SUPER
40 CHEMISTRY
ALDEHYDES KETONES AND CARBOXYLIC ACID
Practise 40 Most Important Questions to Crack IIT JEE MAINS
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Q-1 - 11823075
Convert
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Q-2 - 11485600
Convert
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Q-3 - 11485993
Convert the following :
(a)
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Q-4 - 20220882
Identify product (A) & (B) from the given product P , Q , R :
(A) A=P , B=Q
(B) A=Q , B=R
(C) A= Q , B=P
(D) A= R , B= P
CORRECT ANSWER: C
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Q-5 - 20221041
O
∣∣ NaNH 2 HC ≡ CH H 3O ⊕ 1H 2 / Pd Al 2O 3
CH 3 - C - CH 3 → P → Q → R → S → DT
What is the final product T.
O
∣∣
(A) H 3C - C ∣ CH3 = C - C - CH 3
OH
∣
(B) CH 3 - C - CH 3
∣
H 2C = CH
CH 3
∣
(C) CH 3 - C - CH - CH 3
CH 3
∣
(D) CH 3 = C - CH = CH 2
CORRECT ANSWER: D
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Q-6 - 20594940
Which of the following is not the product of an intramolecular aldol
condensation?
(A)
(B)
(C)
(D)
CORRECT ANSWER: C
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Q-7 - 19103165
Which β-keto acid shown will not undergo decarboxylation?
(A)
(B)
O
∣∣
(C) Ph - C - CH 2 - CO 2H
O
∣∣
(D) CH 3 - C - CH 2 - CO 2H
CORRECT ANSWER: B
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Q-8 - 20221172
The Birch reduction of benzoic acid gives:
(A)
(B)
(C)
(D)
CORRECT ANSWER: A
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Q-9 - 20221180
SOCl 2 Me 2NH ( C )
Ph - CO 2H → A → B → Ph - CHO
, unknown reagent (C) is:
(A) LiAlH 4
(B) NaBH 4
(C) LiAlH(t - BuO) 3
(D) Pℂ /CH 2Cl 2
CORRECT ANSWER: C
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Q-10 - 20594895
base
Ph - CH = CHCHO + CH 3CH = CHCHO → EtOH , Δ (A)87 %
, product of this reaction is:
(A) Ph(CH = CH) 2 - CHO
(B) Ph(CH = CH) 3CHO
(C) Ph - (CH = CH) 4CHO
(D) Ph - CH = CH - CH = CH - CH 3.
CORRECT ANSWER: B
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Q-11 - 15411966
The major product of the following reaction sequence is
(A)
(B)
(C)
(D)
CORRECT ANSWER: A
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Q-12 - 15411967
The compound which would yield 5 - Oxo- 2 - methylhexanal on
reductive ozonolysis
(A)
(B)
(C)
(D)
CORRECT ANSWER: B
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Q-13 - 15411968
The major product in the following reaction is
(A)
(B)
(C)
(D)
CORRECT ANSWER: D
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Q-14 - 15411970
The major product H of the given reaction sequence is
Θ CN 95 % H 2SO 4
CH 3 - CH 2CO - CH 3 → G - → Heat H
(A) CH 3 - CH = C ∣ CH 3 - COOH
(B) CH 3 - CH = C ∣ CH 3 - CN
(C) CH 3 - CH 2 = C ∣ CH3 - COOH
(D) CH 3 - CH = C ∣ CH 3 - CO - NH 2
CORRECT ANSWER: A
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Q-15 - 15411971
The number of adol reaction (s) that occurs in the given
transformation is
(A) 1
(B) 2
(C) 3
(D) 4
CORRECT ANSWER: C
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Q-16 - 15411977
What is X?
(A) CH 3COOH
(B) BrCH 2COOH
(
(C) CH 3CO ) 2O
(D) HOC - COOH
CORRECT ANSWER: C
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Q-17 - 15411984
which of the following has the most acidic hydrogen?
(A) 3 - hexanonoe
(B) 2, 4 - hoxanedione
(C) 2, 5 - heaxnedione
(D) 2, 3 - hoxanedione
CORRECT ANSWER: B
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Q-18 - 15411994
When acetaldehyde is treated with Fehling's soluion , it gives a
precipitate of
(A) Cu
(B) CuO
(C) Cu 2O
(D) Cu + Cu 2O + CuO
CORRECT ANSWER: C
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Q-19 - 15411997
Reagent (s) which can be used to bring about the following
transformation is (are)
(
(A) LiAIH 4 in C 2H 5 ) 2O
(B) BH 3 in THF
(C) NaBH 4 "in"C 2H 5OH
(D) Raney Ni/ H 2 in THF
CORRECT ANSWER: C
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Q-20 - 15411999
After completion of the reactions (I and II) , the organic compound
(s) in the reaction is /are
(A) reaction I : P and reaction II : P
(B) reactionI : U, acetone and reaction II : Q, acetone
(C) reaction I : T, U acetone and reaction II : P
(D) reaction I : R, acetone and reaction II : S, acetone
CORRECT ANSWER: C
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Q-21 - 20220886
Above conversion can be carried out by :
(A) Clemmensen reduction
(B) Wloff-Kishner reduction
(C) LiAIH 4
(D) NaBH 4
CORRECT ANSWER: B
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Q-22 - 20220888
Increasing order of equilibrium constants for the formation of a
hydrate :
(A) IV < III < II < I
(B) IV < III < I < II
(C) I < II < III < IV
(D) II < III < I < IV
CORRECT ANSWER: C
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Q-23 - 20220890
Predict the product of hydrolysis of the above molecule .
(A)
(B)
(C)
(D)
CORRECT ANSWER: C
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Q-24 - 20220898
Relationship between products (Q) and (S) is :
(A) Positional isomer
(B) Chain isomer
(C) Stereoisomer
(D) Functional isomer
CORRECT ANSWER: D
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Q-25 - 20220902
Which sequence represents the best synthesis of hexanal ?
CH 3CH 2CH 2CH 2HexanalCH 2CH = O
(A) 1. CH 3CH 2CH 2CH 2Br + NaC ≡ CH
2. H 2O, H 2SO 4, HgSO 4
O
∣∣
(B) 1. CH 3CH 2CH 2CH = CH 2 + CH 3 C OOH
2. CH 3MgBr , diethyl ether
3. H 3O +
4. Pℂ, CH 2Cl 2
O
∣∣
(C) 1. CH 3CH 2CH 2CH 2 C CH 3
O
∣∣
2. CH 3 C OOH 3. LiAlH 4
H 2O 5. Pℂ, CH 2Cl 2
(D)
CORRECT ANSWER: D
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Q-26 - 15710627
The reaction of compounf P with CH 3MgBr (excess) in
(C2H5 _ (2)O followed by addition of H 2O give Q the compound
Q on treatment with H 2SO 4at 0 C gives R. the reaaction of R with
CH 3COCl in the presence of anhydrous AlCl3inCH 2Cl 2 followed
by treatment with H 2O produces compound S. [Et in compound P is
ethyl group] The product S is The product S is
(A)
(B)
(C)
(D)
CORRECT ANSWER: A
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Q-27 - 15710629
P and Q are isomer of dicraboxylic acid C 4H 4O 4 Both decolourixe
Br 2 /H 2O. On heating , P forms the cyclic anhydride. Upon
treatment with duilute alkaline KMnO 4. P as well a Q could produce
one or more than one from S,T and U.
Compounds formed P and Q are, respectively
(A) Optically active S and optically active pair (T.U)
(B) Optically inacthive S and optically inactive pair (T.U)
(C) Opticaly active pair (Y.U) and optically active S
(D) Optically inactive pair (T.U) and optically inactives S
CORRECT ANSWER: B
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Q-28 - 20594915
An organic commpound with the jmolecular formula C 9H 10O forms
a 2,4-DNP derivative, reduces tollen's reagent and undergoes
cannizaro reaction, on vigorous oxidation it gives 1,2-
benzenedicarboxylic acid. Structure of organic compound is:
(A)
(B)
(C)
(D)
CORRECT ANSWER: B
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Q-29 - 20594922
Identify
product and name of reaction.
(A)
(B)
(C)
(D)
CORRECT ANSWER: B
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Q-30 - 20594924
OH O
∣ ∣∣ HO - Na 2CO 3
CH 3 - C H - CH 2 - C - H → ( Reduction aldol ) (A), 3HCHO +A →
Product (B) of the above reaction is:
(A)
(B)
(C)
(D)
CORRECT ANSWER: C
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Q-31 - 20594925
OH - Δ
CH 3CH = CHCHO → Aldol condensation →
Product A is
(A) CH 3(CH = CH) 3CHO
(B) CH 3CH 2CH 2(CH = CH) 2CHO
( )
(C) CH 3 CH 2CH 3 CH = CH - CHO
(D) none is correct.
CORRECT ANSWER: A
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Q-32 - 20594927
product (C)
is:
(A)
(B)
(C)
(D)
CORRECT ANSWER: C
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Q-33 - 20594937
Compound X undergoes the following reaction sequence. What is
the structure of compound X?
(A)
(B)
(C)
(D)
CORRECT ANSWER: D
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Q-34 - 20594941
Compound (X) is obtianed by which of the following reaction?
(A)
(B)
(C)
(D)
CORRECT ANSWER: A
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Q-35 - 20594939
Structure of (B) is:
(A)
(B)
(C)
(D)
CORRECT ANSWER: A
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Q-36 - 20220908
H 2O
→ drop of H 2SO 4 Positive Tollens test
Compound (A) is :
O
∣∣
(A) CH 3 - C - CH ∣ OCH 3 - CH 2 ∣ OCH 3
O OCH 3
∣∣ ∣
(B) CH 3 - C - C ∣ OCH 3 - CH 3
O
∣∣
(C) CH 3 - C - CH 2 - CH ∣ OCH3 - OCH 3
O
∣∣
(D) H - C - CH 2 - CH 2 - CH ∣ OCH3 - OCH 3
CORRECT ANSWER: C
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Q-37 - 20220910
Compound (P) is :
O
∣∣
(A) CH 3 - C - CH 2 - CH 2 - CH 2 - CH ∣ OH - CH 3
O OH
∣∣ ∣
(B) CH 3 - C - CH 2 - CH - CH 2 - CH 2 - CH 3
O
∣∣
(C) CH 3 - C - CH 2 - CH 2 - CH 2 - CH 2 - CH 2 - OH
O OH
∣∣ ∣
(D) CH 3 - C - CH ∣ CH 3 - C ∣ CH 3 - CH 3
CORRECT ANSWER: C
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Q-38 - 20220911
Correct order of reactivity of following compounds towards
Grignard reagent ?
(A) I > II > III
(B) II > I > III
(C) II > III > I
(D) I > III > II
CORRECT ANSWER: B
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Q-39 - 20220914
What reagent and /or reaction conditions would you choose to bring
about the following conversion ?
(A) 1. LiAlH 4, 2. H 2O
(B) H 2O, H 2SO 4 , heat
(C) H 2O, NaOH , heat
(D) Pℂ, CH 2Cl2
CORRECT ANSWER: B
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Q-40 - 20220915
81 % yield , Product of the reaction is :
(A)
(B)
(C)
(D)
CORRECT ANSWER: C
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