Level 2 Notes 2024 - 04chemical Bonding
Level 2 Notes 2024 - 04chemical Bonding
Learning Outcomes
Students should be able to:
(a) describe the formation of ions by electron loss/gain and that these ions usually have the
electronic configuration of a noble gas.
(b) describe the relationship between group number and the ionic charge of an element.
(c) describe, including the use of ‘dot-and-cross’ diagrams, the formation of ionic bonds
between metals and non-metals, e.g. NaCl; MgCl2.
(d) deduce the formulae of simple compounds from the relative numbers of atoms present
and vice versa.
(e) deduce the formulae of ionic compounds from the charges on the ions present and vice
versa (including polyatomic ions).
(f) state that ionic materials contain a giant lattice in which the ions are held by electrostatic
attraction, e.g. NaCl (students will not be required to draw diagrams of ionic lattices).
(g) relate the physical properties (including electrical property) of ionic compounds to their
lattice structure.
(h) describe the formation of a covalent bond by the sharing of a pair of electrons and that the
atoms in the molecules usually have the electronic configuration of a noble gas.
(i) describe, using ‘dot-and-cross’ diagrams, the formation of covalent bonds between non-
metallic elements, e.g. H2; O2; H2O; CH4; CO2.
(j) deduce the formulae of common covalent compounds from the naming and vice versa.
(k) deduce the arrangement of electrons in other covalent molecules.
(l) relate the physical properties (including electrical property) of covalent substances to their
structure and bonding.
All noble gases (except helium) have 8 valence (outermost) electrons. These
gases have very stable electronic configuration, as evidenced by their general
lack of reactivity.
In nature, there is a tendency for atoms to lose, gain or share electrons until they
form a stable electronic configuration of a noble gas (duplet or octet).
Most atoms desire to have eight valence electrons (octet).
The tendency for atoms to react until there are eight valence electrons is known
as the “octet rule”. The octet rule is used as a guideline to deduce the electronic
configuration of ions in a compound.
An exception to this rule applies to atoms with only one electron shell. They
require only 2 valence electrons (duplet) for stability.
2 Ions
An ion is an atom or a group of atoms that has an electrical charge, e.g. H+, Na+, Ca2+,
Fe2+, Fe3+, Cl–, O2-, N3-, NH4+, SO42–, CO32–, NO3–
Ions are formed when an atom or a group of atoms loses or gains electrons.
The electrical charge of an ion is the net electrical charges of all protons and
electrons in an atom or group of atoms.
ion
lose e gain e
gas
Fig. 1.4 Formation of oxide ion, O2-
Most of the non-metallic atoms have 4 to 7 valence electrons.
It is easier to gain 1 to 3 electrons as compared to losing 5 to 7 valence electrons
to attain the noble gas configuration.
Non-metallic atoms with 4 valence electrons tend to share electrons and
undergo covalent bonding. (will be discussed later)
The negative charge arises because there are now more electrons than
protons.
Legend: represents an electron of the original atom, X represents an electron of another atom
2. Which ion has the correct number of electrons, neutrons and protons shown?
3. Which does not have the same number of electrons as an atom of argon?
A S2– B Cl–
C Ca2+ D Al3+
4. Which particle has a different number of electron shells from the others?
A Al3+ B O2–
C Cl– D Ne
5. Three elements, X, Y and Z, have consecutive increasing atomic numbers. If element Y is a noble
gas, what will be the symbol for the ions formed by elements X and Z in their compounds?
Q 16 18 18
R 17 18 18
The ionic charge of an ion is dependent on the number of valence electrons its atom
contains.
Elements in the same Group have the same number of valence electrons. Hence,
they form ions of the same charges and have similar chemical properties.
group number 1 2 13 14 15 16 17 18
This is because
chemical
number of 1 2 3 4 5 6 7 2 reactions only
valence or involve the
electrons 8 valence
charge on the +1 +2 +3 NA –3 –2 –1 NA electrons!
ion
4 Ionic Bonding
Definition:
The reacting atoms gain or lose electrons in order to achieve stability, i.e.
attain a noble gas electronic configuration.
Example 1: How would a sodium atom form a bond with a chlorine atom?
Step 2: Consider how each atom would achieve a noble gas electronic configuration.
For sodium, Na, it needs to lose one electron:
In doing so, it becomes an ion with a charge of +1, as there are now 11 protons and
10 electrons.
In doing so, it becomes an ion with a charge of –1, as there are now 17 protons and 18
electrons.
Step 3: Consider the ratio of cation and anion needed to form one electrically neutral
compound.
Since one sodium atom needs to lose one electron and one chlorine atom needs to gain
one electron, one sodium atom can bond with one chlorine atom in a ratio of 1:1.
Fig. 1.7 Sodium atom losing 1 electron to chlorine atom to form sodium ion and chloride ion
Step 4: Represent the ionic bonding in sodium chloride through a ‘dot-and-cross’
diagram.
Legend:
electron of sodium
electron of chlorine
Remember to
include a legend.
Example 2: How does a magnesium atom form a bond with a chlorine atom?
Step 2: Consider how each atom would achieve a noble gas electronic configuration.
Step 3: Consider the ratio of cation and anion needed to form one electrically neutral
compound.
(student to draw)
2+ –
Mg
2 Cl
a) Lithium fluoride
b) Magnesium oxide
c) Sodium oxide
e) Calcium fluoride
f) Aluminium oxide
1) The formula of some ions can be deduced from the Periodic Table.
E.g. A magnesium atom has 2 valence electrons. It loses 2 electrons to form a cation
(positive ion) and thus the formula of the magnesium ion is Mg2+.
E.g. An oxygen atom has 6 valence electrons. It gains 2 electrons to form an anion
(negative ion) and thus the formula of the oxide ion is O2–.
2) The table below summarises the charges of the ions formed by the elements in the
various groups of the Periodic Table.
group 1 2 13 14 15 16 17 18
charge –3 –2 –1
+1 +2 +3
of ion NA (non- (non- (non- NA
(metal) (metal) (metal)
formed metal) metal) metal)
3) The table below shows the formulae of common transition metal ions that cannot be
deduced from the Periodic Table.
ion charge
copper(II) Cu2+ +2
iron(II) Fe2+ +2
iron(III) Fe3+ +3
4) A polyatomic ion is a charged particle that contains more than one atom.
In any given chemical compound, the elements always combine in the same proportion
with each other. Thus, chemists use chemical symbols and numbers to efficiently and
elegantly represent the ratio of constituent elements present in an ionic compound.
1) All units in the chemical formula are electrically neutral. Hence, all positive charges
must balance out the negative charges in an ionic compound.
(i) Write down the ions with the charges, e.g. Xm+Yn–
(ii) Move the values m and n diagonally (but without the charges). The chemical
formula of the ionic compound is hence XnYm.
K+ SO42–
Note!
Polyatomic ions have their charge belonging to the
entire ion e.g. −2 belongs to SO42–.
2 1
sodium fluoride
magnesium sulfide
aluminium oxide
potassium oxide
copper(II) chloride
iron(III) oxide
2. Write the formula of the following ionic compounds involving polyatomic ions.
potassium sulfate
magnesium nitrate
calcium carbonate
copper(II) hydroxide
ammonium sulfate
6 Covalent Bonding
Definition:
Example 1:
How does a hydrogen atom bond with another hydrogen atom?
Step 2: Consider how each atom would achieve a noble gas electronic configuration
(duplet in this case since there is only one electron shell).
If both hydrogen atoms were to share their electron, both atoms would have 2 valence
electrons attaining a noble gas electronic configuration:
Legend:
H H H H and x are electrons of hydrogen
H H H–H H2
1
Full structural formula of a molecule shows clearly how all atoms are joined to each other via displaying
all covalent bonds. The atoms are drawn apart and are joined by lines. Each bond is made up of a pair of
electrons. Each line represents a single covalent bond. A double line represents a double covalent bond
(4 electrons involved). A triple line represents a triple covalent bond (6 electrons involved).
2
Molecular formula shows the exact number of each atom of element present in the molecule.
Example 2:
Why is a water molecule formed from hydrogen and oxygen H2O and not HO?
Step 1: Consider the electronic configuration of a hydrogen atom and an oxygen atom.
H: 1 O: 2.6
Step 2: If only 1 hydrogen atom shared its electron with an oxygen atom, the resulting
diagram would be:
Legend:
H O electron of hydrogen
x electron of oxygen
This substance would be unstable as the oxygen atom only has 7 valence electrons.
However, if 2 hydrogen atoms combine chemically with 1 oxygen atom, the oxygen atom
would have achieved a stable octet and the two hydrogen atoms would have achieved
stable duplet configuration.
Legend:
H O electron of hydrogen
x electron of oxygen
O
H–O–H H2O
H H
Example 3:
How is an oxygen molecule formed? (student to draw)
O O O=O O2
Cl Cl
N N
ammonia Legend: electron of N and x electron of H
(NH3)
N
H H
H C H
…………………
O
O C
………………… Cl P Cl
Cl
substance ‘dot-and-cross’ diagram full structural formula
(show ALL electrons)
hydrogen chloride Legend: electron of H and x electron of Cl
Molecular formula:
…………………
H Cl
…………………
H H
2. Identify if each of the substances has ionic or covalent bonds or neither by ticking in the corresponding
boxes.
ionic covalent
neither
bonds bonds
(a) carbon dioxide, CO2
(b) methane, CH4
(c) sodium chloride, NaCl
(d) water, H2O
(e) magnesium bromide, MgBr2
(f) calcium chloride, CaCl2
(g) neon, Ne
(h) magnesium oxide, MgO
(i) oxygen, O2
(j) potassium hydroxide, KOH
3. How many electrons in one molecule of ethene, C2H4 are not involved in bonding?
A 0
B 2
C 4
D 8
A B C D
Description In sodium chloride (NaCl), every Na+ ion is bonded to 6 other Cl– ions,
and every Cl– ion is bonded to 6 other Na+ ions. (Fig. 1.12). In nature,
the ions are arranged in such a way to maximise the interaction of
oppositely charged ions.
The structure and bonding give rise to the following properties of ionic compounds.
Reason: They have giant ionic crystal lattice structures. A lot of energy is
needed to overcome the strong electrostatic forces of attraction between the
oppositely charged ions.
Reason: In the solid state, the ions are held in their fixed positions by strong
electrostatic forces of attraction. Ions are not mobile (i.e. cannot move freely) to
conduct electricity. (recall the characteristics of particles described by Kinetic
Particle Theory)
Bonding Within each molecule, the atoms are held together by strong
covalent bonds.
The structure and bonding give rise to the following properties of simple covalent
substances.
Note: The covalent bonds within the molecules are NOT broken during
melting/boiling.
(b) They generally do not conduct electricity in all states.
Reason: They typically exist as neutral molecules, they do not have any mobile
charge carriers (ions or electrons) to conduct electricity.
Exceptions: Acids e.g. HCl are good conductors of electricity due to their mobile
ions in solution.
Note: Other physical properties of ionic compounds/simple covalent substances will be covered
in Level 3 Chemistry.
Get it right!
Misconception: Covalent substances have low melting and boiling points because the
covalent bonds are weak.
Fact: The covalent bonds formed between the atoms in the molecules are strong, but the
intermolecular forces of attraction between the molecules are weak.
During melting/boiling, only the weak intermolecular forces of attraction between the
molecules are overcome, which requires little heat energy. The covalent bonds between
the atoms in the molecules are not broken.
PHYSICAL PROPERTIES
IONIC COMPOUNDS SIMPLE COVALENT SUBSTANCES
Examples: sodium chloride (NaCl), Examples: water (H2O), carbon dioxide
magnesium oxide (MgO) (CO2), ammonia (NH3), oxygen (O2),
nitrogen (N2)
Reason: They have a giant ionic crystal Reason: They have a simple molecular
lattice structure. A lot of energy is needed to structure. Little energy is needed to
overcome the strong electrostatic forces of overcome the weak intermolecular forces of
attraction between the oppositely charged attraction between the molecules.
ions.
Ionic compounds do NOT conduct Covalent substances generally do not
electricity in the solid state but are good conduct electricity at any states.
conductors in the molten and aqueous
states.
Reason: In the solid state, the ions are held Reason: They have no mobile charge
in their fixed positions by strong carriers (ions or electrons) to conduct
electrostatic forces of attraction. The ions are electricity.
not mobile to conduct electricity.
In the molten or aqueous state, the
electrostatic forces of attraction are
overcome. The ions are mobile to conduct
electricity.
1. Which correctly describes the compound formed between sodium and chlorine?
a) Magnesium fluoride has a high melting point and boiling point. [2]
b) Magnesium fluoride can conduct electricity in the aqueous state but not in the solid state. [2]