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Chemical Kinetics Formula Sheet (Edustudy Point)

The document discusses key concepts in reaction rates and kinetics including: 1) The rate of a reaction can be expressed as the decrease in concentration of a reactant (R) over time or the increase in concentration of a product (P) over time. 2) The order of a reaction refers to how the rate depends on the concentrations of reactants, represented by x for reactant A and y for reactant B. 3) Reaction rates follow characteristic equations depending on if they are zero order, first order, or another order. Key equations are provided to calculate rates and half lives.

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28K views4 pages

Chemical Kinetics Formula Sheet (Edustudy Point)

The document discusses key concepts in reaction rates and kinetics including: 1) The rate of a reaction can be expressed as the decrease in concentration of a reactant (R) over time or the increase in concentration of a product (P) over time. 2) The order of a reaction refers to how the rate depends on the concentrations of reactants, represented by x for reactant A and y for reactant B. 3) Reaction rates follow characteristic equations depending on if they are zero order, first order, or another order. Key equations are provided to calculate rates and half lives.

Uploaded by

sadguruply88
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Class 12 th

CHEMISTRY

Designed by

Edustudy point
❖ Rate of Reaction
𝑫𝒆𝒄𝒓𝒆𝒂𝒔𝒆 𝒊𝒏 𝒄𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝑹
= 𝑻𝒊𝒎𝒆 𝒕𝒂𝒌𝒆𝒏

𝑰𝒏𝒄𝒓𝒆𝒂𝒔𝒆 𝒊𝒏 𝒄𝒐𝒏𝒄𝒆𝒏𝒕𝒓𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝑹
=
𝑻𝒊𝒎𝒆 𝒕𝒂𝒌𝒆𝒏

−∆ [ 𝑹 ] ∆[𝑷]
= = K = Rate constant
∆𝒕 ∆𝒕
x y
Reaction:- A + B → Products ⟹ Rate = K [A] [B]

❖ 0rder of Reaction
= x + y
X = order of Reaction with respect to A

y = order of Reaction with respect to B

❖ Zero order Reactions


[𝑹]० − [𝑹]
K = 𝒕

❖ First order Reactions


𝟐.𝟑𝟎𝟑 [𝑹]०
K = 𝒍𝒐𝒈 [𝑹]
𝒕

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For more formula sheets visit @Edustudy point


❖ Half life of a zero order Reaction
[𝑹]०
t1/2 = 𝟐𝑲

❖ Half life of a first order Reaction


𝟎.𝟔𝟗𝟑
t1/2 = 𝑲

❖ Integrated Rate Equation for a


gaseous state
𝟐.𝟑𝟎𝟑 𝑷𝒊
K = 𝒕
𝒍𝒐𝒈 𝟐𝑷𝒊 − 𝑷𝒕

Ea = Activation Energy

A = frequency factor

❖ Arrhenius Equation
K = A e-Ea/RT
𝑲𝟐 𝑬𝒂 𝟏 𝟏
𝒍𝒐𝒈 = 𝒍𝒐𝒈 =൤ − ൨
𝑲𝟏 𝟐. 𝟑𝟎𝟑 𝑹 𝑻𝟏 𝑻𝟐

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For more formula sheets visit @Edustudy point


❖ Collision theory of Chemical
Reactions
𝟏
Rate = = P ZAB e-Ea/RT
𝝆

ZAB: The collision frequency of rectants A and B

P: Probability factor

e-Ea/RT: Fraction of molecules with energies equal


to or greater than Ea

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