Analysis of Process Steam Demand BRASIL 2007 PDF
Analysis of Process Steam Demand BRASIL 2007 PDF
www.elsevier.com/locate/enconman
a
Faculdade de Engenharia Mecânica, Universidade Estadual de Campinas, Caixa Postal 6122, CEP 13083-970 Campinas-SP, Brazil
b
Departamento de Ingenierı́a Mecánica, Universidad de Zaragoza, C/ Maria de Luna, 3, 50018 Zaragoza, Spain
Abstract
The sugarcane industry represents one of the most important economic activities in Brazil, producing sugar and ethanol for the inter-
nal and external markets. Moreover, thermal and electric energy is produced for self-consumption, using sugarcane bagasse as fuel in
cogeneration plants. Almost all the sugarcane plants in Brazil are self-sufficient in terms of energy supply and in the last few years some
of them have been selling their surplus electricity for the grid. The reduction of process steam requirements and the use of more efficient
cogeneration systems are new alternatives to increase the surplus electricity generation. The purpose of this paper is to analyze the steam
demand reduction on sugar and ethanol process and alternatives for cogeneration systems in sugarcane plants, aiming at the surplus
electricity generation increase.
2007 Elsevier Ltd. All rights reserved.
0196-8904/$ - see front matter 2007 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2007.06.038
A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987 2979
allowing the increase of electricity generation by the including, maximum utilization of vapour bleeding, use
cogeneration system. Some works are found in the litera- of continuous sugar boiling pans, replacement of direct
ture indicating the best options for the process thermal drive steam turbines of mills by electric engines and
integration in sugar process. Many of them use the pinch increase of live steam parameters and boiler efficiency.
point method and apply an exergetic analysis of sugar fac- Little information is found in the literature about etha-
tories. Guallar [6] made an exergetic analysis of a beet nol and integrated sugar and ethanol process. Modesto
sugar process with thermal integration. Christodoulou et al. [15] made a exergetic cost analysis for sugarcane eth-
[7] proposed a thermal integration of a sugar beet factory anol process and identified that the cogeneration system
using pinch technology to evaluate the use of six or seven generate more than 50% of the total irreversibility gener-
effects of evaporation with falling film evaporator and ated in the plant, being followed by the juice extraction sys-
plate heat exchangers. Tekin and Bayramoglu [8] used tem with more than 30% of the total.
structural bond coefficients to evaluate the influence of The distillation system of ethanol process consumes a
some operating system parameters on the beet sugar fac- large amount of process steam for its heating requirements.
tory exergy loss. Increasing on steam power plant boiler Rein [13] and Seemann [16] show that thermal integration
efficiency and reduction of diffusion and exhausted steam of the columns with dual pressure distillation system can
temperature, were identified as important measures for be used to reduce steam demand. The dehydration step
exergy loss minimization. Bayrak et al. [9] performed an used to produce anhydrous ethanol, normally operates
energy and exergy analysis of a sugar beet plant in Tur- with azeotropic distillation with benzene or cyclohexane.
key, concluding that most of the irreversibility generation Dehydration with molecular sieves can be used to reduce
occurs on the juice extraction system. A thermal integra- considerably steam requirements of this step.
tion of the process is recommended as an important mea-
sure of irreversibility reduction.
Other studies are applied to sugarcane factories. Ram 4. Process simulation
and Banerjee [10] evaluated two evaporation systems
designs using exergy analysis. Paz and Cárdenas [11] stud- A sugar and ethanol plant that operates 4000 h and
ied improvements on sugarcane factories energy balance crushes 2,000,000 t of sugarcane during the harvest season
using exergy analysis. Thermal integration of the factory was simulated using the EES software [17]. Sugar and eth-
is proposed using vapour bleeding, juice heating with con- anol are produced, being half of the juice produced at the
densates, sugar boiling with vapour from the 2nd effect and extraction system used for sugar production and half for
introduction of falling film evaporators. Ensinas et al. [12] ethanol production. Molasses obtained as a by-product
present a thermoeconomic optimization procedure for the of the sugar process is used for ethanol production, being
design of evaporation systems and heaters network in cane mixed with the juice for ethanol in the mash preparation
sugar factories. Thermal integration of the process was step. The bagasse produced at the extraction system is used
obtained with minimum cost of operation and investments. as fuel at the cogeneration system.
Rein [13] shows some opportunities to reduce the pro-
cess steam demand to get the cane sugar factory into bal- 4.1. Base case
ance or to be able to generate a surplus of bagasse for
cogeneration or by-products opportunities. These are some A base case was simulated, representing the typical
options presented: sugar and ethanol process in Brazil. The plant is not ther-
mally integrated and all the heating requirements are
• Maximum evaporation in multiple effect evaporators, attended using exhausted steam from the cogeneration sys-
not in the pans, increasing the solid content of the syrup tem. Table 1 shows some parameters adopted for the sim-
as high as possible. ulation of the process and the cogeneration system. Some
• Increase the number of evaporator effect. of the process equipments are characterized below:
• Use of vapour 1, 2 or even 3 on the pan floor.
• Minimize the amount of water used in pans and • Extraction system with electrified mills.
centrifugals. • Juice heating at treatment system from 35.0 C to
• Use liquid/liquid heaters to do the first stage of heating 105.0 C.
of raw juice with condensate. This also serves the pur- • Evaporation systems with five effects. Juice entering at
pose of cooling down condensates for use as imbibition 97.0 C in the first effect and being concentrated from
on the mills. 13.4% to 65.0% of solid content.
• Use of vapours for juice heating. • Sugar boiling system with two-boiling scheme.
• Increase the bleed vapour temperatures to gain more • Fermented liquor heating from 30.0 C to 90.0 C.
from bleeding vapour. • Distillation scheme with stripping and rectifying col-
umns at atmospheric pressure.
Upadhiaya [14] presents some important measures to • Dehydration system composed by azeotropic distillation
increase electricity generation in cane sugar factories, with cycle-hexane.
A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987 2981
Table 2 Table 4
Exhausted steam consumption – base case Exhausted steam consumption – improved case
Stream Exhausted steam demanda (kg/s) Stream Exhausted steam demand (kg/s)a
Raw juice heating for sugar process 9.8 Raw juice heating for sugar process –
Raw juice heating for ethanol process 9.8 Raw juice heating for ethanol process –
Juice evaporation 16.3 Juice evaporation 23.7
Sugar boiling 10.5 Sugar boiling –
Sugar drying 0.1 Sugar drying 0.1
Fermented liquor heating 8.4 Fermented liquor heating –
Distillation 20.2 Distillation 14.8
a a
Saturated steam at 2.5 bar of pressure. Saturated at 2.5 bar of pressure.
2982 A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987
Table 5
Process steam demand
Steam demanda (kg steam/t cane)
Base case 540
Improved case 278
a
Saturated steam at 2.5 bar of pressure.
5. Cogeneration systems
Table 7
Parameters adopted for configurations III and IV
Parameter Value
a
Gas production (kg/kg dry bagasse) 2.3
Electricity consumption of bagasse dryer (kJ/kg of dry bagasse)b 35
Pressure ratio 11
Combustor outlet temperature (C) 1050
Gas turbine isentropic efficiency (%) 85
Gas compressor isentropic efficiency (%) 85
Air compressor isentropic efficiency (%) 85
HRSG pinch point temperature (C) 10
HRSG approach temperature (C) 5
a
Ref. [19].
b
Biomass is dried from 50% to 15% of moisture content [21].
Table 8
Clean gas composition adopted for configurations III and IV
Clean syngas element Fraction (% volume)
Air 0.5
CO 21.7
CO2 11.4
CH4 2.9
C2H4 1.0
H2 16.3
H2O 3.2
N2 43.0
Table 9
Parameters of live steam
Fig. 5. Sketch of configuration IV. Pressure (bar) Temperature (C)
L1 60 480
based on biomass gasification, producing the fuel for a L2 80 510
L3 100 540
gas turbine. Exhaust gases from the gas turbine are used
2984 A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987
6. Results Table 12
Electricity surplus for configuration II
6.1. Configuration I Surplus electricity production (kWh/t cane)
Base case Improved case
For the configuration I the following results presented in L1 65.8 90.1
Tables 10 and 11 were obtained. L2 71.7 95.9
As can be seen in Table 10, surplus bagasse between 4% L3 76.3 100.6
and 8% was calculated for the base case. Even increasing
live steam pressure and temperature, steam requirements
can be attended by available bagasse. New systems with the steam turbine, responsible for steam expansion from
higher live steam parameters can increase surplus electricity 2.5 bar to condensation pressure, produces around 2–4%
generation considerably, reaching 70 kWh/t of cane for the of the total power, requiring for that, new equipments as
highest live steam level as shown in Table 11. condensers and water cooling systems. Only for large units
For improved case, with lower process steam require- this condensing turbine can represent an important amount
ments, the steam produced by the cogeneration system is of power generation.
limited by the process demand and as a consequence, the
surplus electricity decreases. A second consequence is that 6.3. Configuration III
the bagasse surplus reaches more than 50% of the total
bagasse produced. In this case the large quantity of surplus In this configuration 420 kg steam/t cane can be pro-
bagasse may be used to provide steam for other by-prod- duced, being not able to attend base case steam demand.
ucts process or as feedstock for other activities. It could Around 29% of additional bagasse would be available to
be used, for example, for animal feed or as raw material produce process steam requirements of the base case.
for pulp and paper and boards production [13]. Other For the improved case, 34% of bagasse surplus is gener-
by-products could be also produced with bagasse as etha- ated, producing 67.0 kWh/t cane in the gas turbine. If all
nol and chemicals, but is not yet a reality on large-scale the bagasse were consumed, the surplus of electricity gener-
usage. ation could reach 114.9 kWh/t of cane, only 14% more
than configuration II with live steam level L3. Thus, config-
6.2. Configuration II uration III seems to be not feasible for electricity genera-
tion when compared with configuration II, which is a
In this configuration all the available bagasse is con- commercial technology.
sumed by the cogeneration system. The steam demand
reduction obtained in the improved case can increase more
6.4. Configuration IV
than 30% the surplus electricity generation when compared
with base case (Table 12). Moreover, this configuration
The possible steam production that could be obtained
permits the electricity generation on crushing and non-
using available bagasse in configuration IV is presented
crushing season.
in Table 13. As it can be seen, the possible steam produc-
For the base case, configuration II showed to be not
tion is around than 332 kg steam/t cane for live steam pres-
interesting, since the power produced by the last stage of
sure L1 and 302 kg steam/t cane for L3. This configuration,
as the previous one, can not provide the steam require-
ments for the base case, due to limitations of steam gener-
Table 10
Bagasse surplus for configuration I ation found in power cycles with biomass gasification. To
attend the base case steam demand, more than 60% of
Bagasse surplus (%)
additional bagasse would be necessary for the live steam
Base case Improved case
level L1 and almost 80% for L3.
L1 7.7 52.5 On the other hand, for the improved case, the steam
L2 5.8 51.5
requirements can be attended with this configuration, pro-
L3 4.2 50.7
ducing more than 170 kWh/t cane of surplus electricity as
shown on Table 14. This configuration showed to be able
Table 11
Electricity surplus for configuration I
Table 13
Surplus electricity production (kWh/t cane) Possible steam production with available bagasse for configuration IV
Base case Improved case Steam production (kg steam/t cane)
L1 54.7 14.2 L1 332
L2 62.9 18.5 L2 316
L3 69.8 22.0 L3 302
A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987 2985
Table 14 Table 16
Surplus electricity production for improved case with configuration IV Performance parameters for improved case
Surplus electricity production (kWh/t cane) Configurations I II III IV
Improved case EUF (LHV – %) L1 84.28 52.98 75.37 69.76
L2 84.22 54.07 75.37 69.91
L1 171.2
L2 172.0 L3 84.17 54.96 75.37 69.96
PHR L1 0.25 0.75 0.56 1.19
L3 172.2
L2 0.28 0.79 0.56 1.19
L3 0.30 0.82 0.56 1.19
gex(%) L1 26.01 23.10 29.93 34.86
to produce between 70% and 90% more surplus electricity L2 26.73 23.93 29.93 34.97
than configuration II, which also consumes all the available L3 27.32 24.60 29.93 35.01
bagasse. It is known that power cycle based on biomass
gasification is in a different stage of development than
steam based power cycle but when it reaches a commercial • Energy fuel utilization
scale the possibility of surplus electricity generation in
W e þ Qu
sugar and ethanol plants would be widely greater than with EFU ¼ ð1Þ
steam cycles. Ef
Other complementary fuels could be used to increase where We is the net electricity power output, Qu is the use-
energy input necessary for this configuration, being cane ful heat rate delivered to the process and Ef is the fuel en-
trash one of the most interesting ones for sugarcane plants. ergy consumed. The net electricity power (We) considers
This residue is usually burnt at the harvest field, but with the electricity generated by the steam and gas turbines, dis-
the reduction of this practice in the coming years, part of counting the electricity consumed by pumps, compressors
it could be recovered and used as fuel at the cogeneration and dryers where applicable. Ef considers the energy con-
system. Macedo et al. [3] estimates that a quantity of tent of the consumed fuel.
125 kg trash/t cane could be collected and used for electric-
ity generation. • Power-to-heat ratio
The natural gas is another option too, since it could be
We
used for co-firing at the gas turbine together with the syn- PHR ¼ ð2Þ
Qu
gas [23].
• Exergetic efficiency
6.5. Performance parameters assessment
W e þ Bq
Many performance parameters for cogeneration systems gex ¼ ð3Þ
Bf
are found in the literature but not all of them are consid-
ered relevant to a combined heat and power plant like where Bq is the exergy of useful heat delivered to the pro-
cogeneration systems of sugarcane plants, providing heat cess and Bf is the exergy of the consumed fuel. Exergies
for the process and surplus electricity to be sold to the grid. of vapour and gases streams were calculated following
Some of performance parameters presented by Horlock standard procedures [26]. The bagasse exergy was evalu-
[24] and Huang [25] have been calculated for the different ated based on Sosa-Arnao and Nebra [27] procedure.
configuration analyzed in this paper (Eqs. (1)–(3)). Tables The energy utilization factor (EUF) considers the useful
15 and 16 show the values calculated for base and heat (Qu) and the net electricity produced by the plant (We)
improved cases, respectively. as products with equal weights. This criteria is considered
not satisfactory to compare the different configurations,
once electricity is difficult to produce and more valuable
than useful heat [24]. Power heat ratio and exergetic effi-
Table 15 ciency are considered more useful to compare cogeneration
Performance parameters for base case systems [24,25].
Configurations I II For the base case configuration I showed to be more
EUF (LHV – %) L1 84.28 77.11 interesting for surplus electricity generation. It can con-
L2 84.22 78.22 sume great part of the bagasse produced by the process
L3 84.17 79.10 and generates almost the same electricity than configura-
PHR L1 0.25 0.25 tion II, with similar exergetic efficiency.
L2 0.28 0.28 Configuration III showed to be not interesting even for
L3 0.30 0.30 improved case. Its PHR indicates the deficiency of this con-
gex (%) L1 26.01 25.35 figuration to produce electricity, being respectively 46%
L2 26.73 26.17 and 213% lower than configuration II and IV for live steam
L3 27.32 26.85
level L3.
2986 A.V. Ensinas et al. / Energy Conversion and Management 48 (2007) 2978–2987
The adoption of configuration IV together with the pro- and managers for available process data and FAPESP,
cess steam demand reduction of improved case show the CAPES and CNPq for the financial support to do this
advantage of combined cycle. This configuration presents study.
the highest exergetic efficiency and PHR when compared
with other configurations.
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