24-12-2323 - JR - Star Co-Sc (Model-B) - Jee - Main - CTM-27 - QP Final
24-12-2323 - JR - Star Co-Sc (Model-B) - Jee - Main - CTM-27 - QP Final
           Q( 2  1)               Q( 2  1)                 Q( 2  1)               Q( 2  1)
      1)                      2)                        3)                      4)
            2 2 0                  2 2 0                      2 0                    2 0
                                      24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
8.   A linear charge of uniform density enters a cubical region in the condition shown
     with constant speed  and then leaves it. Flux out of cube,  versus time t, graph is
                                                                 
                                                           4
                                                                                  t
                                   24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                                                   
9.                                                               
      The electric field in a region is given by E  8 x  4 x3 iˆ  2 y ˆj  2 z kˆ N/C where x, y, z
11.   A total charge Q is broken into two parts Q1 and Q2 and they are placed at a distance
      R from each other. The maximum force of repulsion between them will occur when
      1) Q2 = Q/3, Q1 = 2Q/3                     2) Q2 = 3Q/4, Q1 = Q/4
      3) Q2 = Q/2, Q1 = Q/2                      4) Q2 = 3Q/4, Q1 = 3Q/4
12.   A charged particle of mass m = 1 kg and charge q  2  C is thrown from a horizontal
      ground at an angle   450 with speed 20 m/s. In space a horizontal electric field
       
       E  2 107 v / m exists. The range of the projectile on the horizontal ground is
16.   In a conductor a large number of free electrons which can move freely inside are
      available. If a conductor is given some charge, the charge
      1) is distributed uniformly throughout the conductor
      2) is distributed non uniformly throughout the conductor
      3) resides on the surface of the conductor
      4) resides at the centre of mass of the conductor
17.   A ring is in x y plane with its centre at origin. If the linear charge density of the ring
      is 2λ,-2 λ. λ and -λ in first, second third and fourth quadrants of the ring, then
      electric field at the origin will be along
      1) x axis            2) – ve x axis      3) y axis          4) – ve y axis
                                     Q
18.   In the Gauss law statement 
                                  E.ds  0
      1) E is due to charges lying inside the Gaussian surface
      2) E is due to charges lying outside the Gaussian surface
      3) Q is the charge lying outside the Gaussian surface
      4) Q is the charge lying inside the Gaussian surface
19.   Two point charges Q each are fixed at (-2,0) and (2,0).The Electric field at the point
      (2,2) is represented by
      1)                    2)                     3)             4)
20.   A simple pendulum with an insulating thread has a charge of Q on its bob of mass m.
      Due to a horizontal electric field E the string in equilibrium makes an angle of 450
      with the vertical. Then charge Q is
      1) mg/E             2) mg/     E         3)       mg/E      4) 2mg/E
                                      24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                                          SECTION-II
                                (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will
        be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21.    A point charge of 1 C placed at (0,0,4 m). The flux through a square of side 8 m lying
                                                                        q
       in xy plane with its center at the origin is found to be             Nm2/C. Then x is
                                                                       x 0
22.    A charge Q is lying on the axis of a ring (of a radius R) at a distance of             3R from its
                                                                Q
       center. The flux through the ring is found to be             . Then x is
                                                               x 0
23.    A thin hemispherical shell is having uniform surface charge of density  . Then the
                                                                                     
       electric field at the centre of curvature of the shell is found to be             . Then x is
                                                                                    x 0
24.    The degrees of freedom of oxygen gas at high temperatures is
25.    60 % of a diatomic gas molecules are disassociated into monoatomic molecules at the
       same temperature. Then the percentage increase in internal energy is
26.    One mole of a monoatomic gas undergoes a process given by TV-1/2 where T is
       temperature and V is the volume. The specific heat of the process is 13R/x where R is
       universal gas constant. Then x is
27.    One mole of monoatomic gas is subjected to isothermal process at the temperature of
       27 0C.If loge2 = 0.7 and if final volume = 8(initial volume) then the work done during
       the process is found to be xR where R is universal gas constant. Then x is
28.    A semi-circular rod is joined at its ends to a straight rod of the same material and
       same cross-sectional area. The junctions are maintained at different temperatures. The
       ratio of the rates of heat transfer through the semi-circular rod and straight rod is
       found to be x/π. Then x is
                                 24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
29.   An aluminium rod and a copper rod of lengths 20 cm each and cross-sectional areas
      0.20 cm2 each joined together are maintained at temperatures as shown. The junction
      is maintained at a constant temperature 40°C and the two ends are maintained at
      80°C. If the conductivities are
      KAl = 200 W/m-oC and Kcu = 400 W/m-oC then the amount of heat taken out from
      the cold junction in one minute in joules is
                                           
30.   An electrostatic field is given by           ˆ 2 /C
                                           E  2 x kNm      . The triangular surface shown is a
      height of h and width b. If the electric flux through the triangular surface shown in
      figure is mb2h/n where m and n are integers of least possible value. Then m +n is
                                      24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
CHEMISTRY                                                                         Max.Marks:100
                                             SECTION – I
                                (SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
===========================================================================
                               Na           Cold KMnO4
31.    H 3C  C  C  CH 3 
                            Liq . NH 3
                                        A         B Find nature of ‘B’.
                                                                    Conc.H3PO4
                                                                         
OH
OH
1) 2)
OH
3) 4)
33.    Choose the reaction sequence that would best accomplish the preparation of
       2-methylcyclohexanol:
                                                                 Br2/CCl4
                                                                                 Major product:
                                                       OH
Br
                             Br
      1)                                                    2)
                                                                                                  Br
                                              OH
                  Br                                                       Br
                           O
      3)                                                    4)
      CH3
                                 Hg(OAc)2, D2O
35.           C        CH2                         Major product:
                                  NaBD4, OH
      CH3
36.    Which molecule will give following dicarboxylic acid upon treatment with acidic
       solution of KMnO4 ?
                                                                 O
                                                                      O
                                         HO
                                                                            OH
                                              O             O
      1)                                                    2)
                                      24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
3) 4)
                     OH              Cl2
37
                                    NaHCO3
.
                 O
                                                                       Cl
                                                                                                OH
                                                                                 OH
                                                                                        4
      1)         O        O     2            O         O    3)
           HO                                                                           )
                                                                            O               O   O
                                     Cl                           Cl
                                                                   Cl2
                                                                 CH3OH
                          CH3                                                   CH3
                          Cl                                                     OCH3
      1)                                                   2)
                          OCH3                                                   Cl
                      H                                                     H
                          CH3                                                   CH3
                          Cl                                                     OCH3
      3)                                                   4)
                           H                                                     H
OCH3 Cl
39.                  HCHO, H
                                           Major porduct:
                       H2 O
                                                                            OH                  OH
                     OH                           OH
      1)                      2)                           3)                         4)
                                                                                OH                  OH
                     OH                           OH
                                       24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                        HOCl            NaOH,
40.                              (A)                 (B)
                                        H2 O         70%
                                        25°C
NO2
       1) R  P  S  Q 2) P  R  Q  S                   3) Q  R  P  S        4) S  R  Q  P
42.    Propane can be best prepared by the reaction:
                                    Ct2O
       1) CH 3CH 2 I  CH 3 I  Na    
                                        H 2O
       2) CH 3CH 2COONa  CH 3COONa 
                                     Electrolysis
                                                  
                                        Et2O
       3) CH 3CH 2 Br   CH 3 2 CuLi    
                             NaOH
       4) CH 3CH 2CH 2COONa 
                             CaO , 
                                     
       1) CH 3  CH  CH 2                                 2) CH 3  CH  CH 3
                    |      |                                            |
                    I      I                                            I
       3) CH 3  CH 2  CH 2  I                           4) I  CH 2  CdH 2  CH 2  I
                                               24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
1) HO N O 2) H N O
3) 4) All of these
CHO
                                                                     H+
                                                                               A
1) 2) 3) 4)
            OH
                             Br2                          MeOH
46.                                    HBr + (P)                     (Q) ; Product (Q) is :
                   Cl
                         O                               O                                                      O
                                                                                        O
                                Cl                                                                                  OMe
      1)                               2)    Br                          3)                         4)
            CH3O                                               OMe
                                                                              CH 3  C  OMe              CH3
47.                     H2SO4
                                       (A) ; Product (A) is:
                                     (Major)
                                                                                 OH                             OH
                                                      OH
      1)                             2)                        3)                              4)
                                                 24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
48.
                          CH3
                                                                       CH3    CH    CHO
      1)    CH3           C         CH2                       2)
                                                                              CH3
                              O
                      O                                                       CH3
                      
      3)                                                      4)
            CH 3  C  CH 2  CH 3                                     CH3    C     CH2
OH
50.                                        H+ (excess)
      HO                                                  (A). Product (A) is:
OH
      1)                             2)                           3)                      4)
                                           24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                                             SECTION-II
                                   (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will
        be
 evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
C O H
                       O
             COOH          COOH                      COOH                   COOH        OH          OH
                                       CH3
                                                                F
                                                                                                          CH3
             NO2                                                            CH3
             OH                        OH
                                                 NO2
                                                                H  C  OH              H 3C  C  OH
                                                                                               
                                                                     O                         O
NO2 NO2
52.    the total number of carboxylic acid groups in the product P is _____
                                                 O
                                                            O
                                                                               
                                                                    (1) H2O,
                                                                O                   P
                                                                    (2) O3
                                                                    (3) H2O2
O O
       (i)                 H
                       O            (ii)                            (iii)                    (iv)
             CH3
                                             24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                                                                                                                          OH
                     OH                                 OH                                 O       OH
                                                                                                                      O   S    O
                                          O2 N                  NO2
O Me NO2
55.   How many of the following reactions, leads to the formation of diastereomers?
                                                                          Ph           H
              H3 C                               HCl
                      C         CH        CH3                                                                HBr
      (i)                                        CCl4          (ii)
                H                                                                                            CCl4
                                                                             CH3
                                                                      H               D
               Ph                         HBr                                              HCl
                      C         CH2                           (iv)             CH
      (iii)                               CCl4                                             CCl4
                H
                                                                               CH
                                                                               Ph
                                                                     Ph
                            CH3
                                                                                                  HCl
      (v)                                                     (vi)
                                                                                                  CCl4
                           CH2
                                                                                       CH3
56.   How many of the following addition reactions are syn addition reaction?
                                                                               H3 C                      CH3
              H3 C                    CH3
                                                                                                                      H2, Ni
                                                  Br2                                      C      C
                      C         C                                     (ii)
      (i)                                         CCl4                              D                    D
                 H                    H
                                 H 2 , Pd  BaSO4                                               Na , Liq. NH 3
      (iii) H 3C  C  C  CH 3                                 (iv) H 3C  C  C  CH 3 
                                CH3
                                      1. PhCO3H                                                       Br2 + H2O
      (vii)                                                           (viii)
                                      2.H / H2O
                          CH3
                                   24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
57.   How many different products (excluding stereoisomer) can be obtained by following
      reaction?
HCl, CCl4
58.   Identify number of compounds from the following, which liberate CO2 on reaction
      with NaHCO3
                  O                                                 O
                                                                                    HO               O
                   C    OH ,                OH ,                     S      OH ,                         ,
                                                                     O              HO              O
                            O
      H3C                                                                      O
                                                                                
            N                  C    OH , O2N                      OH ,   CH 3  C  OH , H 3C  C  CH
      H3C
59.   How many compounds from following exhibit d-orbital resonance.
NH3 PH3
      Cl                                                                                         
            C    Cl ,                                  F            F ,
                                    ,              ,         C          PH3 , Cl  O  Cl , Br  S  Br
                                                                                                 
            Cl                                                F
61.    If two vertices of a triangle are (4, 2, 1) and (5, 1, 4). If the centroid is (5, 2, 3), then
       the third vertex is
       1) (3, 4, 5)               2) (6, 2, 3)               3) (6, 3, 2)             4) (6, 3, 4)
62.    If the orthocenter and centroid of a triangle are O (-3, 5, 1) and G (3, 3, -1)
       respectively, then the distance between the circumcenter and the origin is
       1) 2 3                     2) 2 11                    3) 2 15                  4) 2 17
63.    A line makes an angle  both with x and y axes. A possible value of  is in
                                                                 3                      
       1)  0,                 2)  0,                 3)  ,                4)  , 
            4                        2                        4 4                   3 6
                                                                  x 1 y  2 z 1
64.    The distance of the point (4, 2, 5) from the line                        is
                                                                    6    3     2
       1) 3                       2) 4                       3) 5                     4) 2
65.    The shortest distance between the line x  y  z and x  y  1  0  z is
            1                            1                            1                       1
       1)                         2)                         3)                       4)
            2                            2                            3                       6
                                                                  t
66.    If the lines x  1  s, y  3   s , z  1   s and x  , y  1  t , z  2  t are coplanar,
                                                                  2
       then  =
                                                                      1
       1) -2                      2) -1                      3)                      4) 0
                                                                      2
                      x4 y2 zk
67.    If the line              lines on the plane 2 x  4 y  z  7 , then k is
                       1   1   2
       1) 0                       2) -7                      3) 7                     4) -1
68.    The distance of the origin from the image of (1, 2, 3) in the plane x  y  z  5 is
       1) 17                      2) 29                      3) 34                    4) 41
69.    OABC is regular tetrahedron of unit edge. Its volume is
              1                          1                                1                   1
       1)                         2)                         3)                       4)
                3                        6                            3 2                    6 2
                                            24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
75.   If the equation of the plane passing through the point (-1, 2, 0) and parallel to the
              x y 1 z  2     x 1 y 1 z 1
      lines              and              is ax  by  cz  1 , then the value of (a+b+c)
              3   0   1         1    2   1
      is
      1) 3                            2) 4                            3) 5                         4) 10
76.   If the coordinates of the point where the line x  2 y  z  1  0  x  2 y  2 z  5 intersect,
      the plane x  y  2 z  7 is  x0 , y0 , z0  , then  x02  y02  z02  equal
1) 7 2) 14 3) 21 4) 28
                                                                      for x  0 is
                                                        x3
      1) [0, )                       2) [2, )                       3) [4, )                    4) [6, )
                                             24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                  sin  4k  1 x
                                  ,       x0
                         3 x
                  tan  4k  1 x                 
        f  x                   ,       0 x     , can be made continuous at x = 0 is
                         5x                       2
                 
                 
                           1        ,      x0
                                                                      5
       1) 1                               2) 2                   3)                        4) 0
                                                                      4
79.    One of the vertices of an equilateral triangle is (2, 3) and the equation of its opposite
       side is x  y  2  0 . The area of triangle is
                                                                      3 3
       1) 3 3                             2) 6 3                 3)                        4)       6
                                                                       2
                              1 2                  2 1
                              and B   4 3 , then the value of Det   adj A  2 AB   is
                                                                                       1
80.    If matrices A  
                        3 4              
       (Where Det (X) represents determinate of matrix ‘x’)
                                                                           1                    1
       1) -2                              2) 12                  3)                       4)
                                                                          12                    8
                                                      SECTION-II
                                         (NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will
        be
 evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. If the line passing through P (5, 1, a) and Q (3, b, 1) crosses the yz – plane at
         17 13 
      R  0, ,    , then find the value of (a+b)
         2 2 
                                                                               1           1
82.    If the length of shortest distance between the two lines                   x  1   y  3  z  2 and
                                                                               2           4
                                                     a
      3 x  y  2 z  4  0  2 x  y  z  1 is       where a and b are coprime then find the value of
                                                     b
      (a+b)
                                        24-12-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-27_Q’P
                    x2 y 3 4 z     x 1 4  y z  5
83. If the lines                and                are coplanar for k   and
                     1    1   k         k   2     1
      k       then find the value of     6  .
                                                                                           x 1 y  3 z  4
84.    Two intersecting lines lying in a plane P1 have equations                                          and
                                                                                             2    1    3
       x 1 y  3 z  4
                      If the equation of plane P2 is 2 x  y  z  21 and distance between
        1    2     4
       P1 and P2 is d, then find the value of d2.
             x  3 y 1 z  2
       And                  and at greatest distance from origin is 4x  ay  bz  c , then
               1     2    3
       find the value of (a+b+c).
86.    If the projections of a line segment on the x, y and z axes in 3 – dimensional space
       are 2, 3 and 6 respectively, then the length of line segment is
87. A plane passes through the point (0, -1, -2) and is perpendicular to the planes
                                                                                                
       x  y  2 z  0, 2 x  y  z  0 . The distance of the origin from it is                    then  =
                                                                                                 3
88. If the plane x  y  z  1 is rotated through 900 about its line of intersection with the
89. If a, b and c are non – zero and non – coplanar vectors such that
                                                                                       2
              
        ab  b  c
                       b  c    c  a   c  a    a  b   k a b c         then find k
                                                      2            2           2                      2
90.    For any vector a , the value of  a  i    a  j    a  k  is equal to k a then k =