Safety Data Sheet
This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)
Product name FORAY® ABC Multi-Purpose Dry Chemical
1. Identification
1.1. Product Identifier
Product name FORAY® ABC Multi-Purpose Dry Chemical
1.2. Other means of identification
Product code 009361
Synonyms None
Chemical Family No information available
1.3. Recommended use of the chemical and restrictions on use
Recommended use Fire extinguishing agent.
Uses advised against Consumer use.
1.4. Details of the Supplier of the Safety Data Sheet
Company Name Tyco Fire Protection Products
One Stanton Street
Marinette, WI 54143-2542
Telephone: 715-735-7411
Contact point Product Stewardship at 1-715-735-7411
E-mail address
[email protected]1.5. Emergency Telephone Number
Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887
2. Hazards Identification
Classification
This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
2.2. Label Elements
Hazard Statements
The product contains no substances which at their given concentration, are considered to be hazardous to health
Precautionary Statements
2.3. Hazards Not Otherwise Classified (HNOC)
Not Applicable.
2.4. Other Information
Unknown Acute Toxicity 5.7001% of the mixture consists of ingredient(s) of unknown toxicity
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 2 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
3. Composition/information on Ingredients
3.1. Mixture
The following component(s) in this product are considered hazardous under applicable OSHA(USA)
Chemical name CAS No. weight-%
Ammonium dihydrogen phosphate 7722-76-1 60 - 100
Ammonium sulfate, technical 7783-20-2 7 - 13
Attapulgite 12174-11-7 1-5
4. First aid measures
4.1. Description of first aid measures
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
eye irritation persists: Get medical advice/attention.
Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.
Inhalation If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
Ingestion If swallowed. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2. Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms None known.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
Note to physicians Treat symptomatically.
5. Fire-fighting measures
5.1. Suitable Extinguishing Media
Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
5.2. Unsuitable Extinguishing Media
None.
5.3. Specific Hazards Arising from the Chemical
None in particular.
5.4. Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.
5.5. Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. Accidental release measures
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 3 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
6.1. Personal precautions, protective equipment and emergency procedures
Personal Precautions Provide adequate ventilation. Avoid creating dust. Avoid breathing
dust/fume/gas/mist/vapors/spray.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental Precautions
Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into
surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so.
Prevent product from entering drains. See Section 12 for additional Ecological Information.
6.3. Methods and material for containment and cleaning up
Methods for Containment Stop leak if you can do it without risk. If sweeping of a contaminated area is necessary use
a dust suppressing agent which does not react with product. Dike far ahead of spill; use dry
sand to contain the flow of material. Absorb with earth, sand or other non-combustible
material and transfer to containers for later disposal.
Methods for Cleaning Up Following product recovery, flush area with water.
7. Handling and Storage
7.1. Precautions for Safe Handling
Advice on safe handling Avoid generation of dust. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local
exhaust ventilation. Use personal protective equipment as required. Wash thoroughly after
handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Store in a well-ventilated place. Keep cool. Keep container tightly closed. Guard against
dust accumulation of material. Use care in handling/storage.
Incompatible Materials Strong acids.
8. Exposure Controls/Personal Protection
8.1. Control Parameters
Exposure guidelines
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL
Attapulgite TWA: 1 mg/m3 respirable - - -
12174-11-7 particulate matter
ACGIH (American Conference of Governmental Industrial Hygienists). OSHA (Occupational Safety and Health Administration of
the US Department of Labor). NIOSH IDLH: Immediately Dangerous to Life or Health.
8.2. Appropriate Engineering Controls
Engineering controls Ensure adequate ventilation, especially in confined areas.
8.3. Individual protection measures, such as personal protective equipment
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 4 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection No special precautions are needed in handling this material.
Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment.
Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits
8.4. General hygiene considerations
Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
9.1. Information on basic physical and chemical properties
Physical State powder
Odor odorless Color Yellow
Odor Threshold No data available
Property Values Remar
ks •Met
hod
pH No data available
Melting point/freezing point No data available
Boiling point / boiling range No data available
Flash Point No data available
Evaporation Rate No data available
Flammability (solid, gas) No data available
Flammability limit in air
Upper flammability limit: No data available
Lower flammability limit: No data available
Vapor Pressure No data available
Vapor Density No data available
Specific gravity No data available
Water Solubility No data available
Solubility in Other Solvents No data available
Partition coefficient No data available
Autoignition Temperature No data available
Decomposition Temperature No data available
Kinematic viscosity No data available
10. Stability and Reactivity
10.1. Chemical Stability
Stable under recommended storage conditions.
10.2. Reactivity
No data available
10.3. Possibility of hazardous reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 5 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
10.4. Conditions to Avoid
Extremes of temperature and direct sunlight.
10.5. Incompatible Materials
Strong acids.
10.6. Hazardous decomposition products
Carbon oxides. Nitrogen oxides (NOx).
11. Toxicological Information
11.1. Information on Likely Routes of Exposure
Product information
Inhalation May cause irritation of respiratory tract.
Eye Contact May cause irritation.
Skin contact May cause irritation.
Ingestion Ingestion may cause irritation to mucous membranes.
Acute Toxicity
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Ammonium dihydrogen phosphate = 5750 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) -
7722-76-1
Ammonium sulfate, technical = 2840 mg/kg ( Rat ) - -
7783-20-2
11.2. Information on Toxicological Effects
Symptoms No information available.
11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin Corrosion/Irritation No information available.
Serious eye damage/eye irritation No information available.
Sensitization No information available.
Germ Cell Mutagenicity No information available.
Carcinogenicity Attapulgite (palygorskite fibers) is a hydrated magnesium aluminum silicate. Long
palygorskite (attapulgite) fibers (>5 micrometers) are possibly carcinogenic to humans
(Group 2B). Short palygorskite (attapulgite) fibers (<5 micrometers) cannot be classified as
to their carcinogenicity to humans (Group 3). The attapulgite present in this product
contains fibers 0.5-2.5 um range, so would be considered by IARC as Group 3.
Chemical name ACGIH IARC NTP OSHA
Attapulgite - Group 3 - X
12174-11-7
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
Reproductive Toxicity No information available.
STOT - Single Exposure No information available.
STOT - Repeated Exposure No information available.
Aspiration Hazard No information available.
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 6 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
11.4. Numerical Measures of Toxicity - Product information
The following values are calculated based on chapter 3.1 of the GHS document mg/kg
12. Ecological Information
12.1. Ecotoxicity
Not classified.
7.2% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical name Algae/aquatic plants Fish Crustacea
Ammonium sulfate, technical - LC50 96 h 460 - 1000 mg/L LC50 48 h = 14 mg/L Daphnia
7783-20-2 Leuciscus idus static; LC50 96 h magna; EC50 24 h = 423 mg/L
123 - 128 mg/L Poecilia reticulata Daphnia magna
semi-static; LC50 96 h = 126 mg/L
Poecilia reticulata; LC50 96 h > 100
mg/L Pimephales promelas; LC50
96 h 32.2 - 41.9 mg/L
Oncorhynchus mykiss flow-through;
LC50 96 h 5.2 - 8.2 mg/L
Oncorhynchus mykiss static; LC50
96 h = 18 mg/L Cyprinus carpio;
LC50 96 h = 480 mg/L Brachydanio
rerio flow-through; LC50 96 h = 420
mg/L Brachydanio rerio semi-static;
LC50 96 h = 250 mg/L Brachydanio
rerio
Silicic Acid/silica gel, Amorphous EC50 (72h) = 440 mg/L LC50 (96h) static = 5000 mg/L EC50 (48h) = 7600 mg/L
7631-86-9 Pseudokirchneriella subcapitata Brachydanio rerio Ceriodaphnia dubia
12.2. Persistence and Degradability
No information available.
12.3. Bioaccumulation
No information available.
Chemical name Partition coefficient
Ammonium sulfate, technical -5.1
7783-20-2
12.4. Other Adverse Effects
No information available
13. Disposal Considerations
13.1. Waste Treatment Methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Do not reuse container.
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 7 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
14. Transport Information
DOT NOT REGULATED
TDG NOT REGULATED
MEX NOT REGULATED
15. Regulatory Information
15.1. International Inventories
TSCA Complies
DSL/NDSL Complies
ENCS Does not comply
IECSC Complies
KECL Does not comply
PICCS Complies
AICS Complies
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
15.2. US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical name SARA 313 - Threshold Values %
Ammonium dihydrogen phosphate - 7722-76-1 1.0
Ammonium sulfate, technical - 7783-20-2 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard No
Chronic health hazard No
Fire Hazard No
Sudden Release of Pressure Hazard No
Reactive Hazard No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30
Product code 009361 /
Product name FORAY® ABC / PAGE 8 / 8
Multi-Purpose Dry Chemical
_____________________________________________________________________________________________
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
15.3. US State Regulations
California Proposition 65
Classification only applies to Attapulgite with fibers >5 um. This product contains Attapulgite with fibers <5 um.
Chemical name California Proposition 65
Attapulgite - 12174-11-7 Carcinogen
Quartz - 14808-60-7 Carcinogen
U.S. State Right-to-Know Regulations
16. Other information, including date of preparation of the last revision
NFPA Health Hazards 0 Flammability 0 Instability 0 Physical and chemical
properties -
HMIS Health Hazards 0 Flammability 0 Physical Hazards 0 Personal Protection X
Revision date 05-May-2017
Revision note No information available.
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
_____________________________________________________________________________________________
Revision date 05-May-2017 Version 30