Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS-BT Paper -2(2017-P2) Date: 17-12-2023
Time: 02.00Pm to 05.00Pm GTA-08 Max. Marks: 183

KEY SHEET
PHYSICS

1 D 2 B 3 D 4 C 5 D 6 C

7 A 8 AC 9 AC 10 AC 11 ABCD 12 AC

13 AC 14 A 15 A 16 B 17 A 18 B

CHEMISTRY
19 B 20 B 21 C 22 D 23 C 24 D

25 B 26 BCD 27 B 28 AB 29 ABD 30 ABC

31 ACD 32 A 33 A 34 A 35 A 36 C

MATHEMATICS
37 D 38 D 39 D 40 A 41 B 42 C

43 C 44 AB 45 AC 46 CD 47 BCD 48 AC

49 AD 50 ABCD 51 B 52 D 53 A 54 D
 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

SOLUTIONS
PHYSICS
1. Opposite to direction of field potential increases and in the direction it decreases.
2. Due to eddy current disc rotates in the same direction.
1
3 12 ´
h cos i 2 2
3. h/ = =
m cos3 r 2´
3 3
82
8
=
3
4. 2 gR (1 - cos q ) + u 2 = g cos q R
gR 5
u2 + = gR
3 6
gR
u2 =
2
5 gR
V2 =
2
5. First complete the grid, then connect ‘–R’ resistance between B and C.

F
x
q
6.
L
Calculate shear force F(x) and maximizing we will get x =
3
2 æ2 ö
7. MR 2w = çç MR 2 + mR 2 sin 2 q ÷÷÷
5 çè 5 ø
M w0
ò w1dt = ò 5 2
dt
M + m sin q
2
M cos ec 2q Rd q
Dq = w0 ò V
æ 5m ö
M cot 2 q + ççç + M ÷÷÷
è 2 ø
Rw0 cos ec 2qd q
V ò
Dq =
5m
M+
cot 2 q + 2
M

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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s
Rw0 dt
V ò
=
5m
M+
t2 + 2
M
p Rw0 2M
=
V 2M + 5m
1 q2
8. - K ( + x )
4pe0 ( + x )2
= –3 Kx
m
T = 2p
3K
9. Line joining vertex of cone to B will be IAOR.
w = 2w1 cos a
VC = 2w1 cos ah sin a
= (h sin 2a )w1
10. Torque balance along horizontal axis.
11. Conceptual
1 Mm
12. V2 =Q
2 M +m
1
mV 2 = K
2
æ mö
K = çç1 + ÷÷÷Q
çè Mø
æ 1ö 2
1.4 = çç1 + ÷÷÷Q Q = ´1.4
çè 2 ø 3
13. R3 = 300(1 + .0008´ 50) = 312
50 5
DV3 = ´ 312 - 50 ´ = 0.27 V
372 6
14. Initial frequency will be maximum.
15&16
T cos q = T0
T sin q = w x
dy w x
tan q = =
dx T0
w x2
y = y0 +
2T0
17. Consider small cylinder centre at ring.
18. Consider deflection produced by active region.

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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

CHEMISTRY
19. III produces more resonance stabilized carbocation
OH OH
O
CN
NH2

O OH
OH

N
N
20.

CHO
A=
B=
21.
OH

C= D=

22. BrF5 + H 2O  HBrO3 + HF

23. The graph is possible for 2s, 3p, 4d, 5f etc.
24. Bicarbonates do not exist in solution
25. Oxidizing the impurities of cast iron in a reverberatory furnace linned with haematite
which involves formation of volatile oxides
26. In C6 H 5OCH 3 , -OCH 3 does not sufficiently increase electron density on the ring.
Recall that C6 H 5OH undergoes coupling in weakly alkaline medium which converts
C6 H 5OH tothe more reactive C6 H 5O –. In options (b) and (c), presence of electron-
withdrawing — NO2 groups increases electrophilic character to such an extent that these
diazonium cations can couple even with the compounds having weak electron-releasing
groups. Option (d) undergoes coupling reaction easily because – NMe2 is sufficiently
electron-releasing.
27. Bisulphite is a weak nucleophile, and it cannot form crystalline precipitate with
carbohydrates
28. The given reaction is non-redox reaction and the IUPAC name of complex B is sodium
pentacyanidothionitrito-N-ferrate (II).
29. Acidic strength decreases from H 2Te to H 2O
0
30. Ni2O3 ( s ) + Fe( s )  2 NiO ( s ) + FeO ( s ) Ecell = 0.4 - (-0.87) = 1.27V
245.11
DG 0 = -2 ´1.27 ´ 95500 = -245.11kJ / mol h = ´100% = 50.02%
490
31. 3K 2 MnO4 + 4 H '  2 KMnO4 + MnO2 + 2 H 2O
( purple) (brown)
-DH 0 T DS 0 -DH 0 æç 1 ö÷ DS 0
32. ln K c = + ln K c = ç ÷+
RT RT R çè T ÷ø R
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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s
y=mx+c
slope of curve is negative it means DH 0 is positive and value of K c is less than unity
hence reaction is non-spontaneous at standard condition

33.

34.
35&36
 P  H vap  T2  T1 
In  2   X    X  g 
 P1  R  T1T2 
H vap  10.3  2  8.3 kJ Svap  20.75 kJ
H vap 8.3  103
Boiling point =   400 K Y    Y  g 
Svap 20.75
H vap  17.96  10.30  7.66 kJ / mol Svap  20 J / mol K
H vap
Boiling point =  383 K Y is more volatile than X
Svap
For ideal solution PTotal  Px  Py PX  PX0 X X , PY  PY0 X Y
XX = 0.5 XY = 0.5 Px0 at 270 C
 P  H  T2  T1   1  8.3  103 100 5
In  2   In  0    
 P1  R  T1T2   Px  8.3 300  400 6
1 1
 e5/6  2.3  Px0   0.435 atm For Py0 at 270 C
Px0 2.3
 1  H  T  T   1  7.66  103  83 2
In  0   2 1 In  0  
 Py  R  T1T2   Py  8.3  300  383 3
1
Py0   0.5 atm P  PX0 X X  PY0 X Y =  0.435  0.5   0.5  0.5 =0.47 atm
2

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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

MATHEMATICS

37.  
Let bi
i 0
be defined by bn  an  1and note bn  bn21 . The infinite product is then

 0 0
1  b 1 b 0 
2 1  b 4 ........1  b 2k  ..........
 0 
By the polynomial identity

  
1  x 1  x2 1  x4 .......1  x2  ....  1  x  x2  x3  .......  1 1 x
k

1 1 3
Our desired product is then simply  
 
1  a0  1 2  a0 5
38. There are fifteen 1’s so the result is always a multiple of 3.
Now the number has to be a multiple of 10, so we need to insert 9 plus signs in between
the fifteen 1’s, so that the result is a multiple of 10.
Required number of ways = 14C9  2002
39. N  2  t , 2  t , t  P (2cos q , 2sin q ,0)
Dr’s of PN are  2  t  2cos  ,2  t  2sin  , t 
PN is  ler to the line
 2  t  2cos ,2  t  2sin  , t  .1,1, 1  0
2  t  2cos   2  t  2sin   t  0
2cos   2sin   4
3t  4  2cos   2sin  t 
3
24  2  cos  sin   cos   sin  
PN   2  t  2cos     2  t  2sin    t 2 
2 2
3
1
PN min imum = 36 - 24 2
3
 5/ 2 3/ 2 
40.  a : M   
 3 / 2 1 / 2 
 5 1  5 9
M satisfies M 2     M      I  0
 2 2  4 4
M 2  2M  I  0  i.e. M  I   0
2

Let M  I  B, B 2  0 . Now, M = I + B
M n   I  B  I  n C1B  n C2 B 2  ..........
n

 I  nB  I  n  M  I 
 3 3 
1 0   2 2 
M 2024     2024  
0 1   3 3
 
 2 2 

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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

1 0   3036 3036   3037 3036 

    3036 3036    3036 3035
 0 1     

41.
Consider a right triangle AOC such that AO = 36 and CO = x
Consider B on AO such that BO = 25 and AB = 11
x x
tanB  , tanA 
25 36
Angle B – Angle A = Angle BCA
Angle BCA is maximum if the circumcircle of BCA is as small as possible and OC
becomes a tangent to the circle BCA OC 2 = OB.OA = 25.36 = 900
OC = 30
æ æ 30 ö æ 30 öö æ æ 6ö æ 5 öö æ æ 11 öö 11
sin çç tan-1 çç ÷÷÷ - tan-1 çç ÷÷÷÷÷÷ = sin çç tan-1 çç ÷÷÷ - tan-1 çç ÷÷÷÷÷÷ = sin çç tan-1 çç ÷÷÷÷÷÷ =
èç èç 25 ø çè 36 øø èç èç 5 ø èç 6 øø èç èç 60 øø 61
 
1 1  i   1  i 
42. L  lim 
 2
n n 1i  j  n

tan   tan   
 n  n 
 
 2  n 2 
1  n 1     1    
  tan        tan     
i i
 lim 
n 2n2  i 1  n  
 i 1
 n  

  
2
1  1 1  1 1  1  2 
   tan  x  dx     tan  x   dx
2 0  2n 0  
2 2
1  1 1  1    ln  4 
Since n   , we obtain: L    tan  x  dx   
2 0  2 4 
    
43. Let z   x  . Then z  ,  , and 2z  ,  .
4 6 4 3 2
 3   
We have tan  x    cot  x    cot z
 4   4

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2
Then y  cot z  tan z  cos z   cos z .
sin 2 z
2
Since both and cos z are monotonic decreasing in this case,
sin 2z

So y reaches the maximum at z  , where
6
ymax  2  cos   4  3  11 3 .
sin 6 3 2 6
3
44. f  x   cos  x     cos  x     cos  x   
Since f (x) = 0 for all x f     0, f     0 and f     0 .
 
That is cos     cos       1, cos      cos      1 ,
And cos      cos       1,

So, cos      cos      cos       12 .

 2 4 
Since 0        2 , so    ,   ,    ,  . In view of
 3 3 
2
       ,       , it is possible only when         , so
3
4
   .
3
45. cos2 A  cos2 B  cos2 C  2cos A cos B cos C  1
Add cos2 C  2  cos A cos B  sin Asin B  cos C to both sides of the first given
10
equation.  2cos2 C  cos2 C  1
7
3 4
So, cos C is and therefore sin C is .
7 7
11 3
Similarly, cos A = 1 
8 8
10
cos2 A  cos2 B  2sin Asin B cos C  _____________(1)
7
11
cos2 B  cos2 C  2sin B sin C cos A  _____________(2)
8
45  4  2 15  5 3 
cos2 C  cos2 A  2sin C sin A sin B  .
56
46. Solving the ellipse and the first circle

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 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

x2 y2
 2  1 , ( x  2) 2  y 2  4
2
a b
Substitute y 2  4  ( x  2)2 in the ellipse equation, we get
(b 2  a 2 ) x 2  4a 2 x  a 2b 2  0
This quadratic equation has two equal roots
(
16a 4 - 4 b 2 - a 2 -a 2b 2 = 0 )( )
b4
4a 2 + b 4 - a 2b 2 = 0 a2 =
b2 - 4
b2  b3
Area of ellipse =  ab   * *b = = A(b)
2 2
b 4 b 4
dA
= 0 for minimum area
db
Solving that we get b2  6 and a 2 18

 4x4  1
4
x4 x4 3 x4 ex
e xe 4x  e
47. f  x  f ' x   
x x2 x2
1
f ' x   0 x4  1 / 4 x2  1 / 2 x  
2
1
Critical point 
2
f 1  e f 1 / 2  2e1/16

f 1 / 2  2e1/4  2e1/4  f  x   e
1 1 1
 f  x dx  
1/4
 2e dx  edx
1 1 1
2 2 2
æ 1 ö÷ æ ö
2 e1/4 çç1 - ÷ < I < e çç1 - 1 ÷÷
çè 2 ÷ø çè 2 ø÷
e ( 2 -1 )
( )
2 -1 e1/4 < I <
2
1
æ1 1 ö÷ æ ö
I < 2e16 çç - ÷ + e çç1 - 1 ÷÷
ç ÷ è2 ç 2ø ÷ è 2ø
1 1
1
< e16 + e - 2e16 - e
2
48. Tr(A) =Tr(AB – BA) = Tr(AB) – Tr(BA) = 0

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Characteristic equation of A is A2 – (Tr A) A + A I = 0

A2   0 A  A I  0
A2   A I
A = AB – BA
Pre Multiply by A, we get A2  A2 B  ABA
Post multiply by A, we get A2  ABA  BA2
Add both the equations, we get A2  0
49. Since min(S). max(S) < 0, we must have min(S) = –a and max(S) = b for some positive
integers a and b. Given a and b, there are S  2  ab  2 elements left to choose, which
must come from the set   a  1,  a  2........., b  2, b  1 ,which has size a+b–1. Therefore
 a  b  1
the number of possibilities for a given a, b are  .
 ab  2 
In particular, we must have ab  2  a  b  1   a  1 b  1  2 . The possibilities for (a,
b) to (1, n) and (n, 1) for positive integers 2  n  11 (n = 1 case is impossible), and three
extra possibilities: (2,2), (2,3), and 3, 2). In the first case, the number of possible sets is
  2  3 10 11    2  3 11  12
2        ......         2        .....      2    440
  0  1  8   9    2  2  2   3
In the second case the number of possible sets is
 3  4  4
 2   4   4  5 .
Thus there are 445 sets in total.

C (a, b )
C2 (a, b )

C (0,0)

50. A)
CC1 = 3 - R
2
a 2 + b 2 = (3 - R)
(b -1) = R  b = 1 + R
2 2
a 2 = (3 - R) - (1 + R)

( ) (
= 9 + R2 - 6R - R2 + 1 + 2R )
a 2 = 8 - 8R  R = 1 then centre lies on y –axis

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y =1
x2 + y 2 = 9

C2 (a, b )

B)
C1C2 = 3 - R2
1- b = R  b = 1- R
2
a 2 + b 2 = (3 - R)
2 2
 a 2 = (3 - R) - (1 - R) = 8 – 4R
 R = 2 then centre lies on y-axis

R R
R R

C)
(0,0) C

3-R 3-R

C1 C2
2R
(-R,1- R) ( R,1- R)
2 2
R 2 + (1 - R) = (3 - R)
R2 + R 2 + 1- 2R = 9 + R2 - 6 R
 R2 + 4R = 8  R 2 + 4 R + 4 = 12
 ( R + 2)2 = 12  R = 2 3-2= 2 ( 3 -1 )

C (0, 0)

D)

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2 R2 - d 2 = 2 5  R2 - d 2 = 5
 R 2 -1 = 5  R 2 = 6  R= 6
51&52

p - (q + f )
a+d
a-d
f q
a
a-d a +d a
= = = 2R
sin q sin f sin (p - (q + f ))
a + d sin f
= , a = 2 R sin (q + f )
a - d sin q
p
f - q = (given)
2
a sin f + sin q æ q + f ö÷
= = tan çç
d sin f - sin q çè 2 ÷÷ø
2 R sin (q + f ) æ q + f ö÷
= tan çç
d çè 2 ÷ø÷
æ q + f ö÷
 4 R cos 2 çç =d
çè 2 ÷÷ø
a - d = 2 R sin q
æ q + f ö÷
2 R sin (q + f ) - 4 R cos 2 çç = 2 R sin q
çè 2 ÷÷ø
æ q + f ö÷
 sin (q + f ) - sin q = 2cos 2 çç
çè 2 ÷÷ø
æ q + f ö÷
 cos 2q - sin q = 2cos 2 çç
çè 2 ÷÷ø
æ pö
 cos 2q - sin q = 1 + cos ççq + q + ÷÷÷ = 1 - sin 2q
çè 2ø
 cos 2q + sin 2q = 1 + sin q
 - sin q + sin 2q = 1 - cos 2q
1
 1 - 2cos q = -2sin q  cos q - sin q =
2
1 3
 cos 2 q + sin 2 q - 2sin q cos q =  = sin 2q
4 4
7 7 -1 7 +1
cos 2q = sin q = ,cos q =
4 4 4

Sec : Sr.Super60_ NUCLEUS _BT Page 12

 Sri Chaitanya IIT Academy 17-12-2023_Sr.Super60_NUCLEUS ‐BT_Jee-Adv(2017-P2)_GTA-08_Key& Sol’s

Length of the altitude from vertex A =

2
(
2D 2 2 R sin A sin B sin C
= = 2RsinB sinC
)
a 2 R sin A
æ 7 öæ 7 -1ö÷ 2 7 - 7
= 2(1)ççç ÷÷÷ççç ÷=
( )
çè 4 ÷øèç 4 ÷÷ø 16
8a = 7 - 7 (8a - 7)2 = 7
æ 7 -1öæ
÷ 7 öæ
÷ 7 + 1ö÷
ç
( )çç ÷ ç ç
2 1 ÷÷ççç 4 ÷÷ççç 4 ÷÷÷
÷
D 2 R 2 sin A sin B sin C èç 4 øè øè ø
Inradius r = = =
s R (sin A + sin B + sin C ) æ 7 -1 7 7 + 1ö÷
çç + + ÷
ççè 4 4 4 ø÷÷
2 7
(7 -1) 1
= 64 =
æ 2 7 + 7 ö÷ 4
çç ÷÷
ççè 4 ÷ø
53. g(x) = (x – a) (x – b) (x – c)
f(x) = g(x) h(x)
 
x 4  x3  bx 2  100 x  c  x3  ax 2  x  10  x  r 

x 4  x3  bx 2  100 x  c   x3  ax 2  x  10  x  r   0
Comparing coefficients on both sides.
x3 :1   a  r   0 and x :100  10  r   0
 r  90, a  89
g  x   x3  89 x 2  x  10 , h ( x) = x + 90
g(1) = 1 + a + 1 + 10 = 1 – 89 + 1 + 10 = –77
h(1) = 1 + r = 1 + 90 = 91
f(1) = g(1) h(1) = (–77) (91) = 7007
54. a + b = –10
ab = –1010
c + d = 10
cd = 1010
ac(a – c) + ad(a – d) + bc(b – c) + bd(b – d)
= a 2c  ac 2  a 2d  ad 2  b 2c  bc 2  b 2d  bd 2
       
= a 2  b 2  c  d   c 2  d 2  a  b   a  b 2  2ab  c  d    c  d  2  2cd  a  b

 
= 102  2 1010  10  102  2 1010  10
 
=103  20 1010  103  20 1010 = 2(1000) = 2000

Sec : Sr.Super60_ NUCLEUS _BT Page 13