JEE Main – 1 (GEN 2) | JEE - 2025

Date: 31/07/2023 Maximum Marks: 300

Timing: 4:00 PM to 7:00 PM Duration : 3.0 Hours

General Instructions
1. The test is of 3 hours duration and the maximum marks is 300.
2. The question paper consists of 3 Parts (Part I: Physics, Part II: Chemistry, Part III: Mathematics). Each Part
has two sections (Section 1 & Section 2).
3. Section 1 contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE CHOICE is correct.
4. Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be
attempted. You will NOT be allowed to attempt the sixth question. If you wish to attempt any other
question apart from the five already attempted, then you will have to delete any one response from the
five previously answered and then proceed to answer the new one.
The answer to each question should be rounded off to the nearest integer.
5. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc. inside the examination room/hall.

6. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

Marking Scheme
1. Section – 1: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.
2. Section – 2: +4 for correct answer, –1 (negative marking) for incorrect answer, 0 for all other cases.

Name of the Candidate (In CAPITALS) :

Roll Number :

OMR Bar Code Number :

Candidate's Signature : Invigilator's Signature

Syllabus:
Physics: Introduction to Vectors and Forces
Chemistry: Stoichiometry - 1
Mathematics: Quadratic Equations
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PART I: PHYSICS MARKS: 100

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. Two forces, each numerically equal to 5 N, are acting as shown in the Figure. Then the resultant is:

5N

60º
5N
(A) 2.5 N (B) 5N (C) 5 3 N (D) 10 N
2. Given A = 2iˆ + 3 ˆj . The angle between A and y-axis is:
2 2 2 3
(A) sin −1 (B) cos−1 (C) tan −1 (D) tan −1
3 3 3 2
3. The angle between two vectors (2iˆ + 3 ˆj + kˆ) and (−3iˆ + 6kˆ) is:
(A) 0º (B) 45º (C) 60º (D) 90º
4. In the figure shown, the minimum force F to be applied
perpendicular to the incline so that the block does not slide is:
{Take g = 10 m/s2 }
(A) 0 (B) 40 N
(C) 120 N (D) 200 N
5. If | A B |= 3A.B, then the value of | A + B |= ? is:
1/2
 2 2 AB 
(A) ( A2 + B2 + AB)1/2 (B) A +B + 
 3
(C) ( A + B) (D) ( A2 + B2 + 3A.B)1/3

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6. In the figure a block of mass 10 kg is in equilibrium. Identify the string in which the tension is maximum.

(A) A (B) B (C) C (D) Same in B and C

7. A horizontal force of 25N is necessary to just hold a block stationary against a wall. The coefficient of
friction between the block and the wall is 0.4. The weight of the block is:

(A) 2.5 N (B) 20 N (C) 10 N (D) 5N

8. A force of 10N is applied as shown on a 1 kg block which is kept on a horizontal ground. The block is
held at rest against a vertical wall. The normal reaction by the ground and the normal reaction by the wall
4
will respectively be: (Take g = 10 ms−2 &cos37 = )
5

(A) 5 2N , 5 2 N (B) 10 2N, 10 2N

(C) 16 N, 8 N (D) 8 N, 16 N

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9. The maximum and minimum magnitudes of the resultant of two vectors are 23 units and 7 units
respectively. If these two vectors are acting at right angles to each other, the magnitude of their resultant
will be :
(A) 14 (B) 15 (C) 16 (D) 17
10. A man walks 4m towards east and then turns 60° to the north of east and again walks for 4m. Calculate
the net displacement.
(A) 8m (B) 4 2m (C) 6.9 m (D) 5.4 m
11. A block of mass 3 kg is at rest on a rough inclined plane as shown in the figure. The magnitude of net
force exerted by the surface on the block will be: ( g = 10m/s2 )

(A) 26 N (B) 19.5 N (C) 10 N (D) 30 N

12. If the resultant of three forces F1 = piˆ + 3 ˆj − kˆ, F2 = −5iˆ + ˆj + 2kˆ and F3 = 6iˆ − kˆ acting on a particle
has magnitude equal to 5 units, then the value(s) of p is(are):
(A) –4 (B) 2
(C) Both (A) and (B) (D) –2
13. A + B = 2iˆ and A − B = 4 ˆj then A.B is :
(A) 3 (B) –3 (C) 5 (D) –5

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14. Two identical blocks of weight W are placed one on top of the other as shown in figure. The upper block
is tied to the wall. The lower block is pulled to the right with a force F. The coefficient of static friction
between all surfaces in contact is . What is the largest force F that can be exerted before the lower
block starts to slip?

(A) W (B) 2W (C) 3W (D) 4W

15. For figure, m1 = 300kg and m2 = 400kg and system is at rest, Pulleys and rope are ideal, then:

( g = 10m/s2 )

(A) Tension in AB = 3000N (B) Tension in AB = 4000N

(C) Angle  = 37 (D) Angle  = 53
16. What is the maximum value of the force F such that the block shown in the arrangement, does not move
( g = 10m/s2 ) ?

(A) 20N (B) 10N (C) 12N (D) 15N

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17. A system is shown in figure. Blocks 2kg and 3kg are at rest. Force of friction between 2kg and incline is:

(A) 0N (B) 10 N (C) 20 N (D) 30 N

18. A force F = (4iˆ − 5 ˆj + 3kˆ) N is acting at a point having a position vector r1 = (iˆ + 2 ˆj + 3kˆ). The
torque acting about a point having a position vector r = (3iˆ − 2 ˆj − 3kˆ), is:
2

(A) 42iˆ + 30 ˆj − 6kˆ (B) 42iˆ + 30 ˆj + 6kˆ

(C) 42iˆ − 30 ˆj + 6kˆ (D) Zero
19. If a1 and a2 are two non collinear unit vectors and if a1 + a2 = 3 , then the value of
(a1 − a2 ).(2a1 + a2 ) is:
3 1
(A) 2 (B) (C) (D) 1
2 2
20. A particle moves in a circle of radius 1m with a speed of 2m/s. Find the magnitude of change in velocity
of the particle when it has covered three fourth of the circle.
(A) 0 m/s (B) 2 m/s (C) 2 m/s (D) 2 2 m/s

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SECTION-2
Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be attempted.
The answer to each question should be rounded off to the nearest integer.
1. The sum of the magnitudes of two forces acting at a point is 16N. The resultant of these forces is
perpendicular to the smaller force and has a magnitude of 8N. If the smaller force is of magnitude x, then
the value of x is (in Newton):
2. If | A + B |=| A |=| B |, then the angle between A and B in degree is 40 n. Find n.
3. Two vectors a and b are such that | a + b |=| a − b | , the angle between a and b in degree is 15x.
Find x?
4. Given that A + B = C if | A |= 4 , | B |= 5 and | C |= 61 , the angle between A and B in degree is 30
n. Find n?
5. For what value of m, the vector E = 3iˆ + mjˆ − 2kˆ and vector B = miˆ + 7 ˆj + 5kˆ are orthogonal ?

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6. If vectors m = (2iˆ − 3 ˆj)m and n = (−5iˆ + 7 ˆj)m represent two adjacent sides of a parallelogram, then

the area of the parallelogram will be _____________ (in m2 ).

7. Under the action of a force (10iˆ − 3 ˆj − 6kˆ) N, a body of mass 5 kg moves from position (6,5, −3)m to a
position (10, −2,7)m . Calculate the work done (in J) by the force.

8. Two non-zero vectors P and Q are such that P + Q = R and | P |=| Q |=| R |. If angle between P and

Q is n 30, find value of n.

1  m2 
9. If system shown in the figure is in equilibrium then find  ?
3  m1 

10. Find the projection of vector −iˆ + 2 ˆj − 3kˆ along the vector 2iˆ + ˆj − 2kˆ .

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PART II: CHEMISTRY MARKS: 100

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
1. When 40 equivalents of a monoprotic acid is mixed with 20 equivalents of ammonia, the mass of caustic
potash (KOH) required to completely neutralize the mixture is:
[Atomic mass of K = 39.0 u, O = 16.0 u, H = 1.0 u]
(A) 20 gm (B) 56 gm (C) 1120 gm (D) 84 gm
2. TNT is used to make explosives and has a stoichiometry of C7 H5 N3O6 . The element having the highest
percentage in TNT is:
(A) Carbon (B) Hydrogen (C) Nitrogen (D) Oxygen
3. Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason
(R).
Assertion (A): 5 M HCl solution is diluted 10 times, its molarity becomes 50 M.
Reason (R): On dilution, molarity of the solution decreases.
In the light of above statements, choose the most appropriate answer from the options given below.
(A) Both A and R are correct, and R is correct explanation of A
(B) Both A and R are correct, but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct
4. Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason
(R).
Molecular weight
Assertion (A) : Equivalent weight of a base = .
Acidity
Reason (R) : Acidity is the number of replaceable H+ ions in one molecule of the base.
In the light of above statements, choose the most appropriate answer from the options given below.
(A) Both A and R are correct, and R is correct explanation of A
(B) Both A and R are correct, but R is NOT the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

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5. Match List-I with List-II. [M0 is the molecular mass of compounds in List-I]

List-I (Compound) List-II (Equivalent mass)

M0
(P) Al2 (CO3 )3 (I)
1
M0
(Q) HNO3 (II)
2
M0
(R) CaSO4 (III)
6
M0
(S) NaNO2 (IV)
3
Choose the most appropriate answer from the options given below:
(A) P →IV, Q →II, R →III, S →I
(B) P →III, Q →II, R →IV, S →I
(C) P →III, Q →I, R →I, S →II
(D) P →III, Q →I, R →II, S →I
6. The amount of moisture present in 1 tonne of a sample of copper sulphate pentahydrate (CuSO4.5H2O) is
approximately:
Given: 1 tonne = 1000 kg, molar mass of CuSO4  5H2O = 250 g mol−1 , molar mass of

H2O = 18 g mol−1
(A) 36 kg (B) 3600 kg (C) 360 kg (D) 3.60 kg
7. Consider the following reaction sequence:
I. 2AgNO3 + Na 2CO3 ⎯⎯
→ Ag2CO3 + 2NaNO3 [40% yield]

II. 2Ag2CO3 ⎯⎯
→ 4Ag + 2CO2 + O2 [50% yield]
The moles of sodium carbonate required to produce 10 moles of silver (Ag) is:
(A) 10 mol (B) 5 mol (C) 12.5 mol (D) 25 mol

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8. A solution is prepared by adding 2 g of a solute A to 18 g of water. Calculate the mass per cent of the
solvent.
(A) 10 (B) 90 (C) 30 (D) 85
9. Calculate the average atomic mass of an element X using the following data:
% Natural Abundance Atomic Mass
204
X 75 204
206
X 25 206
(A) 204.5 (B) 205 (C) 205.5 (D) 207
10. Number of electrons present in 32 grams of methane (CH4 ) gas is:

[Atomic mass of C = 12 u, H = 1 u; NA = 6 1023 mol−1]

(A) 12 1023 (B) 12 1024 (C) 6 1023 (D) 6 1024

11. The density of 3 M aqueous solution of NaCl is 1.25 g mL−1. Calculate the molality of the solution.
[Use: Atomic mass of Na = 23u, H = 1u, O = 16u, Cl = 35.5u]
(A) 2.79 (B) 2.20 (C) 1.40 (D) 1.10

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12. 100 mL, 0.1 M HCl is mixed with 50 mL, 0.1 M NaOH. The molarity of resulting solution is:
1 1 1
(A) M (B) M (C) M (D) 1M
20 10 30
13. Complete neutralization occurs when 20 mL of a sample of 0.2 M H2SO4 reacts with 40 mL of a sample
of 0.1 M base. The acidity of the base is:
(A) 2 (B) 3 (C) 4 (D) Data insufficient
14. In which mode of expression, the concentration of the solution remain independent of temperature?
(A) Molarity (B) Mole fraction (C) Normality (D) % (w/v)
15. Given below are two statements:
Statement-I : 1 mol of H2SO4 is neutralized by 2 mol of NaOH
Statement-II : 1 equivalent of H2SO4 is neutralized by 1 equivalent of NaOH.
In the light of above statements, choose the correct answer from the options given below.
(A) Both Statement-I and Statement-II are correct
(B) Both Statement-I and Statement-II are incorrect
(C) Statement-I is correct but Statement-II is incorrect
(D) Statement-I is incorrect but Statement-II is correct
16. The volume of a drop of water is 0.04 mL. How many H2O Molecules are there in a drop of water?
[d = 1.0g mL−1] (NA = 6.023 1023 )
(A) 1.34 1021 (B) 6.02 1023 (C) 5.5 1020 (D) 3.011023

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17. Which of the following has highest mass?
−1
[Use : NA = 6 10 mol , atomic mass of N = 14u, H = 1u, O = 16u, C = 12u]
23

(A) 1 g-atom of hydrogen (B) 2.4 g of O2

(C) 0.1 mole of N2 (D) 3 1020 molecules of CO2

18. The molality of a sulphuric acid solution is 0.2. Calculate the total weight of the solution having 1000g of
solvent.
(A) 1000 g (B) 1098.6 g (C) 980.4 g (D) 1019.6 g
2
19. In certain reaction 1.88 moles of TiCl4 is reacted with 4 moles of Mg. Calculate % yield of Ti if only
3
moles of Ti is actually obtained. (Reaction involved TiCl4 + 2Mg ⎯⎯
→ Ti + 2MgCl2 )
(A) 35.46% (B) 66.6% (C) 100% (D) 60%
20. Two samples of NaOH of 1.5 M and 0.50 M are mixed. What volumes of these samples are taken
respectively in order to prepare 1.20 M NaOH solution assuming no water is added.
I. 20 mL, 20 mL II. 70 mL, 30 mL
III. 35 mL, 15 mL IV. 42 mL, 18 mL
(A) I, II, III only (B) II, III only (C) II, III, IV only (D) I, II, IV only

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SECTION-2
Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be attempted.
The answer to each question should be rounded off to the nearest integer.
1. On heating KClO3 , 68.1 L of O2 gas at STP is formed. Calculate moles of KClO3 taken.
−1
[Use: Vm = 22.7 L mol ]

2. C3H6O2 ⎯⎯
→ C3H4O + H2O (75% yield)
(Acrolein)

If 18.5 gm of the reactant is initially taken, the amount of acrolein formed is y 10−1 g. Calculate y
(Nearest integer)
[Atomic mass (in amu) : C = 12, H = 1, O = 16]
3. What is the total mass of the products formed, when 51 g of H2S is oxidized by oxygen to produce
water and sulphur dioxide according to the given reaction. Give your answer in grams.
2H2S + 3O2 ⎯⎯
→ 2H2O + 2SO2
4. Phenolphthalein (C20 H14O4 ) solution has a density of 1.3g / cm3 , which is used as an acid-base
titration indicator. If 100 mL of 3.9% (w/v) of its stock solution is to be used to perform a titration which
required 3 drops of phenolphthalein per titration, the maximum number of students which can perform
the titration individually is/are________. [Given: Volume of 1 drop of phenolphthalein = 0.05 mL,
Atomic mass of C = 12.0 u, H = 1.0 u, O = 16.0 u]
5. How many of the following compounds have their equivalent mass equal to their molecular mass?
H2SO4 , KOH, H3PO2 , CH3COOH, HNO3 , Ca(OH)2 , Mg(OH)2 , NH3

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6. 6.3 gm of hydrated oxalic acid (COOH)2  nH2O was dissolved in deionized water to prepare 100 mL
solution. 10 mL sample of it required 20 mL of 0.5 N KOH solution for complete neutralization. The
value of n is ________. (Nearest integer) [Atomic mass (in amu) : C = 12, O = 16, H = 1]
7. On heating a sample of Epsom salt (MgSO4  x H2O) it becomes anhydrous by losing 51.22% of its
mass. The value of x is ________. (Nearest integer)
[Atomic mass (in amu) : Mg = 24, S = 32, O = 16, H = 1]
8. A compound contains 16% sulphur by mass. What will be its least molar mass?
[Use : Atomic mass of S = 32u]
9. (a) H2 (g) + O2 (g) ⎯⎯
→ H2O( )
(b) N2 (g) + H2 (g) ⎯⎯
→ NH3 (g)
(c) H2 (g) + I2 (g) ⎯⎯
→ HI(g)
(d) CO(g) + H2 (g) ⎯⎯
→ CH3OH( )
If one mole of both the reactants are taken in each reaction separately, then the number of reaction/s in
which hydrogen does not get completely consumed is/are ________.
10. 4.9 g of H2SO4 is present in 100 mL of the solution. What is the normality (N) of the solution?

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PART III: MATHEMATICS MARKS: 100

SECTION-1
This section contains 20 Multiple Choice Questions. Each question has 4 choices (A), (B), (C) and (D), out of which
ONLY ONE CHOICE is correct.
 
1. If  and  are the roots of the equation x2 − 2 x − 1 = 0 then find the value of + .
 
(A) 3 (B) –3 (C) –6 (D) 6
2. Find x; if 1 + 2log( x+2) 5 = log5 ( x + 2)

9
(A) (B) 23 (C) –23 (D) 25
5
3. If log 2 log 1 log 2 x  0 then integral value of x which satisfy the equation:
2
(A) 1 (B) 2 (C) 3 (D) No integral value
4. Number of value of x which satisfy x2 − 2 x + 10 = x + 14;

(A) 1 (B) 2 (C) 0 (D) 3

5. Find sum of value of x which satisfy 2 | x + 3|2 − | x + 3| = 3 ?
3
(A) +6 (B) –6 (C) (D) 0
2
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6. Solve the inequality and find x.
1 1
 2
x + x x − 3x + 10
2

5  5 
(A) (−2, 0)   ,10  (B) (−1, 0)   ,  
2  2 
(C) (−2, 2) (D) None of these

7. The number of roots of the equation ( x2 + 2x − 4) = x − 3 .

(A) 1 (B) 2 (C) 3 (D) 4
8. If the roots of the quadratic equation x2 − 4 x − log3 a = 0 are real then least value of a is:
1 1
(A) 81 (B) (C) (D) None of these
81 64
5
9. The maximum value of the expression .
x2 + 3x + 10
31 31 4 20
(A) (B) (C) (D)
20 4 31 31
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10. If  and  are the roots of the equation 2x(2x +1) = 1then  is equal to:

(A) 2(+1) (B) −2(+1) (C) 2(−1) (D) 2 2

11. If the equation 2 x2 + 3x + 4 = 0 and ax2 + bx + c = 0 have a common root then a : b : c equals:
( a, b, c  R & a  0)
(A) 1:2:3 (B) 2:3:4 (C) 4:3:2 (D) 3:2:1
12. The diagram shows the graph of y = ax + bx + c; then
2

s1 : a  0, s2 : b  0, s3 : c  0, s4 : b2 − 4ac = 0

(A) s1 and s2 correct (B) s2 and s3 correct

(C) s2 and s4 correct (D) all correct

13. If  and  are roots of the equation x2 − 2 x − 1 = 0 and Sn = n + n ; n  1 . Then which of the
following is correct.
(A) S10 = 2S9 − S8 (B) S5 = 82
(C) S5 = 72 (D) None of these

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14. If the roots of x2 − (a − 3) x + a = 0 are such that both of them are greater than 2, then:
(A) a [7,9] (B) a [7, ) (C) a [9,10) (D) [7,9)
 
15. If ,  are roots of equation x2 − 2x −1 = 0 then find equation whose roots are and :
 +1  +1
(A) 4 x2 − 1 = 0 (B) 2 x2 − 1 = 0
(C) x2 − 4 x − 1 = 0 (D) x2 − 4 = 0
If k1  k2 and ( k1 − k2 )  12 then equation ( x − k1 ) ( x − k2 ) + 3 = 0 has: ( k , k2  R )
2
16.

(A) Both root in ( −, k1 ) (B) Both roots in ( k2 , )

(C) Both roots in ( k1, k2 ) (D) One root in ( −, k1 ) as other in ( k2 , )

x2 − 6 x + 5
17. The least value of expression is: ( x  R )
x2 + 2 x + 1
1 1
(A) −1 (B) − (C) − (D) None of these
2 3
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( ) ( )
x −3 x −3
18. The number of real root(s) of 3 + 2 2 + 3− 2 2 = 6 is:
(A) 0 (B) 2 (C) 4 (D) 1
19. The sum of the roots of the equation 3x − 2 − x − 3 = 10 is:
11 33
(A) (B) (C) –1 (D) +1
4 4
3 5
(log2 x)2 + log2 x− 1
20. If the product of the roots of the equation, x 4 4 = 2 is b
; (where a, b  N ), then the
a
least value of a + b is:
4
(A) − (B) –1 (C) –2 (D) 19
3
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SECTION-2
Section 2 contains 10 Numerical Value Type Questions Out of which ONLY 5 (any) questions have to be attempted.
The answer to each question should be rounded off to the nearest integer.
1. If one real root of the quadratic equation 81x2 + kx + 256 = 0 is cube of the other root, then the value of
|k| is:
2. The value of  such that sum of the squares of the roots of the quadratic equation
x2 + (3 − ) x + 2 =  has the least value is:
3. The number of all possible positive integral values of  for which the roots of the quadratic equation,
6 x2 − 11x +  = 0 are rational numbers is:
4. If quadratic equation (2 + 1) x2 − 4x + 2 = 0 always have exactly one root in the interval (0, 1) then
number of possible integral value of  is:
5. Let   0,  R . If  and  are roots of equation x2 − x + 2 = 0 and  and  are roots of the

equation, 3x2 − 10 x + 27 = 0 then is equal to:

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6. If a x = b, b y = c, c z = a , (a  1, b  1, c  1) then the value of xyz is:

7. Number of integral value of x which satisfy the equation || x −1| +2| 1
8. Let f ( x) = (a2 + a + 2) x2 − (a + 4) x − 7, x  R . If unity lies between the roots of equation
f (x) = 0 then number of integral value of a is:
9. If ,  be the roots of 4x2 −16x +  = 0,  R such that 1    2 and 2    3 then the number of
integral solution of  is:
10. The number of solution of equation log4 ( x − 1) = log2 ( x − 3) is :

SPACE FOR ROUGH WORK

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