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HNMR

This document provides an overview of 1H NMR spectroscopy and discusses 14 problems related to interpreting 1H NMR spectra. The document explains key concepts for 1H NMR spectra including chemical shifts, number of proton sets, multiplicity, and integration. It then lists 14 problems involving identifying compounds from their molecular formulas and 1H NMR data, interpreting spectra, and distinguishing between similar compounds based on their predicted 1H NMR patterns.

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37 views

HNMR

This document provides an overview of 1H NMR spectroscopy and discusses 14 problems related to interpreting 1H NMR spectra. The document explains key concepts for 1H NMR spectra including chemical shifts, number of proton sets, multiplicity, and integration. It then lists 14 problems involving identifying compounds from their molecular formulas and 1H NMR data, interpreting spectra, and distinguishing between similar compounds based on their predicted 1H NMR patterns.

Uploaded by

Nax
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1HNMR Tutorials

RELATIVE POSITIONS OF PROTON ABSORPTION


1) Chemical Shift
2) No of Sets of Protons = No of Peaks
Set of Proton: Contains protons (H) chemically and magnetically •
equivalent (have same environment)

1 SET 2 SETS 2 SETS


3) Multiplicity (Splitting)
Multiplicity = n+1 •
n= no. of unequivalent protons on adjacent carbon •
4) Integration
Integration= no. of H in each set (or) Ratio of H •
PROBLEMS
• Problem 1: Identify and interpret the following spectra exhibit IR
band at 1680-1700 cm-1
PROBLEMS
• Problem 2: Identify and interpret the following spectrum
PROBLEMS
• Problem 3: Which compound
have the following 1H NMR
spectra with explanation
PROBLEMS
• Problem 4: Identify and interpret the following spectrum
PROBLEMS
• Problem 5: : Identify the compound with Molecular formula C 5H10O
for the following 1HNMR spectrum and interpret it?
PROBLEMS
• Problem 6 :

Identify the following compound whose molecular formula is C5H12O2


with explanation.
1H NMR: 4.1 (s, 6H), 1.8 (s, 6H).
PROBLEMS
• Problem 7 :

• Identify the compound whose molecular formula C6H12O2with


explanation.
• 1HNMR: 3.85 (d, 2H, J = 7.2 Hz),
2.0 (s, 3H),
1.92 (9 line pattern with appropriate intensities, 1H, J = 7.2
Hz) 0.9 (d, 6H, J = 7.2 Hz).
PROBLEMS
• Problem 8:
• In each of the following pairs of compounds which of the
underlined protons has the greater chemical shift ? i.e. the farther
downfield signal or the higher frequency signal ?
PROBLEMS
• Problem 9:
• Identify each of the following compounds from 1H NMR data and
molecular formula. The number of hydrogens responsible for each
signal is shown in parentheses.
•
PROBLEMS
• Problem 10 :
• How would you distinguish 1H NMR spectra of the following
compounds?

•
PROBLEMS
• Problem 11:
• How would integration distinguish 1H NMR spectra of the following
compounds?
PROBLEMS
• Problem 12 :
• Indicate the number of signals and multiplicity of each signal in 1H
NMR spectrum of each of the following compounds ?
• Problem 13 : Home Work
• How would you distinguish 1H NMR spectra of the following compounds?
• Problem 14 : Home Work
Label each set of chemically equivalent protons, using a for the set that will be •
at the lowest frequency (farthest upfield) in the 1H NMR spectrum, b for the
next, … Indicate the multiplicity of each signal.
PROBLEMS
• TRY IT : Grade
Problem 1 :
• Which set of protons in each of the following compounds is the
least shielded ?
• Which set of protons in each compound is the most shielded ?
PROBLEMS
• TRY IT : Grade
Problem 2:
• In each of the following compounds, which set of the underlined
protons has the greater chemical shift? i.e. the farther downfield
signal or the higher frequency signal?
Thank You
22 ADD A FOOTER MM.DD.20XX

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