09112023 Assignment # 01 Ranker’s Batch
ORGANIC CHEMISTRY
(Topic : Salt Analysis & Practicle Organic Chemistry)
(for JEE-Mains & Advanced 2024)
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01. A solution of a salt on treatment with NH4SCN gives red coloured compound and on
treatment with a solution of K4Fe(CN)6 develops blue colouration. The red and blue
colours respectively are :
(a) Ni(SCN)2 and Ni2[Fe(CN)6] *(b) Fe(SCN)3 and Fe4[Fe(CN)6]3
(c) Co(SCN)2 and Co2[Fe(CN)6] (d) Fe(SCN)2 and Fe2[Fe(CN)6]
02. Manganese salt + PbO2 + conc. HNO3 The solution acquires purple colour. The colour
is due to :
*(a) HMnO4 (b) a lead salt (c) Mn(NO3)2 (d) H2MnO4
03. The group reagent for the V group radicals is :
*(a) (NH 4)2CO3 (b) (NH4) 2SO 4 (c) NH4Cl (d) (NH4) 2C2O 4
04. The sulphides of which one of the following groups of elements are soluble in yellow
ammonium sulphide :
*(a) As , Sb and Sn (b) As , Cd and Sn (c) Cd , Cu and Bi (d) Hg , Cu and Cd
05. Which of the following is incorrectly matched ?
(a) Fe4[Fe(CN)6]3 – blue *(b) K2Fe[Fe(CN)6] – red
(c) Cu2[Fe(CN)6] – chocolate brown (d) Fe3[Fe(CN)6]2 – blue
06. The only cations present in a slightly acidic solution are Fe3+ , Zn2+ and Cu2+. The re-
agent which when added in excess to this solution would identify and separate Fe3+ in
one step is :
(a) 2 M HCl *(b) 6 M NH3 (c) 6 M NaOH (d) H2S gas
07. Concentrated aq. sodium hydroxide can separate a mixture of :
(a) Al3+ and Sn2+ *(b) Al3+ and Fe3+ (c) Al3+ and Zn2+ (d) Zn2+ and Pb2+
08. Which of the following gives a ppt. with Pb(NO3)2 but not with Ba(NO3)2 ?
(a) Na2HPO4 *(b) NaCl (c) Na 2SO 4 (d) Na2CrO4
09. Identify the correct order of solubility of Na2S, CuS and ZnS in aqueous medium :
(a) CuS > ZnS > Na2S (b) ZnS > Na2S > CuS
(c) Na2S > CuS > ZnS *(d) Na2S > ZnS > CuS
10. When H2S gas is passed through the HCl containing aqueous solution of CuCl2 , HgCl2 ,
BiCl3 and CoCl2 , it does not precipitate out :
(a) CuS (b) HgS (c) Bi2S3 *(d) CoS
11. A red solid insoluble in water. However, it becomes soluble, if some KI is added to
water. Heating the red solid in a test tube, results in liberation of some violet coloured
fumes and droplets of a metal appear on cooler part of the test tube. The red solid is :
(a) Pb3O4 *(b) HgI2 (c) HgO (d) (NH 4) 2Cr 2O 7
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12. When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white
precipitate is produced. The metal is identified as :
*(a) Zn (b) Fe (c) Pb (d) Hg
13. A solution when diluted with water and boiled, gives a white precipitate. On addition
of excess of NH4Cl/NH4OH, the volume of precipitate decreases leaving behind a
white gelatinous precipitate. Identify the precipitate which dissolves in NH4OH /
NH4Cl :
*(a) Zn(OH)2 (b) Al(OH)3 (c) Mg(OH)2 (d) Ca(OH)2
14. When H2S gas is passed through the HCl containing aq. solution of CuCl2 , SnCl2 ,
BiCl3 and NiCl2 , it does not precipitate out :
(a) CuS (b) SnS (c) Bi2S3 *(d) NiS
15. A metal salt solution forms a yellow ppt. with sodium chromate solution and a white
ppt. with sodium sulphate solution. However, it gives no ppt. with sodium chloride or
iodide solution. The metal salt is :
(a) Pb(NO3)2 *(b) Ba(NO3)2 (c) AgNO3 (d) Cu(NO3)2
16. A certain light geen salt gives ammonia on heating with NaOH solution. Its aqueous
solution gives white ppt. with barium chloride solution. Aqueous solution also shows
the presence of Fe(II) ion. The salt likely to be :
(a) ferrous sulphate *(b) Mohr’s salt (c) ferric alum (d) potash alum
17. Which one of the following set of elements can be detected using sodium fusion ex-
tract ?
*(a) Sulfur, Nitrogen, Phosphorous, Halogens
(b) Phosphorous, Oxygen, Nitrogen, Halogens
(c) Nitrogen, Phosphorous, Carbon, Sulfur
(d) Halogens, Nitrogen, Oxygen, Sulfur
18. To an aqueous solution containing ions such as Al3+, Zn2+, Ca2+, Fe3+, Ni2+, Ba2+ and
Cu2+ was added conc. HCl, followed by H2S. The total number of cations precipitated
during this reaction is/are :
*(a) 1 (b) 3 (c) 4 (d) 2
19. Reagent, 1-naphthylamine and sulphanilic acid in acetic acid is used for the detec-
tion of
(a) N2O (b) NO3– (c) NO *(d) NO2–
20. Which of the following compound is added to the sodium extract before addition of
silver nitrate for testing of halogens ?
(a) Hydrochloric acid (b) Sodium hydroxide (c) Ammonia *(d) Nitric acid
21. An organic compound ‘A’ is oxidized with Na2O2 followed by boiling with HNO3. The
resultant solution is then treated with ammonium molybdate to yield a yellow pre-
cipitate. Based on above observation, the element present in the given compound is:
(a) Nitrogen *(b) Phosphorus (c) Fluorine (d) Sulphur
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22. Copper wire test for halogens is known as :
(a) Duma’s Test *(b) Beilstein’s Test (c) Liebig’s Test (d) Lassigne’s Test
23. Beilstein’s test is used for the estimation of which one of the following elements ?
(a) S *(b) Cl (c) C and H (d) N
24. Lassaigne's test for the detection of nitrogen will fail in the case of:
(a) NH2CONH2 (b) NH2CONHNH2 . HCl
*(c) NH2NH2 . HCl (d) C6H5NHNH2 .2HCl
25. The function of boiling the sodium extract with conc. HNO3 before testing for halo-
gen is :
(a) to make the solution acidic (b) to make the solution clear
(c) to convert Fe2+ to Fe3+ *(d) to destroy CN– and S2– ions
26. Sodium nitroprusside when added to an alkaline solution of sulphide ions produces a
colouration :
(a) red (b) blue (c) brown *(d) purple
27. Positive Beilstein test shows that :
(a) halogens are surely present (b) halogens are absent
*(c) halogens may be present (d) none of the above
28. While titration of dilute HCl solution with aqueous NaOH, which of the following will
not be required ?
(a) Clamp and phenolphthalein (b) Burette and porcelain tile
*(c) Bunsen burner and measuring cylinder (d) Pipette and distilled water
29. To an aqueous solution containing ions such as Al3+, Zn2+,Ca2+, Fe3+, Ni2+, Ba2+ , Sr2+
, Bi3+ , Cd2+ , Co2+ ,Cu2+ was added conc. HCl followed by H2S.
The total number of cations precipitated during this reaction is/are :
(a) 2 *(b) 3 (c) 1 (d) 4
30. Match List-I with List-II :
List-I (Metal Ion) List-II (Group in Qualitative analysis)
(A) Mn2+ (i) Group-III
(B) As3+ (ii) Group-II A
(C) Cu2+ (iii) Group-IV
(D) Al3+ (iv) Group-II B
Choose the most appropriate answer from the options given below :
(a) (A)-(i), (B)-(iv), (C)-(ii), (D)-(iii)
*(b) (A)-(iii), (B)-(iv), (C)-(ii), (D)-(i)
(c) (A)-(iv), (B)-(ii), (C)-(iii), (D)-(i)
(d) (A)-(i), (B)-(ii), (C)-(iii), (D)-(iv)
31. In the flame test of a mixture of salts, a green flame with blue centre was observed.
Which one of the following cations may be present ?
*(a) Cu2+ (b) Sr2+ (c) Ba2+ (d) Ca2+
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32. List I [Elements] List II [Colour imparted to the flame]
A. K I. Brick Red
B. Ca II. Violet
C. Sr III. Apple Green
D. Ba IV. Crimson Red
Choose the correct answer from the options given below :
(a) A-II, B-IV, C-I, D-III (b) A-IV, B-III, C-11, D-I
(c) A-II, B-I, C-III, D-IV *(d) A-II, B-I, C-IV, D-III
33. When a solution of mixture having two inorganic salts was treated with freshly pre-
pared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on
treatment with neutral FeCl3, it gave deep red colour which disppeared on boiling
and a brown red ppt was formed. The mixture contains :
(a) SO32– and CH3COO– *(b) CH3COO– and NO3–
(c) C2O42– and NO3– (d) SO32– and C2O42–
34. List I (Complex) List II (Colour)
A. Mg(NH4)PO4 I. brown
B. K3[Co(N02)6] II. white
C. MnO(OH)2 III. yellow
D. Fe4[Fe(CN)6] 3 IV. blue
Choose the correct answer from the options given below :
(a) A-III, B-IV; C-II, D-1 (b) A-II, B-IV, C-I, D-III
(c) A-II, B-III, C-IV, D-1 *(d) A-II, B-III, C-1, D-IV
35. An inorganic Compound 'X' on treatment with concentrated H2SO4 produces brown
fumes and gives dark brown ring with FeSO4 in presence of concentrated H2SO4.
Also Compound 'X' gives precipitate 'Y', when its solution in dilute HCl is treated
with H2S gas. The precipitate 'Y' on treatement with concentrated HNO3 followed by
excess of NH4OH further gives deep blue coloured solution, Compound 'X' is :
(a) Pb(NO3)2 (b) Pb(NO2)2 *(c) Cu(NO3)2 (d) Co(NO3)2
36. Which one of the following when dissolved in water gives coloured solution in nitro-
gen atmosphere ?
(a) Cu2Cl 2 (b) ZnCl2 *(c) CuCl2 (d) AgCl
37. List-I (Anion) List-II (Gas evolved on reaction with dil.H2SO4)
(A) CO3 2–
(I) Colourless gas which turns lead acetate
paper black
(B) S 2–
(II) Colourless gas which turns acidified
potassium dichromate solution green
(C) SO 3 2–
(III) Brown fumes which turns acidified KI
solution containing starch blue
(D) NO2 –
(IV) Colourless gas evolved with brisk efferves
cence, which turns lime water milky
Choose the correct answer from the options given below.
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(a) (A)-(III), (B)-(I), (C)-(II), (D)-(IV) (b) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
(c) (A)-(IV), (B)-(I), (C)-(III), (D)-(II) *(d) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
38. A white precipitate was formed when BaCl2 was added to water extract of an inor-
ganic salt. Further, a gas 'X' with characteristic odour was released when the formed
white precipitate was dissolved in dilute HCl. The anion present in the inorganic salt
is :
(a) I– *(b) SO32– (c) S2– (d) NO2–
39. List-I [Cations] List-II [Group reagents]
A Pb , Cu
2+ 2+
(i) H2S gas in presence of dilute HCl
B Al3+, Fe3+ (ii) (NH4)2CO3 in presence of NH4OH
C Co , Ni
2+ 2+
(iii) NH4OH in presence of NH4Cl
D Ba2+, Ca2+ (iv) H2S in presence of NH4OH
(a) A iv, B ii, C iii, D i (b) A i, B iii, C ii, D iv
(c) A iii, B i, C iv, D ii *(d) A i, B iii, C iv, D ii
40. Which element is not present in Nessler's reagent ?
(a) Iodine *(b) Oxygen (c) Mercury (d) Potassium
41. Formation of which complex, among the following, is not a confirmatory test of Pb2+
ions ?
*(a) Lead nitrate (b) Lead chromate (c) Lead iodide (d) Lead sulphate
42. Element not present in Nessler’s reagent is :
(a) Hg , K *(b) N , O (c) I , K (d) Hg , I
43. In the given chemical reaction, colors of the Fe2+ and Fe3+ ions, are respectively :
5Fe2+ + MnO4 + 8H+ Mn2+ + 4H2O + 5Fe3+
(a) Yellow, Green (b) Yellow, Orange (c) Green, Orange *(d) Green, Yellow
44. In base vs. Acid titration, at the end point methyl orange is present as :
*(a) quinonoid form (b) heterocyclic form (c) phenolic form (d) benzenoid form
45. Assertion A : Phenolphthalein is a pH dependent indicator, remains colourless in acidic
solution and gives pink colour in basic medium.
Reason R: Phenolphthalein is a weak acid. It doesn't dissociate in basic medium.
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is NOT the correct explanation of A.
*(c) A is true but R is false (d) A is false but R is true
46. A compound 'X' is a weak acid and it exhibits colour change at pH close to the equiva-
lence point during neutralization of NaOH with CH3COOH. Compound 'X' exists in
ionized form in basic medium. The compound 'X' is :
(a) methyl orange (b) methyl red
*(c) phenolphthalein (d) eriochrome Black
47. 25 mL of silver nitrate solution (1 M) is added dropwise to 25 mL of potassium iodide
(1 M) solution. The ion(s) present in very small quantity in the solution is/are :
*(a) Ag+ and I– both (b) K+ only (c) NO3– only (d) I– only
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