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university of buea chm201 exam 2024

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Document 8

university of buea chm201 exam 2024

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2peterliman
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L UNIVERSITY OF BUEA FACULTY OF SCIENCE FIRST SEMESTER EXAMINATIONS - 2022024 DEPARTMENT: CHEMISTRY ‘COURSE INSTRUCTORS: NforBeckley/Anoro‘Toh-Boyo/Ekane MONTH: Janay ‘COURSE CODE & NUMBER: CHM 201 YEAR 2024 COURSE TILE: GENERAL CHEMISTRY Dave: .xeram. ‘TIME: 10:30-1230 TIME ALLOWED: 2 HOURS (CREDIT VALUE: 6 ‘VENUE: ALL HALLS INSTRUCTIONS: ANSWER ALL QUESTIONS. There are two parts of the examination: Parts A and B ‘The Gueston paper must be returned alongside the answer bookies DO NOT TAKE 11 AWAY! PART A: Choose the correct auswer and neatly mark the corresponding letter on the multiple choice section of your answer booklet with an X. « Whict of the following is a buffer solution? CH COOH 4) H:SQc+ CuS0, B) CH;COOH + CH;COONH, C) NaCl + NaOH ‘D) CHsCOONe + CHsCOOH Q2. The sclubility product expression for tin(I{) hydroxide, Sn(OH)a, is A)[So*]JOH] B) [Sn*P[OH] ©) [Sn JOH? D) [Sn P[OH] Q3. The molar solubility of PbBr2 is 2.17 x 10° M at a certain temperature. Caloulate Key for PbBr. A)6.2x 10% B)64x107 C)4.1x10% D)3.4x 10% Q4. What is the molar solubility, s, of Bas(POs)2 in terms of Ksp? A)S=[Key4]¥ B)s=Kep!® C)s=[Kg/27]!5 D) 8 =[Kep/l08]" QS. A reaction is reversible because A) reactants are reactive B) products are reactive C) products are stable D) reactants are stable Q6. A large value of Ke means that at equilibrium A) less reactants and more products B)more reactants and less product C) same amount D) none Q7. Which one of the following will change the value of an equilibrium constant? A) Adding other substances that do not react with any of the species involved in the equilibrium B) Varying the initial concentrations of reactants C) Changing temperature D) Varying the initial concentfations of products. * Q8. At equilibrium, A) The rates of the forward and reverse reactions are equal 8) The rate constants of the forward and reverse reactions are equal chemical reactions have ceased D) The value of the equilibrium constant is 1 Q9. Dissolving table salt (NaCI): Is it a physical or chemical change? A)Physical B) chemical C) neither D) both chemical and physical chan are unveived i ts of chemical indicator in solution consist : 7 Swacial and its conjugate base B) Strong acid and its conjugate ee ie in Weak acid and its conjugate acid D) Strong acid and its conjugate aci . ee ‘ Bee 1. Which of the following is used as an indicator in the titration of a strong acid and a weak bas on Phenolphthalein B) Thymol blue C) Fluorescein D) Methyl orange Qi2. The idea! indicator for the titration of strong acid and weak base should have pH range between ~A)5-3 B)4-6 C)8-10 D)7-8 itrati 2 ith a 13) The following titration curve is the kind of curve expected for the titration of a acid with a ___ base, = — pH 7 mL added A) strong, strong B) weak, strong C) strong, weak D) weak, weak Q14, Which of the following is a weak acid? A)HCL “B)HNO: C)HF —D) HaS0s QIS. What is the pH of a 0.01 M NaOH solution? Al B)7 O10 D)i4 Q16. Which of the following solutions will have the highest pH? A)O.IMHCIl B)0.1MNaOH C)0.1MNaCl D) 0.1 MHSOs QI7. A solution with a pH of 3 is how many times more acidic than a solution with a pH of 6? A)10 B) 100 C) 1000 D) 10000 Q18.What is the result of mixing a strong acid and a strong base in equal amounts? A) Neutral solution B) Acidic solution C) Basic solution) No reaction occurs Q19.Which of the following is a characteristic of a strong acid? A) It partially dissociates in solution. _B) It completely dissociates in solution, ©) It has a pH greater than 7 D) None of the above 20, Which of the following statements about the equilibrium constant (Kw) for water is true? _ A) Kw is equal to 1.0 x 10" at 25°C, B) Kw represents the dissociation of water int ions. C) Kw is higher at higher temperatures D) Alll of the above Q21. Ine solution, whai does Ky represent? A) Acid dissociation constant B) Base dissociation cor ‘ant C) Ion product of water D) uilibriwn consent Agee Wists she common ion effec ‘A) The dwsrease in solubility cf a salt due to the presence of a common ion B) che increase ia solubility of a salt dus to the presence of a common ion C) The change in pH when a strong acid is added to a weak acid solution 1D) The change in pHi when a weak base is added to a strong acid solution 228. Which of the following is an amphoteric substance? a adtmion cevim iytroxide (NaOH) B) Hydvochlovic acid (HCI) C) Water (H20) D) Nitric # HNOs ation wi is added to it? spans to the pH of a solution when a strong base is added to _ — aes B) deureases C) remains constant D) depends on the concentration of the base (2. What isthe pH ofa solution with a [H"] concentration of 1.0.x 107 M? 2 By? Ol Ds 226. Whatis the pO#T ofa solution with a (OH-] concentration of 1.0.x 10% M? ASB)? C7 D)3 . What is the value of Kw (ionization constant of water) at 25°C? 2g A)LOx10™ — B)1.0x107 —C) 1.0x 10" 1D) 1.0.x 107 Q2S.\What is the pH of a 0.1 M solution of acetic acid (Ka = 1.8 x 105)? A)13 B24 O47 D)62 Q29. Which of the following is NOT an example of a conjugate acid-base pair? A)NaOH/NeCl B)NHs*/NH3 C)HCI/Cl_D) acetic acid /sodium acetate 30. What name is given to the energies which accompanied the following chemical reaction? Naw) — Na @ ‘A) Heat of formation B) Heat of dissociation C) Lattice energy D) Heat of neutralization Q31. Which of the following electronic configurations corresponds to Zn”* (Zn=30) A) [ Ar]3d"° B) [ Ne]3d!° C) [ Ar]3d!°4s? D) Non of the above ‘Q32. Which of the following elements is an example of an exception to the octet rule in covalent 25. Which pair of numbers represents the assigned formal charge to the bromine and chlorine atoms in the interhalogen molecule: BrCls, NEr0,Cle0 B)Br=I,Cl=1 C)Br0,Clel D)Br=1, Cl=0. Q34. Which of the following electronic configurations correspond to the O* ion, A){Ne] 8) [He}2s’2p* C) [Ar] DB) [He]2s?2p* Q55. The increasing order of ionic radii of the f¢ OF he inre followiny ions is Li*, Be? 0? F, +4) Li’ < Be <0?

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