CONFIDENTIAL

DAY. 08

2023 II 01 1100 (E)

JM-434

CHEMISTRY (55)
Model Answers and Scheme of Marking

Time : 3 Hrs. (11 Pages ) Max. Marks : 70

Nites
() Scheme of marking should be strictly followed.
(i) Answers given below are not necessarily complete answers but are
guidelines for assessment.
(ii) Any alternative correct method should begiven full credit.
iv) Unit must be written as per the standard rules. Deduct half mark for
wrong unit or no unit.
() n case ofMCOs [ie. Q.() to ()] evaluation should be done for the first
attempt only.
(vi) For each MCQ, correct answer must be written along with its alphabet.
e.g. (a).../(b).../ (c)...)...
No mark (s) shall begiven, ifonly thecorrect answer or the alphabet of
the correct answer is written.
(vii) Individual questionwise marks should be written for each section
(exchuding marks of extra questions) inside the answer book and the
total should be rounded up sectionwise only.
(Section A (0. No. land Q. No.2); Section B (. No.3 to Q. No. 14):
Section C (Q. No. 15 to Q. No.26); Section D (. No. 27 to Q. No.31)]
(vii) Total of marks for each section should be written on the cover page of
the answer book sams as inside.
(ix) In case of chemical reactions deduct ½mark if proper conditions
are not written..

o434 Page 1 P.T.0.

 255] 694 n
SECTION -Á
Q. 1. Seleet andwrite the correet answer i
Page nNor13 (i) (e) f= 4 (1)
53 (i) = (a) 1.585 10- mol dm3 (1)
(bike 2303 Pi
128 (ii)
log10 3p1-P (1))
112(iv) (b) 5.916 BM (1)
i16 (v) () [Pt Br, (NH,),j Br, (1)
211 (vi) = (d) CH,=CH -CH,-X (1)
239 (vi) = (b) CH;-CH=CHCH, CH, OH (1)
260
(viii) (c) acetöne (1)
205(ix) (6) a-1,4-glycosidiclinkage (1)
g2(x) - (a) Isoprene ()
(10
Q. 2. Answer the following questions :
348 (1) X-ray diffraction (XRD) -
285 (i) Ethylamine or Ethanamine (1)
(1)
138 (iv) Na,AlF6 (1)
g0t (v) cisplatin
28 (vi) K kgmol- or °Ckgmol-1 (1)
oois ve
84 (vii) AG<0 (1)
1000k 10 x10-2 1000
C 5x10-45 -=20n-'emmol-! (1)
(8)
|o434 Page 2
 SECTION -B
Attempt any EIGHT of the following questions : |16]
)88 Lanthanoids Adinords
Q. 3. Any four correct points. Mak oxid"'sike shows owi dnghubea Yax4=2
Do not foym
Gecter tendency o
complex easly (2)
Non -ruiotve |orna Compler cOmp
35 Pi-P (ccpt ponethiun ) All ave' yadioacie
Oxocuions
Q. 4. Ldnthonoids do nør Acinoi Js Rovm ()
Pi form oxO CUOns such as vot e
640-600 Most ot th e S ar
Lanthqnod the acHnoi ds qre
cOLOU less
co loured ions
640 LanhntJe ydroidoo
40 Spl4 6s2
X, =0.062
640 16 (1)
chemisty of chemistytor pollwhon
is the usetly (2)
940
Green
PrevenHon h envirornmen con dous design oP
Q. 5. Correct definitioH chemicod produo's cnd pocesses ht (1)
Su bStunce
gsi Any wocorrect advantages of nanoparticles and nanotechnology. (1)
Teuices beome nore e{euent malce soloy powe moe economical (2)
wUrig ot thrtaeniag dis eases e cancet qnd isbete
Q. 6. Correct explanation of dre Paund a heelHee
Jo t<y notgud In hiS depeCt the foye'gn atoms
I8 (a) Substitutional impurity defect Sites in place ot hosr oms (1)
aoms dTe isplated From thuY Jtce sCs bt impurity aons
19 (b) Interstitial impurity defect In tniS detect tne impun(1)
ahoms Ocepintesi iad spaces t lattce stuure
(2)

Q.229
7. +H,SO, AO- setH ++H,0 (1)
rea? fuming
SÕ,H
220 C,H,- Br +CH,COOAg-A CH, COOC,H, t AgBr (1)

Acd'e bu tley s0luhin AsolwHun containing (2)

Q. 8Correct definition a wek acid cnd its s t s Ui tn Song (1)
basee
CeFFeet example-ofeach (1)
59
Ksp = (1)(2) s2 =4s?
ksp2 4s m (2)
Page 3 P.T.0.
 242
Q.9.
Q. 9aa) C,H,-NH, +CHCI, +3KOH -C.H«NC+3KCH3H,0 (1)

b) CH,-NH, +HNO, NaNO, +HCI

+HC C,H,-OH+N, T‘+HCI (1)
273-278K
(2)
108 (5-)
Q. 10. E° cell=E'ah-E =-0.136-(-0.403)v=0.267 v (A)

AG°=nFEell
=-2x96500 x 0.267 (4)
=-51.53kJ -51531I -S1s3 1voltCuas (1)
Y Y
(2)
249
Q. 11. Cp H, O| +H,0c"H0, +CoHË20% (1)
Glucose Fructose

5
316 OH
HOH¢ pHo
4 ischer oy
(4)
StUtire,
3 2

OH OH
D-boy
(2)

12. Correct definition Gztensi ve popery!-pper depend on (1)

dmountot mn tet
p0 .". W=0 (l)
67
(2).
13.,HO0C- (CH,)4 -COOH #H,N-(CH,)%-NH,
Q.938 (2)

°o0c-(CH,),-Coo°H,N-(CH)% -NH,1
4533K (4)
high pressure

Page 4
0 43 4
 Te-(CH2)4--NH- (CH,)% NH +21,0 (1)

Q. 14. (a) Correct structure H-0- o chloi aud (1)

(b) Correct structure yo ()
peroxy disulphuvieaue
2)
SECTION-C
Attempt any EIGHT of the following questions : [24]
molecules Pom
How ofsolvent
Q. 15. Correct definition of osmosis olNenl
Solven t tu solHon (1)
T d m Spont0geeus Pow fSolvent mo lecae
e3tATHen into so" 0rfom morc. lol. S0n tomer
ATb= Kb Xm
nolabnBut m-= 1000xW, (A)
M, WË in

.:. ATb= Kbx:1000 × W (A)

M,W,
1000KbW2
(V)
ATbx W
3)

p. 16. 1) CH, -CH, -OH+ HO C-CH;

244

CH,-C-0C,Hs+H,0 (1)
Ht
cooCHs t Caoo.
O43 4 Page 5 P.T.O,
Ptiine
 eLco5\o0-os3
( (3 0000 - o-y17)
(tlis214)
co:7l40e5-33
248 QH
(1)
(ü) +Zn +Z0
250
A
’2C,H,Cl+ POCl, (1)
(i) CzHs-0-C;Hs +PCI^
(3)
015m
Q. 17, Data i slo7, =0|, Ga 0-os m,cs (A)
(33) Fomula Ka =dc, t c ,
Substitution (o)x0 o5 dyx o Sx(64 (4)
15 X0L
Degree of dissociation < 0: 0577 (1)
% dissociation = 5.773 3 (2)

Dehychohlgen ioni- Removal of holvgen atom dnd ahdrgen 3)

aomrom
Q.
aybon eKpia? Itreaio
18.
225
CAFreet definition and explanation of dehydrohalogenation
reaction. eHcsDr (1+)
230 Use of CFC n arnire sol.Slowing cagert ()
230 Environnental effect to ams pucdeing mtend
distey oenelor in otmoshre (A)
oone depleHoo| sicIN Cancete )argao d mte
20L, V 3L ,Te 3ools, 22&314
(3)
Q. 19. Data (mmnol to mol) Yz n 2000mmo] = 2 mo)
Wmax Formula \Wmag -2303nRT Jes,
(A+A)
Substitution Wmax-203x2% 83)4xo0Joo
-20222-2.02es
Correct answer with proper unit (½+ ½)
IntersHH ay cOmpds!- when Smal toms ke (3)
Q. 20. Correct definition (e<plo?) drogen,orborn d itgen are tpped
inne intersiHl spaeS wlhin The (1)
14s Ferrous alloys with example avec e Intey H wmnds
Non-ferroSa (½+ A)
saloys with example (½+ A)
Frous loys -heveoms ot othe elements 'smsted
yandonly in aom! ot von ia hre mire et nidcel
chomium stelswole steeL e
0 434 un-termous (3)
tuniHo alotge one
etel othee dhan inon with a
b min g hom o
e- bassy wwea is an ally ot cuppe and cino
Q. 21. Diagram (1)
Necessary labelling (1)
Applications offuel cell (2 x2=1)
in aomobile 3)
space. Cralts
()
22, Oxidation state of Co is +3
D.202

3d 4s 4p

()
3d 4s 4p 4d
SPdouter complex (4)
Octahedral complex (4)
()
Paramagnetie
(3)
. 23, Certain reaction which areexpected to be of higher order follow (eKlan
melaen)
12, the first order Kinetics is called Pseudo-first order reaction. (1)

A P
-d[A] (2)
rate = K[A]
[Alt
d(AJ= -K|4 (1)

(4)
Kt=(A1 -[A],
(3)

0434 Page 7 ÉIO.

 (4)
24. () Aldehyde or Ketonecontaining
Q.272 -H
addition-elimination reaction (A)
() Also called nucleophilic

CH,--H+CH,--H 9 Nab CH,- CH-CH- Þ-H (1)

OH H"
H
A H,0

a, ßunsaturated aldehyde (1)

But -2 enattaH
(3)
(1)
Q. 25. Atomicity - O, diatomic others polyatomic
142
(1)
magnetic property-O,paramagnetic others diamagnetic
oxidation state - -2, - 1,+2 for Oxygen ant (1)
Others show -2, +2, +4, +6 oxidation states.
(3)

Q. 26. ) CH, C-OH CH,C (1)

279
+ Concdes°y O+H,0
CH, C-OH P, O,cH,C

dry ether
274 (i) CH, -CO0H +LiAlH, +CH,-CH, -OH (1)
-NH CH,
N-methylaniline OR (VatA)
224 N-methylbenezenamine
(3)

0 434 Page 8
 SECTION - D

Attempt any THREE of the following questions : [12]

Q. 27. For 99,9% disintegration For 90% disintegration
|34

'99,9=2.303 yxlog.(Al, '90= 2.k303 log 100

k
2.133 [Al, 10

2203xEx log 101o

k
'90=2.303
k
x11 ()

'99.9 =3x (2.303)

k
1mark t t
90=3x 99.9 (1+2)

183
Gd(Z= 64) [Xe]4f'5a!6s2 (1)
350 Carbon black (1)
(4)

Q. 28. AH=AU+PV, - PV, ov ()

PVj =nRT, PV,= ngRT (()

AH= AU+ nRT -nRT (4)

AH = AUn, - n)RT
(2)
AH=AU + AnT
a neuoyl<, o eyos in
327 Correct definition Te proes by wich
The bond that connects a-amino acids to each other is called
31° peptide bond (1)
OR

C-NH Bond is called peptide bond (1)

(4)
P.T.O.
Page 9
 nM
Q. 29. P= (2)
8 N Xa

for fcc n=4

4x108
6.022 x102 x(400 x10-10 (V)

p=4x108/ 6.022 x64 x10-!

P=ll220 g (1)
22 Acetaldehyde and methyl Ketones and alcohols containing
Ciseptgt CH-CHOH group warmed with NaOH and I, gives yellew
Ppt (1)

NaOH
CH3- C -CH3 +3 NaOl CHI;
ketner aldehtea
Xis ole
+CH,C0ONa + 2NaOH (1)

4)
Q. 30. Correct definition Diastereomners!- ophCel iso mecs wheh are
198 not iroy images ot each o her
Iog
198
cis isomer and Trans isonerH Co (Ata)
j08 Correct definition (1)
Aete

167 Ozone bleaches in absence of mojsture so it is also known as

dry bleach reyui rea
(1)
Relerece elecho ele da electwde hse poteaHia s.
drbitraiy tadcen ds cer is exacH y (<nOwn.
l<nou

0434 Page 10
 Myot
Na Mt
Ø QH
Q. 240
31. +NaOH A HCI, (1)
pressüf¿

QH OH
Br. Br
247(+ 3Br,/water 43HBr (1)
Br
84 Stability is due to halffilled p-orbital ofGroup-15 (1)
(49 Any two uses of dioxygen (1)
G) For yespireion i) in shcel manifacuring (4)
) 099en cylinders in hospitlountnee Ting,
high alHtude ying i ) Comhisim ot fuels Rghdrne
xyetene Acime toT welyt cutiny sreee
GPISelemets have. hP Plleel p-osbitals . moye Stable
4 hus ghet vae o ionisei on enthalpy then leyP

o43 Page 11