2022

Solved Paper - 2022 1

Solved Paper ONLINE

25th July 2nd Shift

6. The first ionization enthalpies of Be, B, N and O follow the
order
SECTION-A (MULTIPLE CHOICE QUESTIONS) (a) O < N < B < Be (b) Be < B < N < O
1. Match List I with List II. (c) B < Be < N < O (d) B < Be < O < N
List I List II 7. Given below are two statements.
(Molecule) (Hybridization ; Shape) Statement I : Pig iron is obtained by heating cast iron with
(A) XeO3 I. sp3d ; linear scrap iron.
(B) XeF2 II. sp3 ; pyramidal Statement II : Pig ion has a relatively lower carbon content
(C) XeOF4 III. sp3d3; distorted octahedral than that of cast iron.
In the light of the above statements, choose the correct answer
(D) XeF6 IV. sp3d2 ; square pyramidal
from the options given below:
Choose the correct answer from the options given below: (a) Both statement I and statement II are correct.
(a) A-II, B-I, C-IV, D-III (b) A-II, B-IV, C-III, D-I (b) Both statement I and statement II are not correct.
(c) A-IV, B-II, C-III, D-I (d) A-IV, B-II, C-I, D-III (c) Statement I is correct but statement II is not correct.
2. Two solution A and B are prepared by dissolving 1 g of non- (d) Statement I is not correct but statement II is correct.
volatile solutes X and Y, respectively in 1 kg of water. The 8. High purity (>99.95%) dihydrogen is obtained by
ratio of depression in freezing points for A and B is found to (a) reaction of zinc with aqueous alkali.
be 1 : 4. The ratio of molar masses of X and Y is (b) electrolysis of acidified water using platinum electrodes.
(a) 1 : 4 (b) 1 : 0.25 (c) 1 : 0.20 (d) 1 : 5 (c) electrolysis of warm aqueous barium hydroxide solution
3. Ka1, Ka2 and Ka3 are the respective ionization constants for the between nickel electrodes.
following reactions (A), (B) and (C). (d) reaction of zinc with dilute acid.
(A) H2C2O4 H+ + HC2O–4 9. The correct order of density is
(B) HC2O–4 H + HC2O2–
+ (a) Be > Mg > Ca > Sr (b) Sr > Ca > Mg > Be
4
(c) Sr > Be > Mg > Ca (d) Be > Sr > Mg > Ca
(C) H2C2O4 2H+ + C2O2–
4
10. The total number of acidic oxides from the following list is
The relationship between Ka1, Ka2 and Ka3 is given as
NO, N2O, B2O3, N2O5, CO, SO3, P4O10
(a) Ka3 = Ka1 + Ka2 (b) Ka3 = Ka1 –Ka2 (a) 3 (b) 4 (c) 5 (d) 6
(c) Ka3 = Ka1/Ka2 (d) Ka3 = Ka1 × Ka2 11. The correct order of energy of absorption for the following
4. The molar conductivity of a conductivity cell filled with 10 metal complexes is
moles of 20 mL NaCl solution is Lm1 and that of 20 moles A. [Ni(en)3]2+  B. [Ni(NH3)6]2+
another identical cell having 80 mL NaCl solution is Lm2. C. [Ni(H2O)6]2+
(a) C < B < A (b) B<C<A
The conductivities exhibited by these two cells are same. The
(c) C < A < B (d) A<C<B
relationship between Lm2 and Lm1 is
(a) Lm2 = 2Lm1 (b) Lm2 = Lm1 / 2 12. Match List I with List II.
(c) Lm2 = Lm1 (d) Lm2 = 4Lm1 List I List II
5. For micelle formation, which of the following statements are (A) Sulphate I. Pesticide
correct? (B) Fluoride II. Bending of bones
A. Micelle formation is an exothermic process.
(C) Nicotine III. Laxative effect
B. Micelle formation is an endothermic process.
C. The entropy change is positive. (D) Sodium arsinite IV. Herbicide
D. The entropy change is negative. Choose the correct answer from the options given below:
(a) (A) and (D) only (b) (A) and (C) only (a) A-II, B-III, C-IV, D-I (b) A-IV, B-III, C-II, D-I
(c) (B) and (C) only (d) (B) and (D) only (c) A-III, B-II, C-I, D-IV (d) A-III, B-II, C-IV, D-I
2 Chemistry

13. Major product of the following reactions is Choose the correct answer from the options given below:
O (a) A-III, B-I, C-IV, D-II (b) A-III, B-IV, C-I, D-II
2 HBr
(c) A-II, B-I, C-IV, D-III (d) A-II, B-IV, C-I, D-III
O
18. Glycosidic linkage between C1 of a-glucose and C2 of
Br Br Br b-fructose is found in
O Br O
(a) (b) (a) maltose (b) sucrose
O O (c) lactose (d) amylose.
(c) Br O Br 19. Some drugs bind to a site other than the active site of an
enzyme. This site is known as
O
Br (a) non-active site (b) allosteric site
Br O (c) competitive site (d) therapeutic site.
(d)
20. In base vs acid titration, at the end point methyl orange is
O
present as
14. What is the major product of the following reaction? (a) quinonoid form (b) heterocyclic form
–
OH (c) phenolic form (d) benzenoid form.
H
H2O
SECTION - B (NUMERICAL VALUE TYPE)
O Attempt any 5 questions out of 10.
O O OH
21. 56.0 L of nitrogen gas is mixed with excess of hydrogen gas
(a) H (b) H and it is found that 20 L of ammonia gas is produced. The
volume of unused nitrogen gas is found to be L.
O O O
22. A sealed flask with a capacity of 2 dm3 contains 11 g of propane
(c) H (d) H gas. The flask is so weak that it will burst if the pressure become
2 MPa. The minimum temperature at which the flask will burst
15. Arrange the following in decreasing acidic strength. is °C. [Nearest integer]
OH OH OH OH (Given : R = 8.3 J K–1 mol–1, Atomic masses of C and H are
12u and 1u, respectively.) (Assume that propane behaves as
an ideal gas.)
NO2 OCH3 23. When the excited electron of a H atom from n = 5 drops to
NO2 OCH3 the ground state, the maximum number of emission lines
(A) (B) (C) (D) observed are .
(a) A > B > C > D (b) B > A > C > D 24. While performing a thermodynamics experiment, a student
(c) D > C > A > B (d) D > C > B > A made the following observations.
CH3MgBr H3O+ HCl + NaOH → NaCl + H2O, DH = 57.3 kJ mol–1
16. CH3 - CH2 - CN A B CH3COOH + NaOH → CH3COONa + H2O,
Ether
Zn – Hg
C  DH = –55.3 kJ mol–1
The correct structure of ‘C’ is HCl The enthalpy of ionization of CH3COOH as calculated by the
(a) CH3 - CH2 - CH2 - CH3 student is kJ mol–1. [Nearest Integer]
O
25. For the decomposition of azomethane,
(b) CH3 - CH2 - C - CH3 CH3N2CH3(g) → CH3CH3(g) + N2(g), a first order reaction, the
OH variation in partial pressure with time at 600 K is given as
(c) CH3 - CH2 - CH - CH3 Slope = –3.465 × 104
(d) CH3 - CH2 - CH = CH2  p
ln  
17. Match List I with List II.  p° 
t/s
List I List II The half life of the reaction is × 10–5 s.
(Polymer) (Used for items)  [Nearest integer]
(A) Nylon 6, 6 I. Buckets 26. The sum of number of lone pairs of electrons present on the
(B) Low density polythene II. Non-stick utensils central atoms of XeO3, XeOF4 and XeF6, is .
(C) High density polythene III. Bristles of brushes 27. The spin-only magnetic moment value of M3+ ion (in gaseous
(D) Teflon IV. Toys state) from the pairs Cr3+/Cr2+, Mn3+/Mn2+, Fe3+/Fe2+ and
Solved Paper - 2022 3

Co3+/Co2+ that has negative standard electrode potential, is 29. The separation of two coloured substances was done by paper
B.M.  [Nearest integer] chromatography. The distance travelled by solvent front,
substance A and substance B from the base line are 3.25 cm,
28. A sample of 4.5 mg of an unknown monohydric alcohol,
2.08 cm and 1.05 cm, respectively. The ratio of Rf values of A
R–OH was added to methylmagnesium iodide. A gas is to B is .
evolved and is collected and its volume measured to be 30. The total number of monobromo derivatives formed by the
3.1 mL. The molecular weight of the unknown alcohol alkanes with molecular formula C5H12 is (excluding stereo
is g/mol. [Nearest integer] isomers) .

1. (a) : 6. (d) : Ionization enthalpy generally increases on moving from

F F left to right along a period. But the trend is some what different
Xe here.
F F
O The first I.E. of N is greater than O due to presence of stable half
Square pyramidal
filled 2p orbitals.
sp3d2
The first I.E of Be is greater than B due to presence of stable fully-
filled 2s orbitals.
7. (b) : The iron obtained from blast furnace contains about 4%
carbon and many impurities (e.g., S, P, Si, Mn). This is known as
pig iron. Cast iron is made by melting pig iron with scrap iron and
coke. It contains lower C content (about 3%)
8. (c)
9. (c) : The density of elements of alkaline earth metals first
k f × w × 1000
2. (b) : Depression in freezing point, DTf = decreases from Be to Ca and then steadily increases from Ca to
m ×W
Ba. Thus, Ca has the least density.
Molar mass of solute X and Y is mx and my respectively
Property Be Mg Ca Sr Ba
Weight of solute X and Y = 1 g (given) –3
Density/g cm 1.84 1.74 1.55 2.63 3.59
W (wt. of solvent) = 1 kg (given)
10. (b) : B2O3, N2O5, SO3 and P4O10 are acidic in nature while
∆T f (A) 1 my
m y (Molar mass of y ) NO, N2O, CO are neutral oxides.
\ = ; =
∆T f (B) mx (Molar mass of x ) 4 mx 11. (a) : Complexes having more strong field ligands absorb
⇒ mx : my = 4 : 1 = 1 : 0.25 more energy due to increase in D0 and hence, greater splitting of
3. (d) : d-orbital.
H2 C 2 O4  H + + HC 2 O−4 ⇒ Ka1 The order of increasing field strength is en > NH3 > H2O.
HC 2 O4−  H + + C 2 O24− ⇒ Ka 12. (c)
2
+
H 2 C 2 O 4  2H + C 2 O24− ⇒ Ka3 Br
13. (d) : O HBr O
\ Ka3 = Ka1 × Ka2 (Read HC2O42– as C2O42–) O O
Br
Br O HBr
k × 1000 Λm1 M
4. (a) : Λm = ⇒ = 2 O
M Λm M1
2

Λm1  20 × 1000 20  1 H OH H +
= × = 14. (b) :
Λm
2
 80 10 × 1000  2 O O
O OH
\ Lm2 = 2Lm1 H
5. (a) H
O
4 Chemistry

15. (a) : –NO2 group stabilises the phenoxide ion to the greatest 11
extent due to –I and –R effect. (2 × 106 Pa) × (2 dm3) = × (0.083 × 105 Pa) × T
44
The further order of acidity is due to the –I and +I effects of ( R = 0.083 bar and 1 bar = 105Pa)
NO2 and OCH3 groups respectively. T = 1927.7 K = 1654.7°C ≈ 1655°C
16. (a) : NMgBr 23. (10) : (n = 5)
CH3MgBr (n = 4)
CH3 CH2 CN Ether
CH3CH2 C CH3
H3O+ (n = 3)
(A)
O (n = 2)
CH3CH2CH2CH3
Zn – Hg
CH3 CH2 C CH3 (n = 1) (Ground state)
HCl
(C) (B) n(n −1)
Maximum number of emission lines =
17. (b) 2
18. (b) : Glycosidic linkage between C1 of a-glucose and C2 of 5(4)
⇒ = 10
b-fructose is found in sucrose. 2
6 24. (2) : HCl + NaOH → NaCl + H2O; DH1 = –57.3 kJ mol–1
CH2OH
5 O 1
CH3COOH + NaOH → CH3COONa + H2O;
H H H HOH2C O H  DH2 = –55.3 kJ mol–1
4 1
O 2 5 CH3COOH CH3COO– + H+, DH3 = ?
HO OH H Glycosidic
3 2 H HO CH 2OH DH3 = DH2 – DH1 = –55.3 – (–57.3) kJ mol–1 = 2kJ mol–1
linkage
H OH 3 4
Sucrose OH H 1  po   p
25. (2) : k = ln ⇒ ln   = − k t
19. (b) : Some drugs do not bind to the enzyme’s active site. t  p   po 
These bind to a different site of enzyme which is called allosteric  p
site. In a plot between ln   v/s t, slope = – k
 po 
20 (a) : Methyl orange has quinonoid form in acidic solution
and benzenoid form in alkaline solution. – k = –3.465 × 104 s–1
21. (46) : N2 + 3H2 → 2NH3 0.693 0.693
For a first order reaction, t1/2 = =
(56 L ) (20 L ) k 3.465 × 104
2.5 mol 0.89 mol
\ t1/2 = 2 × 10–5 s
22.4 L of N2 = 1 mol
1 O F
1 L of N2 = mol F F F F
22.4
26. (3) : Xe Xe Xe
1 F F F F
56 L of N2 = × 56 = 2.5 mol O O O
22.4 F

22.4 L of NH3 = 1 mole of NH3 The sum of number of lone pair of electrons is 3.
1 27. (4) : The standard reduction potential of Cr3+ / Cr2+ is – 0.407 V.
1 L of NH3 = mol
22.4
Spin only magnetic moment, m = n (n + 2)
1
20 L of NH3 = × 20 = 0.89 mol of NH3 (n → no. of unpaired electrons)
22.4
= 3 (3 + 2) = 3.87 B.M ≈ 4 B.M
Now, 2 moles of NH3 require = 1 mol of N2
1 28. (33) : R – OH + CH3 MgI → CH4(↑)
0.89 mol of NH3 = × 0.89 mol N2 = 0.45 mol N2                    3.1 mL
2
22400 mL of CH4 = 1 mol
Since, 1 mol of N2 = 22.4 L
⇒ 3.1 mL of CH4 = 1.38 × 10–4 mole
0.45 mol = 22.4 × 0.45 = 10.08 L
Moles of CH4 = Moles of R-OH = 1.38 × 10–4 mole
⇒ Volume of unused N2 = (56 – 10.08) L = 46 L
Weight of sample (w) = 4.5 mg = 4.5 × 10–3 g
22. (1655) : PV = nRT Molar mass (M) = ?
Solved Paper - 2022 5

w w (4.5 × 10−3 ) g 30. (8) : H3C CH3 = 3 mono substituted products

Now, n = ⇒M= ⇒
M n 1.38 × 10−4 mole CH3
⇒ 32.6 g/mole 33 g/mol = 4 mono substituted products
H3C
CH3
Distance moved by the substance from base line
29. (2) : Rf =
Distance moveed by the solvent from base line CH3

2.08 1.05 R f (A) 2.08 CH3 CH3 = 1 mono substituted product

Rf (A) = and Rf (B) = \ =
3.25 3.25 R f (B) 1.05 CH3
= 1.98 ≈ 2.