INSTITUTE OF BASIC AND BIOMEDICAL SCIENCES
PHY 101 2022/2023 ACADEMIC YEAR
TUTORIAL SHEET 11: THERMODYNAMICS
1.The change in 𝐸𝑖𝑛𝑡 for any transition between two equilibrium states, can be defined by
a) 𝐸 = 𝑄 − 𝑊
b) 𝐸 = 𝑄 + 𝑊
Under which initial assumptions is equation a) and b) defined?
2. A gas is compressed at a constant pressure of 0.800 atm from 9.00 L to 2.00 L. In the process, 400 J of
energy leaves the gas by heat.
a) What is the work done on the gas? [567𝐽 𝑜𝑟 − 567𝐽]
b) What is the change in its internal energy? [ 167𝐽]
3. Heat is added to 2 mol of an ideal monatomic gas confined to a cylinder with a movable piston at one end.
The gas expands quasi-statically at a constant temperature of 600 K until its volume increases from 3V to 6V.
a) What is the change in internal energy of the gas?
b) How much work does the gas do? [6915.40J or -6915.40J]
c) How much heat is added to the gas? [6915.40J]
d) Calculate the change in entropy? [11.53J/K]
4. One mole of an ideal gas does 3 000 J of work on its surroundings as it expands isothermally to a final
pressure of 1.00 atm and volume of 25.0 L. Determine
a) the initial volume [0.00765 m3]
b) the temperature of the gas. [ 305K]
5. A 1.00-kg block of aluminum is heated at atmospheric pressure so that its temperature increases from
22.0°C to 40.0°C. Find
a) the work done on the aluminum, [ -48.6mJ or 48.6mJ]
b) the energy added to it by heat, [16.2 kJ]
c) the change in its internal energy. [16.2 kJ]
6. When 2.00 g of water at 100°𝐶 changes from the liquid to the gas phase at atmospheric pressure, its
change in volume is 2.5 × 10−3 . (𝐿𝑉 = 2260000𝐽/𝐾𝑔)
a) How much heat must be added to vaporize the water? [668j]
b) How much work is done by the water against the atmosphere in its expansion? [252.5J or -252.5J]
(c) What is the change in the internal energy of the water? [415.5J]
7. Heat is slowly added to a 500𝑔 chunk of ice at 0℃ until it completely melts into water at the same
temperature. What is the entropy change of the ice? (𝐿𝑓 = 334000𝐽/𝐾𝑔) [611.40J/K]
8. A gas is taken through the cyclic process described in Figure below.
(a) Find the net energy transferred to the system by heat during one complete cycle.
[12.0 kJ]
(b) If the cycle is reversed, that is, the process follows the path ACBA, what is the net
energy input per cycle by heat? [-12.0kJ]