VELAMMAL IIT&NEET ACADEMY
XII IIT                                    GTM-02                                   Dt: 22.12.2023
PHYSICS                                                                                     MAX.MARKS: 100
                                                SECTION – I
                                      (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1.      The total number of turns and cross-section area in solenoid is fixed. However, its length
        L is varied by adjusting the separation between windings. The inductance of solenoid
        will be proportional to:
        (A) 1/ L                  (B) L                     (C) 1/ L2                 (D) L2
2.      The figure shows a Young’s double slit experimental setup. It is observed that when a
        thin transparent sheet of thickness t and refractive index μ is put in front of one of the
        slits, the central maximum gets shifted by a distance equal to n fringe widths. If the
        wavelength of light used is λ , t will be:
                2nDλ                      nDλ                       2Dλ                      nλ
        (A)                       (B)                       (C)                       (D)
               a  μ  1               a  μ  1                a  μ  1                μ 1
3.      A system of three charges are placed as shown in the figure:
        If D >> d, the potential energy of the system is best given by:
             1          q 2 qQd                                1         q 2 qQd 
        (A)              2                              (B)                2
            4πε 0       d    D                                4πε 0      d 2D 
                1       q 2 2qQd                                 1       q 2 qQd 
        (C)                                             (D)             2 
               4πε 0    d    D2                                 4πε 0    d    D 
4.   If ‘M’ is the mass of water that rises in a capillary tube of radius ‘r’, then mass of water
     which will rise in a capillary tube of radius ‘2r’ is:
                                   M
     (A) 4 M                 (B)                    (C) M                 (D) 2 M
                                   2
5.   An HCl molecule has rotational, translational and vibrational motions. If the rms
     velocity of HCl molecules in its gaseous phase is v , m is its mass and k B is Boltzmann
     constant, then its      temperature will be:
         mv 2                    mv 2                   mv 2                  mv 2
     (A)                     (B)                    (C)                   (D)
         3k B                    7k B                   5k B                  6k B
6.   Following figure shows two processes A and B for a gas. If ΔQA and ΔQ B are the
     amount of heat absorbed by the system in two cases, and ΔU A and ΔU B are changes in
     internal energies, respectively, then:
     (A) ΔQ A  ΔQ B ;ΔU A  ΔU B                   (B) ΔQ A >ΔQ B ;ΔU A  ΔU B
     (C) ΔQ A <ΔQ B ;ΔU A <ΔU B                     (D) ΔQ A > ΔQ B ;ΔU A > ΔU B
7.   A uniform cable of mass ‘M’ and length ‘L’ is placed on a horizontal surface such that
            th
     its   part is hanging below the edge of the surface. To lift the hanging part of the
           1
          n
     cable upto the surface, the work done should be:
                                   MgL                    2MgL                  MgL
     (A)MgL                  (B)                    (C)                   (D)
                                   2n 2                    n2                    n2
8.   The following bodies are made to roll up (without slipping) the same inclined plane from
                                                                                   R
     a horizontal place: (i) a ring of radius R, (ii) a solid cylinder of radius     and (iii) a solid
                                                                                   2
                          R
     sphere of radius       . If, in each case, the speed of the center of mass at bottom of the
                          4
     incline is same, the ratio of the maximum heights they climb is:
     (A) 10 : 15 : 7         (B) 20: 15: 14         (C) 4 : 3 : 2          (D) 14 : 15 : 20
9.    A signal A cosωt is transmitted using v0sin ω0 t as carrier wave. The correct amplitude
      modulated (AM) signal is:
                                                                         A                  A
      (A) v 0sin  ω0 1  0.01A sinωt  t         (B) v0 sin ω0 t+     sin  ω0  ω  t+ sin  ω0 + ω  t
                                                                         2                  2
      (C) v0 sin ω0 t+A cos ωt                        (D)  v0 +A  A cos ωt sin ωt
10.   A stationary horizontal disc is free to rotate about its axis. When a torque is applied on
      it, its kinetic energy as a function of θ , where θ is the angle by which it has rotated, is
      given as kθ 2 . If its moment of inertia is I then the angular acceleration of the disc is:
            k                          k                    k                         2k
      (A)     θ                  (B)      θ           (C)      θ                (D)      θ
            I                          2I                   4I                         I
11.   A simple pendulum oscillating in air has period T. The bob of the pendulum is
                                                                                                   1
      completely immersed in a non-viscous liquid. The density of the liquid is                      th of the
                                                                                                  16
      material of the bob. If the bob is inside liquid all the time, its period of oscillation in this
      liquid is:
                   1                           1                    1                         1
      (A) 2T                     (B) 2T               (C) 4T                    (D) 4T
                  10                          14                   15                        14
12.   For a given gas at 1 atm pressure, rms speed of the molecules is 200 m/s at 127 0C . At
      2atm pressure and at 2270C , the rms speed of the molecules will be:
      (A) 80 m/s                 (B) 80 5 m / s       (C) 100 m/s               (D) 100 5 m / s
13.   The magnetic field of a plane electromagnetic wave is given by:
      
      B  B0ˆi cos  kz  ωt    B1ˆjcos  kz  ωt  .Where B0  3  105 T and B1  2  106 T .The rms
      value of the force experienced by a stationary charge Q  10 –4  C at z = 0 is closet to:
      (A) 0.9 N                  (B) 0.6 N            (C) 0.1 N                 (D) 3  102 N
14.   The stream of a river is flowing with a speed of 2 km/h. A swimmer can swim at a speed
      of 4 km/h. What should be the direction of the swimmer with respect to the flow of the
      river to cross the river straight?
      (A) 600                    (B) 900              (C) 1200                  (D) 1500
15.   A rigid square loop of side ‘a’ and carrying current I 2 is laying on a horizontal surface
      near a long current I1 wire in the same plane as shown in figure. The net force on the
      loop due to the wire will be:
                                    μ 0 I1I 2                                  μ 0 I1I 2
      (A) Repulsive and equal to                 (B) Attractive and equal to
                                      2π                                         3π
                                                                               μ 0 I1I 2
      (C) Zero                                   (D) Repulsive and equal to
                                                                                 4π
16.   Taking the wavelength of first Balmer line in hydrogen spectrum ( n = 3 to n = 2) as
      660nm , the wavelength of the 2nd Balmer line (n =4 to n = 2) will be
      (A) 889.2 nm          (B) 642.7 nm         (C) 488.9 nm          (D) 388.9 nm
17.   A solid sphere of mass ‘M’ and radius ‘a’ is surrounded by a uniform concentric
      spherical shell of thickness 2a and mass 2M. The gravitational field at distance ‘3a’ from
      the centre will be:
            2GM                   2GM                  GM                    GM
      (A)                   (B)                  (C)                   (D)
             3a 2                  9a 2                9a 2                  3a 2
18.   A ball is thrown vertically up (taken as +z-axis) from the ground. The correct
      momentum height(p-h) diagram is:
      (A)                   (B)                  (C)                   (D)
19.    The pressure wave, P  0.01 sin 1000t – 3x  NM –2 , corresponds to the sound produced by
       a vibrating blade on a day when atmospheric temperature is 00 C . On some other day
       when temperature is T, the speed of sound produced by the same blade and at the same
       frequency is found to be 336 ms 1 . Approximate value of T is:
       (A) 120 C                  (B) 110 C              (C) 150 C                (D) 40 C
20.    A wire of resistance R is bent to form a square ABCD as shown in the figure. The
       effective resistance between E and C is: (E is mid-point of arm CD)
              1                         7                      3
       (A)      R                 (B)      R             (C)     R                (D) R
             16                         64                     4
                                                 SECTION-II
                                        (Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Have to Answer
any 5 only out of 10 questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21.    In the density measurement of a cube, the mass and edge length are measured as
        (10.00  0.10) kg and (1.00  0.01)m , respectively. The error in the measurement of
       density is:  in kg/m3 
22.    A moving coil galvanometer has resistance 50 and it indicates full deflection at
        4mA current. A voltmeter is made using this galvanometer and a 5k resistance. The
       maximum voltage, that can be measured using this voltmeter, will be  in V 
23.    An NPN transistor is used in common emitter configuration as an amplifier with
       1k load resistance. Signal voltage of 10 mV is applied across the base-emitter. This
       produces a 3mA change in the collector current and 15μA change in the base current of
       the amplifier. The input resistance is  in k Ω 
24.   The electric field of light wave is given as
                  2πx                   14  ˆ N
      E  103 cos         7
                               -2π  6  10  t  j .This light falls on a metal plate of work
                    5  10                     C
      function 2eV. The stopping potential of the photoelectrons is(in V)
25.   A concave mirror for face viewing has focal length of 0.4 m. The distance at which you
      hold the mirror from your face in order to see your image upright with a magnification
      of 5 is (in m)
26.   Determine the charge on the capacitor in the following circuit:  in μC 
27.   A rectangular coil (Dimension 5 cm×2 cm ) with 100 turns, carrying a current of 3A in
      the clock-wise direction, is kept centered at the origin and in the X-Z plane. A magnetic
      field of 1T is applied along X-axis. If the coil is tilted through 450 about Z-axis, then the
      torque on the coil is:  in Nm 
28.   A string is clamed at both the ends and it is vibrating in its 4th harmonic. The equation
      of the stationary wave is Y =0.3 sin  0.157x  cos(200πt) . The length of the string is: (in
      m) (all quantities are in SI units)
29.   A capacitor with capacitance 5μF is charged to 5μC . If the plates are pulled apart to
      reduce the capacitance to 2μF , how much work is done?  in μJ 
30.   A body of mass 2 kg makes an elastic collision with a second body at rest and continues
      to move in the original direction but with one fourth of its original speed. What is the
      mass of the second body?(in kg)
CHEMISTRY                                                                                  MAX.MARKS: 100
                                               SECTION – I
                                     (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31.
32.     The one that will show optical activity is: (en = ethane-1, 2-diamine)
        (A)                                             (B)
        (C)                                             (D)
33.
34.     Liquid ‘M’ and liquid ‘N’ form an ideal solution. The vapour pressures of pure liquids
        ‘M’ and ‘N’ are 450 and 700 mm Hg, respectively at the same temperature. Then correct
        statement is:
        ( X M = mole fraction of ‘M’ in solution; X N = mole fraction of ‘N’ in solution;
        YM = mole fraction of ‘M’ in vapour phase; YN = mole fraction of ‘M’ in vapour phase)
              X M YM                                          X M YM
        (A)      >                                      (B)      
              X N YN                                          X N YN
                                                              X M YM
        (C)  X M  YM    X N  YN                  (D)      
                                                              X N YN
35.   Among the following the set of parameters that represents path functions, is:
      (a) q + w              (b) q               (c) w                  (d) H – TS
      (A) (b) and (c)                            (B) (b), (c) and (d)
      (C) (a), (b) and (c)                       (D) (a) and (d)
37.
38.   The major product of the following reaction is:
      (A)                    (B)                   (C)                   (D)
39.   The organic compound that gives following qualitative analysis is:
      Test                   Inference
      (a) Dil. HCl                   Insoluble
      (b) NaOH solution              Soluble
      (c) Br2 /water                 Decolourization
      (A)                                    (B)
      (C)                                    (D)
40.   Aniline dissolved in dilute HCl is reacted with sodium nitrite at 00C . This solution was
      added dropwise to a solution containing equimolar mixture of aniline and phenol in
      dil.HCl. The structure of the major product is:
      (A)                                    (B)
      (C)                                    (D)
41.
42.
43.   The major product of the following reaction is :
      (A) CH3CH 2CH 2CHO                     (B) CH3CH  CHCH 2OH
      (C) CH 3CH 2CH 2CO 2CH 3              (D) CH3CH 2CH 2CH 2OH
44.   The element having greatest difference between its first and second ionization energies,
      is
      (A) Ca             (B) K               (C) Ba             (D) Sc
45.   The major product of the following reaction is :
                 1 DCl1equiv 
      CH3C  CH  2Dl      
      (A) CH3 CD I CHD Cl                  (B) CH 3C  I  Cl  CHD 2
      (C) CH 3CD 2CH  Cl  I                (D) CH 3CD  Cl  CHD  I 
46.
47.   The increasing order of reactivity of the following compounds towards aromatic
      electrophilic substitution reaction is
      (A) D < B < A < C                        (B) A < B < C < D
      (C) D < A < C < B                        (D) B < C < A < D
48.    The correct order of the oxidation states of nitrogen in NO, N 2O, NO 2 and N 2O3 is:
       (A) N 2O < N 2O3 < NO < NO2                    (B) NO 2 < NO < N 2O3 < N 2O
       (C) NO 2 < N 2O3 < NO < N 2O                   (D) N 2O < NO < N 2O3 < NO2
49.    The major product of the following reaction is:
       (A)                    (B)                     (C)                    (D)
50.    Which of the following statements is not true about sucrose?
       (A) The glycosidic linkage is present between C1 of α  and C1 of β  fructose
       (B) It is a non-reducing sugar
       (C) It is also named as invert sugar
       (D) On hydrolysis it produces glucose and fructose
                                              SECTION-II
                                     (Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Have to Answer
any 5 only out of 10 questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
51.    The number of water molecule(s) not coordinated to copper ion directly in CuSO 4 .5H 2O,
       is X: Then value of X is
52.
53.
54.   The correct IUPAC name of the following compound is
      x  chloro  y  methyl  z  nitrobenzene , then x + y+z will be
55.   For a reaction,
      N 2  g  + 3H 2  g   2NH 3  g  ; identify dihydrogen ( H 2 ) as a limiting reagent in the
      following     reaction mixtures.  x g of N 2 + y g of H 2  , then x  y will be
      (A) 14g of N 2 + 4g of H 2          (B) 28g of N 2 + 6g of H 2
      (C) 56g of N 2 + 10g of H 2         (D) 35g of N 2 + 8g of H 2
56.   The osmotic pressure of a dilute solution of an ionic compound XY in water is four
      times that of a solution of 0.01 M BaCl2 in water. Assuming complete dissociation of
                                                                                 
      the given ionic compounds in water, the concentration of XY in mol L–1 in solution is
                        a
      a  10 b .Then     =
                        b
57.   For any given series of spectral lines of atomic hydrogen, let  V   V max   V min be the
      difference in maximum and minimum frequencies in cm –1 . the ration  V Lymann /  V Balmer
      is a:b ,then a  b will be
58.
59.   The standard Gibbs energy for the given cell reaction in kJ mol –1 at 298 K is:
      Zn  s  +Cu 2+  aq   Zn 2+  aq  +Cu  s  ,E 0 =2 V
      [Faraday’s constant F = 96500 C mol –1 ]
60.
MATHEMATICS                                                                                                       MAX.MARKS: 100
                                                       SECTION – I
                                             (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
                                                                       x2
61. If the function f: R–{1, –1}  A defined by f  x                      is surjective, then A is equal to:
                                                                     1 x2
       (A) R  1,0                     (B) R  1,0                            (C) R  1            (D) 0, 
62.    Let p,q  R. if 2  3 is a root of the quadratic equation, x 2 + px + q = 0, then
       (A) q 2  4p  14  0                                                         (B) p 2 - 4q  12  0
       (C) p 2 - 4q - 12  0 (D) q 2 - 4p - 16  0
               ^       ^            ^     ^      ^                                                      
63.    Let   3i + j and β= 2i j+3k if   1  2 , where 1 is parallel to  and  2 is
                                                
       perpendicular to  then 1  2 , is equal to:
          1         ^      ^   ^ 1                  ^        ^         ^                ^      ^   ^            ^         ^   ^
       (A) 3 i +9 j+5 k  (B) 3 i 9 j+5 k                               (C) 3i +9 j+5k         (D) 3i 9 j 5 k
          2                      2               
                              sec
                                      23
64.     The integral                       x cos ec 4 3 x dx is equal to: (Here C is a constant of integration)
                                                    3        4
       (A) 3 tan -1 3 x + C                (B)  tan                 3x    +C        (C) 3cot1 3 x + C     (D) 3 tan --1 3 x + C
                                                    4
65.    Let R = {(3, 3) (5, 5), (9, 9), (12, 12), (5, 12), (3, 9), (3, 12), (3, 5)} be a relation
       on the set A ={3, 5, 9, 12}. Then, R is:
       1) reflexive, symmetric but not transitive                                       2) symmetric, transitive but not reflexive.
       3) an equivalence relation                                                       4) reflexive, transitive but not symmetric
66.
67.   If f(x) is a non-zero polynomial of degree four, having local extreme points at x = –1, 0,
      1; then the set S = {x  R; f (x) = f(0)} contains exactly:
      (A) four irrational numbers
      (B) four rational numbers
      (C) two irrational and one rational number
      (D) two irrational and two rational numbers
68.   A spherical iron ball of radius 10 cm is coated with a layer of ice of uniform thickness that
      melts at a rate of 50 cm3/min. When the thickness of the ice is 5 cm, then the rate at which
      the thickness (in cm/min) of the ice decreases, is:
69.   The value of cos2 100 - cos 100 cos 500 + cos2 500 is
      (A)
             3
             2
               1 cos200        (B)
                                         3
                                         4
                                                                    (C)
                                                                          3
                                                                          2
                                                                                                  (D)
                                                                                                           3
                                                                                                           4
                                                                                                              cos200
         1 1 1 2 1 3                       1 n 1 1 78                           1    n
70.   If                      ............                , then the inverse of         is:
          0 1  0 1  0 1               0 1   0 1                        0   1
             1  12                    1 0                            1 0                            1      13 
      (A)                       (B)                             (C)                         (D)                 
              0  1                   13 1                         12 1                          0      1
                                               i        
71.   All the points in the set S  
                                              i
                                             
                                                    :   R
                                                           
                                                           
                                                                
                                                            i  1 lie on a: 
                                                          
      (A) straight line whose slope is 1                            (B) circle whose radius is 2
      (C) straight line whose slope is –1                           (D) circle whose radius is 1
72.   Let the sum of the first n terms of a non-constant A.P., a1 , a 2 , a 3 , …… be
                n n -7
      50 n +               A, where A is a constant. If d is the common difference of this A.P., then
                   2
      the ordered pair d ,a 50  is equal to:
      (A) (A, 50 + 46A)                                             (B) (A, 50 + 45A)
      (C) (50, 50 + 45A)                                            (D) (50, 50 + 46A)
                     2
                              sin3 x
73.   The value of                     dx is:
                     0
                          sin x  cos x
            2                        1               1                          2
      (A)                       (B)              (C)                            (D)
             4                          2                 4                            8
74.
                                                    dy
75.   The solution of the differential equation x       2 y  x 2  x  0 with y 1  1, is
                                                    dx
                x3   1                                        x2   3
      (A) y        2                           (B) y           2
                5 5x                                          4   4x
                4     1                                       3        1
      (C) y  x3                                (D) y  x 2 
                5    5x2                                      4       4 x2
76.
77.   Slope of a line passing through P(2, 3) and intersecting the line, x + y = 7 at a distance of
      4 units from P, is:
78.
79.
80.     Let  and  be the roots of the equation x 2  x  1  0 . Then for y  0 in R,
        y 1              
              y         1     is equal to:
                1        y 
       (A) y  y 2  3           (B) y 3  1            (C) y 3                    (D) y  y 2 1
                                               SECTION-II
                                      (Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Have to Answer
any 5 only out of 10 questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
81.     If the standard deviation of the numbers –1, 0, 1, k is 5 where k > 0, if k is equal to
        n 6 ; then n is
82.     Let f(x) = 15–|x – 10|; x  R. then the number of values of x, at which the function,
       g(x)=f(f(x)) is not differentiable, is:
                                                         2 log8 x 6
83.    If the fourth term in the Binomial expansion of  +x          x > 0 is 20  8 , then a
                                                                                         7
                                                         x       
       value of x is
84.     A committee of 11 members is to be formed from 8 males and 5 females. If m is the
       number of ways the committee is formed with at least 6 males and n is the number of
       ways the committee is formed with at least 3 females, then: m  n is equal to
85.    In a class of 140 students numbered 1 to 140, all even numbered students opted
       Mathematics course, those whose number is divisible by 3 opted Physics course and
       those whose number is divisible by 5 opted Chemistry course. Then, the number of
       students who did not opt for any of the three courses is
86.     If one end of a focal chord of the parabola y 2  16x is at (1, 4), then the length of this
       focal chord is:
            10
87.   Let    f a  k   16 210 1 , where the function f satisfies f(x + y) = f(x) f(y) for all
            k 1
      natural numbers x, y and f(1) = 2. Then the natural number ‘a’ is:
                                                                         1 1 1   1
88.   Four persons can hit a target correctly with probabilities          , , and respectively. If all
                                                                         2 3 4   8
      hit at the target independently, then the probability that the target would be hit, is:
89.   The area (in sq. units) of the region A   x, y  : x 2  y  x  2 is
                                                      
                                                       2 cos x  1      
                                                      
                                                                   ,x 
                                                  cot x  l
                                      , by f ( x )                    4
90.   If the function f defined on  6 3         
                                                      
                                                                         is continuous, then k is
                                                      
                                                        k ,         x 
                                                      
                                                                        4
      equal to