JEE (Main + Advanced) / Chemistry / Thermodynamics & Thermochemistry
Thermodynamics & Thermochemistry Assignment -2
SINGLE CORRECT QUESTIONS
1. Out of boiling point (I), entropy (II), pH (III) and density (IV), intensive properties are
(A) I, II (B) I, II, III (C) I, III, IV (D) All of these
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2. A gas C v,m = R behaving ideally was allowed to expand reversibly and adiabatically from
2
1 litre to 32 litre. Its initial temperature was 327° C. The molar enthalpy change (in J/mole) for the
process is :-
(A) –1125 R (B) – 575 R (C) –1575 R (D) None of these
3. An ideal gas is taken around the cycle ABCDA as shown in figure. The net work done during the cycle is
equal to :-
(A) Zero (B) Positive (C) Negative (D) We cannot predict
4. An amount Q of heat is added to a monoatomic ideal gas in a process in which the gas performers a work
Q/2 on its surrounding. The molar heat capacity of gas (in cal/K-mol) for the process is.
(A) 3R (B) 5R (C) 4R (D) 2R
5. Statement-1 : There is no change in enthalpy of an ideal gas during compression at constant
temperature.
Statement-2 : Enthalpy of an ideal gas is a function of temperature and pressure.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
6. Statement-1 : Due to adiabatic expansion, the temperature of an ideal gas always decreases.
Statement-2 : For an adiabatic process, U = w.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
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MULTIPLE CORRECT ANSWER TYPE
7. Select the correct option -
(A) Hf(H, g) is equal to Hatomisation of H2(g)
(B) HBE(H–H) is equal to Hf of H(g)
(C) HBE(H–H) is equal to Hatomisation of H2(g)
(D) Hcombustion [H2, g] is equal to Hf [H2O, ] at 300K
8. Which of the following statement is (are) correct ?
(A) For any reaction rH = f Hproduct – f Hreactant
o o
(B) ΔHf of CO2(g) is same as the Hcomb. of carbon (graphite)
o o
(C) For all exothermic gaseous reactions, (B.E.)reactants > (B.E.)products
(D) For a reaction N2(g) + O2(g) ⎯→ 2NO(g), the heat at constant pressure and the heat at constant
volume at a given temperature are same
9. The standard enthalpies of formation of CO2(g), and HCOOH(l) are –393.7 kJ/mol and –409.2 kJ/mol
respectively :
(A) –393.7 kJ/mol is the enthalpy change for the reaction C(s) + O2(g) → CO2(g)
(B) the enthalpy changes for the reaction CO2(g) + H2(g) → HCOOH(l) would be –15.5 kJ/mol
(C) the enthalpy changes for the reaction
H2O + CO → HCOOH is –409.2 kJ/mol
(D) the enthalpy changes for the reaction
H2(g) + CO2(g) → H2O(l) + CO(g) is –409.2 kJ/mol
10. From the following data at 25°C
Reaction rH° kJ/mol
1 1
H2(g) + O2(g) ⎯→ OH (g) 42
2 2
1
H2(g) + O2(g) ⎯→ H2O(g) –242
2
H2(g) ⎯→ 2H(g) 436
O2(g) ⎯→ 2O(g) 495
Which of the following statement(s) is/are correct:
(A) rH° for the reaction H2O (g) ⎯→ 2H(g) + O(g) is 925.5 kJ/mol
(B) rH° for the reaction OH(g) ⎯→ H(g) + O(g) is 502 kJ/mol
(C) Enthalpy of formation of H(g) is –218 kJ/mol
(D) Enthalpy of formation of OH(g) is 42 kJ/mol
MATCHING TYPE
11. Match the column–I :-
Column–I Column–II
(1) C(graphite) + O2(g) → CO2(g) (P) Hformation
(2) C(graphite) → C(gas) (Q) Hcombustion
(3) CH3COOH(aq) + OH⊝ (aq) → CH3COO–(aq) + H2O() (R) Hatomization
(4) CH4(g) → C(g) + 4H(g) (S) H neutralization
(A) (1) S, R ; (2) Q, R ; (3) S; (4) – R (B) (1) P, S ; (2) P, R ; (3) P; (4) – R, Q
(C) (1) P, Q ; (2) P, R ; (3) S; (4) – R (D) (1) R, Q ; (2) P, R ; (3) R; (4) – S
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12. Match the enthalpy change (H) mentioned in list-II for 16 gm O2 with the various reaction in
list-I.
List–I List–II (H in kJ)
(P) 2C2H2 + 5O2(g) ⎯→ 4CO2(g) + 2H2O(l), H– 2601 kJ (1) –285.8
(Q) H2(g) + 1/2O2(g) ⎯→ H2O(g), H= –285.8 kJ (2) –196.75
(R) 3FeO(s) + 1/2O2(g) ⎯→ Fe3O4(s), H = –302.4 kJ (3) –260.1
(S) Cgraphite + O2(g) ⎯→ CO2(g), H = –393.5 kJ (4) –302.4
(A) P – 4; Q - 1; R - 3; S – 2 (B) P – 3; Q - 1; R - 4; S - 2
(C) P – 3; Q - 4; R - 1; S–2 (D) P – 2; Q - 3; R - 1; S – 4
COMPREHENSION TYPE
Comprehension # 1
Paragraph-(I) for Question Nos. 13 to 14
Thermodynamics stability is often used in chemical reactions to predict extent of reactions or to predict
the preferred product in some reaction. Thermodynamically a more stable substance will be the one
which has lower Gibb’s free energy. In various cases it might be decided on the basis of enthalpy,
however that may not always be true. The thermodynamic data therefore can be used for predicting
stability among isotopes & to decide the possible transformation. Based on this information & the data
given below, answer the questions that follow.
Data:
Hof of Sn(white) = 0, Hof of Sn(gray) = –2.1 kJ/mol, S° of Sn(white) = 52 J/K mol, S° of Sn(gray) = 44 J/K-mol
All above data at 300 K. Density of Sn(w) = 7.36 g/ml Density of Sn(g) = 5.769 gm/ml One such
transformation is ‘tin pest’ which is an autocatalytic, allotropic transformation of the element tin
causing deterioration of tin objects at low temperatures.
13. Which of the following graph is correct for the allotropic transition Sn(white) → Sn(gray) at 1 bar &
300 K.
G G
(A) (B)
Xan(A) = 1 Xan(A) = 1 Xan(A) = 1 Xan(A) = 1
G G
(C) (D)
Xan(A) = 1 Xan(A) = 1 Xan(A) = 1 Xan(A) = 1
14. As temperature is reduced, what can be predicted for objects containing tin
(A) Transformation from white tin to gray tin occurs changing it to a more brittle form.
(B) There will be a contraction in volume observed due to the allotropic change.
(C) No change takes places
(D) None of these
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INTEGER TYPE
15. The equilibrium constant of the reaction 2C3H6(g) C2H4(g) + C4H8(g) is found to fit the
expression
1088 K
lnK = –1.04 –
T
Calculate the standard reaction enthalpy at 400 K.
16. For the reaction SO2(g) + 1/2 O2(g) SO3(g) ; H°300 = –95 kJ/mole,
S°300 = –95.0 J/K mole. Find the value of ln kp for this reaction at 300 K.
17. A Carnot cycle has an efficiency of 40%. Its low temperature reservoir is at 9°C. What is the
temperature of source (in °C)?
18. The enthalpy of formation of ethane(g), ethylene(g) and benzene(g) from the gaseous atoms are
–2840, –2275 and –5530 kJmol–1 respectively. Calculate the magnitude of resonance energy of benzene
(in kJ/mole). The bond enthalpy of C–H bond is given as equal to + 410 kJ/mol.
ANSWER KEY
Question 1 2 3 4 5 6 7 8 9 10
Answer C C A A C B CD ABD AB AD
Question 11 12 13 14 15 16 17 18
Answer C B C A 9.04 26.70 197 25
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