Time: 3:15 Hrs.

II PUC CHEMISTRY (34) QUESTION PA PERS 2 Max. Marks: 70

Instruction:
1. The question paper has four parts. All parts are compulsory.
2. Part-A carries 20 Marks. Each question carries 1 Mark.
Part-B carries 08 Marks. Each question carries 2 Marks.
Part -C carries 12 Marks. Each question carries 3 Marks
Part -D carries 30 Marks. Each question carries 5 Marks
3. Write balanced chemical equations and draw diagrams wherever necessary.
4. Use log tables and simple calculators if necessary. (Use of scientific calculator is not allowed)

PART-A
I. Select the correct option from the given choices. 1 x 15 = 15
1. If the solute dissociate then molecular mass is
a) Increases b) Decreases
b) First increases then decreases d) Remains unchanged
2. Quantity of electricity required for reduction of one mole of Mg2+ ion is.
a) 96500 C b) 95500 C c) 193000 C d) 19300 C
3. Which of the following is the example for inert electrode?
a) Gold electrode b) Copper electrode
c) Zinc electrode d) Silver electrode
4. A reaction is second order with respect to reactant. How is the rate of reaction affect. If
concentration of reactant is doubled.
a) Rate = 2K b) Rate = 4K c) Rate =8K d) Rate =16K
5. The maximum oxidation state shown by the transition element is
a) Manganase b) Mangnasium c) Chromium d) Copper
6. The coordination number of a metal in coordination compound is
a) Same as primary valency b) Sum of primary and secondary valencies
c) Same as secondary valencies d) None of the above
7. The geminal dihalids is
a) 2,2 – dichloropropane b) 1,2 - dichloroethane
c) Vinyl chloride d) Allyl chloride
8. The most acidic compound among the following is
a) Phenol b) p-cresol c) p-nitrophenol d) Picric ac
9. Ethylene glycol is an example for
a) Monohydric alcohol b) Dihydric alcohol
c) Trihydric alcohol d) Non of this .

10. Tollen’s reagent is

a) Silver nitrate solution b) Ammonical silver nitrate solution
c) ammonium nitrate solution d) Silver chloride solution
 11. Carboxylic acids reacts with metals to form salts with liberation of
a) H2 b) N2
c) CO2 d) CO
12. Carbylamine reaction is answer by
a) Phenol b) Aldehyde c) 1° amines d) 2° amine
13. IUPAC name of (𝐶𝐻3)3𝑁 is
a) Methanamine b) N, N-dimethyl methanamine
c) N-methyl ethanamine d) N-ethyl methanamine
14. The rickets diseas is caused by deficiencies of
a) Vitamin - D b) Vitamin - A c) Vitamin - E d) Vitamin - C
15. The nitrogen base present only in RNA not in DNA is
a) Adenine b) Thiamine c) Uracil d) Guanine
II. Fill in the blanks choosing the appropriate word from those given in the brackets.
1X5=5
[Zero order reaction, Acetylation, Revers osmosis, Cu, Phosgen]
16. Desalination of sea water is application of .
17. Decompostion of HI on surface of gold is example of .
18. The non-transitional metal present in brass is .
19. The poisonous gas formed when chloroform is exposed to air and light is .
20. To get monosubstituted product of analine is protected by the processs .
PART- B
III. Answer any THREE of the following. Each question carries 2 marks. 2x3=6
21. Give any two applications of Henry’s law.
22. Draw the graph of potential energy versus reaction co-ordinate to show the effect of
catalyst on activation energy.
23. Write any two postulates of Werner’s theory of coordination compounds.
24. Explain Wurtz-fittig reaction with an example.
25. Complete the following equation and name the reaction: 𝑅 − 𝐶𝐻2𝐶𝑂𝑂𝐻 ⎯ x⎯H 2⎯
O ⎯
z Re d P
→

26. Draw the Haworth structure of sucrose.

PART - C

IV. Answer any THREE of the following. Each question carries 3 marks. 3x3=9
27. How is potassium permanganate manufactured write chemical equations
28. Write the difference between Lanthanoids and Actinoids.
29. a) 3d transition metals and their compounds are good catalysts. Give two reasons. 2m
b) Give the formula for the calculation of spin only magnetic moment. 1m
 30. Using VBT explain the geometry, hybridisation and magnetic property of
[𝐶oF6]3-𝑖𝑜𝑛. (𝑍 𝑓𝑜𝑟 𝐶𝑜 = 27)
31. a) What are homoleptic complexes? Give an example. 2m
b) Write the IUPAC name of the complex 𝐾4[𝐹𝑒(𝐶𝑁)6] 1m
32. a) Draw the energy level diagram to show splitting of degenerated orbitals in an o
tetrahedral crystal field. 2m
b) Write the type of isomerism exhibited by coordinate complexes having ambidentate
ligands. 1m
V. Answer any TWO of the following. Each question carries 3 marks 2x3=6
33. What are maximum boiling azeotropes? Give example.
34. Define molar conductivity? How is it related to concentration and conductivity?
35. a) State Kohlrausch law of independent migration of ions. 2m
b) Write the mathematical expression for limiting molar conductivity of sodium chloride
1m
36. Derive integrated rate equation for the rate constant of a zero order reaction.
PART-D
VI. Answer any FOUR of the following. Each question carries 5 marks 4 x 5 = 20
37. a) Explain 𝑆N1 mechanism taking alkaline hydrolysis of t-butyl bromide as example.
3m
b) Explain Finkelstien reaction with an example. 2m
38. a) How is phenol manufactured from cumene process? Give its chemical reaction. 3m
b) What is the product formed when formaldehyde is treated with Grignard reagent.
Write its reaction. 2m
39.a) How do you prepare methoxy ethane by Williamson reaction? 2m
b) How does anisole react with nitrating mixture? Write equation. 2m
c) Name the major product obtained when phenol is treated with zinc dust. 1m
40. a) Explain the mechanism of addition of HCN to aldehyde in the presence of NaOH. 3m
b) How do you prepare acetaldehyde from acetyl chloride? Name the reaction. 2m
41.a) How does benzene react with acetyl chloride in the presence of anhydrous AlCl3?
Give equation 2m
b) Explain Cannizzaro reaction with an example. 2m
c) Complete the reaction: 1m
 42. a) Explain Hoffmann bromamide degradation for the preparation of aniline. 2m
b) How do you convert benzene diazonium chloride into chlorobenzene by Gatterman
reaction? Give equation. 2m
c) Arrange Ammonia, Aniline and Methanamine in the increasing order of their basic
strength. 1m
43. a) Write chemical reaction to elucidate, 3m
i) Six carbon atoms is glucose are in straight chain.
ii) The presence of carbonyl group.
iii) Presence of aldehyde functional group.
b) What are reducing Sugars? Give an example. 2m
PART – E (PROBLEMS)
VII. Answer any THREE of the following. Each question carries THREE marks. 3 x 3 = 9
44. The boiling point of benzene is 353.23 K. When 1,80 g of non volatile solute is dissolved
in 90gof benzene the boiling point of solution is raised to 354.11 K. Calculate molar mass
of solute. ( Kb for benzene is 2,53K Kg per mol).
45. A solution is prepared by dissolving 18 gm of glucose in 150 g of water. The resulting
solution was found to have boiling point of 100.340 C. Calculate Ebullioscopic constant
for water.
46. The resistance of M/10 solution is found to be 2.5 × 103 ohms. Calculate the molar
conductance. (Cell constant = 1.15 𝑐𝑚–1)
47. Calculate the EMF of the cell in which the following reaction takes place.
𝑁𝑖(s) + 2𝐴𝑔+(0.002𝑀) → 𝑁𝑖+2(0.16𝑀) + 2𝐴𝑔(s)(𝐸cell
° = 1.05 𝑉)
48. Calculate time in seconds for the decomposition of nitrogen pentaoxide which
follows first order kinetics when concentration of N2O5 is dropped from 0.1 M to
0.001 M (K=6,22 x 10-4 s-)
49. The rate of a reaction increases by 4 times when the temperature of the reaction is raised
from 340 K to 360 K. Calculate the energy of activation of the reaction. Given R=8.314
J/K/mol.