Steel Manufacturing Processes Guide
Steel Manufacturing Processes Guide
STEEL PROCESSES
STEEL MANUFACTURING, TESTING AND PRODUCTS
WHAT IS A METAL/STEEL?
Metal: An element whose electrons* aren’t bound to particular
atoms and have a partially filled valence band.
Valance Band
Diagram
of an Atom
Orbital Electrons (filled ‘rings’)
*’Free electrons in outer ring (valance) are free to move throughout metal – that’s why metals conduct heat, electricity.
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WHAT IS MICROSTRUCTURE?
Microstructure – The fine structure of materials (in a metal or other
material), such as, type, size and arrangement of grains that determine
material properties, which can be made visible at 100x+ magnification and
examined with a microscope. Microstructure can help
Types of Microstructure predict the behavior and/or
failure in certain conditions of
a component made of a
Ferrite: BCC - Iron (Fe) (low solubility for Carbon). particular material.
Cementite: Iron Carbide (Fe3C).
Pearlite: Two phase microstructure composed of
Ferrite and Cementite forms at 1000F-1341F
(one goal of annealing, the cementite
spheroidizes).
Austenite: Present at temperatures above 1414F;
high solubility of carbon (100x greater than
ferrite).
Martensite: Formed when austenitic steel is rapidly
cooled preventing diffusion of carbon (like a
supersaturated solution).
Bainite: Consists of Ferrite and Cementite forms at
lower temp than pearlite (420-1000F).
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INTEGRATED STEELMAKING – PROCESS FLOW
Hot Strip
Mill
YouTube video
Steel from Start to Finish: https://www.youtube.com/watch?v=9l7JqonyoKA
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INTEGRATED STEELMAKING
Diagram of a Blast Furnace
Iron Ore (pelletized)
Heated Air
Supersonic heated air used to react
with coke, travels @ ~450-650 mph,
1700-2400°F 5
INTEGRATED STEELMAKING
Steelmaking – BOF & LMF
*** Si killed steels today generally would only be required for some case-hardened, electrical or carburized applications.
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INTEGRATED STEELMAKING
Steelmaking - Degassing
Process of removing carbon from liquid steel to produce ultra-low carbon steel with
improved ductility. Removal of O2, H2 and N2 gases from liquid steel is also necessary
since these gases harm the properties of steel.
R-H Degasser
Steel Products
• Flat Products
o Plate
o Hot Rolled Sheet
o Coated Sheet
o Cold Rolled Sheet
o Cold Rolled Strip
Tundish
Weirs and dams
Bigger is better
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INTEGRATED STEELMAKING
Continuous Casting
The Mold
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INTEGRATED STEELMAKING
Integrated production of Hot Bands
Reheats Removes Rolling mill for
Hot Strip Mill
steel black converting
stock oxide from steel
bars surface of ingots into
before iron or blooms,
being steel at billets, or slabs
rolled high
temps
Serves
to crop Surface
the texture/finish
transfer of iron or
bar at its steel, usually
head rough and
and tail lacks lustre
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INTEGRATED STEELMAKING
Integrated Production of Hot Bands
• Purpose: Take slab from cast slab dimensions to prepare for
finishing mills.
• Establishes crown and coil width.
• Generally the slab is twice the finished thickness.
• Austenite grains are deformed and re-crystalized with each
rolling pass.
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INTEGRATED STEELMAKING
Finishing Mills
• Finishing mill temps
o Steel enters at 1950-1550F
o Steel exits at 1750-1550F
• Temperature selected depends upon properties desired.
• Determines shape and gauge.
• Generally takes 6-7 mill stands to reduce to final gauge.
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INTEGRATED STEELMAKING
The Coilers
• High temps produce coarse
grains (1250-1300F).
• Low temps produce smaller
grains (1100-1200F).
• Lower temps produce flat grains
(950-1050F).
• It depends upon the properties
you want.
• The smaller the grain the harder
the material.
• The larger the grain the softer
the material.
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MINIMILL PRODUCTION OF HOT BANDS
Process Flow: Thin Slab Molds – Thinnest (~2”)
Bulge in top of mold allows room for the SEN
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INTEGRATED VS. MINI-MILLS
Cast Height – Higher cast Slab Thickness – Thicker slab allows
height allows more time for more time for solidification/NMI’s to
NMI’s to diffuse to top of mold float to top
Integrated mill Integrated Slab x-section
Mini-mill
NMI flow
Mini Mill Slab x-section
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COMMON SOURCES OF LAMINATION
Steelmaking
• Oxygen reacts with elements forming oxides which aren’t
“trapped” by the slag
• Improper taping of ladle
Continuous Casting
• Liquid steel comes in contact with oxygen
• Improper mold practices
• Poor flux / casting practices Analysis of inclusion:
• Ladle Slag, Tundish Flux, Mold
Hot Strip Mill powder NMI’s all have fairly
distinct compositions
• Rolled over scratches • HSM related NMI’s usually form
• Rolled in scale of iron oxide
• Poor side guide practices
• Frictional pickup during coiling of steel
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PICKLING: WHAT IS IT
Dryers
Acid Tanks
Contain Hydrochloric Acid at an elevated temperature
Pickling is a metal surface
Rinse Tanks treatment used to remove
Deionized water spray to remove acid from strip surface impurities, such as stains,
inorganic contaminants, rust or
Dryer scale from ferrous metals.
Dry the strip to remove any chance of rust forming
Oiling
Oil is applied to top surface at down coiler on exit end of line and wrap to wrap transfer coats
bottom surface
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PICKLING
Acid Pickling
• Remove surface scale on hot rolled coils prior to cold rolling or further processing
• Hot rolled coils are processed through an acid bath to produce a pickled (oiled)
product free of surface scale and rust
Eco Pickling
• EPS = Eco Pickled Surface
• Mechanical vs Acid Scale Removal (environmentally friendly)
• Blasts surface of the black band with a slurry of steel grit and water
Continuous Pickling
• Coils are welded or “stitched” together
• Accumulating towers allow for constant line speed though pickling section (800-1200
ft/min line speed)
• Scheduling is limited by width, gauge and alloy
Push-Pull Pickling
• Coil is fed or “pushed” through line until received into take-up (recoil) reel then
“pulled” through
• Slower line speed of 200-400 ft/min, but greater flexibility in scheduling and grades of
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steel that can be processed
COMMON APPEARANCE AND CAUSES OF STAINING
Appearance
• Light to dark brown - most often line stop related
Causes
• Line stops
• Rinse temperature
• Spray pressure
• Excessive turbulence in the rinse bath
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THE DIFFERENCE BETWEEN RUST AND STAIN
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COLD ROLLING
Rolling metal at a temperature below the softening point of the metal
to create strain hardening (work-hardening).
Why
• Produce gauges that are lighter than hot rolled steel
• Improve thickness tolerance
• Improve surface
• Improve shape
• Obtain a wide range of metallurgical properties
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COLD ROLLING
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TYPES OF COLD MILL ROLL CONFIGURATIONS
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ANNEALING
Full hard cold rolled steel is annealed by heating to a specified temperature,
holding for a specified length of time, and cooling.
Benefits of hydrogen:
Typical annealing temperatures are 1100 F to 1400 F. • Higher heat diffusivity
Steel is annealed in atmospheres that protect the steel • More uniform properties
• Cleaner surface / less smut
from oxygen. • No nitrogen pickup at surface
Annealing softens the full hard cold reduced steel to produce improved
mechanical properties.
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ANNEALING
Annealing Metallurgy
Recovery>Recrystallization>Grain Growth
Recrystallization
• New crystals form and consume
the old grains
• Function of time and temperature
• Large change in mechanical
properties
Grain Growth
• Large grains consume small
grains
• Moderate change in mechanical
properties
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TEMPER ROLLING
Light cold reduction after annealing
Why?
• If formed without temper rolling, steel will experience localized
bending called discontinuous yielding (Luder lines).
• To prevent this, the steel is rolled introducing many small locations
(dislocations) for steel to start yielding from, so any forming or
drawing done on steel produces a smooth surface, free from luder
lines.
Also…
• Set final mechanical properties
• Impart final surface finish
• Improve flatness
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TEMPER MILL
• Improves shape Luder Line Prevention
• Better surface
• Gauge correction
• Eliminates Luder lines
• Minimizes chance of
coil breaks during
further processing
COIL BREAKS - CR
• Reduces effect of
camber during slitting
COIL BREAKS - HR
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TENSION/ROLLER LEVELING
Shape defects that leveling can correct:
CANNOT CORRECT
Barrier Protection
• All coatings protect the base metal by providing a shield from the
environment.
Galvanic Protection
• Coatings that offer cathodic protection to the steel substrate; also
known as galvanic or sacrificial protection.
• Prevent corrosion even if base metal is exposed.
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COATED PRODUCTS – CATHODIC PROTECTION
Anode
Cathode
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COATED PRODUCTS - GALVANNEAL
Galvanized
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COATED PRODUCTS – GALVANIZED SURFACE FINSHES
Spangle
• Crystalline appearance on surface
• Obtained by adding lead or antimony to the
zinc bath
• Undesirable for painted applications
• WS Delta and Spartan produce a “spangle
free” product
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COATED PRODUCTS – GALVANIZED SURFACE TREATMENT
Coating weight: amount of zinc coating applied to a product for a given surface area.
Prevents “White Rust” - zinc oxide may form from moisture intrusion or condensation
during shipment or storage.
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SLITTING / BLANKING
Slitting
• Master coils are cut (slit) to various
widths by means of passing material
through a tooling set-up called an
arbor. The arbor sets the width of the
material with precision hard-tooling
spacers.
• Rubber stripper rings keep the strip
flat and level.
• The material is “cut” with high
carbon alloy slitting knives which are
off-set between the top and bottom
arbors.
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SLITTING / BLANKING
Anatomy of a Slit Edge
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SLITTING / BLANKING
Edge Types
Illustrations are examples only; actual edge profiles may vary from illustrations.
No. 4 Edge
No. 1 Edge (round)
(round) Rounded corners – may be flat
Radius approximately with slitting fracture visible
equal to ½ thickness across the edge
No. 6 Edge
(square)
Radial corners – may have
slitting fracture visible across
the edge
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THE STEEL TREE – PLAIN CARBON AND HSLA
Steel
Alloy Steels
Low carbon – Offered as basic grade or as HSLA – Structural members where weight is
structural grade. a consideration
Medium carbon – Offered as basic grade or UHSS – Safety members in cars
structural grade Dual Phase (DP) – Applied in areas which
High carbon – Offered as basic grade require higher forming for required TS,
Specifications – Can be to recognized crumple zones.
standard or customer specific. Specifications – Can be to recognized
Part forming/customer expected properties standard or customer specific
critical to know for non-structural grades Part forming is critical for CR HSLA grades,
less so for standard grades 44
TYPES / GRADES OF STEEL
Low Carbon Hot Rolled vs Cold Rolled
Hot Rolled Grades Hot Rolled Steel
• Commercial Steel (CS) • Black or pickled surface
• Drawing Steel (DS) • Heavier thicknesses
o Option boron
o Need to exercise caution on using boron • Wider gauge tolerance
• Not as flat
Cold Rolled Grades • Less mechanical property control
• Commercial Steel (CS)
Cold Rolled Steel
• Drawing Steel (DS) • Uniform/smooth surface
• Deep Drawing Steel (DDS) • Lighter thicknesses
• Extra Deep Drawing Steel (EDDS) • Tighter gauge tolerance
• Vacuum degassed/IF • Improved flatness
• More mechanical property control
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TYPES / GRADES OF STEEL
Low Carbon
Commercial Steel (CS) Drawing Steel (DS/DDS) Extra Deep Drawing Steel (EDDS)
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TYPES / GRADES OF STEEL
.30 carbon and above 41XX(Cr, Mo), 51XX(Cr), Low carbon levels (under .15)
(1030 – 1095) 61XX(CrV)
Primarily heat treated or Improved hardenability Alloyed with a small amount of Nb, Ti
“full hard” parts (heat treat response) over or V
high carbon
-Precipitate strengthening and grain
refinement
Can be annealed to lower Improved high temperature Better formability than high carbon steels
strength/improve properties
formability
Boron can be added for Domestic specs
hardenability -SAE J1392
-ex 050 XLF
-SAE J2340
-ex 340 XF
-ASTM A1011 and A1008
-ex HSLAS-F Grade 50 Class 2
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TYPES / GRADES OF STEEL
Tensile strength (TS) is the capacity of a material or structure to withstand loads tending to elongate. Tensile
strength resists tension (being pulled apart). It is measured by the maximum stress that a material can withstand
while being stretched or pulled before breaking.
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METALLURGY OF AHSS
MULTIPHASE Structure Manage Phase Transformation Coupled
Key Factors: PROCESS and CHEMICAL COMPOSITION
PROCESS = control the structure at high temperature + the continuous
cooling
« Conventional »
Strip Temperature steels
CGL or CAL
TRIP steels
DP steels
time (s)
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TRIP – TRANSFORMATION INDUCED PLASTICITY
• Dispersion of hard second phases
in soft ferrite creates initial high
work hardening rate.
• Retained austenite also
progressively transforms to
martensite with increasing strain.
• Transformation increases work
hardening at higher strain levels.
• Typically used in place of DP where
formability is an issue.
• Available in different strength
levels. Specified by minimum
tensile strengths of 590, 690, 780
and 980 MPA.
• Most applications are Cold Rolled
or coated Cold Rolled.
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Complex Phase (CP)
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MARTENSITIC STEELS
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PRESS HARDENED STEELS (PHS)
• Hot Stamped Steels, Boron Steels
• Medium carbon boron steels – similar to 10B21
• Excellent formability at elevated temperatures
• Processing: austenitize, hot form, in-die quench
• Oxide removal and corrosion protection: Bare vs. aluminized vs. zinc coated
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STEEL TESTING
Common Types of Steel Tests
Hardness Testing
Superficial Hardness Testing
Tensile Testing
Surface Roughness Measurement
Charpy Test
Hardness Testing
• One of the oldest methods of evaluating a material.
• Variety of test methods, scales, machines etc.
• Most common is Rockwell Hardness Testing
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STEEL TESTING
Common Types of Steel Tests
Hardness Testing
Superficial Hardness Testing
Tensile Testing
Surface Roughness Measurement
Charpy Test
Tensile Strength
• Various standards:
Ex: ASTM E8, JIS Z 2241, DIN DIN EN ISO 6892-1
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STEEL TESTING
Common Types of Steel Tests
Hardness Testing
Superficial Hardness Testing
Tensile Testing
Surface Roughness Measurement
Charpy Test
Ra: It is the average deviation of the profile from the mean line. However it doesn’t
differentiate between peak and valley height/depth(units-micro-inches)
1 2 3 4 5 58
STEEL TESTING
Common Types of Steel Tests
Hardness Testing
Superficial Hardness Testing
Tensile Testing
Surface Roughness Measurement
Charpy Test
• Invented in 1900
• Measures impact
strength of
materials
• Used in steel
primarily for low
temperature
strength for
rollover structures
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Credit: Jordan, Jeremy. Ductile to brittle transitions in materials. Materials Science. Nov 2016.