SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr.

C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAM ILNADU  M AHARASTRA  DELHI  RANCHI
A right Choice for the Real A spirant
ICON Central Office - Madhapur – Hyderabad
Sec: Jr. C-120 Jee M ain D ate: 09-12-23
Ti me: 09.30Am t o 12.30N oon WTM -23 M ax. M ar k s: 300

KEY SHEET
PHYSICS
1) 4 2) 2 3) 3 4) 3 5) 2
6) 1 7) 3 8) 4 9) 2 10) 3
11) 1 12) 3 13) 1 14) 3 15) 1
16) 2 17) 2 18) 3 19) 2 20) 4
21) 15 22) 41 23) 11 24) 5 25) 11
26) 4 27) 40 0 28) 60 29) 5 30) 18

CHEMISTRY
31) 1 32) 1 33) 4 34) 1 35) 1
36) 1 37) 2 38) 1 39) 4 40) 1
41) 2 42) 3 43) 2 44) 3 45) 4
46) 3 47) 1 48) 3 49) 3 50) 3
51) 9 52) 4 53) 10 54) 5 55) 6
56) 7 57) 6 58) 3 59) 4 60) 5

MATHEMATICS
61) 3 62) 4 63) 2 64) 3 65) 4
66) 1 67) 3 68) 2 69) 4 70) 1
71) 4 72) 4 73) 3 74) 4 75) 3
76) 4 77) 1 78) 3 79) 1 80) 2
81) 99 7 82) 1 83) 9 84) 2 85) 14 94
86) 18 87) 18 88) 2 89) 2 90) 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

SOLUTIONS
PHYSICS
1. 4
By energy conservation u1  u2  u n1cvT  n2 cvT2   n1  n2  cvT

n1T1  n2T2 PV P T T  PV  PV 2 2
T n1  1 1
; n2  2V2 T  1 2 1 1
n1  n2 R1 RT2 PV1 1T2  PV
2 2T1

2. 2

3RT
V V T
M
3. 3

3RT 1
VRMS  VRMS 
M M
4. (3) Conceptual
5. (2) Conceptual
6. 1
Tl
Let mutual length = l T1 = 4N l1  l1  l T2 = 5N l2  l2  l l 
AY
T1 l1 4 l l
Tl    1
T2 l2 5 l2  l

7. 3

3RT M T
VRMS  T  2T M  VRMS 
M 2 M
8. 4

KT T 2 T2 P1  350   5  10
4

    2   
7
 4  10  2.3  10
6
2
2d P P 1 T1 P2  300   1  10
4

9. 2
Weight of mass kept = Weight of water displaced by that mass. mg  d l v g

mg = 1000  0.7  0.53 g m = 87.5 kg

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

10. 3
Conceptual
11. 1
R R R
Cp – Cv= H 2 C p  Cv  a  N2 C p  Cv  b  2a = 28b a = 14b
M 2 28
12. 3
P1 T1 T2 309
P T  P2  P1  P2  270   278 kpa
P2 T2 T1 300

13. 1
1 1 1 1 1 1
   
R R1 R2 R a b

14. 3

 l l l l ml 2 kl 2  6k 
    2kx  Where x   I  2k         
 2 2 2 2 12 2 m

6k 2 m 1 1 6k
   w2 w  T  2 f  
m w 6k w 2 m
15. 1
1 l 2 1 l    2 l2  l1
1l1   2l2  1  2 1 1 
 2 l1  2 l1 2 l1

16. 2

w  k w  m V f 2  Vi 2  vf at x  2 vi at x  0 vf  3  2  2 2  4 
1
vi = 4
2
1
Vf = 16 w   5  (162  42 )  60 J
2
17. (2) conceptual
18. (3) conceptual
19. 2

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

 1 1 1 T
t  t t t
Vavg 2n d 2Vavg nVavg P 3RT P

T M

t1 T1 P2 6  108 300
    2 t2  4  108
t2 T2 P1 t2 500

20. (4) Conceptual

21. 15
n1cp1  n1cp2 4 8 3R
 mix  n1  1, cp1  R, cv1 
n1cv1  n2cv2 4 2 2
5R 7 R
32 7 5R 1 
n2   1, cp2  R, cv2   2 2  12  1.5
32 2 2 3R 5R 8
1  1
2 2
22. 41

3RT 3R 573
VH 2  VN 2   40.8 = 41
2 28
23. 11
f 5 3
U  U O 2  U N2 U  n RT  2  RT  4  RT = 11 RT
2 2 2
24. 5
5n P2
PV = n R T P1V1 = n R (250) P2(2V1) =   2000  5
4 P1

25. 11

1 1  PV
PV 2 2

PV  P2  0.9V
p
P2   1.11 p
0.9
26. 5

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

p
Vs 
s

r  1 105
330 
1.3
r  1.41
2
r  1
f
f 5
27. 400

200 300 400

v T  v2  =400
v2 400 3
28. 60
t 0 X  X0 t 86  80
 t  T = 600 C
100  0 X 100  X 0 100 90  80

29. 5

x2 dy x 102
yx 0 1   0 x = 10 y max = 10  5
20 dx 10 20
30. 18
z 3u 1 y
  =18%
z u 2 y
CHEMISTRY
31. Conceptual
32. Conceptual

33. Conceptual

34. Conceptual

35. Conceptual

36. Conceptual

37. Conceptual

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

 1 1 
38. v  R 2  2 Z2
 n1 n2 
39. Conceptual
40. Conceptual

41. CH  CH 
O3
Seo2
 CHO  CHO


 


H
H 2 SO4
   H 2O
 
OH O H2
42.
NH

NH 2  C  NH 2
43.

CH  CH 3 
H 
CH  CH 3
OH OH 2   H 2O

44.
3

2
 
4  C H  CH 3

1,2H
Shift

5


 
Major
3

45. CH 4  3Cl2 
hr
 CHCl3 
Ag Power
 CH  CH Read hot Fe tube


Exess g H 2
Ni

46. Aliphatic

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S


1Mole
H2


Non aromatic
O
CH 3 C Cl
  C  CH 3
ACH 3

Aromatic
Cl


Cl3
AlCl3


Aromatic
47. Electron releasing groups  E.A.S +M  EAS than -M III>I>II>Iv
48. Nitration of Benzene is electrophilic aromatic substitution reaction, then electron releasing
groups more favors than electron withdrawing groups

Cl

AlCl3
  AlCl4
1
49. methyl shift
2

CH 3 CCl3

50. CH 3  Cl 

AlCl3
 
Cl2 / hr
Exess


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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

CH 3 CCl3


Zn / HCl

Br2
Fe
EAS

Br Br

51. Conceptual
52. Conceptual
53. Conceptual 4

54. Conceptual
55. Conceptual

C CH 3

56.  7 Sp 2 .C

57. Electron with drawing groups are not favor to friedel craft alkylation & acylation
58. -NO, - Cl , Br- are weakly deactivate groups and O&P director for E.A.S
Group

59. The substituents show +M effect so, they are ortho, para directors for E.A.S
60. Halogenation to aromatic compounds is a E.A.S Reaction
So EAS  ERG
MATHEMATICS

61. Given P  x1  t  x2  x1  , y1  t  y2  y1  , z1  t  z2  z1   divides the line segment joining points

A  x1, y1 , z1  and B  x2 , y2 , z2  externally Let P divide AB in  :1 ratio where   0.

t t t
Using section formula weget     0  as   0  0 t  0 or t  1
1 t 1 t t 1

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

a p 5 4 41
62. A   2,4,5 B   3,5, 4 a : b   z1 : z2  5 : 4  5: 4 p : q   y1 : y2  4 :5    
b q 4 5 20

a  b  c  3 ˆj  kˆ
63. a   b  c    a .c  b   a .b  c rq vector  
a  b  c  10

 a b c   a b c   a b c 
64. p.  a  b   q .  b  c   r .  c  a   a .b   a  c  2d    0  0  0
 a b c   a b c  a b c 

=1-1+1=1

65.  a  b    c  d    a b d  c  a b c  d 
  a b d  c  0   a b d  c a , b , c coplanar  a b c   0 
3 3
Now a b d   a b sm 6i d  1  1.1. .1.1 1  
2 2

 a  b   c  d   
2  iˆ ˆj kˆ  iˆ  2 ˆj  2kˆ  
   
3  6 3 3  3 3

66. 3a  5b  2c  0

 a , b , c are coplanar b  c and c  a are perpendicular to the plane certainly a , b , c

Hence b  c c  a   b  c    c  a   0   a  b   0  0

 5
67. G   0, 1,  A   2,3, 4 B   3, 4,2 C   2, 5,1 D  4G  A  B  C
 2

  3, 2,3
73
GD 
2

68.  a  b    c  d   5c  6d Let r  a  b  r   c  d   5c  6d   r .d  c   r .c  d  5c  6d

  a b d  c   a b c  d  5c  6d   a b d   5, a b c   6  a .b   a  c  2d 

  a b a  c  2d    a b a    a b c   2  a b d   0  6  2  5  = 4

69. Given A  1,2,3 B  3, 1,5 C   4,0, 3 AB  17 BC  66 CA  49  7

As AB2  CA2  BC 2  C is right angled at A S  mid poin of BC

 7 1 
  , ,1
2 2 

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

P1   x1 , y1 , z1  P2   x2 , y2 , z2  P3   x3 , y3 , z3  Let x2  Rx1 x3  R 2 x1 y2 Ry1 y3 R 2 y1

70.
x1 y1 z1
Now Rx1 Ry1 R 2 y1  0  p1 , p2, p2 are collinear
2 2 3
R x1 R y1 R z1

71. AB  BC  CA  6  ABC is an equilateral Triangle.

H  G  S  I H  G  S  I  4G   8,8,8

72. AB  BC  CA  6 ABC is equilateral  G  H  S  I  3,1,4  OS  0.

73. 4m  n  22 17m  4n  93
Solving above two equations, we get m=5 and n = 2
 A is a square matrix of order 5 and | A | = 5-2=3

Now, we know that adj  KA   K n1 adjA, where A is a matrix of order n

  mA   adj  5 A   551  adjA   543  adjA  Again, adj 54 adjA  

  54  adjA  adjA  516 | A |52 . A  51633 A
4

Now, det  n adj  adj mA    det  2.516.33. A 

  2.516.35  det A  25.580.315.3  25.580.316  65.580.311

 a  11, b  80 and c  5  a  b  c  80  11  5  86

 5 2 
74. A   5,0,0 B   0, 2,0 C   0,0,6 G   , , 2
3 3 

AG AG 4 8 21
75. AP  AG  4  16  4  64 
3 3 3 3

76. By vertical angle bisector theorem

AD divides BC in the ratio of BD:CD=3:13
77. Let ABCD be the rectangular sheet whose corner ‘C’ is folded over along EF so that to reach
the edge AB at ‘C’ Let EF  x FEC    FEC 1  

In BEC1 BE  C1E cos    20   x cos  cos 2 BC = BE+EC  1   x cos  cos 2  x cos 

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

1
x
cos  1  cos 2 

x is minimum when cos 1  cos 2   in maximum

Let Z  Cos 1  Cos 2 

dz
 2 cos  sin 2   sin  1  cos 2 
d

dz
For Maximum 0
d

 d 2z 
 Sin  2  3sin 2    0
2
 Sin   as Sin  0  Now  2   0
3  d 

2 1
 x is minimum when sin   Minimum of x 
3 Cos 1  cos 2  

1 1 3 3
  
Cos  2 Sin 2  1
.2.
2 4
3 3

78. f 1  2 f  2   3 f  3 .....  xf  x   x  x  1 f  x 

where x  2 with f 1  1.We have for x  2

f 1  2 f  2   3 f  3  .....  xf  x   x  x  1 f  x 

Now we will replace x by  x  1 , we get

x  x  1 f  x    x  1   x  1 x  2  f  x  2  f  x  1

x 1  x  2   xf x  x  1 f x  1 x  2
        
f  x  1 f  x  f  x

1 1 1
f  2   ; f  3   . Now, f  2022  
4 6 4044

 1 
Similarly, f  2028  
 4056 

1 1
So   4044  4056  8100
f  2022  f  202558 

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 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

79. Since, the given vectors are coplanar.

 1 1
1 2  0   10  4   1 5  3   1 4  6  0  10  4  5  3 10  0
3 4 5

 10  5     4  5     5  3  0     5
 50  10  20  4 2  5  3  0  4 2  27  45  0  4 2  12  15  45  0

15 5
  4  15   3  0    3 and      2 and  
4 4

  25 225  
80   2   2   80  4  9    
458
  

 16 16  

16
 80  2290
  , S

 a  2 x    3 x   0 from 
1/3 1/3

80. We have, l lim 1/3   By, L’ Hospatal’s Rule’ we have

c a  3a  x    4x  0
1/3


2 3
2/3 
 3a   3a   2 . 2 1/3
2/3

1 4  
 3 9
 4a   4a 
2/3 2/3

 1   2   1995  1 1
81. f  x   f 1  x   1 f  f   ........  f    997.5  =997
 1996   1996   1996  2 2

82. Draw graph and find out No. of points of intersections

  2 r 
   
 
r
K
6r K
1   3  2
83. S k   tan 1  2 r 1 2 r 1  by3   tan
2r
Let    t
3    2 r 1
  3
r 1 2 r 1
 3
2
 1 
  3  

 2t 
 t k 1
3    2t  2 2
K K
  tan 1     tan 1  t   tan 1   S k  tan 1    tan 1  
2t  r 1   3  3 3
r 1 1  t 
 3

2 3 a

S  tan 1    tan 1 0  Cot 1    Cot 1   a  3
3 2 2

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Sec: Jr.C 120 Page 12
 SRI CHAITANYA IIT ACADEMY, INDIA 09-12-2023_Jr. C-120 __Jee-Mains_WTM-23 _KEY & Sol’S

2 n Lcm of 2 , 2 n 
84. Period of Sin nx  Period of Sin  2 n f x 
n x period of HCF of n,1

Period of   x cos  ca 2  2n Now 2n  4  n  2.


85.
 
  
1494  : Let v   a  b   2iˆ  ˆj  2kˆ   iˆ  2 ˆj  kˆ 

 v   2    iˆ   2    ˆj   2    kˆ


Now, v . 3iˆ  2 ˆj  kˆ  0 
 3  2     2  2       2  0  2  8  0    4


We have,   19  
v .a  
 2    iˆ   2    ˆj   2    kˆ  . 2iˆ  ˆj  2kˆ
 19

a 3
3
 57  4  2    2  4  2  9  2  57  38  57    and   6
2
  3  3 
 v   12   iˆ  9 ˆj   12   kˆ  2v  21iˆ  18 ˆj  27 kˆ
 2  2
2
 2v  212   18  27 2  1494
2

86. A3  0  I  A  f  A   I  A  f  A   I  A I  A   I  A  A2   I  A   I  2 A  2 A2

87. ABCD is a square AC  BD  BD  3 2

iˆ ˆj kˆ
a  b  2 1  1  2iˆ  2 ˆj  kˆ
2 2 2
88. a b  3 c a  8  c  a  2c .a  8
1 1 0

 c  1 Now  a  b   c  a  b c sin 30 

3
.
2

 26 
D = Midpoint of BC AB 2  AC 2  2  AD 2  CD 2 
3
89.  2  20  2  AD2    AD 
 4  2

90. Clearly OA=OB=OC O  Circum center , but given O=orthocenter

Circum centre = orthocenter ABC is equilated        60

  Cos  2       1  3 .

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Sec: Jr.C 120 Page 13