)

CO\FIDE\TTAL* (SULIT*)

SIJIL TINGGI PERSEKOLAHAN MALAYSIA

CHEMISTRY
PAPER 2

MAJLIS PEPERIKSAAN MALAYSIA

(NIALAYSIAN EXAN{I\TATTONS COLNCIL)

1 Hour 30 Minutes
Instructions to candidates:
DO NOT OPE\[ THIS QUESTTON PAPER UNTIL YOU ARE ALLOWED TO DO SO.
K ,lnswer all cluestions in Section A.
K Anstret' all cluestions in Section B.
Anstrer two cltrestiorts onlt in Sectiort C.

All v'orking should be shown. For nrullet'ical ens\\'ers, utlits should be quoled v.her.et'er
ctppt'oprt0te.
.lttslrers ntat' be v'ritten eitlter in English or. Malar.
Fill in rour personal details on page Il.

Arahan kepada calon:

JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARIi{}i
BERBUAT DENIIKIAN.
Jatrah semua sctulen dalam Baltogian A.
Jcnctb semua .soalqn dctlam Bahagian B.
Jctvab dua soalan sahcla dalam Bahagion C.

Semua kerict hendakltth diturtjukkon. Bagi jcntctpan berangka, unit hendaklah dint'atctkan cli
n1 cil1 Q-t11 A n 0 t'an g s e s ll Qt.

Jcnrapon ltoleh ditulis dqlam hahosa Inggeris etau bqhasa f,Ielqru.

Isi mctklumctt diri anda pada halaman 11.

I This question paper consists of 20 printed pages and ,l blank pages.

I (Kertas soalan ini terdiri daripada 20 halaman bercetak dan,l halaman kosong.)
I
O Majlis Peperiksaan Malaysia 2021
-.^ STPNI 2021 - 962t2 [Turn or-er (Lihat halaman sebelah)
-X *This question paper is CONFIDENTIAL until the examination is over. CONFIDENTIAL*
I.,
I (*Kefias soalan ini SULIT sehingga peperiksaan kertas ini tamat.) (SULIT*)
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Section A ll5 marksl

Ansv'e r all qu est iorts,

Indicate the correct ans\r'er on the '\{ultip/e-choice,lnsver Sheet provided.

The energy profile of a reaction is shou'n belou'.

Enthalpl"

Progress ofreaction

Which reaction is represented by the energy profile?

A OH (aq) + H-(aq) + HrO(l) H:O(l) +2H(g) + O(g)

I
C H.(s) -r_ :O.te) -----------r> H,O(l) H,O(g) --------------r- H.O(s)

The standard enthalpy change of hydration. AIli.d of several ions are given in the table belou

lon A11],o/kJ mol '

Li- 519

Na- --406

CI -364
B. -33s

Which statement is not true about the AH'n.uof the ions abol'e7
A The magnitude of the All:,.d depends on the ability of the ions to attract vn'ater molecuies.

B The A,F1on.o of the ions are negative due to the attractions betu,een ions and lr'ater dipoles
u'hich release energy.
C The A11"n,o of the ions are directly proportional to tire ionic sizes.
D The value of the Allon.obecomes more negative u-hen the charge density of the ion increases.

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The standard enthalpies

3 Carbon monoride and carbon dioxide are t$'o stable oxides of carbon'
carbon monoxide and carbon dioxide are 1ll kJ mol-' and -394 kJ
mol'^
of forrnation of
monoxide under standard conditions?
respecti'ely. What is the enthalpy of combustion of carbon
r B I C -505 kJ mol
I D -616 kJ mo1
A +172 kJ mol -283 kJ mol '

4 An electrochemical equation of iron is shown belorv'

2Fer-(aq) + Fe(s) 3Fer'(aq) E'."r,: +0'40 V

What could be deduced from the equation?

A The mass of the anode increases.

B The reaction involves the transfer of one electron'

The standard reduction potential of aqueous Fe'- is more positive than that
of the aqueous
C
Fer-.
Fer- at 25 'C
D The concentration of aqueous Fe''- is equai to the concentratron of aqueous
and 0 V.

5 The standard reduction potentials of several half-ceils are given below.

Ci.(g.t t 2e :# 2Cl (aq) E': +1'36 V

Br.tl t + 2e <- 2Br (aq) E' : + '09 V
1

r:\s/ Ls .--
, , t r 1^ 2I (aq) Eo : -0'54 \'

Fe' (aq) - e Fe: {aq 1 E' :'0'rI V

(aq) Eo : +0'36 V
[Fe(CN)n]r (aq) + [Fe(CN)o]r

Based on the half-cells abol'e. g'hich mixture reacts spontaneously?

A Cl, andFeSO., B Fe,(SOt)' and KCI

C K.[Fe(CN)u] and KBr D Kr[Fe(CN)o] and Kl

6 The half-cell equations for the conosion of iron are gir,'en belou'.

+ 29 <-
Fer-(aq1 Fe(s) E" : -0.44Y
O,(g) + 2HrO(l) + 'le 4OH (aq) E" : +0'40 V

What could be deduced from the electrochemical reaction of the corrosion of iron
above?

A The corrosion of iron is non-spontaneous at pH 7'

B The cell voltage is +0.42 V rvhen half of the mass of Fe has conoded'

C The cell voltage decreases u'hen the pressure of O. decreases to 0'5 atm'

D The redox reaction is at equilibrium rvhen the concentration of aqueous Fer- is

1.0 mol dm '.

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7 A molten compound, I^ is electroivsed using a current of 2'1 A for 28 minutes to liberate

0.0183 mol of a gas at the anode. What is'\?
r]
[Farada.v constant- F' is 96 500 C mol
A NaOH B NaCl C A1rO. D MgtN'

g on their radii?
which is the conect sequence of species in ascending order based
A Ne. Na . Mg: B Mg' ' Ne' Na-

c Mgr . Na . Ne D Na-. Ne. Mgl

g 3 0f the Periodic Table?

which statement is true about the oxides of the elements of Period
A A1l basic oxides are soluble in u'ater'

B Alumlniurn oride has the highest melting point'

C Magnesium oride is more basic than sodium peroxide'
The oxides of sulphur fotm strong and rveak acids in aqueous
solutions'
D
10 Which Staternent is not true about Sr and Ba compounds?

A SICO. and BaCO. are themally stable'

B Sr(OH), and Ba(OH). are soluble in u'ater'
C SrO and BaO are ionic comPounds'

D SrSO, and BaSO, are used in medicine'

compounds going do$'n the

11 which statement is true about the trend of elements and their
group fbr elements of Group 14 of the Periodrc Table?

A The acidit-v of the dioxides increases'

B The stability of the monoxides increases'

C The metallic character of the elements decreases'

DTlrestrengthofcor'alentbondofthetetrachloridesincreases.
at high temperature but only lcl't
12 Three chloride compounds, xclr, lclr and ZClt" are stable
represented by XClr' lclr and ZCI'?
and ZClrundergo hydrolysis. Which compounds are

lclr lclr zcll

A CCl.+ Siclr GeCl-'
B Siclr CCl.+ SnClr
C CClr SnCir PbCl-+
D SnClr Siclr GeCl,

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COT{FIDENTIAL* 8

concentrated sulphuric acid'?

l3 Which is true about the reaction bettileen a halide ion and
A The reaction v,'ith Cl liberates yellou'-green llmes'

B The reaction u'ith I liberates brou'n fumes'

C The reaction r'vith Cl produces SO, gas'

D The reaction rvith I produces H'S gas'

14 Tn o test tubes. P of CuSO]' An excess aqueous solution of

and Q, contain aqlleous soiution
which is the final colours of
NH. is added into P and concentrated HCI solution is added into Q.
the soiLrtion'l
PA
A Dark blue Green

B Green BIue

C Dark blue Bror'vn

D BlLre Bror"'n

l5 A schernatic reaction is shon.n belorv'

. sCN
JLl\> HrN(CHr)rNHl
[FetH;o)n1' [Fe(H,o).(SCN)]--

Which statement is true about the above reaction'l

A The coordination number changes from six to three'
B The oxidation number of the central metal ion changes'

C The cornplex is the most stable complex due to the chelating elfect'
[Fe(H,N(CH.)"NH]).]r
to trigonai planar'
D The geometry of the compler changes ft'om octahedral

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Section Bl15 ntarksl

,1 n s v' e r all qu es ti ort s .

Write the answers in the spaces provided'

16 (a) A cell notation of a reaction is gir en belou"

Pt(s) L H,(g) H-(aq) l1 Sn'-1aq;, Snt-(aq) I Pt(s)

f?t
(i) Write the half-cell equations fbr the above reactlon' t-]

Cathode:.....

(ii) Write the overall equation for the reactton' t1l

lJ

(iii) Identify the oxidisrng agent in the reactton' t1l

!

l-:
molten
(b) An electnc cunent of 0.50 A flou's through an electrolytic cell u'hich contaitls tJ

BaC1" for 30 minutes.

(i) the molten BaClt' [2]
Calculate the electric charge, in coulombs, that florn's through

I
!

i?l
(ii) Calculate the mass of Ba deposited at the cathode L-J

lFaraday constant. F. is 96 500 C

mol ']

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has the
l7 A coordination compound of cobalt is [CoC1,(NHTCH.CH]NH])']C1' The cornpound
properlies as fbllou's:

' Solid
. \ iolet
' Soluble in u'ater
(a) State the oxidatron state of cobalt in [CoC1,(NH'CH:CH:NHr)]]C1' t1l

(b) Write the electronic configuration of the cobalt ion' t1l

(c) State the coordination number of cobalt in [CoC1,1NH]CHTCH'NH:)']CI' Erplain -vour

ans\\;er. t3]

:-.
!

(d) Predict the number of moles of silver chloride produced u'hen one mole of
lcocl"(NH,CHTCH.NH.),]C1 is treated rvith
an excess aqueous silver nitrate. Erplain .vour
L- t
ans\\'er.
!
lJ

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CONFTDENTIAL* 16

Section C 130 marks)

Ansv'er two questions onb.

yotr mat. atlsy,et. ct/l tlte questiotls but. onh' the .first two airstlers v'i/l be ntarketl. Ili'ite tlte
otl.\tret's o1 the cttlsrt'er sheels proviclecl. Begin each ansv'er on a new page o,/'tlte ttttstet'sheet'

gir"en in
1g The standard enthalpy changes involved in the formation of strontiLrm oxide. SrO. are
the table belou'.

Standarcl enthalpr change aff kJ mol '

Lattice energy of SrO 33 10

Enthalpy change of fbnnation of SrO -590

t,1 )
First electron affinity of ox,vgen
Second electron affinitl' of oxYgen X
Enthalpy change of atomisation of strontium -164
-r248
Enthalpy change of atornisation of oxygen
First ionisation energ;- of strontium -5,18

Second ionisation energy of strontium +1060

(a) Construct the Born-Haber cycle for SrO and determine the value ofX. l7l
(b) Explain the difference betu,een the first electron affinity of oxygen and X. t4l

(c) Based on the standard enthalpy change of lbnnation of SrO and the standard enthalpy
chan-9es belor'l'.

SrO(s) + CO,(g) ------------> SrCO.(s) A11" : 234 k'l

C(s) + O.(g) 4 CO,(g) A-F1" : 39.t kJ

f?l
calculate the standard enthaipy change of formation of strontium carbonate. SrCO.. L-)

(d) Compare the relative stabilities of SrO and SrCO.' trl

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19 The elements of Group 2 of the Periodic Table are known as alkaline earth metals.
(a) State the properties of the reactions and w'rite the chemical equation when magnesium and
barium react u,ith $'ater respectivell. t6]

(b) Explain u.hy magnesium sulphate is soluble in r.vater but barium sulphate is insoluble in
water. t4l

(c) Explain the acid-base propefiles of the hydroxides of Group 2 of the Periodic Table from
tit
berylliurn to barium. I'f

20 (a) Tetrachlorides of Gror.rp 1-l of Periodic Table are liquids atroom temperature.

(i) Compare the reaction betu'een each of the tetrachlorides rn'ith water.
fil
t-f

l\l
(ii) Erplain the trend of thermal stability of the tetrachlorides. L- l

(b) Sheet silicates are knorvn as phyllosilicates. Drau' and describe the structure ofthe sheet
f5t
silicate. Gir,'e one example of tl,e silicate. L- I

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