Metallogenyandgeodynamicsofthe Aktiuz Boordu Mining District Northern Tien Shan Kyrgyzstan
Metallogenyandgeodynamicsofthe Aktiuz Boordu Mining District Northern Tien Shan Kyrgyzstan
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Keywords: Geodynamics; Gold; REE; Rare metals; Ore reserves; Genetic model
Fig. 2. Stratigraphic column of the Aktiuz-Boordu Mining District and main rock types (courtesy of Y. Karaev, V. Nikonorov , L. Nogaeva, R.
Maksumova, modified by R. Djenchuraeva).
                               R.D. Djenchuraeva et at. I Journal of Asian Earth Sciences 32 (2008) 280-299                     283
visions: the Kokbulak (migmatite with metapelite substra-              and their zoning relative to sub-latitudinal rift-like struc-
tum) and Kapchigay suites (migmatite with metabasite sub-              tures clearly indicate a complex geodynamic environment,
stratum) instead of the Tegermenty suite. The collision stage          comparable to the Gulf of California (Solomovich, 1987,
was characterized by obduction of the ophiolite on continen-           1997).
tal blocks, with intense deformation, tectonic melange, par-               Plutonic activity in the volcanic arc began with the
tial melting (migmatites) and emplacement of granitic                  intrusion of diorite-tonalite and ending with calc-alkaline
plutons. U-Pb zircon dating for the Kemin Group migmatite              rocks emplaced in an accretionary environment. In the
yields an age of 2200 ± 50 Ma (Kiselev, 1999).                         Aktiuz-Boordu Mining District, these Devonian granite
    Subduction systems were responsible for the formation              intrusions are superimposed upon the Northern Tien Shan
of Cambrian-Early Ordovician oceanic island arcs and of                Caledonides, including the southern regions of Southern
the Middle Ordovician continental volcanic arcs in the                 and Central Kazakhstan. The Chimbulak leucocratic gran-
Northern Tien Shan. Intense volcanic activity was accom-               ite complex is located in the Taldybulak-Boordu field and
panied by formation of tholeiitic and slightly evolved                 is part of the Devonian alkaline granite suite. These include
calc-alkaline volcanics (Bakirov and Ghes, 1993).                      stocks of alaskite, alkaline granites and quartz syenites.
    The Nogaisai and the Sonkultau intrusive suites in oce-            They are similar to the Central Kazakhstan granites, such
anic island arcs are represented by sheetlike intrusions.              as the Maytas intrusion. The low absolute and relative alu-
They consist of the Early Ordovician gneissic plagiogra-               mina content, the presence of high agpaitic coefficient val-
nites, diorites, and granodiorites. In the adjacent area, dio-         ues, as well as increased overall alkalinity, with dominant
rite intrudes the Lower Cambrian Karaarcha Formation                   Na, are characteristic of this Devonian magmatism.
and is overlapped by Middle Ordovician sediments.                      According to Solomovich (1997), this geochemical signa-
    The Cambrian-Early Ordovician subduction was com-                  ture is the major feature that distinguishes these rocks from
pleted by the Middle Ordovician, followed by collision of              other Tien Shan granites. Based on their similar REE sig-
island arcs with the North Tien Shan Continent. After col-             nature, these granites correspond to subalkalic syenite-
lision of the island arcs with continental blocks, subduction          alaskite.
of oceanic crust continued resulting in the development of                 Widespread intra-plate rifting occurred in the Late
continental volcanic arcs, perhaps forming an Andean type              Permian-Early Triassic. A system of narrow grabens was
margin. Volcanic-plutonic associations of these continental            established and was filled with subalkali basalt and andes-
margins are of calc-alkaline and shoshonite affinity (Ghes,            ite lavas. This period is characterized by the formation of
1999).                                                                 mineral systems containing REE, rare metals, Sn, Li, and
    The intrusive complexes of the Kyrgyz Range com-                   Be.
prise granodiorite, granodiorite porphyry, and quartz                      In the Aktiuz-Boordu Mining District the Permian
monzonites. Isotopic mineral age determination from                    intrusive suite occurs as linear bodies of subalkalic leucog-
these rocks, using the K-Ar system, yielded 470-480                    ranites, granophyres and alaskite. Rare-metal-bearing
Ma for biotite and 450^190 Ma for amphibole (Stratifitsi-              granophyres are a facies of the subalkalic leucogranites,
rovannye, 1982). The development of the superimposed                   and locally associated with breccia pipes. The isotopic
volcanic belts is typical for the Kyrgyz and Kungey                    age of the Kuperlisay leucogranite was determined at
ranges. The Middle Ordovician calc-alkaline volcano-plu-               260 Ma (Krylow et al., 1960), whilst the K-Ar age of
tonic activity of the continental margin led to the forma-             microcline from granophyres yielded ages of 225-230 Ma
tion of porphyry copper-gold systems (Djenchuraeva and                 (Kim, 1972). However, there is another point of view con-
Maksumova, 1993).                                                      cerning the granites and mineralization ages. Analyzed
    The Late Ordovician-Silurian collision completed the               samples of the Aktiuz granite intrusion taken from the
establishment of the vast Kyrgyz-Kazakh continent. In                  Kutessay II open pit showed a SHRIMP U-Pb zircon
the south, it was bordered by the Turkestan Paleo-ocean,               age of 416 Ma, which led some authors to suggest a Devo-
and in the north, by the Djungaro-Balquash oceanic basin.              nian age for the Aktiuz REE mineralization (Konopelko
Gold mineralization associated with collision process is               et al., 2006; Chiaradia et al., 2006). The Permian ore-bear-
mainly represented by silicification zones with orogenic               ing granites with REE mineralization significantly differ
gold lodes hosted in shears associated with thick nappe-               from the Devonian ones by parameters, such as composi-
thrust zones.                                                          tion, geochemistry, and rare earth element patterns
    Devonian magmatism was then superimposed on the                    (Solomovich, 1997).
Caledonides of the Northern Tien Shan, forming a volcanic                  The mineral systems of the Aktiuz-Boordu Mining Dis-
belt with a molasses basin in the back-arc zone. The onset             trict include porphyry copper, quartz-tourmaline-gold-
of this magmatic activity resulted in formation of andesite            sulphide veins, quartz-tourmaline-gold-bismuth veins,
(trachyandesite)-dacite-rhyolite associations of the Early             barite-base-metal and epithermal gold-silver (Early-Mid-
Devonian Almerec Formation. Andesite and trachyande-                   die Paleozoic) as well as REE and rare metals (Upper
site are predominant. Volcanic rocks and small monzo-                  Paleozoic). These mineral systems are mainly within the
nite-syenite intrusions of the Kyzylsu Formation make                  Precambrian basement metamorphic rocks of the district,
up a volcanic-plutonic association. These rock associations            namely the Archaean Aktiuz, and the Paleoproterozoic
284                           R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299
                           Fig. 3. Distribution of the ore deposits and occurrences in the Aktiuz-Boordu area.
                                     R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299                              285
Table 2
Possible reserves (Pi) and resources (P2) in the Taldybulak
Levoberezhny ore field Taldybulak    Chimbulak       Kuranjailau   Total
Levoberezhny (flank and deep         Western         (tons)        (tons)
levels) (tons)                       (tons)
34.4 (/>,)*                                          24.0          114.4
40.0 (P2)'                            16.0
steep columnar bodies are mainly controlled by faults.                  ated with monzodiorite stocks and dykes. The mineraliza-
Gold-sulphide disseminated mineralization is associated                 tion of this ore field is characterized by a wide range of
with the top of the shear zone and controlled by quartz-                altered rocks, localized not only within the crater of the
tourmaline veinlets. The steeper veins are generally associ-            stratovolcano, but also along the periphery of volcano-
                                       R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299                                      287
Table 3
Chief characteristics of the Taldybulak Levoberezhny ore deposit
Name and form of orebodies                Square (m2)     Extension by strike (m)      Extension by the dip (m)      Thickness (m)       Part of reserves (%)
"Major" zone sheet-like orebody           30,000          1500                         1000                          80                 60.5
"Northern" zone sheet-like orebody        12,000           600                         1500                          56                 23.3
"Upper" ribbon-like zone                    3600           720                          500                          10.5               11.2
"Western" zone                              1800           240                          600                          50-100              5.0
1 2 3
Fig. 6. Model of metasomatic (1 (. mineral (2). and geochemical (3) zoning of the Taldybulak Levoberezhny gold deposit. Alteration columns: A, frontal;
B, prefrontal; C. intermediate D. rare mmerals: Q. quartz: Car. carbonate; Ser, sericite; Tu, tourmaline; Pfs, potash feldspar; CI, clay minerals; Py, pyrite;
Chp, chalcopyrite. Details in t a x
288                                R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299
influx of meteoric fluids in the hydrothermal system. The                         (5) Post-ore pyrite appears in quartz-carbonate lodes
Rear (D) sub-ore zone of alteration column is character-                              and has compound forms mainly of octahedron
ized by potassic alteration, developed on gneisses and                                habit. Cubic pyrite is represented in small quantities
migmatite, and represented by an assemblage of K-feld-                                within the frontal zone,
spar-biotite-albite and quartz. The latest alteration events
are barren quartz-carbonate veins and veinlets with pyrite                       Thus, the cubic forms are typical for the rear zone of the
disseminations. The mineralization consists of gold-sul-                     Taldybulak Levoberezhny deposit and in zones B and C,
phide-quartz (with sulphide content of 5-20% mainly as                       within quartz-sericite-pyrite-chlorite and quartz-carbon-
pyrite (90%) and chalcopyrite (10%), which is related to                     ate-fuchsite altered rocks in combination with pentagonal
the emplacement of the monzonite complex within an                           dodecahedrons. Such regularity is typical also for the Mak-
active continental margin in Devonian-Carboniferous                          mal, Altyn-Jylga and the Kumtor gold deposits (Pak, 1992,
times. Pyrite is developed in all zones, increasing from                     2005).
the rear zone towards the pre-frontal zone and ranges from                       The major ore minerals are gold, pyrite and chalcopy-
about 1% in zone D to 2-3% in zone C, 2-10% in zone B,                       rite. Pyrite and chalcopyrite contain 55.6% and 43% Au,
10-20% in separate quartz-sulphide bodies, then it sharply                   respectively. In the ore block, the minimum Au content is
decreases in frontal zone A. First generation Au minerali-                   4.2 g/ton, with a lower cutoff grade of 1 g/ton. Maximum
zation linked with the alteration envelopes is developed                     depth of the ore zone is 600 m (Table 4).
in zones B and C. Second generation Au mineralization                            Analysis of geological and geophysical data from the
is associated with quartz-sulphide bodies, mainly pyrite                     Taldybulak Levoberezhny deposit indicates that the
with minor chalcopyrite predominantly developed in pre-                      deposit is located on the southern edges of positive gravity
frontal B zone.                                                              anomalies are associated with induced polarization anom-
    A total of 18 morphological types of pyrite crystals have                alies and increased K abundance (Figs. 7 and 8). Generally,
been identified within the mineralized zone, with cubic                      Au is localized in an "intermediate" zone, but it is not
(100) and pentagonal dodecahedron (210) crystals domi-                       found within the negative gravity anomalies. Among the
nant and octahedrons (111) less frequent. Several genera-                    radioactive elements (U, Th and K), K dominates as a
tions of pyrite were recognized corresponding to different                   result of the pre-ore potassic alteration. Thus, established
alteration zones (Malyukova, 1999; Pak, 1992, 2005) with                     alteration zoning is reflected in the mineral-geochemical
the variety of crystal habits increasing from barren inter-                  signatures and the evolution of pyrite crystals. This serves
vals towards productive mineral assemblages, as described                    as a basis for the development of a general genetic model
below.                                                                       of the ore deposit that can be used both as forecasting
                                                                             and prospecting tools in the Aktiuz-Boordu Mining
  (1) Primary cubic pyrite of unaltered rocks is predomi-                    District,
      nant in the rear zone (D).
  (2) Pre-ore pyrite with cubic habit and with a combina-
      tion of cubic with pentagonal dodecahedrons                           2.2. The Aktiuz ore field
      (100)+ (210) is widespread in both quartz-sericite
      and quartz-carbonate altered rocks and is typical                         In the Aktiuz ore field, the metamorphic rocks are sub-
      for intermediate (C) and prefrontal (B) zones.                         divided into the Aktiuz complex and Kuperlisay suite. The
  (3) The quartz-tourmaline-pyrite association is charac-                    Aktiuz complex is between 2800 and 2900 m thick, was
      terized by the widest variety of pyrite morphology                     dated at 2780 Ma (Bakirov and Korolev, 1979) and con-
      dominated by pentagonal dodecahedrons (210) local-                     sists of gneisses, crystalline schists, amphibolites, marbles,
      ized in the prefrontal zone (B) of the alteration column.              and migmatites. These metamorphic rocks are folded into
  (4) Pyrite of the late productive stage (quartz-gold-sul-                  the large Tuktugurbulak recumbent anticline and the small
      phide association) is characterized by a sharp pre-                    Aktiuz anticline. The Kuperlisai suite is 3900 m thick and
      dominance of pentagonal dodecahedrons (210)                            consists of amphibole schists and foliated metabasic rocks,
      often combined with octahedron edges. These forms                      The Formation was dated at 2500 Ma (Bakirov and Koro-
      are typical for the upper part of the prefrontal zone.                 lev, 1979). Metagabbro and gneissic granitoids intruded the
Table 4
Ore reserves for the Taldybulak Levoberezhny ore deposit
Ci (thousand tons)     Average content,   Au (tons)        C 2 (thousand   Average      Au (tons)   Pi (thousand   Average content Au,   Au
                       Au (g/ton)                          tons)           content                  tons)          (g/ton)               (tons)
Identified reserves
5601.9                 6.04               33.823           5227.8          5.97         30.702      -              -                     -
Identified subeconomic resources
1941.7                  2.61                5.073           808.0          2.81          2.270      5379.3         6.41                  34.485
                                R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299                          289
Fig. 7. Induced polarization map and isolines of geoelectrical prospecting for the Taldybulak Levoberezhny gold deposit.
metamorphic rocks of the Aktiuz complex and Kuperlisay                   Permian subalkali leucogranites. The syenite consists of
suite.                                                                   plagioclase, alkali feldspar, and amphibole. Quartz, clino-
    The 37CMU0 Ma Caledonian Tasa-Kemin batholith is                     pyroxene and biotite are rare; apatite, titanite and zircon
north-trending and comprises diorite, granodiorite, adam-                are accessory minerals.
elite, and granite. Granodiorite prevails in the central part               A number of faults traverse the Aktiuz ore field
of the batholith with adamelites and fine-grained granites               resulting into a series of blocks forming a disturbed
exposed in the outer zone. Hercynian (400-250 Ma) intru-                 zone, about 2 km wide, which controlled the emplace-
sions are abundant and diverse. In the Aktiuz ore field                  ment of the Caledonian and Hercynian magmatic rocks,
monzodiorites. quartz diorites, alkaline granites, and                   The ore deposits are located along a north-east striking
quartz syenites occur as dykes and stocks elongated to                   zone. The Kuperlisay pluton in the south-western part
the north-east and in a sub-latitudinal direction. Monzodi-              of the ore field, consisting mainly of leucogranites, is
orites are exposed in the Kutessay open-pit where they cut               wedge-shaped in plan and plunges beneath the metamor-
the amphibole schist of the Kuperlisay suite. Monzodiorite               phic rocks. At the Kutessay II deposit, the upper edge of
is a medium-grained greenish gray rock with parallel orien-              the pluton occurs at a depth more than 400 m. The
tation of plagioclase and amphibole crystals. Plagioclase,               ridges or protrusions of the Kuperlisay pluton are
alkali feldspar, amphibole and quartz are the major rock-                crowned by granophyres cupolas and breccia pipes. The
forming minerals. Apatite, allanite, titanite and magnetite              granophyres host base- and rare-metal mineralization,
occur as accessory minerals: xenoliths of amphibole schists              which includes mineral species, such as cyrtolite, apatite,
are abundant.                                                            thorite, monazite, and titanite. The K-Ar isotopic age
    Permian syenite crops out as northeast-trending dike-                of feldspars from the leucogranite yielded an age of
shaped and lenticular intrusions. Locally, they cut the Cal-             260 Ma (Krylow et al., 1960). The Kuperlisay linear
edonian granodiorite. and in turn, are cross-cut by dikes of             extended granite intrusion (Fig. 9) plunges beneath the
                                              R.D. Djenchuraeva el at. I Journal of Asian Earth Sciences 32 (2008) 280-299                            291
Pre-Cambrian metamorphic rocks towards the northeast                                       The Kutessay II deposit was exploited from 1958 until
and hosts the Kuperlisay Th deposit, Kutessay, Aktiuz                                   1991, and then was abandoned. An additional 51,500 tons
REE-rare metals-base metal deposits, and Kalesay Be                                     of total REE at a grade of 0.22-0.27% remains unex-
deposit. At depth, the granite massif has several ridge-                                ploited. The Aktiuz deposit was mined over the period
like projections (Fig. 9). The Kutessay deposit is located                              1927-1964. The Kalesay deposit was considered as eco-
in one of these ridge-like projections in the north-eastern                             nomic with BeO reserves approved by the former USSR
part of the Kuperlisay intrusion within a granophyre                                    State Reserves Committee in 1970, however the deposit is
stock and brecciated schists. The Aktiuz deposit is                                     now deemed uneconomic. The Kuperlisay Th deposit is
located 1 km further north-east and is associated with a                                associated with sub-alkali leucocratic granites, with high
blind granophyre stock and a breccia pipe. The Kalesay                                  abundances of P (0.2%), Th (0.005%), total REE (0.02-
Be deposit does not have any direct connection with                                     0.04%), and Ta (0.005%).
granites and is located within a zone of fine jointing in                                  The Permian-Triassic intrusions are affected by post-
the southern schist band. Granophyre, granite porphyry,                                 magmatic alteration including early stages of replacement
and aplite-like fine-grained leucogranite crop out as                                   by K-feldspar, albite, and biotite and late stages of sericiti-
minor intrusions that cut the subalkali leucogranite.                                   zation, chloritization and silicification, forming envelopes
Granophyre is a brick-red fine-grained rock with micro-                                 of quartz-sericite and greisens. Thorium-rare earth miner-
cline (53-58 vol %) and quartz (34-47 vol %). The K -                                   alization is widely developed in the quartz-sericite alter-
Ar age of granophyre (two microcline samples) is 225-                                   ation zones. The Th content varies between 0.01% and
230 Ma (Kim, 1972).                                                                     22.3% in high grade ores, averaging 0.2% and in low grade
   In the Aktiuz ore field two mineralization periods have                              ores averaging 0.028-0.04%.
been recognized, separated by an interval of 30-35 Ma:
                                                                                        2.2.1. The Aktiuz REE-Th~Pb deposit
  (1) Early rare-metal mineralization in leucocratic gran-                                 The complex Aktiuz mineral deposit, is located on
      ites; and                                                                         the north-west slope of the Tasa-Kemin mountain range
  (2) REE-rare metal-base metal in granophyres and brec-                                in the Kemin area (76°08'E, 42° 51'N), and contains
      cia pipes.                                                                        Ag, In, Cd, Sn, Mo, Th, U and REE mineralization
                                                                                        (Table 6). The richest upper parts of the ore deposit
   Each period includes a number of stages distinguished                                were developed by ancient miners in the IX-XII centu-
by structural conditions controlling the mineralization,                                ries. In 1942 the deposit was considered for further
geochemical fingerprinting, alteration, composition of ores                             development as a Pb-Zn-Sn project and resulted in
and mineral associations. The mineral resources of the                                  establishment of the first mining enterprise in northern
Aktiuz ore field are represented by the Kuperlisay, Kutes-                              Kyrgyzstan. The deposit was a Th-Pb-Sn mine, also
say, Aktiuz and Kalesay deposits (Table 5). Reserves of Th                              producing Zn, Sn, Au and Cu as by-products from con-
(measured — indicated categories) for Kuperlisay ore                                     centrates. From 1957 onward, the concentrating plant
deposit are in total 541 tons grading 0.065-0.132%, but                                 produced Mo and REE. In 1964 the deposit was
have no economic importance.                                                            exhausted.
Table 5
Ore reserves for the Aktiuz ore field
Metal        Ore lepc - b
                                                     Kutessay                       Aktiuz                          Kalesay                  Total
                            -H nB                    Content       Reserves         Content        Reserves         Content   Reserves       (tons)
                                ' :   -   •          (%)           (tons)           (%)            (tons)           (%)       (tons)
Pb          -               -                        2.51          48500            2.62           44095            -         -              92595
Zn          -               -                        0.48          9000             1.45           24402            -         -              33402
Cu          -               -                        0.06          100              0.15           2536             -         -              3636
Sn          -               -                        0.06          1193             0.17           2549             -         -              3742
Mo          _               -                        0.04          883              0.06           1057             -         -              1940
Th           0.065          5*:                      1 to          6325             0.073          1959             -         -              8825
Ag (g/t)     -              -                        11            16.5             13.0           22               -         -              38.5
ITR20,       -              -                        0.41          88022            0.55           5967             -         -              93989
BeO          -                                       -             -                -              -                0.127     11701          11701
Cd           -                                                     -                0.005          94.7             -                        94.7
In           -              -                        -             -                0.001          26.2             -                        26..5
Zr02         -              -                        •L*           :—32             -              -                -                        24432
Hf           -                                           , __      395              -              -                -                        395
Ta 2 O s     -                                                     2586             -              -                -                        2586
Nb205        -                                              -                       -              -                -                        7326
292                                 R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299
Table 6
Ore reserves for the Aktiuz ore deposit
Reserves           Extracted from 1942 to 1946            Reserves as of 01 July 1946             In the orebody 'Ore stock" as of 01 July 1957
Components                                                Content (%)       Reserves (tons)       Content (%)               Reserves (tons)
Pb                                                        4.65              64445                 1.96                      14245
Zr                 2.40              5300                 2.01              27971                 1.20                      8735
Cu                 0.44              973                  0.36              4955                  0.14                      1050
Ag                 35                7.7                  32                44.2                  9.8                       7.13
In                 0.002             4.0                  0.002             27.5                  0.005                     35.2
Sn                 0.35              774                  0.22              6086                  0.08                      580
Mo                 -                 -                    0.15              1410                  0.05                      363
Cd                 0.008              18.0                0.008             110                   0.001                     7.15
Th                 -                 _                    0.073             1970.9                0.09                      958
U                  -                 -                    0.006             161                   -                         -
ITR203             -                 -                    0.58              5578                  0.55                      5967
Be                 -                 -                    -                 -                     -                         -
rocks. Rose colored orthoclase granophyres occupy the                veins and contains very rich base metal and Sn ores
central part of the stock, with rose-gray quartz-sericite-           covering approximately 600 m2. In the veins and
chlonte alteration in the apical sections of the stocks and          massive sulphide ores, Pb grades range from 9.4%
gray quartz alteration in the hanging wall.                          to 16.1%, Zn from 4.58- 13%, Ag from 18.6 to
   Orthoclasites contain REE and Th mineralization, but              78.7 g/ton, Sn from 0.3% to 0.4%, Th from 0.02%
poor base metallic mineralization (Pb - 0.3-0.7%). In addi-          to 0.04%. In addition, Pb exceeding 2.3%, Au
tion, to REE and Th, the quartz-sericite-chlorite metaso-            (0.2-0.5 g/ton) and U (0.006%) mineralization is
matites contain higher grade base metal mineralization               also present.
(Pb - 0 8-2 0 i. Significantly, quartz metasomatites host        (B) Pre-frontal zone (2550-2474 m). Rich base metal
complex rich economic mineralization (Pb, Zn, Sn, REE,               mineralization of a predominantly massive and vein
Th. and I                                                            type is concentrated in silicified and brecciated schists
    Almost all the breccias, including altered granophyres,          and predominantly quartz bearing altered rocks in
biotite homfeises and the upper part of schist breccias con-         the upper part. Below the 2514-m level, the area of
tain economic Pb. Sn. Th and Mo associated with the REE              economic base metal mineralization increases in size,
mineralization as veins, blind lenses, and breccia bodies.           up to 3200 m 2 , at the expense of the quartz-sericite
The frontal 12550-2590 m), pre-frontal (2474-2550 m),                altered rocks. Tin is associated with Pb and Mo. At
intermedia:.            M74m I. and rear (2213-2393 m) zones         the lower levels (2474 m) of the pre-frontal zone,
are defined by Ike —lure of metasomatic processes, pecu-             complex Pb, Mo, Sn, Th and REE economic mineral-
liarities ::" : - ; rrr-Sei-r.g stock, internal structure and        ization is hosted by quartz-sericite-chlorite altered
the                   f naaltj-type economic mineralization in       rocks and occupies an area of 9000 m2. The Mo ore
the pipe-               These zones are described below.             zone does not exceed an area of2500m 2 .ThePb con-
                                                                     tent sharply decreases with depth from 9.4% to
 (A) The FTCECI         :-'-• -2550 m) is the apical part            3.73%, while Zn increases from 1.32% to 1.75%. Tin
     of the crc-aeaoag sock. In an adit at 2550 m, eco-              grades range from 0.23% to 0.3%, Cu from 0.13%
     nomic mma               5 concentrated in brecciated            to 0.18%, Th reaching 1.4%, averaging 0.03%, EREE
                                                                     is 0.46%.
294
Fig. 12. Distribution of orebodies: cross sections A-A and B-B (Fig. 10) through the Aktiuz ore deposit. Compiled by F. Borisov and R. Djenchuraeva,
using the data of F. Borisov, N. Doroshenko, and N. Trifonov.
 (C) The intermediate zone (2474-2393 m) is characterized                   Zn and Sn contents average 1.57%, 0.91% and 0.12%,
     by a wide distribution of quartz-sericite-chlorite,                    respectively, while the REE content decreases to 0.16%.
     strongly silicified rocks, and brecciated schist and                      The mineral composition of the ores is rather complex
     ore-bearing hornfelses. Economic REE mineraliza-                       with more than 60 minerals identified. Major gangue min-
     tion is present in altered granophyre and brecciated                   erals, typical for all the mineralization stages, are quartz,
     schists. The REE ore zone covers 12,000 m2 at the                      feldspars, sericite, biotite, fluorite and calcite. Ore minerals
     2474-m level with ZREE averaging 0.71%. Base met-                      include parisite, ancylite, ambatoarinite, zircon, malacon,
     als and REE mineralization are localized in the hang-                  cyrtolite, aktiuzit, monazite, and ferrithorite, galena, sphal-
     ing wall of the stock. At the 2433-m level, the average                erite, wurtzite, and marmatite, chalcopyrite, molybdenite
     grades are as follows: Sn 0.20%, Pb 0.7%, Zn 0.69%                     and phenacite, beryl, genthelvine, bavenite, gelbertandite,
     and Mo 0.21%.                                                          and milarite. As a result, the ores are characterized by a
 (D) Rear zone (2393-2213 m). All economic mineraliza-                      complex array of elements that includes Pb, Zn, Th,
     tion is traced in the hanging wall of the ore-bearing                  REE, Mo, Sn, Ag, In, Cd, and Be. In the upper levels
     stock in strongly silicified altered rocks and, occa-                  (2514 m) Pb (9.4-16.17%), Zn (4.0-14.0%), Cu (0.92%),
     sionally, in brecciated schists.                                       Sn (0.5%) and Th (0.1%) have the highest grades, which
                                                                            gradually decrease in the lower levels (2280 m).
   Mineralization was encountered in drill holes below the                      Molybdenum (0.05%-0.19%) is distributed only in the
Kapitalnaya adit. Ore grades of Pb range from 1.57% to                      hanging wall of the ore-bearing stock within the upper
1.87%, Zn from 0.91% to 1.15%, Mo 0.10% and Th from                         and middle horizons of the deposit. REE is dominated by
0.063 to 0.102%. Within the Sn-bearing veins the grades                     the Ce group (92.32% of the total amount of REE, and
of all metallic components are very high: EREE (1.0%,                       the Y group with La 2 0 3 23.32%, Ce 2 0 3 41.8%, Pr 2 0 3
Sn up to 10%, Pb up to 10.0% (averaging 3.4%), Th 0.1%                      4.9%, Nd 2 0 3 19.3%. The Y group (9.68%) includes Sm oxi-
and Zn 0.48%. In the deeper levels up to 2213 m the Pb,                     des (2.99%), Eu oxides (2.51%), Dy (0.82%), and Y
                                       R.D. Djenchuraeva el al. I Journal of Asian Earth Sciences 32 (2008) 280-299                        295
(4.43%). The average content of ZREE at the 2433- and                          Range, about 1 km southwest of the Aktiuz deposit, at
2343-m levels is 0.46% and 0.71%, respectively, whereas                        76°07E, 42°51N. The deposit was discovered in 1943 with
in the ore deposit the EREE average is 0.58%. Accompany-                       reserves calculated in 1951. Ore reserves have been calcu-
ing elements of economic significance are Ag, In, Cd and                       lated at 35 Mton grading 5% Pb, using a cut-off value of
U. Uranium is present as ferrithorite (2.0-3.5%) and mon-                      0.5%. The contour of lead distribution comprising the
azite (0.1%). Economic Be concentrations (0.12%) are                           "Pb orebody" (with Zn, Ag, Sn, Cu, Th credits) locally
found only in stockworks within the footwall rocks. In                         coincides with the contour of the "thorium orebody"
the hanging wall of the stock economic base metals, rare-                      (Th, Pb, EREE) (Table 7). The Kutessay II deposit is of
metal and thorium mineralization are hosted in biotite                         economic importance because of its large REE and base
hornfelses, strongly silicified rocks and brecciated schist                    metal endowment (Kim et al., 2000, 2001). The deposit is
up to the 2234-m level. Possible REE reserves comprises                        hosted by the high-grade metamorphic rocks of the Pre-
12 800 tons at REE 0.16%, with the yttrium group compris-                      cambrian uplifted basement, which comprise amphibole
ing 30-40%.                                                                    schists of the Kuperlisay Formation and gneisses of the
   Additional resources can be found in the tailings at the                    Aktiuz Formation. Both formations were intruded by
Aktiuz concentrating plant. During the period of 1942-                         granophyre, diabase and diorite porphyry stocks and
1953, the average grades of the tailings was 0.81% Pb,                         dykes. The Kutessay porphyry stock is characterized by
1.10% Zn, 0.22% Sn, and 0.01% Th. There are 734,000 tons                       complex morphology and is essentially an apophysis of
of waste giving a total metal content of 5945 tons of lead,                    the Kuperlisay massif of leucocratic granites. The stock
8074 tons of zinc, 1614 tons of tin and 7340 tons of                           has been traced to 300-400 m depth. The northern and
thorium.                                                                       western contacts have dips ranging from 45° to 70°. In
                                                                               the upper parts, dome-like structures, small stocks, and
2.2.2. The Kalesay beryllium deposit                                           apophysis are present (e.g. North Stock and Kutessay-I).
   The Kalesay Be deposit is located in the immediate                          At the surface, the stock is represented by altered grano-
vicinity of the Aktiuz deposit in epidote-albite-actinolite                    phyres and in the center by silexites bodies. In the lower
schist at the contact with gneisses (Figs. 3 and 9). Phenacite                 parts, brecciated schists are located above the small
and other rare metal mineralization is associated with thin                    dome-like ledges. They are in contact with the granophyres
(0.5-1.0 cm), but long (10s and even 100 m) fluorite-feld-                     apophysis, (Kutessay I), covering a total surface area of
spar veinlets concentrated in six linear NE-elongated stock-                   5200 m 2 sharply increasing with depth to 46,000 m2. The
works, without distinct geological boundaries. The                             granophyres are altered to quartz-sericite, quartz-seri-
dimensions of the ore-bearing stockworks are extremely                         cite-chlorite and quartz. The silexites are comminuted to
variable, extending 900 m along the strike and 250 m down                      brecciated, locally with angular quartz fragments and ran-
dip with a maximum thickness of 60 m. The veinlets consist                     domly oriented schistosity, cemented by granophyre, albi-
of orthoclase, albite, and fluorite. Cyrtolite (malacon) is the                tites, garnet-epidote material and quartz. Typical veinlet
most abundant ore mineral with additional bavenite, REE-                       and lens-like style mineralization contain galena, molybde-
carbonates (ambatoarinite), REE-fluorecarbonates (pari-                        nite, ferrithorite, cyrtolite, kuttesaite, pyrite, and hematite,
site, bastnasite), ferrithorite, and phenacite as the major                    Three ore stages can be distinguished: (1) Economic miner-
Be mineral present. Bavenite, scheelite, wolframite, and                       alization containing phosphate-carbonate-fluorine-car-
sulphide have been identified as minor phases.                                 bonate, REE as monazite and yttromonazite, carbonates,
                                                                               fluorine and REE carbonates; (2) complex silicate type
2.2.3. The Kutessay II REE-Th-Nb-Ta deposit                                    REE mineralization and rare-metals predominantly as fer-
   The Kutessay II REE deposit, is located in the Kemin                        rithorite and cyrtolite-malacon; (3) rare-metal-sulphide
area on the northern slope of the Tasa-Kemin mountain                          mineralization and quartz-carbonate-yttrofluorite. Stages
Table J
Metals rr>;- :-; -rJun REE and lead contours of the Kutessay ore deposit (Category - B + Ci + C 2 ) a
Total in c-re ar?ML-                                                              In the "Lead orebod)
Cot"                           _ge content (%)          Reserves (tons)           Component
ZTR-O-                 •.41                             88,022                    Pb                     2.58                    39000
ZrO                        1                            56,414                    Zn                     0.48                     9000
Th                        >                              6325                     Cu                     0.06                     1190
Hf                        <-                               395                    Mo                     0.04                      833
Pb                                                      78,500                    Ag                     8.76 T/T                   11.5
Zn                       —*                              9000                     XTR 2 0 3              0.52                     7640
Cu                                                        1100                    Zr02                   0.48                     6934
Mo                       •                                 833                    Th                     0.063                    1194
Sn                       IV                               1192                    Sn                     0.02                     1153
Ag                        ** •                              16.5
296   R.D. Djenchumeva el al. I Journal of Asian Earth Sciences 32 (2008) 280-299
R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299   297
298                            R.D. Djenchuraeva et at I Journal of Asian Earth Sciences 32 (2008) 280-299
of ore formation can also be divided according to the age             uneven in biotite hornfelses, ranging from 2.0% to 30.9%,
of tectonic movements that have created differently                   averaging 0.41% over the entire deposit,
oriented systems of ore controlling faults. Semi-circular                The ores are radioactive due to the widespread presence
and arcuate fault systems played an important role in the             of ferrithorite. Leucocratic granites and granophyres are
genesis of phosphate-carbonate-fluorine-carbonate ore.                therefore characterized by high levels of radioactivity,
East-west-trending fault systems predominate, preceding               making nuclear geophysical methods the most informative
the silicate type of REE mineralization, whereas base met-            and reliable of the geophysical exploration methods,
als mineralization is controlled by NE striking faults.                  During 1958-1991, a total of 5454 thousand tons of ore
   Orthoclase-biotite-chlorite and dominantly silica                  were extracted from 22,109 tons of REE at average ZREE
altered rocks are associated with the development of                  grade of 0.41%. About 120 minerals, including oxides of
REE, Zr, Th, rare metal and base metals mineralization.               the yttrium group, oxides of La, Nd, Ce dioxide, as well
Economic REE mineralization is associated with quartz-                as various REE metals and alloys were identified. In 1995
sericite-chlorite and quartz-sericite alteration, which               the deposit was abandoned. Measured and indicated ore
develop at depth into Zr-Th-REE mineralization. Base-                 reserves are estimated to total 16,763 tons, containing
metal mineralization is concentrated in the apical part of            44,300 tons of metals; whereas inferred reserves are esti-
the stock.                                                            mated as 3465 tons containing 7200 tons of ZREE grading
   Seventy-seven mineral species have been recognized in              0.22-0.27%. Possible reserves in deep levels (2093-2193 m)
the Kutessay deposit, including REE minerals, and miner-              are estimated as approximately 2400 tons of ZREE 2 0 3
als of Th, Zr, Pb, and Zn. These form economic ores                   (0.16%). The main features of the Aktiuz ore field are pro-
together with other rare metals (Sn, Mo, Nb, Ta, Be) of sec-          vided in Table 8.
ondary importance. The REE are widely distributed and are
a major component of ore bodies, ranging from 0.05% up to              3. Conclusions
19.0% SREE, with an average content of 0.41% (within the
0.52% Pb contour). In the #4 adit, there are massive pockets              The Aktiuz-Boordu Mining District has experienced a
of REE carbonates and fluorine-carbonates with EREE                   complex and multi-stage geodynamic evolution. The
contents up to 30^40% observed. The Th mineralization is              Archaean and Proterozoic crystalline Tien Shan basement
represented by ferrithorite and monazite, averaging                   was uplifted as a result of these geodynamic processes.
0.029% for the whole deposit and 0.063% within the Pb                 High-grade metamorphism, crustal melting and obduction
ore zone. Ferrithorite is a component of silicate REE min-            of oceanic lithosphere onto continental crust were part of
eralization and is notable for the high Th concentration              this geodynamic evolution. The Paleozoic lithotectonic
(46% Th0 2 ), U (3.5-5.8% U 3 0 8 ), and REE (1.82-3.74%              units were formed under various tectonic settings with the
REE 2 0 3 ), mainly as Y. Different forms of ferrithorite occur       formation of island arcs in the Cambrian-Middle Ordovi-
in veinlets according to the following mineral assemblages:           cian, continental collisions during the Late Ordovician-
quartz-monazite-ferrithorite, ferrithorite in biotite rims,           Silurian, active continental margins in the Early Ordovi-
feldspar-monazite-ferrithorite, quartz-ferrithorite, and              cian-Middle Carboniferous, and intraplate tectonics during
quartz-ferrithorite-magnetite-chalcopyrite. Disseminated              the Permian-Triassic. The highly evolved nature of intru-
ferrithorite is rare. Orthoclase-monazite, orthoclase-                sions and the structural peculiarities of this region have
quartz-monazite and quartz-monazite are typical of                    played an important role in the localization of the mineral
phosphate-carbonate-fluorine-carbonate          type; ortho-          systems, discussed in this paper. The majority of Au, base
clase-monazite-ferrithorite and quartz-monazite-ferrith-              metals, REE and rare-metal deposits are hosted by the crys-
orite are typical of silicate type. Zirconium is represented          talline Precambrian basement complex. The richest miner-
by cyrtolite, malacon and zircon as major components of               alization is typically associated with zones of repeated
the silicate type REE mineralization. The average Z r 0 2             deformation and complex multi-aged igneous intrusions
content in typical ores is 0.57% with high contents of Th             from the Precambrian to the Mesozoic. Geophysical and
(0.3-9.0%), U (0.2-0.4%), Y (1.0-4.0%) and Hf (2.0-                   geochemical surveys have demonstrated their usefulness in
5.0%). The principal mineral associations are quartz-chlo-            locating mineral systems that do not outcrop on the surface,
rite-fluorine-malacon, malacon, feldspar-malacon, and
quartz-cyrtolite. Cyrtolite and malacon contain significant            Acknowledgements
quartz and quartz-sericite-chlorite alteration is distributed
along sub-latitudinal zones that can be of economic interest.            Discussions with colleagues Apas Bakirov, Rena Mak-
Rare-metal mineralization (Nb, Ta, W, Sn, Mo, Be) is wide-            sumova, Kadyrbek Sakiev, Valentin Nikonorov, were of
spread, but does not attain economic grades. Nb and Ta are            considerable help while preparing this manuscript. Two
commonly locked in minerals such as rutile, ilmenorutile,             Journal of Asian Earth Sciences reviewers, Dmitry Konop-
ilmenite, zircon, cyrtolite and malacon. Tantalo-niobates             elko and Andrew Glikson, are acknowledged for their con-
including titanocolumbite, pyrochlore, columbite, and                 structive criticism and comments that were particularly
tantalite are of lesser importance, averaging 0.034%                  helpful in improving the manuscript. The final manuscript
N b 2 0 3 and 0.012% Ta 2 Q 5 . Lead content is extremely             benefited greatly from the invaluable help of Franco
       R.D. Djenchuraeva et al. I Journal of Asian Earth Sciences 32 (2008) 280-299   299