FULL SYLLABUS

CLASS –XII

Time: 3 Hrs Date: 31-12-2023 M.M.: 300

Physics : Full syllabus
Chemistry : Full syllabus
Mathematics : Full syllabus
Questions Answers Questions Answers Questions Answers
1 d 31 d 61 c
2 b 32 a 62 b
3 a 33 b 63 c
4 b 34 a 64 c
5 a 35 c 65 a
6 a 36 d 66 d
7 a 37 c 67 c
8 a 38 c 68 d
9 b 39 a 69 d
10 a 40 a 70 a
11 c 41 d 71 d
12 a 42 a 72 b
13 d 43 a 73 a
14 b 44 a 74 a
15 c 45 a 75 a
16 b 46 d 76 c
17 a 47 b 77 b
18 b 48 b 78 b
19 d 49 a 79 c
20 b 50 a 80 d
21 1 51 8 81 2
22 3 52 2 82 0
23 1 53 3 83 6
24 1 54 4 84 5
25 5 55 8 85 2
26 1 56 9 86 5
27 2 57 5 87 1
28 2 58 3 88 6
29 4 59 2 89 1
30 5 60 6 90 8

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 HINTS AND SOLUTIONS
PHYSICS 6. (a)
1. (d) A charged particle of charge q, mass m while
The magnitude of gravitational potential of a solid moving with speed v enters a uniform magnetic
sphere at a distance r from the centre is field B, then, force on charged particle due to
GM magnetic field provides the required centripetal
V (3R 2  r 2 ) force. If r is the radius of the circular path traced
2 R3
by charged particle in the uniform magnetic field,
GM
At r = R, V  then
R
mv 2 mv
Gm 3GM Bqv  or r  i.e., r  m
At r = 0, V '  3
(3R 2 )  r Bq
2R 2R
3V 7. (a)
Clearly, V '  V
2 Required resistance R  G
2. (b) i9
if after division, one of the charge is q the other 30
  100  900
charge will he (4 – q). The force between them 30  10 3
can be written as,] 8. (a)
e E = e v B or v = E/B
9. (b)
Kq(4  q) The formula to calculate the radius of the path
F
d2 followed by the charged particle under an external
For the force between them to be maximum, magnetic field can be written as
dF mv
0 r …(1)
dq Bq
K The perpendicular component of velocity results
 [4  2q]  0
d2 in circular motion, while the parallel component
 q = 2C results in linear motion. Hence, the path of the
3. (a) charged particle is helical in nature, the axis of
The initial charge on the capacitor C1 will be Q = which lies along the direction of the magnetic
C1V. If after closing the switch the charge flown field.
through the circuit is q, the charge on C2 will be q
and C1 will be Q – q. The potential across the 10. (a)
capacitors will be same. Hence, Once a rectangular loop or a square loop is being
Qq q drawn out of the field, the rate of cutting the lines

C1 C2 of field will be a constant for a square and
C2 Q rectangle, but not for circular or elliptical areas.
 q 11. (c)
C1  C2
Here, A = 100 cm2 = 10–2 m2, B = 10–1 T,
CC
 q 1 2 V  = 90° – 30° = 60°
C1  C2
4. (b) dt = 10–4 s, e = ?
The reading of galvanometer will not change with 1  BA cos , 2  0 or d   2  1
switch S open or closed when bridge is balanced. d (0  BA cos ) BA cos 
In this state current through R is same as that e  
dt dt dt
through G.
101  102  cos 60
5. (a) =  5V
10 4
E1  E2 24 6
I    1 ampere
R1  R2  R3 4  1  1 6

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12. (a) % change in de Broglie wavelength =
Here, V = 200 volt, C = 2F, C  = X F    '
   100
1 1   
Decrease in energy = CV 2  C 'V 2
2 2
1  '  1
=  1  100   1    100  75%
= (C  C ')V 2     4
2
1
2  102  (C  C ') (200) 2 19. (d)
2
4  10 2 The value of Q is
C C'   106 F  1F
4  104
Q = (mA – mB – mD)  931.5 MeV
C '  C  1  2  1  1F
13. (d)  Q  (238.05079  234.04363  4.00260)  931.5 MeV
A transformer does not work on d.c.  Q  4.25 MeV
 Es = 0.
14. (b) 20. (b)
15. (c)
hc
As we know, electric field and magnetic field are Using, E  Eg 

related as
E0 = CB0, where, c is speed of light is vacuum 6.6  1034  3  108
 J
 589 109
Also c 
k
 6.6 1034  3 108
 E0  B0  eV  2.1eV
k 589  109  1.6 1019
 E0 k  B0 21. (1)
2q1 L 2q2 x 2q3  2 L  x 
  …………(1)
16. (b) 2 A 0 2 A 0 2 A 0
dq  dq3 dq2
Here, n = 10,  = 6000 Å = 6  10–7 m I 1  ………………….(2)
dt dt dt
From (1), q1L  q2 x  2q3 L  q3 x  0
D = 0.1 cm = 10–3m

Angular position of 10th minima

n 10  6  107
   6  10 3 rad
d 103

17. (a)
dq1 dq dx dq dq dx
The photoelectric emission is possible if the L  x 2  q2 2 3 L x 3  0
dt dt dt dt dt dt
wavelength of the incident light is less than that of 22. (3)
yellow light. Vl iR
E  l 
 l
L L
18. (b) E R
E  l
R  Rh  r L
h h 1
As    or  
mv 2mK K
10 5
E   3  3V
5  4 1 5
' K 1 1
   
 K' 16 4

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 v 3K B  1.5
I   q2  q2   1 mA
L
 K B  0.5 eV
 K A  2eV
23. (1)
28. (2)
W=MB  cos  2  cos 1   1J
n 2  5.3  10 11  21.2  1011
24. (1) n2  4
n2
When bar attains terminals velocity BIL= mg 29. (4)
0.2  9.8 9.8 Fringe shift due to slab in Young’s double slit
I  , D    t
0.6  1 3 experiment is given by x 
d
E is EMF induced in rod and eI=P1 + P2
D
Since, fringe width  0  
0.76  1.2 1.96  3 d
e   0.6V and e  BvT l
9.8 / 3 9.8  0    t
Then, x 

e
vT  1 m / s Putting the values, we have
B
25. (5) 10 106 1.2  1
 0
5 10 7
v0  D  D
m 1    m0  1   105  0.2
u0  fe   fe   0
5 107
 25 
 30  m0 1    m0  6  4 0
 5 
Hence, the value of x =4.
 m0  5 30. (5)
26. (1) For 1
2 2
d D D 1  1 1  5 
2 2 2 2  RZ 2  2  2   R   ………(i)
d  D  D    2 D 1 2 3   36 
d2 108 For 2
D  7
 102 m
2 2  5 10
1 1 1   7 
D  1cm  RZ 2  2  2   R   ……..(ii)
2 3 4   144 
27. (2)
Dividing (ii) by (i)
hc
KA   WA  5  W A ……………..(1) 7

1 144 7
K B  5.3  WB ……………………………(2)  
2 5 20
It is given K B  k A  1.5 ……………..(3) 36
h h 7 7
  So, 
P 2mK 4n 20

 B2  4A2 n 5

h2 4h 2 CHEMISTRY
  K A  4KB
2me K B 2me K A 31. (d)
T2  molality  K b
 K B  4K B  1.5
0.52  m  0.52

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 molality = 1mol kg 1 Magnetic moment   N(N  2)BM where, N
 Urea = 1 mol = unpaired electrons
1000 Cr(24)  [Ar]3d 5 4S1 N  6,   48BM  x
Water   55.55
18
Mn   [Ar]3d 5 4S1 N  6,   48BM  y
1
Mole fractions of urea =  0.018 2 6
56.55 Fe  [Ar]3d N  4,   24BM  z
32. (a)
p n2
 X solute 
p n1  n 2
4 n2 Thus, z  x  y
 39. (a)
40 n1  n 2
40. (a)
1
n1  9n 2 ,  9n 2 Factual
m1 41. (d)
 w1 (solved)  9 n 2 m1 Factual
 9n 2 18  162n 2 42. (a)
Phenoxide ion is less resonance stabilized than
moles of solute AcO  , therefore, nucleophilicity decreases in
Molality = = the order :
kg solvent
CH 3O   HO  (C)  PhO  (A)  AcO  (B) 
1000n 2
=  6.173molal Thus, option (a) is correct.
162 n 2
43. (a)
33. (b) Hydroboration-oxidation gives alcohols
0.0591 [Zn 2  ] corresponding to anti-Markovnikov’s addition
E  E cell  log
2 [Cd 2  ] of H 2 O to alkenes.
0.0591 [Zn 2  ] (i)B H
0.30  0.36  log 2 6
CH 3 — C  CH— CH 2 CH 3 
2 [Cd 2 ] 
(ii)H2 O2 ,OH
|
[Zn 2  ] 0.06  2 CH(CH3 )2
log  2
[Cd 2  ] 0.0591
[Zn 2  ]
  102
[Cd 2  ]
[Cd 2 ]
  0.01
[Zn 2  ]
34. (a)
Ac 10
x   0.05 , % ionisation = 5%
A 0 200
35. (c)
The sum of power of the concentration of the
reaction in the rate law expression is called the
order of that chemical reaction.
X  Y  XY
The order of reaction with respect to X is Thus, option (a) is correct.
d[X]
2.  K[x]2 [Y]
dt 44. (a)
The order of reaction = 2 + 1 = 3
36. (d)
1 1
T50 (second order) =   5000
Ka 2 103  0.1
37. (c)
MnO 4 changes to MnO24  or MnO 2 in basic
medium.
38. (c)
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 47. (b)
CH3
|
1,2  Methyl  H2O
 Shift
 H 3C — C — CH — CH3  
| |  H2
4 CH3
3 Carbocations
(More stable)

CH3
| 48. (b)
H 3C — C — CH — CH3 Ni / H2 and NaBH4 will reduce > C = O to
|
OH >CHOH. Out of reagents (a) and (b), HCl in
A( Major ) reagent (a) will either bring about conversion of
Carbocation (I) gives the minor produce (B) –OH to Cl or bring about dehydration to form a
CH3 d.b in the ring.
|
 H 2O
1  
 CH 3 — C — CH — CH3
H | |
CH3 OH
B( Minor ) Product

48. (a)
50. (a)
51. (8)
45. (a) In the first step oxidation of cyclohexanol to
cyclohexanone by acidified potaSsium
dichromate takes place.
In the second step cyclohexanone reacts with
Grignard reagent followed by hydrolysis to form
a tertiary alcohol.
In last step dehydration of tertiary alcohol leads
to the formation of

In the above molecule the number of sp2

hybridised carbons are 8.

46. (d)

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 x60
52. (2) x0
The relation between Gibbs Free energy and 55. (8)
emf of the cell can be related as follows, 8
CH3
G  nFEcell . 1 2 3 | 4 5 6 7
CH 3 — C H 2 — C H 2 — C H 2 — C H 2 — C H 2 — C H 2 — C H 3
The electrode reactions can be written as
All the carbon atoms are different and hence
follows,
eight monochloro derivatives are possible.

Pb2  2e  Pb G1  2 FEPb 2
/ Pb 56. (9)

Pb 4   4e  Pb G2  4 FE Pb 4 / Pb


Pb 4   2e  Pb 2  G3  2 FEPb 4
/ Pb2

Now, G3  G2  G1

   In the above reaction the Eghyl group of
2 FePb 4  4 Fe
Pb4 / Pb
 2FePb 2
/ Pb
Grignard reagent acts as a strong base. As per
  
 4 Fe Pb4  / Pb
 2E Pb4 / Pb
 2FE Pb2 / Pb the stoichiometric equation the number of moles

 4n  2m  2 EPb of methanol is equal to the number of moles of
4
/ Pb2
ethane.

 4 EPb 4
/ Pb2
 2n  m Volume of methanol = Volume of ethane =

 E  m  2n 2.24ml
Pb 2 / Pb 4

Hence, the value of x =2 Hence, number of moles of ethane

53. (3) 2.24  10 3
n  10 4
On applying law of mass action over slowest 22.4
step, Weight of the gas = Number of moles ×
Molecular mass
R  k[NOBr2 ][NO]
W  n M
The slowest step is the rate determining step.
 104  30  3mg
On applying Law of mass action on equilibrium
of Step I. 57. (5)
No reaction with strong base or acid indicates
[NOBr2 ]
k presence of strong neutrality or non-reactive
[NO][Br2 ]
functional group with a single oxygen. No
[NOBr2 ]  k[NO][Br2 ]
positive 2, 4-DNP test indicates absence of
R  k[NO]2 [Br2 ] carbonyl compound. Same compound formation
= k '[NO]2 [Br2 ] upon hydrogenation indicates single double
The overall order is equal to sum of the powers bond. Thus, it is an ether.
of the concentration terms in the rate law. As per the language of given questions, the best
The overall order of the reaction is 3. possible isomeric structure is
54. (4) Ph — CH  CH — O — CH3 (cis and trans).
The chemical formula of Chromy chloride is So, the answer is 2.
CrO2Cl2 . The oxidation state of chromium in 58. (3)
chromyl chloride (CrO2Cl2 ) is +6. Nitrobenzene converted into Aniline by
Let the oxidation number of Chromium be “x”, Sn  HCl, Fe  HCl, H2 / Rancy Ni .
the oxidation state of oxygen is –2, the 59. (2)
oxidation state of chlorine is –1.
Acid-base reactions are faster than nucleophilic
Then,
addition reaction. So, in the first step acid-base
x  2(2)  2( 1)  0
reaction takes place between alcoholic
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 functional group and Grignard reagent. Now, the Let A  [aij ]23 B  [bij ]32 . Both AB and BA are
second mole of Grignard reagent to react with defined.
aldehyde function group. Hence, at the end of 65. (a)
the reaction a diol is produced on acidification.
x2 x3  1 x5  2
3
Let   x  3 x2  x x3  x 4
x4 x 3  x5 23

60. (6) Expanding along R 1 , we get

A spin-only magnetic moment occurs when an


  x 2 8x 2  8x  x 6  x 8  x 7  x 9 
electron rotates on its own axis and generates a    
 x 3  1 4x 3  24  5x 4  x 5  x 5  2 
magnetic field.
 x6  x8  2x3  3x5  5x2  4x 
  n(n  2) BM  Coefficient of x 2 in the expansion
of  = -5 × 2 = – 10.
Here, n is the number of unpaired electrons. 66. (d)
The greatest integer function [x] is discontinuous at
The unit for a spin-only magnetic moment is the all integral values of x.
Bohr magneton (BM). 67. (c)
dy
 cos x . Therefore, slope of normal =
([Mn(H2O)6]2+ dx
 1 
Mn2+ = 3d5  cos x   1 . Hence the equation of
  x 0
normal is y – 0 ( x – 0) or x + y = 0
  5(5  2)  5.91BM 68. (d)
cos x  sin x
MATHEMATICS  8  sin 2 x dx
61. (c) cos x  sin x
 dx
Here, (3, 3), (6, 6), (9, 9), (12, 12) So, it is 9  (sin x  cos x) 2
Reflexive and (3, 6), (6, 12), (3, 12) So, it is Let sin x + cos x = t
transitive dt 1 t

Here, reflexive and transitive only.

 9  t 2  sin 3  c
62. (b)  sin x  cos x 
= sin 1  c
 3 
f ( x )  sec [log ( x  1  x 2 )] = sec (odd function)
So a = 1, b = 3
= Even function [Since, sec is an even function]
63. (c)
69. (d)
20 
 1 3  84 3
tan 1    sec
1
Let I   ( sin x |  | cos |)
2

 3  3  63 3 0


We know that the period of |sin x| + |cos x| is
1
= tan 
 1 3  1
4 2 3   2
  sec 
 3(1  3)  
3 2 3  2
i.e. I  40  (sin x  cos x) 2 dx
 1  4 0
= tan 1    sec
1

 3 3 2
I  40  (1  sin 2 x )dx
 1 
1 1 3    0
= tan    cos    
 3  2 6 6 3 cos 2 x  2
   cos x cos 0 
 40  x    40    
64. (c)  2 0 2 2 2 

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 I  20[   2]  (3 + c)12 + clm + m2 = 0
70. (a) 2
Given, 1 1
 (3  c)    c    1  0 . Equation (i)
y (x + 1)dx – x2dy = 0 m m
x 1 dy  lies are parallel.
 2
dx 
x y So, roots of equation (i) must be equal
1 1  dy  D=0
   2  dx 
x x  y
 c2 – 4(3 + c) = 0
Now integrating both side we get,
1  c2 – 4c – 12 = 0
log e x   log e y  c
x  (c – 6) (c + 2) = 0
Now on using y(1) = e we get, c = – 2 C = 6 or c = – 2
So, the equation of curve becomes
1 So, positive value of c = 6
loge x   log e y  2
x 76. (c)
1 A number is divisible by both 2 and 3 if and only if
 y  eln x   2
x it is divisible by 6. In the first 100 natural numbers,
1 there are 16 numbers which are divisible by 6.
Hence, lim eln x 1   2  e  0
x 0 x Thus, probability of the required event is
71. (d)
16 4
The given differential equation is not a polynomial C3 /100 C3 
equation in terms of its derivatives, so its degree is 1155
not defined. 77. (b)
72. (b) The number of ways of placing 3 black balls at 10
10
Given, places is C3 . The number of ways in which two
   
a and b be two vectors, where  a | 1, | b | 4 and black balls are not together is equal to the number
 
a .b  2 , of ways of choosing 3 places marked with X out of
   
the eight places.
Now given, c  (2a  b )  3b
       XWXWXWXWXWXWXWX
So, b .c  b .(2a  b )  3b .b
     This can be done in 8 C3 ways. Thus, probability
 b .c   3 | b |2 {as [b 2a b ]  0
   of the required event is
or b .(2a  b )  0 } 8
C3 8 7  6 7
  10
 
 b . c   48 C3 10  9  8 15
73. (a) 78. (b)
(iˆ  ˆj )  (iˆ  ˆj ) 2 kˆ ˆ Given f (x) = 2cos–1 x + 4cot–1x – 3x2 – 2x + 10
Required unit vector is  k. 2 4
| (iˆ  ˆj )  (iˆ  ˆj | 2 f '( x)    6x  2
1 x 2 1  x2
74. (a)
Let P divides the line segment in the ratio of  : 1,  1 2 
  2  2
 3 x  1
x-coordinate of the point P may be expressed as  1 x
2 1 x 
6  3 6  3 f  (x) < 0  f (x) is a decreasing function
x giving  5 so that  = 2. Thus y-
 1  1 Now f (1) =  + 5 and f (– 1) = 5 + 5
2  2 So, range: [a, b]  [ + 5, 5 + 5]
coordinate of P is 2 a =  + 5, b = 5 + 5  4a – b = 11 – 
 1
79. (c)
75. (a)
4 4
Given, 1 + m – n = 0 and 312 + m2 + cln = 0 Let tan 1      tan  
3 3
Now taking n = 1 + m and putting in 312 + m2 + cln
= 0 we get,
312  m 2  cl (1  m )  0
 312 = m2 + cl2 + clm = 0
 (3 + c)12 + clm + m2 = 0

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 3 4 Now plotting the diagram we get,
 cos   and sin  
5 3
1  3 2 
= cos  cos   sin  
10 4 
 3 3 2 4
= cos 1     
10 5 5 5 
9 8
= cos 1   
 50 25 
1 
= cos1 
2 3
80. (d)
Now from the diagram we can say that, f (x) is
We know,
(I – A) (I + A + A2) = I – A3 =I discontinuous at two points x = {–1, 0}
Hence, (I – A)–1 = I + A + A2
81. (2)
86. (5)
The period of sin x and cos 2x is 2 and 1,
respectively. Let,
The period of 2{x} is 1. x3
y  f ( x)
The period of 3{x 2} is 2. 4
x  147
Hence, the period of f ( x) is LCM of 1 and 2, i.e.,
dy
2. We know that, for increasing function 0
dx
82. (0)
sin 1 x   / 2, cos 1 x   So, differentiating the given function
3
9 3 x
 (sin 1 x)3  (cos 1 x)3  f ( x)  4
we get,
8 x  147
83. (6) dy  x 2 ( x 4  441)
det(A) = ad – bc 
dx ( x 4  147)2
Note that det (A) can take value –1, 0 or 1. We
have  x 2 ( x 4  441)
det(A) = 1  ad = 1 bc = 0  0
( x 4  147) 2

 a = 1, d = 1 or (b = 0, c = 0, b = 0; c = 1; x 2 ( x 4  441)
 0
B = 1, c = 0) ( x 4  147)2
and det (A) = – 1  ad = 0 or bc = 1  x4 < 441
This is also possible in 3 cases. dy
Now for maxima/minima 0
–1
 A exists in 6 cases. dx
84. (5)  x4 = 441
Using det (adj A) = (det (A))2, we get  x = , 4 <  < 5
2
(det (A)) = 25  |det (A)| = 5  Maximum value of f (x) is at x = 4 or x = 5
85. (2) 64 125
f (4)  , f (5) 
Given, 403 772
f ( x) |[ x] |  x  [ x]  f (5)  f (4)

x  [ x]  0  x  R  =5
87. (1)
Now using the property of greatest integer function
and simplifying the function we get, cos8x  1
Let I   dx
cot 2x  tan 2x
2  x  2 2  x  1
 cos 2x sin 2x
f ( x ) 1  x  1, 1  x  0 Now D r  cot 2x  tan 2x  
sin 2x cos 2x

 x, 0  x 1

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 cos2 2x  sin2 2x 2cos4x  7  2 2  12 …(2)
=  
sin 2x cos2x sin 4x Taking dot product with b in (1), we get
2cos1 4x 2cos 2 4x.sin x 43
 I dx   dx 6  35  2 2   
2cos 4x 2cos 4x 2
sin 4x
 82  4 2  43 …(3)
1 2cos2 4x.sin x
=  sin8x dx   dx Solving (2) and (3), we get
2 2cos4x
 2 = 1,  = 2
1
= – .cos8x  k So,
16
 
1 a .b  3  10   2  8
Now, – .cos8x  k  A cos8x  k
16  
 a. b  8
 A   1 – 16A = 1
16

88. (6)
y 23/2  y11/ 2  4 . Squaring both sides, we have
y23  y1  16  8 y11/2
 ( y23  y1  16) 2  64 y1
 y26  32 y23  2 y23 y1  y12  32 y1  256  0 .
Hence the degree of the given equation is 6.
89. (1)
1 1
Substitute  t   2 dx  dt
x x
1 2 
When x  , t   and when x  , t  .
  2
2/ 
sin 1/ x
Thus 
1/ 
x2
dx

 /2 / 2

=   sin t dt  cos t

 ( 1)  1


90. (8)
Given:
   
a  c b  c
   
 ac b c  0
  
 (a  b )  c  0
  
So, ( a  b ) || c , hence
  
a  b  c
Where,  is any scalar

  2iˆ  7 ˆj  2kˆ  c …(1)

Taking dot product with a, we get
  2  14  2 2  7

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