PWK-CHEM-01 KCET Mock Test series
Chemistry
1. Acidified KMnO4 oxidises oxalic acid to CO2. 7. The molecule having one unpaired electron, is
What is the volume (in litres) of 10–4 MKMnO4 (1) NO (2) CO
required to completely oxidise 0.5 L of 10–2 M (3) CN (4) O2
oxalic acid in acidic medium?
(a) 125 (b) 1250
8. Among the following species, identify the
(c) 200 (d) 20 isostructural pairs
NF3 NO3− , BF3 , H 3O + , N 3 H
2. Haemoglobin contains 0.33 % of iron by weight.
The molecular weight of haemoglobin is (1) NF3 , NO3− and BF3 , H 3O +
approximately 67200. The number of iron atoms
(at. wt. of Fe is 56) present in one molecule of
(2) NF3 , N3H and NO3− , BF3
haemoglobin are (3) NF3 , H3O + and NO3− , BF3
(a) 1 (b) 6
(4) NF3 , H3O + and N 3 H, BF3
(c) 4 (d) 2
3. The de-Broglie wavelength of a car of mass 1000kg 9. In an adiabatic process, no transfer of heat takes
velocity 36 km/h is (h=6.63 × 10–34 Js) place between system and surroundings. Choose
(1) 6.626 × 10–34 m (2) 6.626 × 10–38 m the correct option for free expansion of an ideal gas
(3) 6.626 × 10–31 m (4) 6.626 × 10–30 m under adiabatic condition from the following.
(a) q = 0, T 0, W = 0
4. Amongst the following set of quantitive impossible (b) q 0, T = 0, W = 0
set is (c) q = 0, T = 0, W = 0
n l m s (d) q = 0, T< Q, W 0
(1) 3 2 –3 1/2
(2) 4 0 0 1/2 10. The conjugate base of H 2 PO 4− is
(3) 5 3 0 -1/2
(1) PO34− (2) P2O5
(4) 3 2 –2 1/2
(3) H3PO4 (4) HPO 24 −
5. The correct order of first ionisation potential of
calcium nitrogen, oxygen and fluorine is 11. Consider the equilibrium reactions,
(1) C > N > O > F K1
H3 PO 4 Ç H + + H 2 PO 4−
(2) O > N > F > C
K2
(3) O > F > N > C H 2 PO 4− H + + HPO 42−
(4) F > N > O > C K3
HPO 24− H + + PO34−
6. The increasing order of the ionic radii of the given The equilibrium constant, K for the following
isoelectronic species is dissociation
(1) Cl– , Ca2+, K+ , S2– H 3 PO 4 3H + + PO34− , is
2– – 2+ +
(2) S , Cl , Ca , K
(1) K1/K2.K3 (2) K1.K2.K3
(3) Ca2+, K+, Cl–, S2–
(3) K2/K1.K3 (4) K1 + K2 + K3
(4) K+ , S2–, Ca2+, Cl–
12. In the reaction 18. In the following reaction
SO2 + 2H2S → 3S + 2H2O
The substance oxidised is
(1) H2S (2) SO2
(3) S (4) H2O
13. Which of the following elements does not show The major product is
disproportionation tendency CH3
|
(1) Cl (2) Br (1) H3C − C − CH − CH 3
(3) F (4) I | |
OH CH 3
14. The structure of iso-butyl group in organic CH 3
compound |
(1) CH3 – CH – CH2 – CH3 (2) CH 2 − C − CH 2 − CH 3
| |
(2) CH3 – CH2 – CH2 – CH2 – OH CH 3
CH3
| CH3
(3) CH3 – C – |
| (3) H3C − C − CH − CH 3
CH3 | |
CH 3 OH
(4)
CH 3
|
(4) H 3C − C − CH 2 − CH 2
15. Correct the increasing order of acidity is as | |
(1) H 2 O,C 2 H 2 , H 2 CO3 , phenol CH 3 OH
(2) C2 H 2 , H 2 O, H 2 CO3 , phenol
(3) phenol,C 2 H 2 , H 2 CO3 , H 2 O 19. Which one of the following statements is false?
(4) C 2 H 2 , H 2 O, phenol and H 2 CO3 (1) Raoult's law states that the vapour pressure of
a component over a solution is proportional to
16. Which of the following carbocations is expected to its mole fraction
be most stable : (2) The osmotic pressure (π) of a solution is given
by the equation π = MRT, where, M is the
molarity of the solution
(1) (2) (3) The correct order of osmotic pressure for
0.01 M aqueous solution of each compound is
BaCl2 > KCI > CH3COOH > sucrose
(4) Two sucrose solutions of same molality
prepared in different solvents will have the
same freezing point depression
(3) (4)
20. KH value for Ar(g), CO2(g), HCHO(g) and CH4(g)
are 40.39, 1.67, 1.83 × 10–5 and 0.413
respectivley.
17. Which does not follow Markownikoff’s rule? Arrange these gases in the order of their increases
(1) CH3 – CH = CH2 solubility
(2) CF3CH = CH2 (1) HCHO < CH4 < CO2 < Ar
CH3 − CH − CH = CH 2 (2) HCHO < CO2 < CH4 < Ar
(3) | (3) Ar < CO2 < CH4 < HCHO
CH3
(4) Ar < CH4 < CO2 < HCHO
(4) CH3 – CH2 – CH = CH2
21. Aluminium phosphate is 100% ionised in 0.01 27. For a reaction between A and B, the initial rate of
Tb reaction is measured for various initial
molal aqueous solution. Hence, is
Kb concentrations of A and B. The data provided are
[A] [B] Initial reaction
(1) 0.01 (2) 0.015
rate
(3) 0.0175 (4) 0.02
(1) 0.20 M 0.30 M 5 × 10–5
(2) 0.20 M 0.10 M 5 × 10–5
22. Limiting molar conductivity of NH4OH, (i.e. om
(3) 0.40 M 0.05 M 1 × 10–4
(NH4OH)) is equal to
The overall order of the reaction is
(1) om ( NH 4Cl ) + om ( NaCl ) − om ( NaOH )
(1) one (2) two
(2) om ( NaOH ) + om ( NaCl ) − om ( NH 4Cl ) (3) two and half (4) three
(3) om ( NH 4 OH ) + om ( NH 4 Cl ) − om ( HCl ) 28. The correct difference between first and second-
order reactions is that
(4) om ( NH 4Cl ) + om ( NaOH ) − om ( NaCl )
(1) a first-order reaction can be catalysed; a
second-order reaction cannot be catalysed
23. In a H2-O2 fuel cell, combustion of hydrogen
occurs to (2) the half-life of a first-order reaction does not
depend on [A]0; the half-life of a second-
(1) remove absorbed oxygen from electrode
order reaction does depend on [A]0
surface
(3) the rate of a first-order reaction does not
(2) create potential difference between the two
depend on reactant concentrations; the rate of
electrodes
a second-order reaction does depend on
(3) produce high purity water
reactant concentrations
(4) generate heat
(4) the rate of a first-order reaction does depend
24. Time required to deposit one millimole of on reactant concentrations; the rate of a
aluminium metal by the passed of 9.65A current second order reaction does not depend on
through molten electrolyte containing aluminium reactant concentrations
ion is
29. For a first order reaction, the concentration
(1) 30 s (2) 10 s changes from 0.8 to 0.4 in 15 min. The time taken
(3) 30000 s (4) 10000 s for the concentration to change from 0.1 M to
0.025 M is
25. The equilibrium constant of the reaction
(1) 30 min (2) 15 min
Cu(s) + 2Ag+ (aq) → Cu2+ (aq) + 2Ag(s);
(3) 7.5 min (4) 60 min
(Given : E° = 0.46 V at 298 K) is
(1) 2.4 × 1010 (2) 2.0 × 1010 30. Which of the following statements is in
(3) 4.0 × 1010 (4) 4.0 × 1015 accordance with collision theory?
d NH3 (i) Rate is directly proportional to collision
26. For the reaction, N2 + 3H2 → 2NH3, if = frequency.
dt
−d H 2
(ii) Rate depends upon orientation of atoms.
–4 –1 –1
2 × 10 mol L s , the value of would (iii) Temperature determines the rate.
dt
be (1) Only (iii) (2) (i) and (ii)
(1) 3 × 10–4 mol L–1 s–1 (3) (ii) and (iii) (4) All of these
(2) 4 × 10–4 mol L–1 s–1 31. What is the general outer configuration of the
(3) 6 × 10–4 mol L–1 s–1 coinage metal?
(4) 1 × 10–4 mol L–1 s–1 (1) ns2, np6 (2) (n – 1)d10, ns1
(3) (n – 1)d10, ns2 (4) (n – 1)d1, ns2
32. Oxidation state of the final product of chromium 39. The correct order of magnetic moments (spin only
in the reaction between K2Cr2O7 and Kl in acidic value in BM) among the following is
medium is (Atomic number Mn = 25, Fe = 26, Co = 27)
(1) +4 (2) +6 (1) [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–
(3) +2 (4) +3 (2) [MnCl4]2– > [Fe(CN)6]4– > [CoCl4]2–
(3) [Fe(CN)6]4– > [MnCl4]2– > [CoCl4]2–
33. Of the ions Zn2+, Ni2+ and Cr3+ (At. nos Zn = 30, (4) [Fe(CN)6]4– > [CoCl4]2– > [MnCl4]2–
Ni = 28, Cr = 24)
40. Among the following compounds, which
(1) Only Zn2+ is colourless and Ni2+ and Cr3+ are
compound undergoes SN1 reaction faster?
coloured
(2) All there are colourless (1) (2)
(3) All three are coloured
(4) Only Ni2+ is coloured and Zn2+ and Cr3+ are (3) (4)
colourless
41. Which is the correct increasing order of boiling
33. A magnetic moment of 1.73 BM will be shown by
points of the following compounds?
one among the following.
1-iodobutane, 1-bromobutane, 1-chlorobutane,
(1) [Ni(CN)4]2– (2) TiCl4 butane
(3) [CoCl6]4– (4) [Cu(NH3)4]2+ (1) Butane 1-chlorobutane < 1- bromobutane <
1-iodobutane
35. The IUPAC name of K2[Ni(CN)4] is (2) 1-iodobutane < 1-bromobutane <
(1) potassium tetracyanonickelate (II) 1-chlorobutane < Butane
(2) potassium tetracyanato nickelate (III) (3) Butane < 1-iodobutane < 1- bromobutane <
1-chlorobutane
(3) potassium tetracyanatonickel (II)
(4) Butane < 1-chlorobutane < 1-iodobutane <
(4) potassium tetracyanonickel (III) 1-bromobutane
36. What is the decreasing order of basicity of 1°, 2° 42. What products are formed when the following
and 3° ethyl amines and ammonia? compound is treated with Br2 in the presence of
(1) NH3 > C2H5NH2 > (C2H5)2NH > (C2H5)3N FeBr3?
(2) (C2H5)3N > (C2H5)2 NH > C2H5NH2 > NH3
(3) (C2H5)2NH > C2H5NH2 > (C2H5)3N > NH3
(4) (C2H5)2NH > (C2H5)3N > C2H5NH2 > NH3
37. The complexes [Co(NH3)6][Cr(CN)6] and (1)
[Cr(NH3)6][Co(CN)6] are the examples of which
type of isomerism?
(1) Ionisation isomerism (2)
(2) Coordination isomerism
(3) Geometrical isomerism
(4) Linkage isomerism
(3)
38. Among the ligands NH3, en, CN– and CO, the
correct order of their increasing field strength, is
(1) CO < NH3 < en < CN–
(2) NH3 < en < CN– < CO (4)
–
(3) CN < NH3 < CO < en
(4) en < CN < NH3 < CO
43. Identify Z in the following reaction series. 47. An aromatic compound 'X' with molecular formula
Alc.KOH
C2 H5l ⎯⎯⎯⎯→ X ⎯⎯⎯
Br2
→ Y ⎯⎯⎯→ Z
KCN C9H10O gives the following chemical tests
(i) It forms 2,4-DNP derivative.
(1) CH3CH2N (2) NCCH2 – CH2CN
(ii) It reduces Tollen’s reagent.
(3) BrCH2 – CH2CN (4) BrCH = CHCN
(iii) It undergoes Cannizzaro reaction.
44. Arrange the following compounds in decreasing (iv) On vigorous oxidation, 1, 2-
order of their boiling points CH3CHO, benzenedicarboxylic acid is obtained.
CH3CH2OH, CH3OCH3, CH3CH2CH3 Compound X is
(1) CH3CH2CH3 < CH3OCH3 < CH3CHO <
CH3CH2OH (1) (2)
(2) CH3CH2CH3 < CH3CHO < CH3OCH3 <
CH3CH2OH
(3) CH3CH2CH3 > CH3CHO > CH3OCH3 >
CH3CH2OH
(4) CH3CH2OH > CH3CHO > CH3OCH3 > (3) (4)
CH3CH2CH3
48. Reaction by which, benzaldehyde cannot be
45. prepared?
(1) + CrO2Cl2 and CS2 followed by H3O+
Major product is
(2) + H2 in presence of Pd-BaSO4
(1)
(3) + CO + HCl in presence of anhy. AlCl3
(4) + Zn / Hg and conc. HCl
(2)
49. Identify Z in the sequence of reactions,
HBr/H O C H ONa
CH3CH 2 CH = CH 2 ⎯⎯⎯⎯⎯
2 2 → Y ⎯⎯⎯⎯⎯
2 5
→Z
(3) (1) CH3 – (CH2)3 – O – CH2CH3
(2) (CH3)2CH2 – O – CH2CH3
(3) CH3(CH2)4 – O – CH3
(4) CH3CH2 – CH(CH3) – O – CH2CH3
(4) 50. The final product of the following reaction is/are
46. In a set of reaction, m-bromobenzoic acid gave a
product D. Identify the product D.
(1)
(1) (2) (2)
(3)
(3) (4)
(4)
51. Compound A, C8H10O, is found to react with NaOl 55. An organic amino compound reacts with aqueous
(produced by reacting Y with NaOH) and yields a nitrous acid at low temperature to produce an oily
yellow precipitate with characteristic smell. A and nitrosoamine. The compound is
Y are respectively.
(1) CH3NH2
(2) CH3CH2NH2
(1)
(3) (CH3CH2)3N
(2) (4) CH3CH2 – NHCH2CH3
(3) 56. The correct statement about the following
disaccharide is
(4)
52. Tert-butyl methyl ether on heating with Hl gives a
mixture of
(1) tert-butyl alcohol and methyl iodide
(1) Ring (l) is pyranose with -glycosidic link
(2) tert-butyl iodide and methanol
(3) isobutylene and methyl iodide (2) Ring (l) is furanose with -glycosidic link
(4) isobutylene and methanol (3) Ring (ll) is furanose with -glycosidic link
(4) Ring (ll) is pyranose with -glycosidic link
53. 57. Which of the following hormones is produced
under the condition of stress which stimulates
glycogenolysis in the liver of human beings?
The final product ‘C’ in the above reaction is
(1) Thyroxine
(2) Insulin
(1) (2) (3) Adrenaline
(4) Estradiol
58. Which one give below is a non-reducing sugar?
(3) (4) (1) Lactose
(2) Glucose
(3) Sucrose
54. Given the following sequence of reactions, (4) Maltose
NaCN OH − Br / NaOH
CH3CH 2l ⎯⎯⎯→ A ⎯⎯⎯⎯⎯⎯⎯
→ B ⎯⎯⎯⎯⎯
2 →C
Partial hydrolysis
The major product ‘C’ is 59. The term anomers of glucose refers to
(1) CH3CH2NH2 (1) isomers of glucose that differ in configuration
(2) CH3CH 2 C − NHBr at carbons one and four (C-1 and C-4)
|| (2) a mixture of D-glucose and L-glucose
O
(3) enantiomers of glucose
(3) CH3CH2 – COONH4
(4) isomers of glucose that differ in configuration
(4) CH 3CH 2 − C − NBr2
|| at carbon one C-1
O
60. D-(+)-glucose reacts with hydroxylamine and
yields and oxime. The structure of the oxime would
be
(1)
(2)
(3)
(4)
Get the Solutions on: https://www.youtube.com/@PWKannada | Date: 13-04-2024.