Sec: JR.

IIT_*CO-SC(MODEL-A) Date: 21-01-24

Time: 3 Hrs Max. Marks: 198
21-01-24_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-21_SYLLABUS

PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 20-01-24

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 20-01-24

MATHEMATICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 20-01-24

Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 24) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 25 – 30) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 42) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 43 – 48) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. Let R be the radius of the circle passing through the origin and cutting orthogonally each
2R
of the circles x 2  y 2  8y  12  0 and x 2  y 2  4x  6y  3  0 . The value of is equal to
5

2. Let P(, ) be the orthocentre of the triangle with vertices A(3, 4), B  13, 2 3  and


C 2 5, 5 . 
The value of [] is equal to (where[.] is G.I.F.)

3. For x, y, z, t  R , if sin 1 x  cos 1 y  sec1 z  t 2  2 t  3 , then the value of

  2 
sec  tan 1 x  tan 1 y  tan 1 z  tan 1  t   is equal to
  
  

4. Let P(x)  0 be a fifth – degree polynomial equation with integer coefficients such that
P(2)  13 and P(10)  5 . If there exists an integer k such that P(k)  0 , then the value of

k  12 is equal to

5. Let f(x) be a three times differentiable function (defined on R) such that f(x) has at least
five distinct real zeroes, then minimum number of distinct real zeroes of the equation
f (x)  6f '(x)  12f ''(x)  8f '''(x) = 0 is / are

6. If the length of the smallest path that can be traced from the point (0, 0) to the point

 
2  1, 1 without traversing inside the curve x 2  y 2  2 2x  1  0 is of the form

a
 b; a, b  N , then value of a  b is equal to
16

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
7. Let F be the family of circles passing through the points A(3, 7) and B(6, 5). Which of
the following is/are true?

A) If P is a point on the circle of the family F with least area, then PA 2  PB2  AB2

B) Only two circles of the family touch the x -axis

C) For every point on the line 2x  3y  27  0 the, powers are equal with respect to every
member of the family

D) If every member of the family cuts the circle x 2  y 2  4x  6y  3  0 , then the variable

common chords pass through  2, 

23
 3 

8. Let f (x)  cos 1 (cos 2x) and g(x)  | cos x | . Then

A) Number of solutions of the equation f (x)  g(x) in [0, 2] is 4

B) max{f (x), g(x)} is a periodic function

C) min{f (x), g(x)} is non -differentiable at 9 points in the interval [0, 2]

D) min{f (x), g(x)} is an even function

 
9. Equation of the plane passing through the line of intersection of the two planes r .n1  q1
     
and r . n 2  q 2 (where n1  n2  0 ) , and parallel to the line of intersection of r. n 3  q 3 and
 
r. n 4  q 4 is

  

 n1 n 3 n 4 
A) Is independent of the value of the ratio   
n 2 n 3 n 4 

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
  
 n1 n 3 n 4 
B) Is dependent on the value of the ratio   
n 2 n 3 n 4 


C) independent of q1 and q 2

D) independent of q3 and q 4
  
10. Let a, b & c be variable vectors of lengths 1, 2, & 3 respectively. Define the expression E
as follows;
        
E | a  2b  3c |2  | b  2c  3a |2  | c  2a  3b |2

Then, E can assume which of the following value(s)?

A) 30 B) 100 C) 200 D) 250

11. Consider a function f : A  B such that n(A)  a, n(B)  b(a, b  N) . Which of the following
statement(s) must be CORRECT?

A) If f is one – one and onto, then a  b

B) If f is one – one and into, then a < b

C) If f is many – one and onto, then a > b

D) If f is many – one and into, then a < b


 e x  1  ax
 , x0
 x2
12. Let f (x)   b, x  0 . Then
 x
 sin
 2 , x0
 x

1
A) f(x) is continuous at x  0 if a  1, b 
2

1
B) f(x) is discontinuous at x = 0 only when b 
2

C) f (x) has a non – removable discontinuity at x  0 if a  1

1
D) f (x) has removable discontinuity at x  0 if a  1, b 
2

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
cos x cos 2x cos 3x  cos 4x cos 5x cos 6x
13. The value of lim is equal to
x 0 1  cos 2x cos 4x cos 6x

Let f(x) be a polynomial function such that f (x)f    1

1 f (x)
14.  xf    x  R  0 . If
x x x

f (2)  30 , then the value of f (3) is equal to

n
2k (k 2  2k  2)
Let Sn   
62
15. . Then, the value of (Sk  1)  2 m , where m =
k 1 (k  1)(k  2)
k 1

3 1 3 3
16. In  ABC , if cos A cos B cos C  and sin Asin B sin C  , then the value of
8 8

tan A  tan B  tan C  tan A tan B  tan B tan C  tan C tan A is equal to

 2 0 0
1
17. If adj A   1 2 0  and | A | 0 , the value of tr(A) is equal to (where adj (A), tr(A) and
2
 3 1 4 

|A| denote adjoint of A, trace of matrix A and determinant of A respectively)

18. Let x, y  (0, 2) such that 2 sin x.sin y  3cos y  6 cos x.sin y  7 . Then, the value of

(tan 2 x  tan 2 y) is equal to

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
 
19. By applying a force F   3xy  5z  j  4zk N a particle is moved along the path y  x 2 from
point (0,0,0) to the point (2,4,0). The work done by the F on the particle in joule
is  2x  3y  5z  . The value of x  y  z is equal to(all distances are measured in metres)

20. A fixed tube with thin but uniform cross section has two arms, one straight, other shaped
as a semicircle of radius R. Initially both arms carry an ideal fluid up to a height R. Now
the equilibrium is disturbed by pushing the fluid in the left arm by a small amount. Fluid
is then released and allowed oscillate. Neglect any friction or viscous forces. If the time
nR
period of oscillations is found to be T     m  ; find the value of m+n.
3g

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
21. In an Atwood machine setup the data is given by m1  103.5  0.2 gram and

m2   43.5  0.2 gram and g  10.00  0.01 m / s 2 is the acceleration due to gravity. The

maximum percentage error in calculation of acceleration of blocks is 1   % . Find x .

x
 30 

22. Consider a uniform sphere of charge with charge density  and radius R. Divide the
sphere into two hemispheres by an imaginary plane. Let the force of repulsion between
 2 R 4
the two hemispherical portions be . Determine n.
2n 0

23. Out of the three conducting identical plates, middle plate is given charge 3  C and other
two plates are not having any charge. If switch S is closed. Find the magnitude of charge
passing through switch S. (in  C ):

24. One mole of oxygen is contained in a rigid container with walls of inner surface area
A, very small thickness d and thermal conductivity k. The gas is at initial temperature
T0 and the surrounding temperature of air is 2T0 . Find temperature of gas at time t (R is

the gas constant)

 
x Ak
t 
If your answer is T0  n  e y Rd  report the value of n + x + y. [ x,y and nare smallest
 

natural numbers to fit the context]

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
25. Two identical discs, each of negligible mass and radius r     are connected by a
uniform rod of mass m and length  as shown in the figure. The disc A is connected
with an ideal spring of spring constant k at its centre. The spring is un-stretched when
  0 0 . There is no slipping at any contact at any point of time during the motion. Choose
the correct statement [Spring always obeys Hook’s Law and mg  k ]. During the
motion, each disc remains in contact with the contact surface.

A) The value of  , when the system is in stable equilibrium is 600

B) The value of  , when the system is in stable equilibrium is 300

kl 2
C) Spring potential energy of the system in the state of stable equilibrium is
8

D) The angular speed of the rod when it passes through the position of the stable
3g
equilibrium is
4l
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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
26. A car-A is moving along positive y-axis with uniform speed 6m/s and car B is moving
towards negative x-axis with uniform speed 8 m/s. At t = 0, car-A is at origin and car Bis
at point P(50 m,0). Choose the correct option(s). If v indicates the rate of change of
distance between the two cars A and B as a function of time.

C) The minimum distance between two cars is 40 m.

D) The minimum distance between two cars is 30 m.

27. One mole of a diatomic gas is taken through a process A  B as shown in the figure. The
gas obeys the relation QA B  WA B  O, where Q and W represents standard symbols

A) the molar heat capacity for process AB is 5R/4

B) the heat supplied in the process is (5/2) P0 V0

C) for A to B, temperature initially decreases and then increases

D) the temperature goes on increasing from A to B

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
28. Two blocks of masses m and 4m lies on a smooth horizontal surface connected with a
spring in its natural length. Mass m is given initial velocity V0 as shown in figure. Which
of the following is true about mass m during its subsequent motion?

A) Whenever KE of m is maximum in CM frame, the KE is maximum in ground frame

also.
B) Value of maximum and minimum kinetic energy is same in CM and ground frame.

C) Minimum kinetic energy is zero in CM frame but non-zero in ground frame.

D) Maximum and minimum kinetic energy of m in ground frame are, respectively,

1 2
mv0 and zero.
2

29. A light and thin rod of length  is lying on horizontal table. Two small balls of
masses3m and m are fixed on the ends of the rod. The rod is free to rotate about fixed
vertical axis passing though midpoint of rod. A third ball of mass 2m is fastened to ball
of mass m through a string of length  as shown in figure. The ball is projected
horizontally with speed V as shown.

18 v
A) The angular velocity of rod, just after the string becomes taut is
59 l
9v
B) The angular velocity of rod, just after the string becomes taut is
59 l

5 mv
C) The impulse imparted by string is
59

60 m v
D) The impulse imparted by string is
59

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
30. Consider two solid spherical asteroids of uniform density of mass M and radius R. In
one asteroid a tunnel of very small size of depth R is bored to the centre and in other
asteroid a spherical cavity of radius R/2 is made as shown in the figure. Now, identical
particles of mass m are dropped into the cavities of both asteroids from the top most
point P. If force experienced by particles are FI and FII respectively in cavities of
asteroids I and II, when they are x distance away from the centre of asteroids and If the
time taken by particles to reach the centre of asteroids is TI and TII respectively then:

A) The ratio of FI / FII is equal to 2x/R B) The ratio of FI / FII is equal to x/R

C) The ratio of TI / TII is equal to  / 4 D) The ratio of TI / TII is equal to  / 2

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. A copper wire of length 'L' is suspended vertically from the ceiling by one of its ends. It
is made up of a material of density  . Young's modulus Y and radius r. The elastic
 r 2  2 L3 g 2
potential energy stored in the wire due to its own weight is , where k = ___
12kY

32. A U-tube of base length  is filled with equal volume of two liquids of densities and
2is moving with an acceleration "a" horizontally with the tube on a vertical plane. If
the height difference between the two surfaces (open to atmosphere) becomes zero, then

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
Xa
the height h is given by l , then X  ______
g

33. A positive point charge +Q is located somewhere inside a vertical cone such that the
depth of the charge from the circular base area of the cone is H as shown in the figure. It
is found that the amount of electric flux through the curved surface area of this cone is
4Q
. Now, an extra point charge q is placed vertically above the existing +Q charge at a
7 0

distance 2H above +Q such that the amount of the total flux through the curved surface
2
9Q  12 q 
area of the cone changes to . Then the value of   is
7 0  Q 

34. A ball is dropped from a height h on a inclined plane, ball collides elastically with the
first plane. Find the value of ' h ' (in meter) so that it strikes perpendicular on the second
inclined plane

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
35. A container of mass 200 Kg is moving towards right by applying a constant horizontal
force 100 N. Initial velocity of container is zero. Sand is falling in container with a
constant rate of 1kg/sec with the help of fixed cone as shown in the figure. Find the
velocity of the container (in m/s) at t=100 sec(assume that container is long enough).

36. A dense liquid is completely filled in a closed large container and kept at rest on a
horizontal surface. A steel ball is moving downward with a constant speed of 0.5 cm/sec.
Find the momentum of dense liquid in C.G.S unit, if its density is 3gm / cm3 . . Given that
volume is steel ball of 1.5cm3

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
37. Among the molecules CH 4 , PCl5  g  , PBr5  g  , PCl3 F2 ,ClF3 ,CO 2 ,SF4 ,SF2Cl2 ,CCl4 ,SCl4 and
H2O . The number of molecules having different bond lengths are

38. Two transparent glass flasks ‘A’ and ‘B’ of volume 13.2 litre and 26.4 litre respectively,
connected by a tube of negligible volume. Fitted with a stopcock. Flask ‘A’ contains
32gm CH 4  g  while flask ‘B’ is filled with 71 gm of Cl2  g  both 336 K. The assembly is

irradiated by sunlight, when stopcock was opened. Assuming that CCl4  liq  and HCl(g)
are the products and yield of the process is 50%. Find the final pressure in the container
(in atm). [ R  0.0821 atm  lit mol1K 1 ; consider negligible volume of CCl4 ]

39. Given Mn 2O7 ,CrO3 ,SO2 , NO, N2O, N2O5 ,CO2 ,BaO,CO, P4O10 , V2O3

A = number of acidic oxides

B = number of basic oxides

N = number of neutral oxides

X (A N)B then X is ____

40. Consider the major organic product formed in the given reaction, If [X] is the total
number of double bonds which are in conjugation in major organic product then value of
[X]

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
41.

If ‘X’ is the position of Br (as per IUPAC) in “A” and ‘Y’ is the position of methyl
group (as per IUPAC) in “B” what is the value of X + Y ?

42. How many of the following olefin will give the racemic alcohol after hydroboration
reaction using B2 H 6 in THF followed by oxidation with H 2O 2 / NaOH ?

i) ii) iii) iv)

SECTION - 2 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
43. In the following graph, identify CORRECT statement(s):

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
A) 100% conversion of dimer to monomer is spontaneous

B) At point B, free energy of system becomes constant with time

C) In the region between A and B, reaction has tendency to move in forward direction.

D) In the region between B and C, G for the reaction N2O42NO2 is positive

44. Which of the following is/are CORRECT?

A) de Broglie’s wavelength of an electron is inversely proportional to V1/2 , where V is

applied potential.

B) As n increases, orbit frequency for an electron decreases

C) 2 indicates probability of finding an electron at a point in region around nucleus.

D) Existence of line spectrum for an atom is a consequence of quantisation of energy.

45. A gas obeys P(V–b) = RT. Which of the following are correct about this gas?

R
A) Isochoric curves have slope 
Vb

R
B) Isobaric curves have slope  and intercept = b
P

Pb
C) For the gas compressibility factor  1 
RT

D) Slope = RT and intercept = b for V vs 1/P graph at constant ‘T’

46.

A) B) C) D)

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
47. The ene-yne(s) that produce(s) a chiral compound upon treatment with H 2 and lindlar’s
catalyst is/are:

A) B)

C) D)

48. Consider the isomers of the given compound

Which of the following is/are the chain isomer(s) of (P) ?

A) B)

C) D)

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
SECTION - 3 (Maximum Marks : 24)
This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
49. A definite amount of solid NH 4 HS is placed in a flask already containing ammonia gas at
a certain temperature and 0.1 atm pressure. NH 4 HS decomposes to give NH3 and H 2S and
at equilibrium total pressure in flask is 1.1 atm. If the equilibrium constant K p for the

reaction NH 4 HS  s   NH 3  g   H 2S  g  is represented as z  10 then find the value of
1

z.
50. 10 mL of H2 A (weak diprotic acid) solution is titrated against 0.1 M NaOH. pH of the
solution is plotted against volume of strong base added and following observation is
made.

If pH of the solution at first equivalence point is pH1 and at second equivalence point is
pH 2 . Calculate the value of  pH2  pH1 at 25°C .

(Given for H 2 A
pka 1  4.6

pka 2  8

log 25 = 1.4)
51. A certain mass of anhydrous oxalic acid is converted into H2O , CO2 and CO, on heating
in the presence of H2SO4 . The CO formed reacts completely with iodinepentoxide to
liberate iodine. The iodine thus liberated required 200 ml of 0.2 N thiosulphate. The
mass (in g) of oxalic acid taken was

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Narayana IIT Academy 21-01-24_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-21_QP
52. Identify the positional isomers for the given molecule (X)

53. Find the number chiral dibromide products formed in below reaction.(consider only
NGP)

54. How many alkyl chlorides will gives faster rate of solvolysis than in
aqueous ethanol

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