SAFETY DATA SHEET

DROMUS™ BA TH
SDS according to SS 586

Section 1. Identification
Product identifier : DROMUS™ BA TH
Product code : 42100226
Other means of : Not available.
identification

Relevant identified uses of the substance or mixture and uses advised against
Relevant uses : Metalworking fluid
Uses advised against : Any other purpose.

Supplier's details : Quaker Houghton Singapore

22 Boon Lay Way,
#01-61 Trade Hub 21,
Singapore 609968
T: +65-6235-1544

[email protected]
www.quakerhoughton.com

Emergency telephone : CHEMTREC Singapore: +(65)-31581349 or 800-101-2201

number (with hours of
operation)

Section 2. Hazards identification

This product is hazardous under the Globally Harmonized System
Classification of the : SKIN CORROSION/IRRITATION - Category 2
substance or mixture SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

GHS label elements, including precautionary statements

Hazard pictograms :

Signal word : Warning

Hazard statements : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H373 - May cause damage to organs through prolonged or repeated exposure.
Precautionary statements

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Section 2. Hazards identification

Prevention : P280 - Wear eye or face protection.
P260 - Do not breathe vapor.
P264 - Wash thoroughly after handling.
Response : P314 - Get medical advice or attention if you feel unwell.
P362 + P364 - Take off contaminated clothing and wash it before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice or attention.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.

Other hazards which do not : None known.

result in classification

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

: Not applicable.
Ingredient name % CAS number
Mineral oil ≥50 - ≤75 **
Sulfonic acids, petroleum, sodium salts ≤10 68608-26-4
Distillates (petroleum), solvent-dewaxed heavy paraffinic ≤5 64742-65-0
2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol ≤3 4719-04-4
potassium hydroxide <1 1310-58-3
** May contain : 64742-54-7,64742-65-0,74869-22-0
The mineral oils in the product contain < 3% DMSO extract (IP 346).
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.

Section 4. First aid measures

Description of necessary first aid measures
General advice : Get medical attention. If medical advice is needed, have product container or label
at hand. Use personal protective equipment as required. Remove contaminated
clothing and wash it before reuse. Wash skin surfaces thoroughly after contact.
Inhalation : Move affected person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Get medical attention.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and wash it
before reuse. Get medical attention if symptoms occur.
Eye contact : Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Remove contact lenses, if present and easy to do. Get medical
attention if symptoms occur.
Ingestion : Ingestion may cause gastrointestinal irritation and diarrhea. Do not induce vomiting
unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person.

Most important symptoms/effects, acute and delayed

Inhalation : Not expected under normal use.

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Section 4. First aid measures

Skin contact : pain or irritation,redness,skin rash or hives
Eye contact : pain or irritation,redness,watering
Ingestion : Not expected under normal use.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Use personal protective equipment as required.

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. Use dry chemical, CO₂,
media water spray (fog) or foam.
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst.
from the chemical
Hazardous thermal : In a fire, hazardous decomposition products may be produced. carbon oxides (CO,
decomposition products CO₂) nitrogen oxides sulfur oxides metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training. Put
personnel on appropriate personal protective equipment (see Section 8). Keep unnecessary
personnel away. Avoid breathing vapor or mist. Provide adequate ventilation.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel". Evacuate area.

Environmental precautions : Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Do not allow any potentially contaminated water,
including rain water, runoff from fire fighting or spills, to enter any waterway, sewer
or drain.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Absorb with an inert material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.

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Section 6. Accidental release measures

Large spill : Stop leak if without risk. Move containers from spill area. For large spills, dike
spilled material or otherwise contain it to ensure runoff does not reach a waterway.
Absorb with an inert material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected
including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
incompatibilities materials (see Section 10) and food and drink. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Storage temperature : Not available.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Mineral oil Workplace Safety and Health Act
(Singapore, 2/2006).
PEL (long term): 5 mg/m³ 8 hours. Form:
Mist
PEL (short term): 10 mg/m³ 15 minutes.
Form: Mist
Distillates (petroleum), solvent-dewaxed heavy paraffinic Workplace Safety and Health Act
(Singapore, 2/2006).
PEL (long term): 5 mg/m³ 8 hours. Form:
Mist
PEL (short term): 10 mg/m³ 15 minutes.
Form: Mist
potassium hydroxide Workplace Safety and Health Act
(Singapore, 2/2006).
PEL (short term): 2 mg/m³ 15 minutes.

Appropriate engineering : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
controls local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

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Section 8. Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Eating,
drinking and smoking should be prohibited in areas where this material is handled,
stored and processed. Appropriate techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location. Keep
equipment clean.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers.
Other skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. Appropriate footwear and any additional skin
protection measures should be selected based on the task being performed and the
risks involved and should be approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Thermal hazards : Not expected under normal use. Not relevant/applicable due to nature of the
product.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Clear., Amber.
Odor : Not available.
Odor threshold : Not available.
pH : 9.7 [Conc. (% w/w): 5%]
Melting point : Not available.
Boiling point : Not available.
Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.9121
Solubility : Emulsifies.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flow time (ISO 2431) : Not available.
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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific measures identified.

Incompatible materials : Strong oxidizing materials. strong acids. strong alkalis

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity : Based on available data, the classification criteria are not met.
Route ATE value
Oral 38878.98 mg/kg
Inhalation (dusts and mists) 18.9 mg/l
Numerical measures of toxicity
Product/ingredient name Result Species Dose Exposure
Sulfonic acids, petroleum, LD50 Dermal Rabbit >500 mg/kg -
sodium salts
LD50 Oral Rat >2000 mg/kg -
Distillates (petroleum), LD50 Dermal Rabbit >2000 mg/kg -
solvent-dewaxed heavy
paraffinic
LD50 Oral Rat >5000 mg/kg -
2,2',2"-(hexahydro- LC50 Inhalation Dusts and mists Rat - Male, 0.371 mg/l 4 hours
1,3,5-triazine-1,3,5-triyl) Female
triethanol
LD50 Oral Rat 763 mg/kg -
potassium hydroxide LD50 Oral Rat 273 mg/kg -
Irritation/Corrosion : Causes severe eye irritation. Causes skin irritation.
Product/ingredient name Result Species Score Exposure Observation
potassium hydroxide Eyes - Moderate irritant Rabbit - 24 hours 1 -
mg
Skin - Severe irritant Guinea pig - 24 hours 50 -
mg
Skin - Severe irritant Human - 24 hours 50 -
mg
Skin - Severe irritant Rabbit - 24 hours 50 -
mg
Sensitization : May cause sensitization by skin contact.
Not available.
Mutagenicity : Based on available data, the classification criteria are not met.
Not available.
Carcinogenicity : Based on available data, the classification criteria are not met.
Not available.

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Section 11. Toxicological information

Reproductive toxicity : Based on available data, the classification criteria are not met.
Not available.
Not available.
Specific target organ toxicity (single : Based on available data, the classification criteria are not met.
exposure)
Not available.

Specific target organ toxicity (repeated : May cause damage to organs through prolonged or repeated
exposure) exposure.
Name Category Route of Target organs
exposure
2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol Category 1 inhalation -
Aspiration hazard : Based on available data, the classification criteria are not met.
Not available.

Other information : None identified.

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause sensitization by skin contact.
Eye contact : Causes serious eye irritation.
Ingestion : No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure
May cause damage to organs through prolonged or repeated exposure.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : pain or irritation,redness,watering
Inhalation : Not expected under normal use.
Skin contact : pain or irritation,redness,skin rash or hives
Ingestion : Not expected under normal use.

Section 12. Ecological information

No known significant effects or critical hazards.

Toxicity
Product/ingredient name Result Species Exposure
Sulfonic acids, petroleum, Acute EC50 >100 mg/l Algae - Desmodesmus 72 hours
sodium salts subspicatus
Acute EC50 >1000 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 >1000 mg/l Fish - Pimephales promelas 96 hours
2,2',2"-(hexahydro- Acute EC50 6.66 mg/l Algae - Desmodesmus 72 hours
1,3,5-triazine-1,3,5-triyl) subspicatus
triethanol
Acute EC50 9 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 12 mg/l Fish - Brachydanio rerio 96 hours
potassium hydroxide Acute LC50 80 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours

Persistence/degradability
Not available.

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Section 12. Ecological information

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
2,2',2"-(hexahydro- -2 - low
1,3,5-triazine-1,3,5-triyl)
triethanol

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Empty containers or
liners may retain some product residues. Empty containers retain product residue
and can be hazardous. Care should be taken when handling emptied containers
that have not been cleaned or rinsed out.

Section 14. Transport information

UN IMDG IATA ADR/RID
UN number Not regulated. Not regulated. Not regulated. Not regulated.

UN proper - - - -
shipping name
Transport - - - -
hazard class
(es)

Packing group - - - -
Environmental No. No. No. No.
hazards
Additional information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

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Section 15. Regulatory information

Singapore - hazardous chemicals under government control
None.
International regulations
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

Section 16. Other information

Version : 1
Quaker Houghton Product Stewardship
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
HPR = Hazardous Products Regulations
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Key literature references : SS 586 - Part 1, Part 2, Part 3 Safety data sheets of raw materials, global
and sources for data regulatory body information, scientific literature, and testing data .

Indicates information that has changed from previously issued version.

Disclaimer
This product's safety information is provided to assist our customers in assessing compliance with safety/health/
environmental regulations. The information contained herein is based on data available to us and is correct to the
best of our knowledge, information and belief at the date of its publication. However, no warranty of merchantability,
fitness for any use, or any other warranty is expressed or implied regarding the accuracy of this data, the results to be
obtained from the use thereof, or the hazards connected with the use of the product. Since the use of this product is
within the exclusive control of the user, it is the user's obligation to determine the conditions for safe use of the
product. Such conditions should comply with all regulations concerning the product. The company referenced in this
Safety Data Sheet assumes no liability for any injury or damage, direct or consequential, resulting from the use of this
product unless such injury or damage is attributable to the gross negligence of such company.

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