CH,

-C=
,CH, CH; of mole
of
O
Stability [Ag
][!]
CH1 = i)H O,
of -0.152V [Agl]
-CH - E=-0.80
V. -0.952V
(n =2
n -CH,2CH;
-CH,
CH,
,CH, z I1 - 3n-1 L
C0, required 10 35
13n (X) C1Ak.
KOH_,CH,
=CHi2 AgI log1o
halide lIll 2 -35 : (Y) E°=
-Hlr 60 -CH, equilibrium)
required = 0.80
El-0.152-
0.0591
-c-b
2Peactivity
alkyl :alkee alkane 2 30n I.
10:35 CH, - Agl
-B
CH,
(M-- -Ch,-r
-CH,
CH of alkane 35 =70: +e
-e’Ag
-#
HC1, an is Ag" reaction =Ecell
Ecell at
Peaciivity
ofStab1lity of 10
alkane
30n
+ 0
mole 10Lof -1
3r [Ecell
alkene C,H2,-2| 2 So. Agl Ag Cell
I
(4) (2). (4).(i) (i)
(6) (7) 8)
2
zidethe "} thoe is
carbon ít
so
internedíate
screaes.
dwn
(12P, =(n2P abent,
1.
ff) of 15
iven
by
4 in
COtnipOunds
which Ph-C-CH
-CH; CH-
CH,
N02 H,-CH-
NO; III>I>>[V
22
produce
nature roving »(a2P,' nitrogen.
is test.
Ph--CH
-CH;
ZIdes *(n2!, carbon of :c>b>a>d
order
Stability
yl tdues basiL Lassaignc's
Na,)-M)
AI,0, with CH,
Stability CH,
wll of
NT'
perid, natute ' (n2P,*}test along
HCI,
, while (o2P,12P, (b) :order
211,) st NH,givez
a pas hassc nitrogenouS
cdetm Darnagretic -C
CH-CH;
Ph CH,
Ph--CH-
f thedecteaes
clectm
(62,"-(2). preent Rcactivity
Lassainc's carbocation
Ph-CH
CH, Ph-CH-
CH,
f NH,- Rcactivity
a, yn14 gm 22444 Aloig Proup, not
22 19 also does E
Ph (c)
64
(2),
N In Ph
(2), (3), (2). (a)
(2) (3) (4) (5)
 H,0 ’CaC,0,+
2CH,COONH, S0,‘
H,0 2CH;COOH
2NaCl (Y) +2NaCI
’H,S1
+ Cr(SO,
)> ireen BE.
CO, CH
H +
(I) + (NH),C,0,
(CH,CO0),Ca
+ HO H,SO,
- + B.L.
(CH;C00),Ca CHH
H PbSBlack
than (Z)
OH CH SO,
HSO,
K,Cr,0. ’
less
be
2CH,COOH (white
ppt.)
HNH
’ B.O.
is will CH Pb B.O.
effect
-I II|>|>||>
IV
2HCI
Na.SO, Na,S+ (CH,CO0),
2HCI Molecule 2.5 2.5
butstable ’ Orange
3
-I -I +
extra
of andMostCH, OMe CaCO,
(A) (B) N N N; NË
No M +M +
+ -I(III) C H,S
(IV) (4). (3) (2).
(17)(2).
(18) (19)
(l). (4).
(20)
(I) (II) .. (16)
(15)
3
4d
CH;COOH
+ benzylic
energy.
of
size
H same.
acid.(B(OH)4)
+ C-OC,H,
CH, of bond
--16.11 NH-C-CH;
contraction -Br
monobasic approx. NH, CH, stability
the
Ksp
P,010
CH; C;H,ONa
C,H,OH be
log10 0.0591
0.952 C0, elements
Lanthanide CH-ÇOCH, -0C,H, will
CH,-C-CH,-C
weak + NH-
C
CH, H the
0.0591 > N,0,> H,BO,H,0 Acg0 H, less
S0,
or
log
Ksp a series Br
CH, CH, is carbocation
CI,O,>is
= > H,BO, to NH, CH; More
cell SO, Due
5d C
E & CH:CO0H (13)
(1). (1). (3). (12)
(3). (3). (2).
OT Brn
(10) (11) (14)
(9)
 benzene axial
B.M.
24 dichloro weaker
molecule.
F
Be eF 20°CPCI
Equatorial
bond
=
J4(6) structure. CI hence
2. pm
mer fac -
4 bond
Axial reactive
3441111
= 1, pm
202 and
2)B.M. symmetrical
&
CO, 0tco 240:bond longer
ais
gl n=4 202
p1n
2
has
(n+=B.M.
4.90
BeF,,
Clh90° bond:
Equatorial PCl,
= =n all -0 CI 180° to
Ma,b,
Crt2 BF3,are
F B
240
pm
C
True
(a) True
(b) True (d) Duebonds,
(c) Axial False
fac nicr
CI CI
P
In 24.
2. . 4.
1.
(28)
(25) (26) (27)
4
=150 =TAS 60
AB,(g} acid) association)
=
[Fet|[sCN|
0.1x0.2 2CH,COOH acid
(CH;COOH))
Gx60+x40
AH g, (acetic a/2
massmolecular
acetic mass
Observed
FeSCN?1 3 . 20
0 X =9L’ (SR =0 K = =
500 0.2
5.12
x
+B,(g) mol-! W2 =113.78 of molecular=1-a+ 94.5%
3.2
-x [FeSCN*2] V 110 AG
W
X xW, 20x
M
of
=1-a+
x (Sp-
g, Kf M After degree
association
Before association
weight
3.2 10-2 +20 =0.2
JK-lequilibrium
1000
×
=N,V, = -40 AT,=0.45°C
x 1000x
is Normal
or
Fet
+
SCN x =3.0
-
X
mol = L V, (g) 2 AH
=-
20KJ
40 W,
1000 M(observed)
a
Molecular M(observed) =0.945
M(nomal)
3.1 3.1
=0
Att
=
K,
1 10
x = -V,
N,V,10-1 SA, E 50 =-
= = Given: =
AT; 0.45
= (where 113.78
eqm. AS T= 50
V, so AS Ae a
(21)
6. At 9. 5.(23) 4.(24)
(22)
 (29) 5.
Tsina = mgsin@cos) ..(1)
Tcosa =mgcos²0 ...(2)
CH,-CH, - Ç- CI,
CII,ClH, tan a tan 0 ’ a
(33) (3). Assume 3perpendicular axis I,. I,, and I,
where I, is diamctcr of the ring and I, = I,
MR?
alc. KOH CH,-CH =Ç-CHi, - CH, -CH, 21 + 2MR2
2
(-HBr) 3
cis + trans = 2 products I=MR?
CH, -CH, -Ç=CH- CH, CH, (34) (2).

cis + trans = 2 products

N.

CH,-CH, -C-CH, - CH, -CH,

N
1product
mg
Total S products.
(30) 84.
N, can only be balanced by f,
Conc. NaQH
H0
Zn CH,OH But f, can be zero, as in vertical mg can be
(P) (O balanced by N alone.

(35) (1). GM m =0: GMm

LiAlH, ÇH,OH cH;coCi pH -0-C- CH, Re (R, +h)
CH,OH (Cxcess) CH, 0 -C- CH; mgR
Mol. weight (R) = 62,
,m4 (Re +h)
Mol. weight (S) = 146, Ans. 84 mgRe
4 -mgRe mgR
R +h
Af Au Av
(31) (4). +

3mgRe mgR
Au= Av for optical bench 4 Re+h
2 dy 3R, + 3h =4R, ; h=R/3
x d(Af) au
Au du Jior min error (36) (1). y = f (x ± c : t) is the general wave
=0 equation At t=0,
dy 3 y= f(x) ’y=
du
1
for u= 2f, error is minimum. y= = f(x-1)
Tcosa
tmgsin'0
V2-2x +x? +(x-1)
T
mgsin®(pseudo) f(x- ct) =f(x -1) at t= l’c=lm/s.
Tsina mgsincose

(32) (1). me
 (37) (3). A¢ = 2nn
27 dsin= 2nt &
2

2n Asin r=mv/(qB). so, Vmin rqBnin

5x 1072 xL.6x10 x0.01
min

0-(2n-a2x3% 12
sin 9 1 9x 0-3|
x 10 m/s
1
V100) 12 (43) (1).

144y2 = (1002,) ; yz 1002 252

12
(38) (3). Rate of absorption = Rate of
Pab + Pab P.em emission
eA o T = eA o T, = eA o T
Tp =Remains constant as (To (44) (1).
and T) are
constant. Aci+ dË
(39) (1). Let x mole of the gas dissociate at 1000
KNo. of mole of diatomic gas
molecule
H Sin r
=1-x
No. of moles of monatomic gas
molecules ai +bËi
=2 x x
Energy of diatomic molecules As ai + bË and ci+dj are unit vectors
= energy of monatomic molecule their x components represent sin O
’ (1-x) 5 RT= 2x xRT
3
x=5/I1
1.5 sini=2 sin r
4
Now new no. of moles a =x1.5 =2 xc:
=(1 - x) +2x = l+x=(l6/11) (45) (4). Let the image distance from lens be y
nRT
P=
V
(24-x)
300R
Pressure initially at 300 K=P;= 24-x
1 2
Pressure finally at 1000K -y -X 9 X (24- x) 9
(1+ x)R x1000 16
= Pe = 24x-x2
24 2
(40) (3). QE = Mg
+QE x-24x + 108 =0: x=6 cm, 18cm.
QV = W 1
l45°
d (46) (3). A1 =^2=
30 60
wd mg
Q=
V
2=A, + y ;à= 1/20
kr i ki N= No No No
(41) (3). E =pA :E= 2t/ 4
(2)
0.693
(42) (1). Suppose in 1st region radius of circular t=2t, =2x
path is r & in region 2this is r,. t=2x0.693×20 yrs =27.72 yrs.

6
 (47) (3).
A BX (53) 5.

q2uF

I
(48) (3). B.E. of A = 240 x 924uF
B.E. ofB= 100 x 7.6= 1824 MeV 8.1 =
B.E. of C= 140 x 8.1 810=1134
MeV
MeV
Net charge under dotted box shown
So Q =(810 + 1134) MeV- =-4, tq, =0
1824 MeV
(49)
= 120MeV Finally: VA= 25V
(4). Wattless power pso v
Wattless power =VIsino . 100
100 100
x sin
6 100
A
=2.5 x 103 Watt V2
=
qT2uF
6
(50) (4). At same spot so fringes coin side bov
n =ngag q=25(4) =100 C
3x 700nm =5 x ; y= 420 nm q', =25(2) = 50 uC
100 x 150 Net charge under the dotted box shown
(51) 2. Keg 60 N/mn -q t =-100 +50 =-50 HC
250
2.5 The charge which flows =50 1C
F= ke, X= 60 x N hc
100 2 (54) 4 eVo t o = 10 eV +2.75 eV
3
For left spring X= 2(100) =12.75eV
ho 12.75
3 But
For right spring X n 13.6
2(150) 10000
=0.0625 ’n = 16n=4
1 n? 625
150
100 (55) 2. - RZ?
Soso(9 20m/s Here (Hydrogen) (other)

(52) 3. (/2
As net external horizontal force is zero,
’Z=2
and initial velocity of system is also zero,
(56) 10. m cr
Mball XXball = Mplank Xxplank (backward) 2r
distance travelled by the ball is its m, =10g
5
Range, R=
u sin 20 (20)
2 10 2

7
 required
contact between so to one one -x?
identical, has 1)2
...(1) ..2) which 1)
12x.
on of chord +y=-4 subject4! (-x? -2x x-
= pointchord =0 in
C, cos² 2-(2cos
1) =4common 0 are -4 the
...) I (2)
Xt
y1 --(2
periods
repeated 1x- )
|-9x2x -
(9x anyof yy, - = 3 x of
2)y3 x+
X
+ is 1800 one
+1
3x cquation+ y2) andget y,) cos²1
2x
3x+1 -6= ’ be xx, of -(k- we Ss leasttwobe
2x cos²
comparing, = cos 2(2
2x 3 y) (k-(l) (x,,
4! S4
3
3x
+1 is equation
is,
circles
twoDx equation to x-4 =
g(x)
at repcated x-2 x-
3 X 2x
(1-9x) verify.
now(X,,Socircle
W.r.t.4, x- 2-k
of
locusSC,S,
X
2x = (k+ that is cost
-
3
X
+
3
H
Hence, -6 4x
y'
P locus. x2+ Also, 1)(k+ °C,-S, Note
subject
subject
cos 4cos
get
=
H
Also Let + As on k+1
So, S, 4 We
4 be 4 = =
H
(2). (2). (4).
(63) (64) (65)
8
the cos) 625
2cm 2
by n, B/D LA 24
diameter reflected, = - 25
4cm driver u=V/3. x ¢) 2
2
, water =0.15° 10 sin ) - G.P.
=2lp horn. the width x (7 (0- (0 Ymax
a k=: and in =2.2 = )x =
24 cos in
about
+ly
car,
the by
|-(u/V) or width0.2° 4/3
cm
68
sin® 24 sin )); H.P. are
: the received, observed V)-2n.
fringe )
incrtia mr=
mk2 2n, LAI cm sin =
tan .r
r=625; - - in X
l7 of ng 24 r ) (0 (sin2(0are
-Ip-Iy
-ly: =mr= of frequency - fringe
angular | 88 1.7x
88 =7; ( - sin
speed x 2.2 +
of Frequency Frequency u/ 1-u/VAngular
B D
Lou=105 cose 2 x
and
Moment = cliff
=
n n(1+ air
L I=(7cos
cos
x =r H
I,
2 4 u =
Let n, In acu 1.7 =
2 2
0.15. 68.
(3).yr y =
(2).
(62)
2. 3.
(58) (59) (60) (61)
(57)
 given dx be
x) so
ae(-1,
3) A2=|’A=A-I
ct|<4must
so (cos dx
theorem, (x-a-1)
In x
tan -1)
x+11)
dx dx 2
>I=n
T/3- | -
I 3 I 3 )x
sin
Sandwitch
x)
(cos dx
)xV3-tan
1+3
tan
x)
3-3
1+3
tan
x dx
a²
+
2ax1) andsimultaneously,
satisfied
-
+n)+I) +1)
1) (n'+n V3 T3
) In x) )x +3(a² + 2A
+ (cos x+ tan
(2n
(n'+n + T/3| a a-1>-2 =l»
(1+V3In2
(2n COS
X
- =3(x-
+) +) xncOS - In tan 3(x involuntary
(n (n
to
= n/3(
1/3.
limit
According King
use
dx
x) /3
+ Alternatively:
1+3 4 2 3ax=
x'- -() (2A)
n 6 n 6 cos dx f(x) Clearly,
Limon ’ Limn’ I= 0 (2 2 Iin2 (/3 =
In In f(x)
n/3So, is =
(). n/3 T/3 T/3
T/3
0 A A2
T/3
= 0 3
0 (1). (1).
(69) (70) (71)
9
n+n+n 1)
+ (n+n+1)
n? (2n
x-I 1),nel nr=l1'+2+....+.
+n+rn +1
n+n n+n+r
0 =0 (n+l)
X cos - -,1 2
when
(x1))
n 6
=
y
100 -3 where 2 6'2'6
x 1) 6 M |To
= -1)cos'0 of + V3 continuous
=0 ,keI. n+n+r
n’o n'+n+|
n'+n+2
values (2n +
+
r=1
(x 4 0,
g(g(100)) cos = (2n 2
1, 2
1-: x n
cos30== cos²x
cos²x
=- cos 12+2+.....
n
3y (3 1) = = ,0, 2 n+n+n +1) 6 (n+n'+n)
arc three
cos -1) 1) V3 V3 be 1): (2n
8(g(x))
= cos - (x -
Hence= 4y³ will
(x (x 2 2 =0 + +1)
2 : X=(2kn
Now,So, ..
y=t Alitercos-
Hence 1+
=
X cosx (68)
(1).
Lim
Let cos- cos (x) (n
3 f n
(4). (4).
’ ’
(66) (67)
 given
dx be
x) mustae(-1,3)
so dx (cos dx =A-!
thcorcm,
jdx
x cos
In
dx
x)
In
n/3 - |
tan
|dx 3-3
x
2 1x+-
I=In
1)
1) g?

(x |<4
a-1)
I’A -(9
I 3 x
sin
Sandwitch
x-dx-f
(cos dx W3-
tan
x 1+3
tan
x
dx 3(a²-
+
+ a so A'=
) 6 () n n + ) V3 n/3
In x) 2ax1) andsimultancously,
=
+ + +1) -| (cos + x) at
+|)(2n +)(2n
6n+n2
n’ +
COS
X
T/3 x tan 2 3(x² a-1>-2 =I=2A
x ) + 3(x-
cos
to dx In tan In+3 In 3ax involuntary
x) (1+/3 4 2 =
(n
n
(n
n
1/3. ( In]
According 2cos use
King
cos
T/3
+
dx
0 Alternatively:
21-( x'-f'(x) =
(2A)
satisfied
Lim Lim limitn/3 I= In (2 2
|In n/3( =
Clearly,
n’
-[
(1. n/3 )
In
=| T/3 /3 n/3
= f(x)So, is =
A A²
T/3 /3 0 0 0
3 (1). (1).
(69)
(70) (71)
9
n'+n+n +1) 6(n
+n+1)
1 neI
n2 1+2
+....
n (2n
O y=X- ,n
¬I n+n+r
n'+n+1
X cos (x
1)=0
|1+ , (n+1)
n+n+r
when
7
100 -3 where 2 1)
2 2
n
cos0 x 1) 5TT 62
6 continuous
- x= of + W3 =0
values (2n + ,ke
l. n+n+r
+n'+n+1
n'+n²
+2 r=l
r=l
g(g(100))
(X 0,
4 cos (2n 1,
1
2
<
cos= = 2
=
(3 1) = = x
cos²x
cos 2 2+2+..t
n2
arc30 -3y ,0 three
cos (x- 1) cos(x-l) 0,
, be 2
n+n+n +1) 6(n
+n+n)
g(g(x))
cos - V3 ’ 1) (2n
Hence= Now,4y : (x 2 2 will- 0
(68)
(1).
Lim> ++
2 Hence 1+.
X=
.. =
O Alitercos- cos²x= (2k n’o, (n+1)
Let So, y= cos (x) cosxx=
3 f
(4). n
(4).
’ ’
(66)
(67)
 sl we
....4) 10
-Sx=
a (i1),
b-
=1 1R3. .....() ...(ii) &
....(3) and 2 is ()
tt, t;=-1 x-y=3 RI
but
and
symmetric not c
KPth,
k) point
t, get
we
1
b|< but (given) is or+2)-28
subtracting n
’ ’ 0 -
anti-symmetric.
2R31] about is =18
-(2}' 2about10=
ox,-2)
lin = -2+h-k=0 -2
2
=2 -1
’ is
and|=2>
(2), R a is transitive.
(4) -k k), e ’ R deviation about deviation
t and h)
t,+
1I
P(h,a=0<
a
all is
reflexive
aRb.. R IR2 -c and
2 t, -
=-
Put IAgain,
2 |1-3 Deviation
(3) -1-1(2 of for not Further, not Adding
Given From Locus Ra Again
|a- ’bRa Since n i l Also, i=l
obtain
R
is
R
[: isR 1D n n Il
(1).a (1).
1
(76) (77)
10
is
2q) q)¢
even are
cases b 59 125 ..2)
pb+që) c or = is
+ is and a P(E,) 2at)
+ (2
(| b
tWO
of e so
3/5 even)
=
2/5 or 125 = (at, k),
+
2(£+2p)b+p)b in b 27 one 32 y
a a,
atleastoccurs
125 +
P(E,) then
+
=
odd) number atleast at P(h,
)+ + (2q 2+4=1
q+2p
l+
2q odd 16 25 normal
(q
qb+ + I)a + +3 +3
2q
p+q+2p+ is (number
chosen
is all andeven;can -(PE) 2 5 = 21-) 1
=
E,) 0 =C IfxC’C=0
....(1)
through
-k=0
2)ä 2q chosen and =
2q
+p+ areeven E three
+ =(p+ =(2p
(pa + 2p event even
9 or y) =C. of atequationpassesh)
’p=
|
1&q= a,b,c,is
even
tc) the
P(E, (In dy +
2at -
= _P+q+ (number is y)y t(2a a=1
Here,
+2ri+2r, p+22p is
c thatAl is =
P(E,) = + In =
e) = (1)
2+ +1 c E:(ab c P(E) tx
+ Note
E,: odd: E,: even (x
dy
In
In(In
dx The
dx y+As +
P P ab (74)
(1).
x X at
(4). (2). (2).
’
(72) (73) (75)
 mostof k2-=
integral
-2x
1)<0
(3-x)=(-xX3-x) 27 16
1;b-
6.
at
number (let)
meet

=
k
of 3x 1].
-p
bxË mnaximum
|Z-22|
25
k>0 = y p 6
[0. <0=p(p-
’Number
y 3x² 1-x) = can i.e. 5
ande x) Sx,
parabola
p -
2x³1) C,
’
=proots
1}
1] {0.y three
-
= (x f(1) dx
-
|
=
)K.
bx. o(0.0)
(x,.0)
(1.0
-tA,
16
A, Thus
+ X) a points. in 16
and
k-
22-2
(0. is of
f(x)
=6x (bx') bx2 A| chords 4
0<
=
f(x) As, (1-x)(3-
A and
kek graph for Let
f'(x) f(0)1] (
pe[0, (As,
of
Hence. : bx (0.1 circle common
Hence Draw
values Aliter Now, A,- 6
four
3 9
1 16
A in
6. Aj A
2. (84)
6. (85)
0.
(82) (83)
11
JPI.2,3)
23 36
=9
o=
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