00005232 SAFETY DATA SHEET Page 1

BARENTZ
1425 Norjohn Court, Unit 4
Burlington, ON, L7L-0E6
CANADA
905-338-3172
PRODUCT: Cambrex S31
SECTION 01: IDENTIFICATION
SUPPLIER IDENTIFIER............................ Barentz
1425 Norjohn Court, Unit 4
Burlington, ON L7L-0E6
Canada
905-338-3172
PRODUCT IDENTIFIER............................ Cambrex S31
PRODUCT CODE..................................... S-I-0289 CX
OTHER MEANS OF IDENTIFICATION.... Not available.
RECOMMENDED USE............................. Surfactant.
RESTRICTIONS ON USE......................... Not available.
EMERGENCY TELEPHONE NUMBER.... Barentz (905-338-3172).

SECTION 02: HAZARD IDENTIFICATION

HAZARD CLASSIFICATION..................... Acute Toxicity (Oral) — Category 4. Specific Target Organ Toxicity — Repeated Exposure
— Category 2.
SIGNAL WORD......................................... Warning.
HAZARD STATEMENT............................. H302 Harmful if swallowed. H373 May cause damage to organs (kidneys) through
prolonged or repeated exposure.
PRECAUTIONARY STATEMENT............. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash contaminated skin
thoroughly after handling. P270 Do no eat, drink or smoke when using this product.
P301+P312+P330: IF SWALLOWED: Rinse mouth. Call a POISON CENTER or
doctor/physician if you feel unwell. P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local regulatory requirements.
OTHER HAZARDS.................................... Inhalation of aerosol or fine spray mist may cause serious respiratory problems. Inhaling
fumes or mists from overheating fluoropolymers may cause lung irritation and “polymer
fume fever” a temporary flu-like illness.

SECTION 03: COMPOSITION / INFORMATION ON INGREDIENTS

CHEMICAL NAME AND SYNONYMS CAS # WT. %

Ethoxylated perfluorohexylethanol 52550-44-4 24-26

Water 7732-18-5 Balance

SECTION 04: FIRST-AID MEASURES

ROUTES OF EXPOSURE
INHALATION.......................................... Remove person to fresh air. Keep person in comfortable resting position for breathing . Get
medical attention if symptoms occur.
INGESTION............................................ Rinse mouth with water. Do NOT induce vomiting. Contact physician as needed.
SKIN CONTACT..................................... Remove contaminated clothing immediately. Wash skin with plenty of water. Wash clothing
and clean shoes thoroughly before reuse. Get medical attention if irritation develops and
persists.
EYE CONTACT...................................... Flush with water for at least 15 minutes while holding eyelids open. Check for and remove
any contact lenses. Seek medical attention if irritation develops or persists.
SYMPTOMS AND EFFECTS.................... Inhalation may provoke the following symptoms: irritation, shortness of breath, lung edema,
cough. Eye contact may provoke the following symptoms: lachrymation, redness,
discomfort. Ingestion my provoke the following symptoms: Nausea, vomiting, diarrhea. May
cause damage to organs through prolonged or repeated exposure. Prolonged or repeated
skin contact may aggravate existing skin conditions. Inhalation of mists may aggravate
existing chronic respiratory conditions such asthma, emphysema or bronchitis. Inhalation of
aerosol or fine mist may cause serious respiratory problems.
IMMEDIATE MEDICAL ATTENTION AND All treatments should be based on observed signs and symptoms of distress in the patient.
SPECIAL TREATMENT Consideration should be given to the possibility that overexposure to materials other than
this product may have occurred. Treat symptomatically.

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PRODUCT: Cambrex S31

SECTION 05: FIRE-FIGHTING MEASURES
SUITABLE AND UNSUITABLE ................ Water spray. Foam. Multi-purpose powders. Carbon dioxide.
EXTINGUISHING MEDIA
HAZARDOUS COMBUSTION PRODUCTS This product is non-flammable. However, if involved in a fire or if overheated
(>200°C/392°F), there is a risk of generation of toxic degradation products such as
hydrogen fluoride, carbonyl fluoride, carbon monoxide and carbon dioxide. Toxic products
generated by heat degradation may cause severe respiratory injuries or even death.
Between 425-450°C/797-842°F, toxic particulates with a size of 0.2-0.5µm may be
generated by heat degradation. Over 470°C/878°F, perfluoroisobutylene may be generated
by heat degradation. .
SPECIFIC HAZARDS................................ Container may rupture on heating. Harmful or toxic vapors may be released. .
SPECIAL PROTECTIVE EQUIPMENT .... Wear self-contained breathing apparatus and protective clothing.
AND PRECAUTIONS FOR
FIRE-FIGHTERS

SECTION 06: ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS & ............... Use personal protective equipment. Ensure adequate ventilation . Wash thoroughly after
PROTECTIVE EQUIPMENT handling. Spill area may be slippery.
EMERGENCY PROCEDURES................. Prevent further leakage or spillage if safe to do so. Avoid dispersal of spilled material to
minimize contamination of drains, surface and ground waters . Absorb material with inert
substance and place in appropriate container for safe disposal .
METHODS AND MATERIALS FOR ......... Absorb spills with vermiculite, fuller's earth, or sand. Shovel up and place in a non-metal
CONTAINMENT AND CLEANING UP waste container for disposal. Dike large spills with soil or sandbags to contain it and
prevent its spread. Keep in suitable, properly labeled, closed containers for disposal.

SECTION 07: HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING.. Wear personal protective equipment. Keep container closed. Use only with adequate
ventilation. Do not overheat.
CONDITIONS FOR SAFE STORAGE...... Store in a well-ventilated place. Store in a cool dry place. Keep container tightly closed.
Keep away from heat and sunlight . Storage temperature range: 5-30°C. If material freezes,
gently thaw prior to use. Mild agitation may be required.
INCOMPATIBILITIES................................ Please refer to Section 10 for list of incompatible materials.

SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION

ACGIH TLV OSHA PEL NIOSH

INGREDIENTS TWA STEL PEL STEL REL

APPROPRIATE ENGINEERING .............. In applications where the product will be exposed to elevated temperatures, use local
CONTROLS ventilation to remove potential decomposition products. .
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY PROTECTION............. In operations where mists are generated, wear a NIOSH/MSHA approved respirator that
has been selected by a technically qualified person for the specific work conditions. .
HAND PROTECTION............................. Wear natural rubber gloves. Observe instructions regarding permeability and breakthrough
time provided by the supplier of the gloves. Also take into consideration the specific local
conditions under which the product is used, such as the danger of cuts, abrasion and
contact time.
EYE PROTECTION................................ Wear safety glasses with side shields or goggles. Eye and face protection requirements will
vary dependent upon work environment conditions and material handling practices.
Appropriate ANSI Z87 approved equipment should be selected for the particular use .
SKIN PROTECTION.............................. Wear footwear protecting against chemicals, and impervious clothing. Choose body
protection according to the amount and concentration of the substances in the workplace. .

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE.......................................... Amber liquid.
ODOUR..................................................... Mild characteristic.
ODOUR THRESHOLD.............................. Not available.
pH.............................................................. 5 - 7.
MELTING POINT...................................... Not available.
FREEZING POINT.................................... Not available.
BOILING POINT........................................ Not available.
BOILING RANGE...................................... Not available.
FLASH POINT........................................... Does not ignite .
DENSITY................................................... 1.15 g/ml (25°C).
EVAPORATION RATE.............................. Not available.
FLAMMABILITY (SOLIDS AND GASES).. Not applicable.
UPPER FLAMMABILITY LIMIT................. Not available.

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PRODUCT: Cambrex S31

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES
LOWER FLAMMABILITY LIMIT................ Not available.
VAPOUR PRESSURE.............................. Not available.
VAPOUR DENSITY................................... Not available.
SOLUBILITY.............................................. Water solubility: dispersible.
PARTITION COEFFICIENT - .................. Not applicable : Surface-Active.
N-OCTANOL/WATER
AUTO-IGNITION TEMPERATURE........... Not available.
DECOMPOSITION TEMPERATURE........ Not available.
VISCOSITY............................................... Low viscosity.

SECTION 10: STABILITY AND REACTIVITY

REACTIVITY............................................. Not classified as a reactivity hazard.
CHEMICAL STABILITY............................. Stable under normal conditions.
POSSIBILITY OF HAZARDOUS .............. Under normal conditions of storage and use, hazardous reactions will not occur.
REACTIONS
CONDITIONS TO AVOID.......................... No specific data.
INCOMPATIBLE MATERIALS.................. Oxidizing agents.
HAZARDOUS DECOMPOSITION ........... On combustion or on thermal decomposition: carbon monoxide, aldehydes, flammable
PRODUCTS hydrocarbon fragments.

SECTION 11: TOXICOLOGICAL INFORMATION

INGREDIENTS LC50 LD50

ROUTES OF EXPOSURE
EYE CONTACT...................................... No data available.
SKIN CONTACT..................................... Acute dermal LD50 rat >5000mg/kg.
INHALATION.......................................... LC50 rat 4 h > 5.9 mg/kg.
INGESTION............................................ LD50 415 mg/kg.
SYMPTOMS.............................................. No data available.
TOXICOLOGICAL CHARACTERISTICS
IRRITATION/CORROSION.................... Not classified.
CARCINOGENICITY.............................. This product does not contain any ingredient designated as probable or suspected human
carcinogens by IARC, ACGIH.
SENSITIZATION.................................... Not classified as sensitizing by skin contact.
SPECIFIC TARGET ORGAN TOXICITY Not classified.
(SINGLE EXPOSURE)
SPECIFIC TARGET ORGAN TOXICITY May cause damage to organs through prolonged or repeated exposure.
(REPEATED EXPOSURE)
ASPIRATION HAZARD.......................... Not available.
DELAYED AND IMMEDIATE EFFECTS... No known significant effects or critical hazards.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICITY.......................................... LC50 96hr Oncorhynchus mykiss 36.7 mg/l. ErC50 72hr Pseudokirchneriella subcapitata
88.3mg/l. EbC50 72hr Pseudokirchneriella subcapitata 50.3mg/l. EyC50 72hr
Pseudokirchneriella subcapitata 50.1mg/l. EC50 48hr Daphnia magna 28.8 mg/l.
PERSISTENCE AND DEGRADABILITY... No data available.
BIOACCUMULATIVE POTENTIAL........... Not available.
MOBILITY IN SOIL.................................... Ultimate destination of the product: Water/Sediment .
OTHER ADVERSE EFFECTS.................. No known significant effects or critical hazards.

SECTION 13: DISPOSAL CONSIDERATIONS

HANDLING PROCEDURES..................... The generation of waste should be avoided or minimized wherever possible.
METHODS OF DISPOSAL....................... Dispose in accordance with local, regional, national, international regulations.
CONTAMINATED PACKAGING............... Since empty containers may retain product residue, follow label warnings even after
container is emptied.

SECTION 14: TRANSPORT INFORMATION

TDG / DOT................................................ Not regulated.
UN NUMBER
PROPER SHIPPING NAME
CLASS
PACKING GROUP
IMDG......................................................... Not regulated.
UN NUMBER

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PRODUCT: Cambrex S31

SECTION 14: TRANSPORT INFORMATION
PROPER SHIPPING NAME
CLASS
PACKING GROUP
IATA.......................................................... Not regulated.
UN NUMBER
PROPER SHIPPING NAME
CLASS
PACKING GROUP
ENVIRONMENTAL HAZARDS................. Not available.
TRANSPORT IN BULK ACCORDING TO Not available.
ANNEX II MARPOL 73/78 AND THE IBC
CODE
SPECIAL PRECAUTIONS........................ Read safety instructions, SDS and emergency procedures before handling.

SECTION 15: REGULATORY INFORMATION

TSCA......................................................... All components are listed or exempted.

SECTION 16: OTHER INFORMATION

DISCLAIMER............................................
All information in this SDS is based upon data obtained from the manufacturer and/or
recognized technical sources. This information is believed to be accurate and is offered
only as a guide to the handling of this specific material and conditions. The use and
handling of this material may require alternate and additional considerations. No warranty
of any kind is given or implied and the company will not be liable for any damages, losses,
injuries or consequential damages which may result from the information contained herein.
PREPARED BY......................................... Regulatory Affairs
LATEST REVISION................................... 2023-09-05

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