Safety Data Sheet

Revision Number: 004.0 Issue date: 04/09/2020

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE 454 SURF. INSENS.INSTANT IDH number: 1337712
AD. known as LOCTITE® 454™
Prism® INSTANT
Product type/use: Cyanoacrylate Item number: 1337712
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.

HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 4
EYE IRRITATION 2B
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

PICTOGRAM(S)

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Avoid breathing vapors,
mist, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a well-
ventilated area. Wear protective gloves, eye protection, and face protection.
Response: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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Ethyl 2-cyanoacrylate 7085-85-0 60 - 100
Treated fumed silica 67762-90-7 5 - 10

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
days. Medical attention should be sought in case solid particles of
polymerized cyanoacrylate trapped behind the eyelid caused abrasive
damage.

Ingestion: Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.

Symptoms: See Section 11.

Notes to physician: Surgery is not necessary to separate accidentally bonded tissues. Experience
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal burns they should be treated
symptomatically after adhesive is removed.

5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.

Unusual fire or explosion hazards: Not available.

Hazardous combustion products: Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Do not use cloths for mopping up. Flood with water to complete
polymerization and scrape off the floor. Cured material can be disposed of as
non-hazardous waste.

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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 7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of
this product. Wash thoroughly after handling. Avoid contact with fabric or
paper goods. Contact with these materials may cause rapid polymerization
which can generate smoke and strong irritating vapors, and cause thermal
burns.

Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

1 ppm STEL
0.2 ppm TWA
Ethyl 2-cyanoacrylate (Respiratory None None None
sensitization)
(Dermal sensitization)
10 mg/m3 TWA 15 mg/m3 TWA Total
Inhalable dust. dust.
Treated fumed silica None None
3 mg/m3 TWA 5 mg/m3 TWA
Respirable fraction. Respirable fraction.

Engineering controls: Use positive down-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Gel
Color: Clear
Odor: Irritating
Odor threshold: 1 - 2 ppm
pH: Not available.
Vapor pressure: < 0.2 mm hg
Boiling point/range: > 149 °C (> 300.2 °F)
Melting point/ range: Not available.
Specific gravity: 1.05
Vapor density: 3
Flash point: 80 - 93 °C (176°F - 199.4 °F) Tagliabue closed cup
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: 485 °C (905°F)
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Polymerises in presence of water.
Solubility in water: Polymerizes on contact with water.
Partition coefficient (n-octanol/water): Not available.
VOC content: < 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Viscosity: Not available.
Decomposition temperature: Not available.

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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 10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.

Hazardous reactions: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and
alcohols.

Hazardous decomposition None

products:

Incompatible materials: Water, Amines, Alkalis, Alcohols.

Reactivity: Not available.

Conditions to avoid: Spontaneous polymerization.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects/Symptoms

Inhalation: May cause respiratory tract irritation. Exposure to vapors above the established exposure limit
results in respiratory irritation, which may lead to difficulty in breathing and tightness in the
chest.
Skin contact: May cause skin irritation. May cause allergic skin reaction. Bonds skin in seconds.
Cyanoacrylates have been reported to cause allergic reaction but due to rapid polymerization at
the skin surface, an allergic response is rare. Cyanoacrylates generate heat on solidification. In
rare circumstances a large drop will burn the skin. Cured adhesive does not present a health
hazard even if bonded to the skin.
Eye contact: Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Ingestion: Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to swallow.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Ethyl 2-cyanoacrylate None Irritant, Allergen, Respiratory
Treated fumed silica None Irritant

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Ethyl 2-cyanoacrylate No No No
Treated fumed silica No No No

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Combustible liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: Combustible Liquid
Identification number: NA 1993
Packing group: III
Exceptions: (Not more than 450 L), Unrestricted

International Air Transportation (ICAO/IATA)

Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: 9
Identification number: UN 3334
Packing group: III
Exceptions: Primary packs containing less than 500ml are unregulated by this mode of
transport and may be shipped unrestricted.

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire, Reactive
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: This product contains a chemical known to the State of California to cause birth defects or
other reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other
components are listed on or are exempt from listing on the Domestic Substances List.
Components listed on the NDSL must be tracked by all Canadian Importers of Record as
required by Environment Canada. They may be imported into Canada in limited quantities.
Please contact Regulatory Affairs for additional details.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes
from the previous version in Section(s): 3

Prepared by: Product Safety and Regulatory Affairs

Issue date: 04/09/2020

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 1337712 Product name: LOCTITE 454 SURF. INSENS.INSTANT AD. known as LOCTITE® 454™ Prism®
INSTANT
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