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Exercise 6.4 - Enthalpy of Formation

This document provides the standard enthalpies of formation (ΔHf) for various compounds and asks the student to use these values to calculate the standard enthalpy of reaction (ΔH°) for several chemical reactions using Hess' Law. It defines standard enthalpy of formation and lists some general rules for using Hess' Law. It then provides 10 practice problems of varying complexity for the student to calculate ΔH° values.

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190 views

Exercise 6.4 - Enthalpy of Formation

This document provides the standard enthalpies of formation (ΔHf) for various compounds and asks the student to use these values to calculate the standard enthalpy of reaction (ΔH°) for several chemical reactions using Hess' Law. It defines standard enthalpy of formation and lists some general rules for using Hess' Law. It then provides 10 practice problems of varying complexity for the student to calculate ΔH° values.

Uploaded by

samuel.bennett
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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AP Chemistry

Exercise 6.4 Name:


Enthalpy of Formation Date: Per:

Compound ΔHf (kJ/mol) Compound ΔHf (kJ/mol)


Hess' Law can be used to determine the enthalpy of reaction
for chemical reactions by using the enthalpies of formation AlCl3(s) -704.2 MnO2(s) -519.7
for the component reactants and products, using the formula: Al2O3(s) -1675.7 NaCl(s) -411.0

ΔH°rxn = Σ ΔH°f, products - Σ ΔH°f, reactants Ca3(PO4)2(s) - 4120.8 NaF(s) -569.0


CaSO4(s) -1434.5 Na2O(s) -414.2
Some general rules relating to Hess’ Law when calculating CH4(g) -74.8 NaOH(s) -426.7
ΔH° for a reaction from enthalpies of formation:
ClF3(g) -163.2 NH3(g) -46.2
• The standard enthalpy of formation for an element in its CO(g) -110.5 N2H3CH3(l) 54
standard state is zero.
∙ Standard states for most elements are their solid, CO2(g) -393.5 NH4Cl(s) -315.4
monatomic state. HCl(g) -92.3 NH4ClO4(s) -295
∙ Standard states for noble gases and H2, O2, N2, F2, HCN(g) 130.5 NO(g) +90.4
Cl2 are gaseous.
HF(g) -268.6 NO2(g) +33.9
∙ Standard state for C(s) is graphite.
∙ Standard states for Hg and Br2 are liquid. HNO3(aq) -207.4 N2O4(l) -20.
∙ Standard state for iodine is diatomic solid (I2). H2O(g) -241.8 SnCl4(l) -545.2
• If you modify the coefficients of a reaction, multiply H H2O(l) -285.8 SnO(s) -286.2
by the same factor.
H3PO4(l) -1271.7 SnO2(s) -580.7
1. Give the definition of the standard enthalpy of formation H2S(g) -20.1 SO2(g) -296.1
for a substance. H2SO4(l) -811.3 SO3(g) -395.2
MgSO4(s) -1278.2 ZnO(s) -348.0
MnO(s) -384.9 ZnS(s) -202.9

2. Write separate reactions for the formation of NaCl, C6H12O6, and PbSO4 that have ΔH° values equal to ΔHof for each
compound.

a. NaCl:
b. C6H12O6:
c. PbSO4:
3. Determine the ΔHo for each of these reactions. State whether each reaction is endothermic or exothermic.

a. 2 CO(g) + O2(g)  2 CO2(g)

b. NaOH(s) + HCl(g)  NaCl(s) + H2O(g)

c. 2 H2S(g) + 3 O2(g)  2 H2O(l) + 2 SO2(g)

4. The standard enthalpy of combustion for xylene, C8H10(l), is -3908 kJ mol-1. Calculate the standard enthalpy of formation
of C8H10(l), in kJ mol-1. (Hint: Write chemical equations for combustion of Xylene.)

Revised: 2019-01-10 Answers: 3) a: -566 kJ, b: -133.8 kJ, c: -1123.6 kJ 4) -669 kJ 5) a: -947.8 kJ, b: -292.2 kJ, c: -176.9 kJ 6) -2674.5 kJ 7) -4592 kJ 8) 162 kJ 9) 52.3 kJ
10) a: -904.4 kJ, b: -113.0 kJ, c: -140.3 kJ
AP Chemistry
Exercise 6.4 Name:
Enthalpy of Formation Date: Per:

5. Use the values of ΔHof in the reference table to calculate ΔH° for the following reactions:

a. 2NH3(g) + 3O2(g) + 2CH4(g) → 2HCN(g) + 6H2O(g)

b. Ca3(PO4)2(s) + 3H2SO4(l) → 3CaSO4(s) + 2H3PO4(l)

c. NH3(g) + HCl(g) → NH4Cl(s)

6. The reusable booster rockets of the space shuttle use a mixture of aluminum and ammonium perchlorate as fuel. A
possible reaction is: 3Al(s) + 3NH4ClO4(s) → Al2O3(s) + AlCl3(s) + 3NO(g) + 6H2O(g). Calculate ΔH° for this reaction.

7. The space shuttle orbiter utilizes the oxidation of methyl hydrazine by dinitrogen tetroxide for propulsion:
5N2O4(l) + 4N2H3CH3(l) → 12H2O(g) + 9N2(g) + 4CO2(g) . Calculate ΔH° for this reaction.

8. Consider the reaction: 2ClF3(g) + 2NH3(g) → N2(g) + 6HF(g) + Cl2(g) ; ΔH° = 1196 kJ . Calculate ΔHof for ClF3(g).

9. The enthalpy of combustion of ethane gas, C2H4(g), is 1411.1 kJ/mol at 298 K. Calculate ΔHof for C2H4(g).

10. The Ostwald process for the commercial production of nitric acid from ammonia and oxygen involves the following
steps. Use the values of ΔHof in the reference table to calculate the value of ΔH° for each of the reactions.

a. 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(g)

b. 2NO(g) + O2(g) → 2NO2(g)

c. 3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g)

Revised: 2019-01-10 Answers: 3) a: -566 kJ, b: -133.8 kJ, c: -1123.6 kJ 4) -669 kJ 5) a: -947.8 kJ, b: -292.2 kJ, c: -176.9 kJ 6) -2674.5 kJ 7) -4592 kJ 8) 162 kJ 9) 52.3 kJ
10) a: -904.4 kJ, b: -113.0 kJ, c: -140.3 kJ

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