ?
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32 Varsity Education Management Pvt. Ltd.
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Physics - VII (Techno solutions (2017 - 18) CALORIMETRY
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m1s1t1 + m2 s2 t 2 m (1 × 0 + 1 × 100 ) 100

= =
TR = m1s1 + m2 s2 m (1 + 1) 2 = 50 °C

(OR)
Water 0 °C and water at 100 °C are mixed then temperature changes reaches to equilibrium
∴ 5 × 1 (T – 0) = 5 × 1 × (100 – T)
∴ 5 × 1 ( T – 0) = 5 × 1 × (100 – T)
T = 100 – T
2T = 100
T = 50 °C

msΔT 40 × 1 × 60
29. Amount of ice melt x = =
L 80
⇒ x = 30 g
amount of ice remaining = 20 g
amount of water remaining = 70 g

20 2
rotio of ice towater = = =2:7
70 7
30. Data insufficient

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