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Issue date: 08/05/2019
Version: 1 (03/05/2019)
SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
Section 1. Identification of the substance or the mixture and of the supplier
1.1 Product Identifier
Product identifier: WANTED (Contains: ALPHA-ISOMETHYL IONONE, COUMARIN, DIHYDRO
PENTAMETHYLINDANONE (DPMI), TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES)
Other identifiers: None
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product uses: Fragrances
1.3 Details of the supplier of the safety data sheet
Company name: Twilight Candle Co
Company address: 48 Sorn Street
Catrine
Ayrshire
KA5 6LY
UK
(Office hours: Monday to Friday 10.00 to 16.00
Contact: Twilight Candle Co
E-Mail address:
[email protected]Company phone: 01290553392
1.4 Emergency telephone number
Emergency contact Outside Office Hours: [email protected]
Section 2. Hazards identification
2.1 Classification of the substance or mixture
Classification under Regulation (EC) No 1272/2008
Class and category of Skin Corrosion / Irritation Category 2
danger:
Eye Damage / Irritation Category 2
Sensitization - Skin Category 1
Hazardous to the Aquatic Environment - Long-term Hazard Category 2
H315, Causes skin irritation.
H317, May cause an allergic skin reaction.
H319, Causes serious eye irritation.
H411, Toxic to aquatic life with long lasting effects.
2.2 Label elements
Signal word: Warning
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
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Product: WANTED
Version: 1
Hazard statements: H315, Causes skin irritation.
H317, May cause an allergic skin reaction.
H319, Causes serious eye irritation.
H411, Toxic to aquatic life with long lasting effects.
Supplemental EUH208, Contains CINNAMAL, CIS-3-HEXENYL METHYL CARBONATE, CITRAL, METHYL
Information: ATRATATE, TETRAMETHYLTRICYCLOPROPANOL. May produce an allergic reaction.
Precautionary P261, Avoid breathing vapour or dust.
statements: P264, Wash hands and other contacted skin thoroughly after handling.
P272, Contaminated work clothing should not be allowed out of the workplace.
P273, Avoid release to the environment.
P280, Wear protective gloves/eye protection/face protection.
P302/352, IF ON SKIN: Wash with plenty of soap and water.
P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P333/313, If skin irritation or rash occurs: Get medical advice/attention.
P337/313, If eye irritation persists: Get medical advice/attention.
P362, Take off contaminated clothing and wash before reuse.
P391, Collect spillage.
P501, Dispose of contents/container to approved disposal site, in accordance with local
regulations.
Pictograms:
Other hazards: Hydrocarbon Concentration %: 1.937%
Section 3. Composition / information on ingredients
3.2 Mixtures
Contains:
REACH Registration Classification for
Name CAS EC %
No. (CLP) 1272/2008
259-174-3,
TETRAMETHYL 54464-57-2,
268-978-3, SCI 2-SS 1B-EH C1;
ACETYLOCTAHYDRON 68155-66-8, 01-2119489989-04-xxxx 20-<50%
268-979-9, H315-H317-H410,-
APHTHALENES 68155-67-9 915-730-3
DIHYDRO SCI 2-EDI 2-SS 1B-EH
PENTAMETHYLINDAN 33704-61-9 251-649-3 5-<10% C2;H315-H317-H319-
ONE (DPMI) H411,-
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
2,6-DIMETHYL-7- SCI 2-EDI 2;H315-
OCTEN-2-OL 18479-58-8 242-362-4 5-<10% H319,-
HEXAMETHYLINDANO
PYRAN 1222-05-5 214-946-9 01-2119488227-29-xxxx 1-<5% EH A1-EH C1;H410,-
ETHYL
EDI 2-EH C2;H319-
TRIMETHYLCYCLOPE 28219-61-6 248-908-8 01-2119529224-45-xxxx 1-<5%
H411,-
NTENE BUTENOL
CIS-2-TERT-
BUTYLCYCLOHEXYL 20298-69-5 243-718-1 01-2119970713-33-xxxx 1-<5% EH C2;H411,-
ACETATE
ATO 4-SS 1B;H302-
COUMARIN 91-64-5 202-086-7 1-<5% H317,-
ALPHA-ISOMETHYL SS 1B-EH C2;H317-
IONONE 127-51-5 204-846-3 1-<5% H411,-
4-METHYL-3-DECEN-5- EH A1-EH C2;H400-
OL 81782-77-6 279-815-0 01-2119983528-21-xxxx 0.1-<1% H411,-
SCI 2-EDI 2-SS 1;
CITRAL 5392-40-5 226-394-6 01-2119462829-23-xxxx 0.1-<1% H315-H317-H319,-
METHYL ATRATATE 4707-47-5 225-193-0 0.1-<1% SS 1B;H317,-
ALLYL
ATO 4-EH A1-EH C2;
CYCLOHEXYLOXYACE 68901-15-5 272-657-3 0.1-<1%
H302-H400-H411,-
TATE
ATO 3-ATD 3-ATI 3-EH
A1-EH C3;H301-H311-
ALLYL CAPROATE 123-68-2 204-642-4 0.1-<1%
H331-H400-H412,-
TETRAMETHYLTRICY SCI 2-SS 1-EH A1-EH
CLOPROPANOL 929625-08-1 482-030-8 0.1-<1% C1;H315-H317-H410,-
CIS-3-HEXENYL
METHYL CARBONATE 67633-96-9 266-797-4 0.1-<1% SS 1B;H317,-
ATD 4-SCI 2-EDI 2-SS
CINNAMAL 104-55-2 203-213-9 <0.1% 1A;H312-H315-H317-
H319,-
Substances with Community workplace exposure limits:
Name CAS EC %
DIETHYL PHTHALATE 84-66-2 201-550-6 20-<50%
Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater
than 0.1%:
Not Applicable
Section 4. First-aid measures
4.1 Description of first aid measures
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
4.2 Most important symptoms and effects, both acute and delayed
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
4.3 Indication of any immediate medical attention and special treatment needed
None expected, see Section 4.1 for further information.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable media: Carbon dioxide, Dry chemical, Foam.
5.2 Special hazards arising from the substance or mixture
In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.
5.3 Advice for fire fighters:
In case of insufficient ventilation, wear suitable respiratory equipment.
Section 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.
6.2 Environmental precautions:
Keep away from drains, surface and ground water, and soil.
6.3 Methods and material for containment and cleaning up:
Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage
immediately by use of sand or inert powder. Dispose of according to local regulations.
6.4 Reference to other sections:
Also refer to sections 8 and 13.
Section 7. Handling and storage
7.1 Precautions for safe handling:
Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as
required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate
ventilation Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving
equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take
precautionary measures against static discharge.
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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Issue date: 08/05/2019
Version: 1 (03/05/2019)
SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
7.3 Specific end use(s):
Fragrances: Use in accordance with good manufacturing and industrial hygiene practices.
Section 8. Exposure controls/personal protection
8.1 Control parameters
Workplace exposure limits:
Ingredient CAS EC Description Value
Long-term exposure limit (8-hour
5
TWA) (mg/m3)
DIETHYL PHTHALATE 84-66-2 201-550-6
Short-term exposure limit (15-
10
minute) (mg/m3)
8.2 Exposure Controls
Eye / Skin Protection
Wear protective gloves/eye protection/face protection
Respiratory Protection
Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure
occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the
following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other
areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the
rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with
organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and
other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is
openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce
possible worker exposures. d) Use closed systems for transferring and processing this material.
Also refer to Sections 2 and 7.
Section 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance: Clear colourless to pale yellow liquid
Odour: Not determined
Odour threshold: Not determined
pH: Not determined
Melting point / freezing point: Not determined
Initial boiling point / range: Not determined
Flash point: > 100 °C
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability or explosive limits: Product does not present an explosion hazard
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
Vapour pressure: 0.01746453 mmHg
Vapour density: Not determined
Relative density: 1.0240 - 1.0280
Solubility(ies): Not determined
Partition coefficient: n-octanol/water: Not determined
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: Not determined
Explosive properties: Not expected
Oxidising properties: Not expected
9.2 Other information: None available
Section 10. Stability and reactivity
10.1 Reactivity:
Presents no significant reactivity hazard, by itself or in contact with water.
10.2 Chemical stability:
Good stability under normal storage conditions.
10.3 Possibility of hazardous reactions:
Not expected under normal conditions of use.
10.4 Conditions to avoid:
Avoid extreme heat.
10.5 Incompatible materials:
Avoid contact with strong acids, alkalis or oxidising agents.
10.6 Hazardous decomposition products:
Not expected.
Section 11. Toxicological information
11.1 Information on toxicological effects
This mixture has not been tested as a whole for health effects. The health effects have been calculated using the
methods outlined in Regulation (EC) No 1272/2008 (CLP).
Acute Toxicity: Based on available data the classification criteria are not met.
Acute Toxicity Oral >5000
Acute Toxicity Dermal >5000
Acute Toxicity Inhalation Serious eye damage/irritation:
Skin corrosion/irritation: Respiratory or skin sensitisation:
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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Not Available ritation Category 2 Sensitization - Skin
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TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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Version: 1 (03/05/2019)
SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
Germ cell mutagenicity: Based on available data the classification criteria are not met.
Carcinogenicity: Based on available data the classification criteria are not met.
Reproductive toxicity: Based on available data the classification criteria are not met.
STOT-single exposure: Based on available data the classification criteria are not met.
STOT-repeated exposure: Based on available data the classification criteria are not met.
Aspiration hazard: Based on available data the classification criteria are not met.
Information about hazardous ingredients in the mixture
LD50/ATE LC50/ATE LC50
Ingredient CAS EC LD50/ATE Oral
Dermal Inhalation Route
ALLYL CAPROATE 123-68-2 204-642-4 300 300 3 Vapour
Not
COUMARIN 91-64-5 202-086-7 500 Not available Not available available
Refer to Sections 2 and 3 for additional information.
Section 12. Ecological information
12.1 Toxicity:
Toxic to aquatic life with long lasting effects.
12.2 Persistence and degradability: Not available
12.3 Bioaccumulative potential: Not available
12.4 Mobility in soil: Not available
12.5 Results of PBT and vPvB assessment:
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
12.6 Other adverse effects: Not available
Section 13. Disposal considerations
13.1 Waste treatment methods:
Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty
containers should be taken to an approved waste handling site for recycling or disposal.
Section 14. Transport information
14.1 UN number: UN3082
14.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENES,
HEXAMETHYLINDANOPYRAN)
14.3 Transport hazard class(es): 9
Sub Risk: -
14.4. Packing Group: III
14.5 Environmental hazards: This is an environmentally hazardous substance.
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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14.6 Special precautions for user: None additional
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
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Product: WANTED
Version: 1
14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code:
Not applicable
Section 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
None additional
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has not been carried out for this product.
Section 16. Other information
Concentration % Limits: EH C2=10.18% EH C3=1.02% EH C4=71.43% SCI 2=33.33% EDI 2=76.
94% EDI 2A=76.94% SS 1=5.00%
Total Fractional Values: EH C2=9.82 EH C3=98.24 EH C4=1.40 SCI 2=3.00 EDI 2=1.30 EDI 2A=1.
30 SS 1=20.00
Key to revisions:
Not applicable
Key to abbreviations:
Abbreviation Meaning
ATD 3 Acute Toxicity - Dermal Category 3
ATD 4 Acute Toxicity - Dermal Category 4
ATI 3 Acute Toxicity - Inhalation Category 3
ATO 3 Acute Toxicity - Oral Category 3
ATO 4 Acute Toxicity - Oral Category 4
EDI 2 Eye Damage / Irritation Category 2
EH A1 Hazardous to the Aquatic Environment - Acute Hazard Category 1
EH C1 Hazardous to the Aquatic Environment - Long-term Hazard Category 1
EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2
EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
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SAFETY DATA SHEET
In accordance with REACH Regulation EC No.1907/2006
Product: WANTED
Version: 1
P261 Avoid breathing vapour or dust.
P264 Wash hands and other contacted skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/eye protection/face protection.
P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301/312 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell.
P302/352 IF ON SKIN: Wash with plenty of soap and water.
P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
P305/351/338
do. Continue rinsing.
P311 Call a POISON CENTRE or doctor/physician.
P312 Call a POISON CENTRE or doctor/physician if you feel unwell.
P330 Rinse mouth.
P332/313 If skin irritation occurs: Get medical advice/attention.
P333/313 If skin irritation or rash occurs: Get medical advice/attention.
P337/313 If eye irritation persists: Get medical advice/attention.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to approved disposal site, in accordance with local regulations.
SCI 2 Skin Corrosion / Irritation Category 2
SS 1 Sensitization - Skin Category 1
SS 1A Sensitization - Skin Category 1A
SS 1B Sensitization - Skin Category 1B
The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions,
recommendations and/or suggestions are made without guarantee.
TWILIGHT CANDLE Co 48 SORN STREET CATRINE AYRSHIRE KA56LY UK
