on between
1
) tember Q
Ne es
Tt ext
ef sueaction in which whe fsroduet
Jess olyee
A °
Cane Con
(malenic ae? d) % Considew the geste CGongecutive Keachou &-
Ape
Viste low) WAl> 18) exb( 4?)
don each [8] = KCAL [ewes - expl-kt))
ee Keke
[ce] = [Ae] (u Ka exbl Kit) “tle? )
Ki
SYaidict Me Conc of LO] with hme =~
1 \.
ee ee
fasy Slow
i tua teeue wn be Alec ct Baud Hew j# will
Convest to € aba function ot dime.
yy
ation sf LA
Conecsil 68
A i
i
3
J
:
5
2 1%
a
4
4
4
a
4
6
C
@
8
CI
3
e
4
3
@
@
3
a
3
2
8
e
9
@
3
3
3
a
3
a
a
" a
time — q
4
4a
ste Ag Kil becomes Guenter the Rint P goes up aud
up aud above . a
; K
isa 2
Slow ee
Th thip , We Slowh foun Bau) i} Heacte dant to give C -
the Concereration of Bip vey frna\) Harough out the
Heaahon.
Concentertatioe
dime —
Ap Kilig decteapes » Conceterotion of B in veny Very
(almest snealig te) rol. Atter gome Hime Cone of B
Gato (it becomes ques! Conptaut) and
d{8] -0
eet
Pearle wcl.O 7 Kila) = ¥.18] [ge
Concenteration of
—Sieady tote abbueximation.
Concestenotion of BL
Deacel CUAON
Uged ino He:
4# Steady state appsioximavien fails a6 Koon we Ki 2K,
becomegtwue- ° ‘he Bteady state appyox tmattor ae
Ky Ka
a—B ao
Write Hhe rate lou fou the buocees diel _ 14 [9]
de i
> Tderh4y the intewmediore In Hoe Site tows ond obbly
Bready Ailate abbriovinahovn OF Ky,
WilAbe - a (elles
mteimediote «
qhe exbueszion of Mote tous fous
Sere) io
Josieduct ~
OES ia) ~ Koll, = eX fay - 1
ae Ko
44 hie, works Only 4, < Ko
Wie Equotion for tre Creo Hon and Congubtion af He
@©oe@eeaoeeseseeseeoegegeedvgeguegaeegeeoesgsvesveeseseanamh de oa #t Sunfoce Reaction Medle + (Aoitin Ron] desesbten)
Phyaleal mane tousten Stcbs one mot giote Conteelling when
pusiface wedction modd)z OMe develebed. Interface ond Tnjwedlace
troup post foroceaacé ate fastens
Susifece Geaction Hotes
_ os. oe
Bieb-5 =" ipyis) Rs
Syn 910112 indo the €qn-S=-
. Subptituting
jo = Pa [163] [2 OE)] - Rs [KW] [Ks (2)]
S
— |'4) bo = Rak K De: Kas
je) o) eS
Ka Ki Keq
pe ene ee ae
13
From Eqn-! &-
Peed ot Ser Sd HOt ey sites
So= $+(As)4 (@8)+ (CS) \(Os)+ GS)
Subz tluting Eqn 9-12 inio tha.
So= St Ki(alls) + K(els) 4 Ky (OL
EO SO ae 0s)
(141 fa) + 404 Hal * Kal) + Ka (2))
Sibstituting Eqn (16) in Eqn (4) =>
fh = aK RS." | 8 |
[\HmALK.® + Kye KeO lL)”
aL | 5 Be Ra KS
TPR AsKjBHKl4KeD + Vs1)>
~ (Caled
fo= Rien ~— Ge ee ts
The Gae Hic Hy Co Helo Rae)
A tbs) — ee
ee [ents ee
tek, Kik, So ————(\)
(ie bat Ket he bet Us bo +Krls
Oeeeoeseeseeseseee
S) + ks (06) +, (ey
ran eeangagenegeseesdvd OvUaRseseseeses Ae Eveui though the Cenglasit Notations in Eqn (lb)ond Eqvll) iz, ket Same
theNalue Of Conptauts Goce - diftue becouze in equilib)!
Conceuteriation 1 Coypidened whetie a& in Eqn( 1%) patitial puessusies
ave Copaidered
Note |
Rote Cont xollivg Bleb ip mot ducsed in the
Jind | think oF the ‘mechaniem and tote Cont Holling fiep
expression 13. give «
deuominator. £o we con
if the Hate.
+ Adgosption Contsol =
pee 2
R
Bleb-| >: A+tS ae (as) (cp)
@)
ps Ss (RS)
Ry
es) =n eg —————=
Sep? >
aiek=3, =:
ip the Hate EontBolling ‘S
Adsorption 1 A (En -1) (Seb)
t= k,AS)= by (Ps)
(Rs)
from #tep-2 == Ki = tas)
= (2S)
Bee Gl cay
