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Thermo Short Notes
Thermodynamics short notes
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Thermodynamics short notes
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CHEMICAL ENGINEERING GATE / PSU EXAM SHORT NOTES. GATE CHEMICAL - ENGINEERING All-IN-ONE 10 SUBJECTS Written by : Ajay Pratap Singh Sir SHORT NOTES www.chemgateacademy.com hemgate Academy @2021 All Rights Reserved | 8305260631 |CHEMICAL ENGINEERING GATE SYLLABUS SHORT NOTES. 1. Mass Transfer: Fick’s laws, molecular diffusion in fluids, mass transfer coefficients, film, penetration and surface renewal theories; momentum, heat and mass transfer analogies; stage-wise and continuous contacting and stage efficiencies; HTU & NTU concepts; design and operation of equipment for distillation, absorption, leaching, liquid-liquid extraction, drying, humidification, dehumidification and adsorption., membrane separations (micro-filtration, ultrafiltration, nano-filtration_and reverse osmosis), 2. Heat Transfer: Equation of energy, Steady and unsteady heat conduction, convection and radiation, thermal boundary layer and heat transfer coefficients, boiling, condensation and evaporation; types of heat exchangers and evaporators and their process calculations. Design of double pipe, shell and tube heat exchangers, and single and multiple effect evaporators. 3. Chemical Reaction Engineering: Theories of reaction rates; kinetics of homogeneous reactions, interpretation of kinetic data, single and multiple reactions in ideal reactors, kinetics of enzyme reactions (Michaelis-Menten and Monod models), non-ideal reactors; residence time distribution, single parameter model; non-isothermal reactors; kinetics of heterogeneous catalytic reactions; diffusion effects in catalysis; rate_and performance equations for catalyst deactivation 4, Instrumentation and Process Control: Measurement of process variables; sensors and_transducers, P&ID equipment symbols, process modeling and linearization, transfer functions and dynamic responses of various systems, systems with inverse response, process reaction curve, controller modes (P, PI, and PID); control valves; transducer dynamics, analysis of closed loop systems including stability, frequency response, controller tuning, cascade and feed forward control 5. Thermodynamics: First and Second laws of thermodynamics. Applications of first law to close and open systems, Second law and Entropy. Thermodynamic properties of pure substances: Equation of State and residual properties, properties of mixtures: partial molar properties, fugacity, excess properties and activity coefficients; phase equilibria: predicting VLE of systems; chemical reaction equilibrium Chemgate Academy @2021 All Rights Reserved | 8306260631 | Www.chemgateacademy.comCHEMICAL ENGINEERING GATE SYLLABUS SHORT NOTES. 6. Fluid Mechanics: Fluid statics, surface tension, Newtonian and non-Newtonian fluids, transport properties, shell-balances including differential form of Bemoulli equation and energy balance, equation of continuity, equation of motion, equation of mechanical energy, Macroscopic friction factors, dimensional analysis and similitude, flow through pipeline systems, velocity profiles, flow meters, pumps and compressors, elementary boundary layer theory, Turbulent flow: fluctuating velocity, universal velocity profile and pressure drop 7. Mechanical Operation: Particle size and shape, particle size distribution, size reduction and classification of solid particles; free and hindered settling; centrifuge and cyclones; thickening and classification, filtration, agitation and mixing: conveying of solids, flow past immersed bodies including packed and fluidized beds, 8. Plant Design and Economics: Principles of process economics and cost estimation including depreciation and total annualized cost, cost indices, rate of return, payback period, discounted cash flow, optimization in process design and sizing of chemical engineering equipments such as compressors, heat exchangers, multistage contactors. 9. Process Calculation: Steady and unsteady state mass and energy balances including multiphase, multi- component, reacting and non-reacting systems. Use of tie components; recycle, bypass and purge calculations, Gibb’s phase rule and degree of freedom analysis. 10. Chemical Technology: Inorganic chemical industries (sulfuric acid, phosphoric acid, chlor-alkali industry), fertilizers (Ammonia, Urea, SSP and TSP); natural products industries (Pulp and Paper, Sugar, Oil, and Fats); petroleum refining and _ petrochemicals; polymerization industries (polyethylene, polypropylene, PVC and polyester synthetic fibers). Chemgate Academy @2021 All Rights Reserved | 8306260631 | Www.chemgateacademy.comNECHADICAL_UPEKA LON PARTICLE MEASURED IN Coane Particle ————.~> Suds on mibimdir Fine Pale = ——~» Sewen Sige —> Altern Vary dine Rate, — ———> Mero + Namencon > Cyclone Sepaer Ul fine file. > W/m 4 ee Smet > Sei () Gps drach Bile [1 b- - Fox a. nen Sphotea Raide = A Fava. given volume sphere has the minimum possible surface area (Shoe, Py = Lauvalenr clamlis o: wowtnel. diam be Susec ana. om paviele Yp= Yelumo of one. parle Pavan di fe EQUIVALENT DIAMETER — ven) (CEB a oo Near tramps onlay Pe 44 as oc tna Clin cur dia 7 fo punve doep = (cated. Porimslon = Pe 1040p Fhghelie vai dis = 4p = Mote) + for Hank -bander = (setted Porimlir = KD, ne) De- De , her Cor F0>/o4 (RO, +102) fo pwsmne dup i FH P< Colum) x for anny crsluc wulivial gs ee 06 7-08® CRvening xoLrs (Smooth roll erwalur ) —> cm 7 Assumption > All jd pantie aren cingular Shope bead al & (odilion — Tees ac. Nant AEN rs 2 NS. Aallir, — > tong | * MO" Sie of product io approtimetl Ks eo ey on? diedim po | tosq - Rta L Rr] Aa ip = 20 | Bohs, R* Radios 4. Roe, Half of angi = of 4+ Pade, froauah aie a Y= Aadiun cf, Seed pantie Nowmabig ade (6 : + Age oe = Ange ip nl oy he ng 40 ect fs che pet Condack (sith a particle to be craked « > 4 oli nbuakable watoiat Jo pas Ancugh.dihesk damaging tha machine alr ou nok “Prue be ‘apt muaundad « Re uv Ppevity jose = Coabijugal foe yale [ox Wa] [vet 0 op en [a= em | i alee “ut ectegntt KAY qiikiol spud @-0), Cosal-1, Ne Ne ¥ INe= yale 1 Re sadn ol will Sats Theil ee 308 Ne» Qreepordent of panicle radivs # Critical speed ~ Ale mivimun arolwinnal spud of, wil. hich The conhia couition Santa. (Wo qpinding) is cule critical spud. oh Bodl mill . Opin Spc inp SOAS ele] Cai angle 135 4. BALL MILL — my ,Pracw | MuraicProwm | Ssctrnattowfs Lachoie | Yaschoe | Peston : i face L ; _ Prvcess Croeers Proven ee imbip |Py2= € Py = Const. ae na ° [se e Pyvi= Ba — tin wee 04% Copsdai) | (essay Pr (view evs [Tek hee on dun Gd oe Suto 04 ju GdT duro durGdt | du- @dr dus dT Wokdwe [up lhcb Phim Buln [Ne Figen) vases fy = PMCP ve We= Rvs Ln ii, ae " tar 19,70 1927 ie V8 -Gat |iGa Gat |, 92 ~ Ye ge 97 On Unt? : | f en, « (A -€e). a | A- tiv di AY en wee |l\ tun 2 gf v> — v v ae dy am | stove) [5-647 ree tytn FL VY | 3g, mH 1 Poluytanple dypenonte Ce) A= Canah | Sener ned neo s ens “+ Opn sp hy) oo 7 + LHe uiey) Cte opon sypstim) ar emak F ee 6 nA Crogy expation, Emogy in ~ Grogyod. —_ [etek nit pstmt} # Work dene - Chesed syste Page sate nf] Pee no ones Rawcoms “(oon snc (eek dow im opens = aby akon poor cor dow cman ay 8 SEM‘Yaw (hos tee) ne = re ig ee WZ i Ouwan mte te dh % bf in wo gan plane svsisanes te 4 paws. eat in the bout Le aime a> he. cove be at ! i “ar he intopee a2 i oe - Gabe dni ‘Sty pe Nw) Cate) Se lh 1 Sime cei Y= $C) Cop aon) oe 2 [n= ea | “Te erlewbte 240 subside Yuen im 04% Auation Doak gp prove. chive Joree ~ (4nd) * 4) how is vo liquid phase pasitivee a core in the bulk be same goth corePah te Wtaper = fla) Yast Pew) 40 caleulali Yne™ culoatdude ep = XAe a9 Atlin OW. igs plows. crivig foe. = (nsf Hew ) TAS = Squilibsiun cove conesgerding fo hulk phase Ceye™ fae = Syl Cane owpntng bulk Gaui phone one 2% Alvopion => colton 19 Yanai?) [era 2x7 Ab | Na 4 Ch $6) ed i Nao bo Cae VeF) | Boaid on ovale Na kUgi~ ta) J OPE Na = kx nb Mab) J Mte x! (Rao tM, “ le Heat Koay * So cn eqlbian ne tgp lve” Coin Hos a ofl) oo ke al otodal rasialowec yas arm Ligue phone = Oupais otaku cinerea ov > Broa > poisaver. dfoud 4 Siguil phane aye Ariane pueg Begin Pe Ye pat ge=NRe Ada 7 =e GCA Fay Ai” “rte testes ea + ff fo PPR» (owallsyekd) 2 oman gh wf it 8 le te CXR Sup dongiheh PER > cre oe fa ah fo com> eof venue oon ar? Gp) Ts... facta 1 Peo Peace acne cata a j g eal «) [FO Pra lar GO| NOE Ae onpursion of Caton! ie cman some fora est Ge (eel 2 PFR 4 Foe foe wet/ese at stu vi _jo.tre C5505 hy, (Cu Ge) T iS Yaa Se é 5+ doy (Cre Ge) oo SE Hy 6 Coman this OND. Shguldloe , aye U1, 1b07. CaMnsrdlon of, Armaan Ane ae Coy 28 Sopa Rival anrargenunt of rctatr = Crees + est) ina pojomanee ewe. Leash oy. ‘dy ME, Daler cog > FR DEIR ou ee, oe~ Rabin bebueon & ayo FC) [FOC] + RID fos ia scarfs pubs drgur—> os & E-Cunee for Qe sr Aor order eat of 7D — 4+ EO- Ze] ye ' rE ‘o Gore Jor Saal est, be wo) 7 F cone fov dual e214 = * GEE Cue tom of inion» [E@ =e] , [F@-i-e-8) fo bin com [rp TT] 2 kD e+ doa PER > or] _ pe ; b-o] BoP gees! 7 VaNiance ORD - _ * en for Saat Ruachaim sapien Cube nyt) alah 4 FER OAS ES 4 oe ® /\Tre8- 12 } Be 8 Afi} Le) a vo ke” mA. at *b Pe i rgomeli Csbaigit Dompare darn le) ox ond cpun to Cimon. arc der onto {b Conse Jo gage per. S => Gat maine negate gauge prnine [a= 34) > Gar rrunaune the pressure db qpncowr Pl ear a mo aagaront ql -huat i U-Shape Ow 210 fo abmuspre Vase. 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Pitch 4 Aainnay ’ we Wel ny — b> PH Mie te fn d= vat BRE » [9% A> Area subloack, Dane Ata 4 = (BE) (x) = Perimeter, Pa3a( (Bop) xc = Age +A oO at Sh ati-ATz-AT Conotatont a ay, Censor Hew ero He tap pote ify 53-46) & +t Fou liquid trial (Hy) Pr 21 (96) Sian, [Prana Fy 5) Te, Anwnal bnbsy logth an Pn ft = beat& Summag ds Pracems Bowel, fusion GG) ‘Amplitude Fatio(ae) Pha shift fish Ord, GD HEL, M17 Be ta Capu’) 2 Pe capacitive, Bs) = hye, Ak < hf, §=-% 3. Pare daad tive t= _ _ A jin oi, ate Mereteeycnaezahy » Beloe qe dr dw) 5 fit ede jw a> WE net > ba! Expt (AW) Grcmd ovr prers GO Yon rgcon ME caTtegye 0 GEE) Cf Conblles —5)= ke AR ke. go TPS conbuler GI hell fe) ake hefirigar go Saw Yow) b. po cerbalo. AED= ke (It GS) ARK fiFEpRE px taut * (to) bp cechean = HOES EH) MMe Ce Ya Bebo! (Gee) one ner fy] paey BY Emit at ett AN | cam faiey f-65 zl [ene] We Wt & po- Covtcos ah y 1 Cover yuo pe Ma ' ro, 5) >=H Conbiol value claraetoistic.— 4 | vate tom as ae Aic-to clase (Peal -opemvelua) Kicbopen Cfail close value) Gal 4 food Signal t Yo Aivaeh acting yale fede achva, vac + Covdidlin = © Lowe ching ceudvullor + Procows variable “ty Condhcllon ‘culpur & Ardler aeing cautrclir > Pygeero viable 4, Coninallen cutee L Rowse aeting ) F Nels = the valve and the conbrcllen alien coork tn oppwaibt. ftncton + Sy dueond vane chunwctaiais Sdeah yoke chovactoislion Hob dopond> ugar sonnlbiirg dep * Gunung Ga vale > BF i def a> he slope of cure Wy Kiva yale = dy ost, be Pe tote PEED | Ma wo | Vertn('e) Ya > G usc opiring Yoh + dyele fae vel he odin of Sha fin = Yoga. + + Reyeguniiy Aunicesn asic 4 vale 5 newline gy, BNE 1 fo roeFollisn Saduatig = Z toque Indy > § Commerc + ee ae eel > Anumriia. Gag) — “bs feonide . ba) Ny SEES 20H extumie Racin Ano-! 500 Pranab ith, Avalide or) 25meo. (150~250abm ) [ Keo OB Haber. Process - High bresause poe High egoae \ ge tr. Ba fom =F Chdalypt = Fe. duon oxide fo» se ole ¥ NH and for wang nea (1260 Ws) sPinmonia nba, ard hry F Raw moliniak > No rom Ai» Ho unm syrasia p> FY Heer Prceras : Modaote Caanuns (200-300 ab ) 4 i Proton Nowy high Prsasune (00 —o00 66") = Fromatea o crise > Oniden luniniuim“ipeoniuim. 01 Sulton ab 272 cone” ¥ Prmsonivon. Preaphale ~ Yn Atoding agqunk for cord apr ave coh. > URER > (INiyCONHg) * ~ ' > Contain 40-42% Neogene (x42), Yad a vihogn {otis > Aloo wad “to make We yrodideryde yal F Raw material - Amumonia — oom Arnie fam syns > ~Phoewas = veces tm ree we il ge a LS oy Hh C2 7 Soracquene ane# tr dy Carde- [Gch OW O ay ZH* Conbe (000) Y= Awe, [922 4054] i. a T oP, Bete oy "yg fy onjcannonte P #8 Ae function ox. os coal Py. 9 ane. une of : + dategrading pow Ge) — ir cr) aay cin 4 fold * he (ae) = 59 OF Ste + CA= 4, Bomaubii’s DE» CRuduale- +o linian. oak order: pe) 4, Bowoullif DE? a one Se P15] 9 ymrhy =e fur yhez (ny SZ 82 49.2= Avis hinear DE ob, oe qeo_ Ynrod ape we om) : on BY Me Comb Fie lye coat elation st TT mat Fas ~ Shavb cons of ely Sh fash hich. ahha _ Ye ConeJOIN CHEMGATE ACADEMY « ONLINE GATE COACHING « POSTAL CORRESPONDENCE COACHING «* ONLINE TEST SERIES Chemgate Academy @2021 All Rights Reserved
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