Revision date: 15/10/2019 Revision: 1

SAFETY DATA SHEET

NITOBOND SBA 25-40 BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOBOND SBA 25-40 BASE

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base Component of Two-Part Epoxy Adhesive System

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Sdn. Bhd.
8, Jalan Trompet 33/8,
Section 33, 40400, Shah Alam,
Selangor Darul Ehsan,
Malaysia.
+603-51025660
+603-51025668
[email protected]

1.4. Emergency telephone number

Emergency telephone +60351025660

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Carc. 1A - H350 Repr. 1B - H360
STOT SE 3 - H335 STOT RE 1 - H372

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

1/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Precautionary statements P261 Avoid breathing vapour/ spray.

P264 Wash contaminated skin thoroughly after handling.
P273 Avoid release to the environment.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P362+P364 Take off contaminated clothing and wash it before reuse.

Contains SILICA FLOUR (<100 micron), SILICA FLOUR, reaction product: bisphenol-A-(epichlorhydrin)
epoxy resin (number average molecular weight ≤ 700), DIBUTYL PHTHALATE, ALKYL
GLYCIDYL ETHER C12/C14

Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe vapour/ spray.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P314 Get medical advice/ attention if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SILICA FLOUR (<100 micron) 30-60%

CAS number: —

Classification
Eye Irrit. 2 - H319
Carc. 1A - H350
STOT SE 3 - H335
STOT RE 1 - H372

SILICA FLOUR 30-60%

CAS number: 14808-60-7

Classification
Eye Irrit. 2 - H319
STOT SE 3 - H335

2/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 10-30%

(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

DIBUTYL PHTHALATE 1-5%

CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 10 M factor (Chronic) = 10

Classification
Acute Tox. 3 - H331
Repr. 1B - H360
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

ALKYL GLYCIDYL ETHER C12/C14 1-5%

CAS number: 68609-97-2 EC number: 271-846-8 REACH registration number: 01-
2119485289-22-XXXX

Classification
Skin Irrit. 2 - H315
Skin Sens. 1 - H317

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove person to fresh air and keep comfortable for breathing. Get medical attention if any
discomfort continues.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse
mouth thoroughly with water. Get medical attention immediately.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Rinse
immediately with plenty of water. Get medical attention if symptoms are severe or persist after
washing. Wash contaminated clothing before reuse.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation May cause respiratory irritation.

Skin contact May cause an allergic skin reaction. Causes skin irritation.

Eye contact Causes serious eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed

3/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Carbon dioxide (CO2). Carbon monoxide (CO).

5.3. Advice for firefighters

Protective actions during Fight fire from safe distance or protected location.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Flush contaminated area
with plenty of water. Avoid the spillage or runoff entering drains, sewers or watercourses.

6.4. Reference to other sections

Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
DIBUTYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
WEL = Workplace Exposure Limit

4/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

ALKYL GLYCIDYL ETHER C12/C14 (CAS: 68609-97-2)

DNEL Workers - Inhalation; Long term systemic effects: 3.6 mg/m³

Workers - Dermal; Long term systemic effects: 1 mg/kg/day

PNEC - Fresh water; 0.0072 mg/l

- marine water; 0.00072 mg/l

DIBUTYL PHTHALATE (CAS: 84-74-2)

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³

Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l

- marine water; 1 µg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Eye wash facilities and emergency
controls shower must be available when handling this product.

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection It is recommended that gloves are made of the following material: Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Do not smoke in work area. Wash hands at the end of each work shift and before
eating,smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly
remove any clothing that becomes contaminated. When using do not eat, drink or smoke.

Respiratory protection Wear a respirator fitted with the following cartridge: Combination filter, type A2/P2.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Paste.

Colour Black.

Odour Mild.

Odour threshold Not available.

pH Not available.

Melting point Not available.

5/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Initial boiling point and range Not applicable.

Flash point > 150°C

Evaporation rate Not available.

Evaporation factor Not available.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or The product is not flammable.

explosive limits

Other flammability The product is not flammable.

Vapour pressure Not available.

Vapour density Not available.

Relative density 1.7 - 1.8 @ 25°C

Solubility(ies) Insoluble in water.

Partition coefficient Not available.

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity 6000 - 7000 P @ 25°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information

Other information None known.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Epoxides.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous Hazardous reactions will not occur under normal transport or storage conditions.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong acids. Strong alkalis. Strong oxidising agents.

10.6. Hazardous decomposition products

6/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Hazardous decomposition Thermal decomposition or combustion products may include the following substances:
products Carbon dioxide (CO2). Carbon monoxide (CO).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - inhalation
ATE inhalation (vapours mg/l) 241.48

Carcinogenicity
Summary May cause cancer.

Reproductive toxicity
Summary May damage fertility or the unborn child.

Specific target organ toxicity - repeated exposure

Summary Causes damage to organs through prolonged or repeated exposure.

Inhalation May cause respiratory irritation.

Skin contact May cause skin irritation. May cause an allergic skin reaction.

Eye contact Causes serious eye irritation.

Toxicological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)

Species Rat

Notes (oral LD₅₀) Based on available data the classification criteria are not met.

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,000.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 20,000.0

Skin corrosion/irritation

Animal data Rabbit Moderately irritating.

Skin sensitisation

Skin sensitisation May cause sensitisation by skin contact.

DIBUTYL PHTHALATE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 8,000.0

mg/kg)

Species Rat

7/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

ATE oral (mg/kg) 8,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,860.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 20,860.0

Acute toxicity - inhalation

Acute toxicity inhalation 4.25

(LC₅₀ vapours mg/l)

Species Rat

ATE inhalation (vapours 4.25

mg/l)

Acute and chronic health INGESTION. May cause stomach pain or vomiting. Inhalation May cause
hazards respiratory system irritation. SKIN CONTACT. May cause skin irritation/eczema.
May cause sensitisation by skin contact. EYE CONTACT. Irritating to eyes.

SECTION 12: Ecological information

Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity Toxic to aquatic life with long lasting effects.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants

DIBUTYL PHTHALATE

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 1.6 mg/l, Salmo gairdneri

Acute toxicity - aquatic LC₅₀, 48 hours: 3.7 mg/l, Daphnia magna

invertebrates

8/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Acute toxicity - aquatic EC₅₀, 96 hours: 0.75 mg/l, Selenastrum capricornutum

plants

Chronic aquatic toxicity

M factor (Chronic) 10

12.2. Persistence and degradability

Persistence and degradability This product is not expected to be readily biodegradable.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Persistence and The product is not readily biodegradable.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential Not available.

Partition coefficient Not available.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Partition coefficient log Pow: 3.242

12.4. Mobility in soil

Mobility The product is insoluble in water. Not considered mobile.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Mobility The product has poor water-solubility.

Adsorption/desorption Water - Koc: 445 @ °C

coefficient

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

9/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
(ADR/RID) RESIN, DIBUTYL PHTHALATE)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN, DIBUTYL PHTHALATE)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN, DIBUTYL PHTHALATE)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS EPOXY
RESIN, DIBUTYL PHTHALATE)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

10/11
Revision date: 15/10/2019 Revision: 1

NITOBOND SBA 25-40 BASE

Hazard Identification Number 90

(ADR/RID)

Tunnel restriction code (-)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of
Hazardous Chemicals) Regulations 2013 (CLASS Regulations)

Guidance Industry Code of Practise on Chemical Classification and Hazard Communication 2014

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional users only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 15/10/2019

Revision 1

SDS number 27871

Hazard statements in full H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H372 Causes damage to organs (Lungs) through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

11/11
Revision date: 20/10/2019 Revision: 1

SAFETY DATA SHEET

NITOBOND SBA 25-40 HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOBOND SBA 25-40 HARDENER

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base Component of Two-Part Epoxy Adhesive System

1.3. Details of the supplier of the safety data sheet

Supplier Fosroc Sdn. Bhd.
8, Jalan Trompet 33/8,
Section 33, 40400, Shah Alam,
Selangor Darul Ehsan,
Malaysia.
+603-51025660
+603-51025668
[email protected]

1.4. Emergency telephone number

Emergency telephone +60351025660

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P264 Wash contaminated skin thoroughly after handling.

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P362+P364 Take off contaminated clothing and wash it before reuse.

1/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

Contains SILICA SAND < 250 micron, EPOXY RESIN DILUENT, ISOPHORONEDIAMINE, POLYMER
OF C-18 UNSATURATED FATTY ACID DIMER WITH TRIETHYLENETETRAMINE & TALL
OIL FATTY ACIDS

Supplementary precautionary P260 Do not breathe vapour/ spray.

statements P261 Avoid breathing vapour/ spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SILICA SAND < 250 micron 30-60%

CAS number: 14808-60-7 EC number: 238-878-4

Classification Classification (67/548/EEC or 1999/45/EC)

Eye Irrit. 2 - H319 -

EPOXY RESIN DILUENT 5-10%

CAS number: 68512-30-1 EC number: 270-966-8

Classification
Skin Irrit. 2 - H315
Skin Sens. 1A - H317
Aquatic Chronic 3 - H412

ISOPHORONEDIAMINE 5-10%
CAS number: 2855-13-2 EC number: 220-666-8 REACH registration number: 01-
2119514687-32-xxxx

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

2/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

POLYMER OF C-18 UNSATURATED FATTY ACID DIMER 1-5%

WITH TRIETHYLENETETRAMINE & TALL OIL FATTY
ACIDS
CAS number: 68082-29-1 EC number: 500-191-5

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Get medical attention if any discomfort continues.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth thoroughly with water. Get medical attention immediately.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if symptoms are severe or persist
after washing. Wash contaminated clothing before reuse.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse immediately with plenty of
water. Continue to rinse for at least 15 minutes. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed
Skin contact Causes severe skin burns. May cause an allergic skin reaction.

Eye contact Causes serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Thermal decomposition or combustion products may include the following substances:
products Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of nitrogen.

5.3. Advice for firefighters

Protective actions during Fight fire from safe distance or protected location.
firefighting

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection, see Section 8.

3/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if safe to do so. Absorb in vermiculite, dry sand or earth and place into containers.
Flush contaminated area with plenty of water. Avoid the spillage or runoff entering drains,
sewers or watercourses.

6.4. Reference to other sections

Reference to other sections For disposal see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
SILICA SAND < 250 micron
Long-term exposure limit (8-hour TWA): WEL 0,1 mg/m³ Respirable crystalline silica
WEL = Workplace Exposure Limit

ISOPHORONEDIAMINE (CAS: 2855-13-2)

PNEC - marine water; 0.006 mg/l

- Fresh water; 0.06 mg/l
- Soil; 1.121 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Eye wash facilities and emergency
controls shower must be available when handling this product.

Eye/face protection The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Provide eyewash station. Use appropriate skin cream to prevent drying of skin. Wash hands
and any other contaminated areas of the body with soap and water before leaving the work
site.

4/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

Respiratory protection Respiratory protection may be required if excessive airborne contamination occurs.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Paste.

Colour Dark Grey

Odour Amine.

Odour threshold Not available.

pH Not available.

Melting point Not available.

Initial boiling point and range > 200°C

Flash point 120°C

Evaporation rate Not available.

Evaporation factor Not available.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Not applicable.

explosive limits

Other flammability Not applicable.

Vapour pressure Not available.

Vapour density Not available.

Relative density 1.6 - 1.8 @ 20°C

Bulk density Not available.

Solubility(ies) Insoluble in water

Partition coefficient Not available.

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity Not applicable.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

9.2. Other information

Other information None known.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Amines.

5/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous Hazardous reactions will not occur under normal transport or storage conditions.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong acids. Strong alkalis. Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Thermal decomposition or combustion products may include the following substances:
products Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of nitrogen.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 7,440.48

Acute toxicity - dermal

ATE dermal (mg/kg) 16,369.05

Skin contact Causes severe skin burns. May cause an allergic skin reaction.

Eye contact Causes severe eye damage

Toxicological information on ingredients.

ISOPHORONEDIAMINE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 1,030.0

mg/kg)

Species Rat

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 1,840.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 1,100.0

SECTION 12: Ecological information

Ecotoxicity The product contains a substance which is harmful to aquatic organisms and which may
cause long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity Harmful to aquatic life with long lasting effects.

6/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

Ecological information on ingredients.

ISOPHORONEDIAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 110 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 23 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic IC₅₀, 72 hours: 50 mg/l, Algae

plants

12.2. Persistence and degradability

Persistence and degradability The product is not readily biodegradable.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Persistence and The product is not readily biodegradable.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient Not available.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient log Kow: 0.99

12.4. Mobility in soil

Mobility Insoluble in water. Not considered mobile.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1760

UN No. (IMDG) 1760

UN No. (ICAO) 1760

7/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

UN No. (ADN) 1760

14.2. UN proper shipping name

Proper shipping name CORROSIVE LIQUID, N.O.S. (CONTAINS ISOPHORONEDIAMINE,
(ADR/RID) Bis(dimethylaminomethyl)phenol)

Proper shipping name (IMDG) CORROSIVE LIQUID, N.O.S. (CONTAINS ISOPHORONEDIAMINE,

Bis(dimethylaminomethyl)phenol)

Proper shipping name (ICAO) CORROSIVE LIQUID, N.O.S. (CONTAINS ISOPHORONEDIAMINE,

Bis(dimethylaminomethyl)phenol)

Proper shipping name (ADN) CORROSIVE LIQUID, N.O.S. (CONTAINS ISOPHORONEDIAMINE,

Bis(dimethylaminomethyl)phenol)

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C9

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

EmS F-A, S-B

ADR transport category 2

Hazard Identification Number 80

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

8/9
Revision date: 20/10/2019 Revision: 1

NITOBOND SBA 25-40 HARDENER

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of
Hazardous Chemicals) Regulations 2013 (CLASS Regulations)

Guidance Industry Code of Practise on Chemical Classification and Hazard Communication 2014

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information For professional use only. Only trained personnel should use this material.

Revision comments This is the first issue.

Revision date 20/10/2019

Revision 1

SDS number 27885

Hazard statements in full H302 Harmful if swallowed.

H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

9/9