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44 views13 pagesPE Assignment
Uploaded by
Shivansh BhatnagarCopyright
© © All Rights Reserved
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/ 13
PHASE EQUILIBRIUM
Assignment
Q1) For the equilibrium, Fe(s) + H2O(1) == FeO(s) + H2(g)
What are the number of components, phases and degrees of fréedom
respectively?
(a) 3,2,3 (b) 2,3,3 (c) 3,3,2 @
Q2) Which of the following statements is/are
1. Thephase diagram of a subst: ie regions of pressure
t answer using the code given below
) 2 and 3 (c) | and3 (d) 2 only
Q3) What will be the number of phases, components and degrees of
freedom respectively of the azeotropic mixture of water and ethanol at
10atm at equilibrium?
2,2and2 (b) 1,2and3(c)2,2and0 —(d) 2,3 and 1
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q4) Solid carbon reacts with oxygen in presence of a catalyst to form
the gaseous oxides CO and CO». What is the number of degrees of
freedom (variance) for the system once equilibrium has been attained?
(a) 0 (b) 1 (c)2 (d)3
Q5) Consider the following statements
1. For a one component system, the maximum ses
that can exist in equilibrium is three.
2. A system can have negative degrees of fr
3. The number of phases in a system doe:
amounts of the various substances,
20g) = FeOys) + Hag)
) 4,3 (c) 3,1 (d) 4,2
Q7) For a pure substance, the triple point in a phase diagram has
(a) One degree of freedom (b) Two degrees of freedom
(c) Three degrees of freedom (d) Zero degree of freedom
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q8) Sulfur can exist in four phases. The possible number of triple
point is
(a) 1 (b) 2 (c)3 (d)4
Q9) The phase diagram of NaCl-H20 is of simple eutectic type, The
iturated NaCl solution
iborane (B) form a compound, which
melts ci . The system exhibits two eutectics, one at
25 mole d 123K and a second at 90 mole percent B and
104K. The points of pure A and B are 131K and 110K,
respectively:
Q10) The phases at 55 mole percent B and 108K are,
(a) Solid AB and a solid B phase *(b) Solid AB and a liquid phase
(c) Solid B and a liquid phase (d) Solid A and a liquid phase
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 QI1) The mixture at 25 mole percent B and at 124K is cooled slowed
to 114K. The resulting phases are
(a) Solid AB and solid A (b) Solid AB and liquid
(c) Solid AB and solid B (d) Liquid and solid A
Q12. For a one component system, the maximum number of phases
that can coexist at equilibrium is
(a)3 (b)2 (1 @ *
Q13. The phase diagrams of CO2 and H20 dififé
(a) The slope of the solid-liquid e
former negative for the latt
is positive for the
ibrium curve is negative for
Q14. The number of degree of freedom for a system consisting of
NaCl(s), Na*(aq) and CI (aq) at equilibrium is
(a)2 (b) 3 (c) 1 (d)4
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q15. The triple point for water is
(a) Unique (b) Depends on both p and T
(c) Depends on p but is independent of T
(d) Depends on T but is independent of p
Q16. The triple point of water is at
(a) 273.16 K (b) 273.16 K and
(c) 273.16 K and 4.58 Torr (d) 760 Tor
Q18. An aqueous mixed solution of NaCl and HCl is exactly
neutralized by an aqueous NaOH solution. The number of components
in the final mixture is
(al (b) 2 (c)3 (d)4
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q19. The lowest pressure at which the liquid phase of a pure substance
can exist is known as
(a) critical point pressure (b) super-incumbent pressure
(c) triple-point pressure (d) saturation vapour pressure
Q20. A certain substance is known to exist in four of
the following is definitely NOT the phase diagram?
nD
wt b) JW,
© la ? | sw,
;
:
Sw
w& s Ww 2
| Se 2:
BD aE
=
GB chemistry @ichemistry.online [4 jehemistryoosagmail.com —— Q21. The number of phases, components and degrees of freedom,
when Ar is added to an equilibrium mixture of NO, O2 and NO» in gas
phase are, respectively,
(a) 1, 3,5 (b) 1,4, 5 (©) 13,4 @) 14,4
Q22. The phase diagram of a pure substance is sketched below.
P2.
The nu of de es of freedom at points P1, P2, and P3,
respectivi
(a) 2, 1,0 (b) 1, 2,0 (c) 2,0, 1 (d) 0, 2,1
Q23. The solid-liquid phase diagram for the Mg-Zn system is shown
in the figure below where the vertical line at X(Mg) = 0.33 represents
the formation of a congruent melting compound MgZnp. The figure is
GB chemistry @ichemistry.online [4 jehemistryoosagmail.com —— divided into seven regions depending upon the physical state of the
system. The composition of the region #6 represents.
70
600}
al
500]
400) 45
300] #4 46
200 @
000 010 020 030 040 050 0.60 0.70 0.80 090 TI
Zn x(Mg)
(a) Singl ase of a solution of
(b) n and solid MgZno.
(c) Two phi iquid and solid MgZn2.
(d) Two phase n solid Mg and solid MgZno.
Q24. A sysi sists of gaseous H2,O2, H2O and CO> where the
amount of CO: is specified and the equilibrium constant for the
reaction 2H2 (g) + O2 (g) == 2H20 (g) is known. The number of
degrees of freedom of the system is
(a)2 (b) 3 (4 (5
GBs chemistry [email protected] [4 jchemistryooaagmaitcom gasosai671 Q25. A pure substance can exists in several different phases A, B,
C,.....Its partial phase diagram is shown below.
Which of the following statements is e above diagram?
(a) The i bi i) é
(b) ymoré than one triple point
(c) A phase
(d) The point ¥
e an island, such as D
oftbeypresent in any phase diagram
Q26. The temperature-dependence of the vapour pressure of solid A
can be represented by log p= 10.0- =“ and that of liquid A by log
p=8.0-. The temperature of the triple point of A is
(a)200 K (b)300 K (c) 400 K (d) 500 K
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q27. The temperature-composition (T-x) phase diagram of the two-
components system made of X and Y is given below. At a temperature
of 288K and starting at the point P, Y is added until the composition
reaches S. Which of the following statements is NOT TRUE?
Mole fraction of Y
(a) At, P, id and liquid are present in almost equal proportions
(b) At Q, the system is all liquid
(c) At S, the system has more solid than liquid
(d) At R, the liquid is pure X
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q28. Phase diagram of a compound is shown below
respectively. If melting point and AH of melti
mole’ respectively, the change in the vol ‘ing is
1
(d) 10cot,
ce, when cooled under a pressure
(b) Liquifies first and then solidifies
(d) Remains unchanged.
Q30. Triple point pressure of substances A, B, C and D are 0.2, 0.5,
0.8, and 1.2 bar, respectively. The substance which sublimes under
standard conditions on increasing temperature is
(ayA (b) B ()C (d)D
CBs chemistry [email protected] [4 jchemistryoosagmaitcom gasosai671 Q31. At the triple point of water C, P, F are respectively
(d) 3, 3, 2
(a) 1, 3,0 (b) 1, 3, 1 (c) 1, 2,0
Q32. The lowest temperatures attainable with a freezing mixture is
(b) Eutectic temperature
(a) critical solution temperature
(d) Critical
(c) Triple point
Q33. The minimum number of phases existing in a
(b) 1
ase diagram (see
(a) 0
Q34. A one-component system with the
is not possible because
the figure)
J masea
= ae
Temperature
(b) OC has positive slops
(c) Both OB and OC are linear
(d) OB, OC and OD cannot all coexist, given OA
M1 ichemistryoosagmailcom 9016988388
Gs chemistry @ichemistry.online Q36. A phase transition process is always
[NET June 2017]
(a) isothermal-isoentropic (b) isochoric-isothermal
(c) isobaric-isochoric (d) isothermal-isobaric
Q37. m: and m2 are the slops (dP/dT) of the solid-liqui
lines in the P-T phase diagrams of H2O and COz, re;
P<10 atm, the values of mj, and m2 are
(a)m,>0 and m2>0
(b) mi>0 and m2<0
(c) mi
