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1 Identification: Acc. To OSHA HCS

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0% found this document useful (0 votes)
27 views90 pages

1 Identification: Acc. To OSHA HCS

Uploaded by

Diego Droyk
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 90

Page 1/10

Safety Data Sheet


acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Information department: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

2 Hazard(s) identification
· Classification of the substance or mixture

GHS01 Exploding bomb

Unstable Explosives H200 Unstable explosive.

GHS04 Gas cylinder

Gases under Pressure - Compressed gas H280 Contains gas under pressure; may explode if heated.

GHS07

Eye Irritation 2A H319 Causes serious eye irritation.


· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS01 GHS04 GHS07

· Signal word Danger


· Hazard statements
Unstable explosive.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
(Contd. on page 2)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 1)
Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 4 Reactivity = 4

· HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
FIRE 4 Fire = 4
REACTIVITY 4 Reactivity = 4

· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
67-63-0 propan-2-ol >10-≤25%
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro >2.5-≤10%

4 First-aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
(Contd. on page 3)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 2)
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals
· PAC-1:
811-97-2 1,1,1,2-tetrafluoroethane 8,000 ppm
67-63-0 propan-2-ol 400 ppm
· PAC-2:
811-97-2 1,1,1,2-tetrafluoroethane 13,000 ppm
67-63-0 propan-2-ol 2000* ppm
· PAC-3:
811-97-2 1,1,1,2-tetrafluoroethane 27,000 ppm
67-63-0 propan-2-ol 12000** ppm

7 Handling and storage


· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about protection against explosions and fires:
Protect from heat.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
(Contd. on page 4)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 3)

· Conditions for safe storage, including any incompatibilities


· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the remaining constituent has no known exposure limits.
811-97-2 1,1,1,2-tetrafluoroethane
WEEL Long-term value: 1000 ppm
67-63-0 propan-2-ol
PEL Long-term value: 980 mg/m³, 400 ppm
REL Short-term value: 1225 mg/m³, 500 ppm
Long-term value: 980 mg/m³, 400 ppm
TLV Short-term value: 400 ppm
Long-term value: 200 ppm
BEI, A4
· Ingredients with biological limit values:
67-63-0 propan-2-ol
BEI 40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
(Contd. on page 5)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 4)
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Color: White
· Odor: Ether-like
· Odor threshold: Not determined.
· pH-value at 20 °C (68 °F): 7
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 82 °C (179.6 °F)
· Flash point: 12 °C (53.6 °F)
· Flammability (solid, gaseous): Not flammable.
· Ignition temperature: 425 °C (797 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Explosive with or without contact with air.
· Explosion limits:
Lower: 2 Vol %
Upper: 12 Vol %
· Vapor pressure at 25 °C (77 °F): 5,515.8 hPa (4,137.2.8 mm Hg)
· Density at 20 °C (68 °F): 1.25 g/cm³ (10.43125 lbs/gal)
· Relative density Not determined.
· Vapor density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
(Contd. on page 6)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 5)

· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 15.3 %
VOC content: 15.31 %
1,140.9 g/l / 9.52 lb/gal
Solids content: 0.0 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
67-63-0 propan-2-ol 3
· NTP (National Toxicology Program)
None of the ingredients is listed.
(Contd. on page 7)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 6)
· OSHA-Ca (Occupational Safety Health Administration)
None of the ingredients is listed.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT, ADR, IMDG, IATA UN1950
· UN proper shipping name
· DOT Aerosols, flammable
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· Transport hazard class(es)
· DOT

· Class 2.2 Gases


(Contd. on page 8)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 7)

· Label 2.2
· ADR

· Class 2 5F Gases
· Label 2.2
· IMDG, IATA

· Class 2.2 Gases


· Label 2.2
· Packing group
· DOT, ADR, IMDG, IATA Void
· Environmental hazards: Not applicable.
· Special precautions for user Warning: Gases
· Hazard identification number (Kemler code): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of living
quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1 except
for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 75 kg
On cargo aircraft only: 150 kg
· ADR
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
(Contd. on page 9)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 8)

· UN "Model Regulation": UN 1950 AEROSOLS, 2.2

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
67-63-0 propan-2-ol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Hazardous Air Pollutants
None of the ingredients is listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value)
67-63-0 propan-2-ol A4
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS01 GHS04 GHS07

· Signal word Danger


· Hazard statements
Unstable explosive.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
(Contd. on page 10)
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Safety Data Sheet
acc. to OSHA HCS
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 9)
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact:
· Date of preparation / last revision 08/12/2022 / -
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Unstable Explosives: Explosives – Unstable explosive
Gases under Pressure - Compressed gas: Gases under pressure – Compressed gas
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
US

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Page 1/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
ProSciTech Pty Ltd
11 Carlton Street, Kirwan QLD 4817 Australia
Telephone Number: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays)
Emergency Contact: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays)
Website: ems.proscitech.com
Emgrid Australia Pty. Ltd.
P.O. Box 118
The Patch VIC 3792
Australia
Tel: 03 9752 1785
Fax: 03 9752 1784
Website: www.emgrid.com.au
· Further information obtainable from: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

2 Hazard(s) Identification
· Classification of the substance or mixture

GHS01 exploding bomb

Unst. Expl. H200 Unstable explosives.

GHS04 gas cylinder

Press. Gas C H280 Contains gas under pressure; may explode if heated.

GHS07

Eye Irritation 2A H319 Causes serious eye irritation.


· Label elements
· GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS).
(Contd. on page 2)
AU

55.0.4
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Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 1)
· Hazard pictograms

GHS01 GHS04 GHS07

· Signal word Danger


· Hazard statements
Unstable explosives.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition and Information on Ingredients


· Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
67-63-0 propan-2-ol >10-≤25%
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro >2.5-≤10%
· Additional information: For the wording of the listed hazard phrases refer to section 16.

4 First Aid Measures


· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
(Contd. on page 3)
AU

55.0.4
Page 3/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 2)
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire Fighting Measures


· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

6 Accidental Release Measures


· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and Storage


· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Protect from heat.
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray onto a naked flame or any incandescent material.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
· Specific end use(s) No further relevant information available.
AU
(Contd. on page 4)

55.0.4
Page 4/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 3)

8 Exposure controls and personal protection


· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
811-97-2 1,1,1,2-tetrafluoroethane
WES Long-term value: 4240 mg/m³, 1000 ppm
67-63-0 propan-2-ol
WES Short-term value: 1230 mg/m³, 500 ppm
Long-term value: 983 mg/m³, 400 ppm
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

9 Physical and Chemical Properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: White
· Odour: Ether-like
(Contd. on page 5)
AU

55.0.4
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Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 4)

· Odour threshold: Not determined.


· pH-value at 20 °C: 7
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 82 °C
· Flash point: 12 °C
· Flammability (solid, gas): Not applicable.
· Ignition temperature: 425 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Explosive with or without contact with air.
· Explosion limits:
Lower: 2 Vol %
Upper: 12 Vol %
· Vapour pressure at 25 °C: 5,515.8 hPa
· Density at 20 °C: 1.25 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 15.3 %
VOC (EC) 96.94 %
Solids content: 0.0 %
· Other information No further relevant information available.

10 Stability and Reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
AU
(Contd. on page 6)

55.0.4
Page 6/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 5)

11 Toxicological Information
· Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation No irritant effect.
· Serious eye damage/irritation Irritating effect.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant

12 Ecological Information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· ADG, IMDG, IATA UN1950
(Contd. on page 7)
AU

55.0.4
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Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 6)

· UN proper shipping name


· ADG 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· Transport hazard class(es)
· ADG

· Class 2 5F Gases.
· Label 2.2
· IMDG, IATA

· Class 2.2 Gases.


· Label 2.2
· Packing group
· ADG, IMDG, IATA not regulated
· Environmental hazards: Not applicable.
· Special precautions for user Warning: Gases.
· Hazard identification number (Kemler code): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· Transport in bulk according to Annex II of Marpol
and the IBC Code Not applicable.
· Transport/Additional information:
· ADG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
(Contd. on page 8)
AU

55.0.4
Page 8/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 7)

· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.2

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Australian Inventory of Industrial Chemicals
All ingredients are listed.
· Standard for the Uniform Scheduling of Medicines and Poisons
None of the ingredients is listed.
· Australia: Priority Existing Chemicals
None of the ingredients is listed.
· GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms

GHS01 GHS04 GHS07

· Signal word Danger


· Hazard statements
Unstable explosives.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P1a EXPLOSIVES
· Qualifying quantity (tonnes) for the application of lower-tier requirements 10 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50 t
(Contd. on page 9)
AU

55.0.4
Page 9/9
Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 8)
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact:
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosives – Unstable explosive
Press. Gas C: Gases under pressure – Compressed gas
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
AU

55.0.4
Page 1/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Information department: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

2 Hazard identification
· Classification of the substance or mixture

GHS04 Gas cylinder

Gases Under Pressure - Compressed Gas H280 Contains gas under pressure; may explode if heated.

GHS07

Eye Irritation - Category 2A H319 Causes serious eye irritation.


· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS04 GHS07

· Signal word Warning


· Hazard statements
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
· Precautionary statements
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Protect from sunlight. Store in a well-ventilated place.
(Contd. on page 2)
CA

55.0.4
Page 2/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 1)
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 4 Reactivity = 4

· HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
FIRE 4 Fire = 4
REACTIVITY 4 Reactivity = 4

3 Composition/Information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
67-63-0 propan-2-ol 10-30% w/w *
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro 1-5% w/w *
* Actual concentration ranges are withheld as a trade secret.

4 First-aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
CA
(Contd. on page 3)

55.0.4
Page 3/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 2)

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about protection against explosions and fires:
Protect from heat.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
· Specific end use(s) No further relevant information available.

8 Exposure controls/ Personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
67-63-0 propan-2-ol
EL STEL: 400 ppm
TWA: 200 ppm
EV STEL: 400 ppm
TWA: 200 ppm
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
(Contd. on page 4)
CA

55.0.4
Page 4/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 3)
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Color: White
· Odor: Ether-like
· Odor threshold: Not determined.
· pH-value at 20 °C: 7
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 82 °C
· Flash point: 12 °C
· Flammability (solid, gaseous): Not flammable.
· Ignition temperature: 425 °C
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Explosive with or without contact with air.
· Explosion limits:
Lower: 2 Vol %
Upper: 12 Vol %
· Vapor pressure at 25 °C: 5,515.8 hPa
· Density at 20 °C: 1.25 g/cm³
(Contd. on page 5)
CA

55.0.4
Page 5/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 4)

· Relative density Not determined.


· Vapor density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 15.3 %
Solids content: 0.0 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
67-63-0 propan-2-ol 3
(Contd. on page 6)
CA

55.0.4
Page 6/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 5)
· NTP (National Toxicology Program)
None of the ingredients is listed.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT/TDG, ADR, IMDG, IATA UN1950
· UN proper shipping name
· DOT/TDG Aerosols, flammable
· ADR 1950 Aerosols
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· Transport hazard class(es)
· DOT/TDG (Transport dangerous goods):

· Class 2.2 Gases


(Contd. on page 7)
CA

55.0.4
Page 7/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 6)

· Label 2.2
· ADR

· Class 2 5F Gases
· Label 2.2
· IMDG, IATA

· Class 2.2 Gases


· Label 2.2
· Packing group
· DOT/TDG, ADR, IMDG, IATA Void
· Environmental hazards: Not applicable.
· Special precautions for user Warning: Gases
· Hazard identification number (Kemler code): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of living
quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1 except
for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT/TDG
· Quantity limitations On passenger aircraft/rail: 75 kg
On cargo aircraft only: 150 kg
· ADR
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
(Contd. on page 8)
CA

55.0.4
Page 8/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 7)

· UN "Model Regulation": UN 1950 AEROSOLS, 2.2

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
67-63-0 propan-2-ol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Canadian substance listings:
· Canadian Domestic Substances List (DSL)
All ingredients are listed.
· Canadian Non-Domestic Substances List (NDSL)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%)
67-63-0 propan-2-ol
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS04 GHS07

· Signal word Warning


· Hazard statements
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
· Precautionary statements
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Protect from sunlight. Store in a well-ventilated place.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
(Contd. on page 9)
CA

55.0.4
Page 9/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022

Trade name: TEFLON SPRAY

(Contd. of page 8)

· Contact:
· Date of the latest revision of the safety data sheet 08/12/2022 / -
· Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
CA

55.0.4
Page 1/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

SECTION 1: Identification of the substance/mixture and of the company/undertaking


· 1.1 Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Laboratory chemicals
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Further information obtainable from: Product safety department
· 1.4 Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

SECTION 2: Hazards identification


· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

exploding bomb

Unst. Expl. H200 Unstable explosives.

Eye Irrit. 2 H319 Causes serious eye irritation.


Aerosol 3 H229 Pressurised container: May burst if heated.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the GB CLP regulation.
· Hazard pictograms

GHS01 GHS07

· Signal word Danger


· Hazard statements
H200 Unstable explosives.
H229 Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
(Contd. on page 2)
GB

55.0.4
Page 2/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 1)
· Precautionary statements
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P373 DO NOT fight fire when fire reaches explosives.
P380 Evacuate area.
P401 Store in accordance with local/regional/national/international regulations.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

SECTION 3: Composition/information on ingredients


· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
EINECS: 212-377-0 substance with a Community workplace exposure limit
CAS: 67-63-0 propan-2-ol >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures


· 4.1 Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures


· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture No further relevant information available.
(Contd. on page 3)
GB

55.0.4
Page 3/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 2)
· 5.3 Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

SECTION 6: Accidental release measures


· 6.1 Personal precautions, protective equipment and emergency procedures Not required.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage


· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Protect from heat.
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray onto a naked flame or any incandescent material.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection


· 8.1 Control parameters
· Additional information about design of technical facilities: No further data; see item 7.
· Ingredients with limit values that require monitoring at the workplace:
811-97-2 1,1,1,2-tetrafluoroethane
WEL Long-term value: 4240 mg/m³, 1000 ppm
67-63-0 propan-2-ol
WEL Short-term value: 1250 mg/m³, 500 ppm
Long-term value: 999 mg/m³, 400 ppm
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
(Contd. on page 4)
GB

55.0.4
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 3)
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

Tightly sealed goggles

SECTION 9: Physical and chemical properties


· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: White
· Odour: Ether-like
· Odour threshold: Not determined.
· pH-value at 20 °C: 7
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 82 °C
· Flash point: 12 °C
· Flammability (solid, gas): Not applicable.
· Ignition temperature: 425 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Explosive with or without contact with air.
· Explosion limits:
Lower: 2 Vol %
Upper: 12 Vol %
(Contd. on page 5)
GB

55.0.4
Page 5/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 4)

· Vapour pressure at 25 °C: 5,515.8 hPa


· Density at 20 °C: 1.25 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 15.3 %
VOC (EC) 96.94 %
Solids content: 0.0 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity


· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information


· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· Additional toxicological information:
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
(Contd. on page 6)
GB

55.0.4
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 5)
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information


· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations


· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information


· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR

· Class 2 5F Gases.
(Contd. on page 7)
GB

55.0.4
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 6)

· Label 2.2
· IMDG, IATA

· Class 2.2 Gases.


· Label 2.2
· 14.4 Packing group
· ADR, IMDG, IATA not regulated
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Gases.
· Hazard identification number (Kemler code): -
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.2

SECTION 15: Regulatory information


· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso category P1a EXPLOSIVES
(Contd. on page 8)
GB

55.0.4
Page 8/8
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022

Trade name: TEFLON SPRAY

(Contd. of page 7)
· Qualifying quantity (tonnes) for the application of lower-tier requirements 10 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50 t
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information


This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosives – Unstable explosive
Aerosol 3: Aerosols – Category 3
Flam. Liq. 2: Flammable liquids – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
GB

55.0.4
Bladzijde: 1/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

RUBRIEK 1: Identificatie van de stof of het mengsel en van de vennootschap/onderneming


· 1.1 Productidentificatie
· Handelsnaam: TEFLON SPRAY
· Artikelnummer: 72619
· UFI: D941-60F6-W00Y-QC3W
· 1.2 Relevant geïdentificeerd gebruik van de stof of het mengsel en ontraden gebruik
Geen verdere relevante informatie verkrijgbaar.
· Toepassing van de stof / van de bereiding Laboratoriumchemcaliën
· 1.3 Details betreffende de verstrekker van het veiligheidsinformatieblad
· Fabrikant/leverancier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Aurion
Binnenhaven 5
6709 PD Wageningen
The Netherlands
Tel: 31 317 415094
Fax: 31 317 415955
email: [email protected]
· Inlichtingengevende sector: Product safety department
· 1.4 Telefoonnummer voor noodgevallen:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

RUBRIEK 2: Identificatie van de gevaren


· 2.1 Indeling van de stof of het mengsel
· Indeling overeenkomstig Verordening (EG) nr. 1272/2008

GHS01 ontploffende bom

Unst. Expl. H200 Instabiele ontplofbare stof.

GHS07

Eye Irrit. 2 H319 Veroorzaakt ernstige oogirritatie.


Aerosol 3 H229 Houder onder druk: kan open barsten bij verhitting.
· 2.2 Etiketteringselementen
· Etikettering overeenkomstig Verordening (EG) nr. 1272/2008
Het product is geclassificeerd en geëtiketteerd volgens de CLP-verordening.
(Vervolg op blz. 2)
NL

55.0.4
Bladzijde: 2/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 1)


· Gevarenpictogrammen

GHS01 GHS07

· Signaalwoord Gevaar
· Gevarenaanduidingen
H200 Instabiele ontplofbare stof.
H229 Houder onder druk: kan open barsten bij verhitting.
H319 Veroorzaakt ernstige oogirritatie.
· Veiligheidsaanbevelingen
P305+P351+P338 BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal
minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
P373 NIET blussen wanneer het vuur de ontplofbare stoffen bereikt.
P380 Evacueren.
P401 Opslaan volgens de plaatselijke/regionale/nationale/internationale voorschriften.
P410+P412 Tegen zonlicht beschermen. Niet blootstellen aan temperaturen boven 50 °C/122 °F.
P501 De inhoud en de verpakking verwerken volgens de plaatselijke/regionale/nationale/
internationale voorschriften.
· 2.3 Andere gevaren
· Resultaten van PBT- en zPzB-beoordeling
· PBT: Niet bruikbaar.
· zPzB: Niet bruikbaar.

RUBRIEK 3: Samenstelling en informatie over de bestanddelen


· 3.2 Chemische karakterisering: Mengsels
· Beschrijving: Mengsel van na elkaar aangevoerde stoffen met ongevaarlijke bijmengingen.
· Gevaarlijke inhoudstoffen:
CAS: 67-63-0 2-propanol >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Aanvullende gegevens:
De woordelijke inhoud van de opgegeven aanwijzingen inzake de mogelijke gevaren is te vinden in hoofdstuk 16.

RUBRIEK 4: Eerstehulpmaatregelen
· 4.1 Beschrijving van de eerstehulpmaatregelen
· Algemene informatie:
Het is mogelijk dat vergiftigingssymptomen pas na vele uren optreden. Om deze reden is medische controle
gedurende minstens 48 uur na een ongeval noodzakelijk.
· Na het inademen:
Frisse lucht toedienen, eventueel beademing, warmte. Wanneer de klachten niet ophouden, een arts raadplegen.
Bij bewusteloosheid ligging en vervoer in stabiele zijligging.
· Na huidcontact: Over het algemeen is het produkt niet prikkelend voor de huid
· Na oogcontact:
De ogen gedurende verscheidene minuten onder stromend water afspoelen terwijl de oogspleet geopend blijft. Bij
aanhoudende klachten een dokter raadplegen.
· Na inslikken: Als de klachten niet minderen, een arts raadplegen
· 4.2 Belangrijkste acute en uitgestelde symptomen en effecten Geen verdere relevante informatie verkrijgbaar.
(Vervolg op blz. 3)
NL

55.0.4
Bladzijde: 3/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 2)


· 4.3 Vermelding van de vereiste onmiddellijke medische verzorging en speciale behandeling
Geen verdere relevante informatie verkrijgbaar.

RUBRIEK 5: Brandbestrijdingsmaatregelen
· 5.1 Blusmiddelen
· Geschikte blusmiddelen:
CO2, bluspoeder of waterstraal. Grotere brand met waterstraal bestrijden of met schuim, dat tegen alcohol
bestand is.
· 5.2 Speciale gevaren die door de stof of het mengsel worden veroorzaakt
Geen verdere relevante informatie verkrijgbaar.
· 5.3 Advies voor brandweerlieden
· Speciale beschermende kleding: Ademhalingstoestel aantrekken.

RUBRIEK 6: Maatregelen bij het accidenteel vrijkomen van de stof of het mengsel
· 6.1 Persoonlijke voorzorgsmaatregelen, beschermingsmiddelen en noodprocedures Niet nodig.
· 6.2 Milieuvoorzorgsmaatregelen: Niet in de riolering/het oppervlaktewater/het grondwater laten terechtkomen.
· 6.3 Insluitings- en reinigingsmethoden en -materiaal:
Besmet materiaal zoals afval volgens punt 13 verwijderen.
Voor voldoende ventilatie zorgen.
· 6.4 Verwijzing naar andere rubrieken
Informatie inzake veilig gebruik - zie hoofdstuk 7.
Informatie inzake persoonlijke beschermingsuitrusting - zie hoofdstuk 8.
Informatie inzake berging - zie hoofdstuk 13.

RUBRIEK 7: Hantering en opslag


· 7.1 Voorzorgsmaatregelen voor het veilig hanteren van de stof of het mengsel
Voor goede ventilatie/afzuiging op de werkplaatsen zorgen.
· Informatie m.b.t. brand- en ontploffingsgevaar:
Beschermen tegen hitte.
Houder onder druk. Beschermen tegen de zon en niet blootstellen aan een hogere temperatuur dan 50°C, bijv.
door gloeilampen. Ook na gebruik niet doorboren of verbranden.
Nietspuiten in de richting van een vlam of een gloeiend voorwerp.
· 7.2 Voorwaarden voor een veilige opslag, met inbegrip van incompatibele producten
· Opslag:
· Eisen ten opzichte van opslagruimte en tanks:
De overheidsbepalingen m.b.t. de opslag van drukgaspakkingen moeten in acht genomen worden.
· Informatie m.b.t. gezamenlijke opslag: Niet noodzakelijk.
· Verdere inlichtingen over eisen m.b.t. de opslag:
Tanks ondoordringbaar gesloten houden.
Tegen hitte en directe zonnestralen beschermen.
· 7.3 Specifiek eindgebruik Geen verdere relevante informatie verkrijgbaar.

RUBRIEK 8: Maatregelen ter beheersing van blootstelling/persoonlijke bescherming


· 8.1 Controleparameters
· Aanvullende gegevens m.b.t. de inrichting van technische installaties: Geen aanvullende gegevens. Zie 7.
(Vervolg op blz. 4)
NL

55.0.4
Bladzijde: 4/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 3)


· Bestanddelen met grenswaarden die m.b.t. de werkruimte in acht genomen moeten worden:
Het produkt bevat geen relevante hoeveelheden van stoffen, die met betrekking tot de werkplaatsen, qua
grenswaarden gecontroleerd moeten worden.
· Aanvullende gegevens: Als basis dienden lijsten die bij opstelling geldig waren.
· 8.2 Maatregelen ter beheersing van blootstelling
· Persoonlijke beschermingsvoorzieningen:
· Algemene beschermings- en gezondheidsmaatregelen:
Verwijderd houden van eet- en drinkwaren.
Verontreinigde kleding onmiddellijk uittrekken.
Vóór de pauze en aan het einde van werktijd handen wassen.
Aanraking met de ogen vermijden.
Aanraking met de ogen en de huid vermijden.
· Ademhalingsbescherming:
Bij korte of geringe belasting ademfiltertoestel; bij intensieve resp. langdurige expositie een van de omringende
lucht onafhankelijk ademhalingstoestel gebruiken.
· Handbescherming:
Het handschoenmateriaal moet ondoorlatend en bestand zijn tegen het product / de stof / de bereiding.
Op grond van falende testen kan geen aanbeveling voor handschoenmateriaal voor het product / de bereiding /
het chemicaliënmengsel afgegeven worden.
Kies handschoenmateriaal rekening houdend met de penetratietijden, de permeatiegraden en de degradatie.
· Handschoenmateriaal
De keuze van een geschikte handschoen is niet alleen afhankelijk van het materiaal, maar ook van andere
kwaliteitskenmerken en verschilt van fabrikant tot fabrikant. Aangezien het product uit meerdere stoffen is
samengesteld, is de duurzaamheid van de handschoenmaterialen niet vooraf berekenbaar en moet derhalve vóór
het gebruik worden getest.
· Doordringingstijd van het handschoenmateriaal
De precieze penetratietijd kunt u te weten komen bij de handschoenfabrikant; houd er rekening mee.
· Oogbescherming:

Nauw aansluitende veiligheidsbril

RUBRIEK 9: Fysische en chemische eigenschappen


· 9.1 Informatie over fysische en chemische basiseigenschappen
· Algemene gegevens
· Voorkomen:
Vorm: Aërosol
Kleur: Wit
· Geur: Etherachtig
· Geurdrempelwaarde: Niet bepaald.
· pH-waarde bij 20 °C: 7
· Toestandsverandering
Smelt-/vriespunt: Niet bepaald.
Beginkookpunt en kooktraject: 82 °C
· Vlampunt: 12 °C
· Ontvlambaarheid (vast, gas): Niet bruikbaar.
(Vervolg op blz. 5)
NL

55.0.4
Bladzijde: 5/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 4)

· Ontstekingstemperatuur: 425 °C
· Ontledingstemperatuur: Niet bepaald.
· Zelfontbrandingstemperatuur: Het produkt ontbrandt niet uit zichzelf.
· Ontploffingseigenschappen: Ontplofbaar met en zonder lucht.
· Ontploffingsgrenzen:
Onderste: 2 Vol %
Bovenste: 12 Vol %
· Dampspanning bij 25 °C: 5.515,8 hPa
· Dichtheid bij 20 °C: 1,25 g/cm³
· Relatieve dichtheid Niet bepaald.
· Dampdichtheid Niet bepaald.
· Verdampingssnelheid Niet bruikbaar.
· Oplosbaarheid in/mengbaarheid met
Water: Niet resp. gering mengbaar.
· Verdelingscoëfficiënt: n-octanol/water: Niet bepaald.
· Viscositeit
Dynamisch: Niet bepaald.
Kinematisch: Niet bepaald.
· Oplosmiddelgehalte:
Organisch oplosmiddel: 15,3 %
VOC (EG) 96,94 %
Gehalte aan vaste bestanddelen: 0,0 %
· 9.2 Overige informatie Geen verdere relevante informatie verkrijgbaar.

RUBRIEK 10: Stabiliteit en reactiviteit


· 10.1 Reactiviteit Geen verdere relevante informatie verkrijgbaar.
· 10.2 Chemische stabiliteit
· Thermische afbraak / te vermijden omstandigheden: Geen afbraak bij gebruik volgens voorschrift.
· 10.3 Mogelijke gevaarlijke reacties Geen gevaarlijke reacties bekend.
· 10.4 Te vermijden omstandigheden Geen verdere relevante informatie verkrijgbaar.
· 10.5 Chemisch op elkaar inwerkende materialen: Geen verdere relevante informatie verkrijgbaar.
· 10.6 Gevaarlijke ontledingsproducten: Geen gevaarlijke ontbindingsprodukten bekend.

RUBRIEK 11: Toxicologische informatie


· 11.1 Informatie over toxicologische effecten
· Acute toxiciteit Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Indelingsrelevantie LD/LC50-waarden:
67-63-0 2-propanol
Oraal LD50 5.045 mg/kg (rat)
Dermaal LD50 12.800 mg/kg (rabbit)
Inhalatief LC50/4 h 30 mg/l (rat)
(Vervolg op blz. 6)
NL

55.0.4
Bladzijde: 6/9
Veiligheidsinformatieblad
volgens 1907/2006/EG, Artikel 31
datum van de druk: 12.08.2022 Herziening van: 12.08.2022

Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 5)


· Primaire aandoening:
· Huidcorrosie/-irritatie Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Ernstig oogletsel/oogirritatie
Veroorzaakt ernstige oogirritatie.
· Sensibilisatie van de luchtwegen/de huid
Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Aanvullende toxicologische informatie:
· CMR-effecten (kankerverwekkendheid, mutageniteit en giftigheid voor de voortplanting)
· Mutageniteit in geslachtscellen Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Kankerverwekkendheid Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Giftigheid voor de voortplanting Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· STOT bij eenmalige blootstelling Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· STOT bij herhaalde blootstelling Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.
· Gevaar bij inademing Gebaseerd op beschikbare gegevens; aan de indelingscriteria is niet voldaan.

RUBRIEK 12: Ecologische informatie


· 12.1 Toxiciteit
· Aquatische toxiciteit: Geen verdere relevante informatie verkrijgbaar.
· 12.2 Persistentie en afbreekbaarheid Geen verdere relevante informatie verkrijgbaar.
· 12.3 Bioaccumulatie Geen verdere relevante informatie verkrijgbaar.
· 12.4 Mobiliteit in de bodem Geen verdere relevante informatie verkrijgbaar.
· Verdere ecologische informatie:
· Algemene informatie:
Waterbezwaarlijkheid (NL): B(4) Weinig schadelijk voor in water levende organismen
Gevaar voor water klasse 1 (D) (Zelfclassificatie): gevaar voor water klein
Niet onverdund of in grote hoeveelheden lozen in grondwater, in oppervlaktewater of in de riolering.
· 12.5 Resultaten van PBT- en zPzB-beoordeling
· PBT: Niet bruikbaar.
· zPzB: Niet bruikbaar.
· 12.6 Andere schadelijke effecten Geen verdere relevante informatie verkrijgbaar.

RUBRIEK 13: Instructies voor verwijdering


· 13.1 Afvalverwerkingsmethoden
· Aanbeveling: Mag niet tesamen met huisvuil gestort worden of in de riolering terechtkomen.
· Niet gereinigde verpakkingen:
· Aanbeveling: Afvalverwijdering volgens overheidsbepalingen.

RUBRIEK 14: Informatie met betrekking tot het vervoer


· 14.1 VN-nummer
· ADR, IMDG, IATA UN1950
· 14.2 Juiste ladingnaam overeenkomstig de modelreglementen van de VN
· ADR 1950 SPUITBUSSEN
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
(Vervolg op blz. 7)
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(Vervolg van blz. 6)

· 14.3 Transportgevarenklasse(n)
· ADR

· klasse 2 5F Gassen
· Etiket 2.2
· IMDG, IATA

· Class 2.2 Gassen


· Label 2.2
· 14.4 Verpakkingsgroep:
· ADR, IMDG, IATA Niet van toepassing
· 14.5 Milieugevaren: Niet bruikbaar.
· 14.6 Bijzondere voorzorgen voor de gebruiker Waarschuwing: Gassen
· Gevaarsidentificatienummer (Kemler-getal): -
· EMS-nummer: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· 14.7 Vervoer in bulk overeenkomstig bijlage II bij
Marpol en de IBC-code Niet bruikbaar.
· Transport/verdere gegevens:
· ADR
· Beperkte hoeveelheden (LQ) 1L
· Uitgezonderde hoeveelheden (EQ) Code: E0
Niet toegestaan als vrijgestelde hoeveelheid
· Vervoerscategorie 2
· Tunnelbeperkingscode D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
(Vervolg op blz. 8)
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(Vervolg van blz. 7)

· VN "Model Regulation": UN 1950 SPUITBUSSEN, 2.2

RUBRIEK 15: Regelgeving


· 15.1 Specifieke veiligheids-, gezondheids- en milieureglementen en -wetgeving voor de stof of het mengsel
· SZW-lijst van kankerverwekkende stoffen
geen der bestanddelen staat op de lijst.
· SZW-lijst van mutagene stoffen
geen der bestanddelen staat op de lijst.
· NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Vruchtbaarheid
geen der bestanddelen staat op de lijst.
· NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Ontwikkeling
geen der bestanddelen staat op de lijst.
· NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Borstvoeding
geen der bestanddelen staat op de lijst.
· Lijst Zeer Zorgwekkende Stoffen (ZZS)
geen der bestanddelen staat op de lijst.
· Lijst van Potentieel Zeer Zorgwekkende Stoffen
geen der bestanddelen staat op de lijst.
· Richtlijn 2012/18/EU
· Gevaarlijke stoffen die met naam genoemd worden - BIJLAGE I geen der bestanddelen staat op de lijst.
· Seveso-categorie P1a ONTPLOFBARE STOFFEN
· Drempelwaarde (ton) voor toepassing van voorschriften voor lagedrempelinrichtingen 10 t
· Drempelwaarde (ton) voor toepassing van voorschriften voor hogedrempelinrichtingen 50 t
· Verordening (EG) nr. 1907/2006 BIJLAGE XVII Beperkingsvoorwaarden: 3
· Richtlijn 2011/65/EU betreffende beperking van het gebruik van bepaalde gevaarlijke stoffen in elektrische en
elektronische apparatuur - Bijlage II
geen der bestanddelen staat op de lijst.
· VERORDENING (EU) 2019/1148
· Bijlage I - PRECURSOREN VOOR EXPLOSIEVEN WAARVOOR EEN BEPERKING GELDT
(Bovengrenswaarde ten behoeve van vergunningverlening op grond van artikel 5, lid 3)
geen der bestanddelen staat op de lijst.
· Bijlage II - PRECURSOREN VOOR EXPLOSIEVEN DIE MOETEN WORDEN GEMELD
geen der bestanddelen staat op de lijst.
· Verordening (EG) nr. 273/2004 inzake drugsprecursoren
geen der bestanddelen staat op de lijst.
· Verordening (EG) Nr. 111/2005 houdende voorschriften voor het toezicht op de handel tussen de Gemeenschap
en derde landen in drugsprecursoren
geen der bestanddelen staat op de lijst.
· Nationale voorschriften:
· Gevaarklasse v. water: Waterbezwaarlijkheid (NL): B(4) Weinig schadelijk voor in water levende organismen
(Vervolg op blz. 9)
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Handelsnaam: TEFLON SPRAY

(Vervolg van blz. 8)


· 15.2 Chemischeveiligheidsbeoordeling: Een chemische veiligheidsbeoordeling is niet uitgevoerd.

RUBRIEK 16: Overige informatie


Deze gegevens zijn gebaseerd op de huidige stand van onze kennis. Zij beschrijven echter geen garantie van
produkteigenschappen en vestigen geen contractuele rechtsbetrekking.
· Relevante zinnen
H225 Licht ontvlambare vloeistof en damp.
H319 Veroorzaakt ernstige oogirritatie.
H336 Kan slaperigheid of duizeligheid veroorzaken.
· Afkortingen en acroniemen:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Ontplofbare stoffen – Instabiele ontplofbare stof
Aerosol 3: Aerosolen – Categorie 3
Flam. Liq. 2: Ontvlambare vloeistoffen – Categorie 2
Eye Irrit. 2: Ernstig oogletsel/oogirritatie – Categorie 2
STOT SE 3: Specifieke doelorgaantoxiciteit bij eenmalige blootstelling – Categorie 3
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RUBRIQUE 1: Identification de la substance/du mélange et de la société/l’entreprise


· 1.1 Identificateur de produit
· Nom du produit: TEFLON SPRAY
· Code du produit: 72619
· UFI: D941-60F6-W00Y-QC3W
· 1.2 Utilisations identifiées pertinentes de la substance ou du mélange et utilisations déconseillées
Pas d'autres informations importantes disponibles.
· Emploi de la substance / de la préparation Produits chimiques pour laboratoires
· 1.3 Renseignements concernant le fournisseur de la fiche de données de sécurité
· Producteur/fournisseur:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Service chargé des renseignements: Product safety department
· 1.4 Numéro d'appel d'urgence:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

RUBRIQUE 2: Identification des dangers


· 2.1 Classification de la substance ou du mélange
· Classification selon le règlement (CE) n° 1272/2008

GHS01 bombe explosant

Unst. Expl. H200 Explosif instable.

GHS07

Eye Irrit. 2 H319 Provoque une sévère irritation des yeux.


Aerosol 3 H229 Récipient sous pression: peut éclater sous l’effet de la chaleur.
· 2.2 Éléments d'étiquetage
· Etiquetage selon le règlement (CE) n° 1272/2008 Le produit est classifié et étiqueté selon le règlement CLP.
· Pictogrammes de danger

GHS01 GHS07

· Mention d'avertissement Danger


· Mentions de danger
H200 Explosif instable.
H229 Récipient sous pression: peut éclater sous l’effet de la chaleur.
H319 Provoque une sévère irritation des yeux.
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(suite de la page 1)
· Conseils de prudence
P305+P351+P338 EN CAS DE CONTACT AVEC LES YEUX: Rincer avec précaution à l'eau pendant plusieurs
minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être
facilement enlevées. Continuer à rincer.
P373 NE PAS combattre l'incendie lorsque le feu atteint les explosifs.
P380 Évacuer la zone.
P401 Stocker conformément à la réglementation locale/régionale/nationale/internationale.
P410+P412 Protéger du rayonnement solaire. Ne pas exposer à une température supérieure à 50 °C/122
°F.
P501 Éliminer le contenu/récipient conformément à la réglementation locale/régionale/nationale/
internationale.
· 2.3 Autres dangers
· Résultats des évaluations PBT et vPvB
· PBT: Non applicable.
· vPvB: Non applicable.

RUBRIQUE 3: Composition/informations sur les composants


· 3.2 Caractérisation chimique: Mélanges
· Description: Mélange des substances mentionnées à la suite avec des additifs non dangereux.
· Composants dangereux:
CAS: 67-63-0 propane-2-ol >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Indications complémentaires: Pour le libellé des phrases de risque citées, se référer au chapitre 16.

RUBRIQUE 4: Premiers secours


· 4.1 Description des premiers secours
· Remarques générales:
Les symptômes d'intoxication peuvent apparaître après de nombreuses heures seulement; une surveillance
médicale est donc nécessaire au moins 48 heures après un accident.
· Après inhalation:
Donner de l'air frais. Assistance respiratoire si nécessaire. Tenir le malade au chaud. Si les troubles persistent,
consulter un médecin.
En cas d'inconscience, coucher et transporter la personne en position latérale stable.
· Après contact avec la peau: En règle générale, le produit n'irrite pas la peau.
· Après contact avec les yeux:
Rincer les yeux, pendant plusieurs minutes, sous l'eau courante en écartant bien les paupières. Si les troubles
persistent, consulter un médecin.
· Après ingestion: Si les troubles persistent, consulter un médecin.
· 4.2 Principaux symptômes et effets, aigus et différés Pas d'autres informations importantes disponibles.
· 4.3 Indication des éventuels soins médicaux immédiats et traitements particuliers nécessaires
Pas d'autres informations importantes disponibles.

RUBRIQUE 5: Mesures de lutte contre l’incendie


· 5.1 Moyens d'extinction
· Moyens d'extinction:
CO2, poudre d'extinction ou eau pulvérisée. Combattre les foyers importants avec de l'eau pulvérisée ou de la
mousse résistant à l'alcool.
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(suite de la page 2)
· 5.2 Dangers particuliers résultant de la substance ou du mélange
Pas d'autres informations importantes disponibles.
· 5.3 Conseils aux pompiers
· Equipement spécial de sécurité: Porter un appareil de protection respiratoire.

RUBRIQUE 6: Mesures à prendre en cas de dispersion accidentelle


· 6.1 Précautions individuelles, équipement de protection et procédures d'urgence Pas nécessaire.
· 6.2 Précautions pour la protection de l'environnement:
Ne pas rejeter dans les canalisations, dans les eaux de surface et dans les nappes d'eau souterraines.
· 6.3 Méthodes et matériel de confinement et de nettoyage:
Evacuer les matériaux contaminés en tant que déchets conformément au point 13.
Assurer une aération suffisante.
· 6.4 Référence à d'autres rubriques
Afin d'obtenir des informations pour une manipulation sûre, consulter le chapitre 7.
Afin d'obtenir des informations sur les équipements de protection personnels, consulter le chapitre 8.
Afin d'obtenir des informations sur l'élimination, consulter le chapitre 13.

RUBRIQUE 7: Manipulation et stockage


· 7.1 Précautions à prendre pour une manipulation sans danger
Veiller à une bonne ventilation/aspiration du poste de travail.
· Préventions des incendies et des explosions:
Tenir à l'abri de la chaleur.
Récipient sous pression: A protéger contre les rayons solaires et à ne pas exposer à une température supérieure à
50°C (par exemple, aux lampes à incandescence). Ne pas percer ou brûler, même après usage.
Ne pas vaporiser vers une flamme ou un corps incandescent.
· 7.2 Conditions d'un stockage sûr, y compris d'éventuelles incompatibilités
· Stockage:
· Exigences concernant les lieux et conteneurs de stockage:
Respecter les prescriptions légales pour le stockage des emballages sous pression.
· Indications concernant le stockage commun: Pas nécessaire.
· Autres indications sur les conditions de stockage:
Tenir les emballages hermétiquement fermés.
Protéger de la forte chaleur et du rayonnement direct du soleil.
· 7.3 Utilisation(s) finale(s) particulière(s) Pas d'autres informations importantes disponibles.

RUBRIQUE 8: Contrôles de l’exposition/protection individuelle


· 8.1 Paramètres de contrôle
· Indications complémentaires pour l'agencement des installations techniques:
Sans autre indication, voir point 7.
· Composants présentant des valeurs-seuil à surveiller par poste de travail:
67-63-0 propane-2-ol
VLEP Valeur momentanée: 980 mg/m³, 400 ppm
· Remarques supplémentaires:
Le présent document s'appuie sur les listes en vigueur au moment de son élaboration.
(suite page 4)
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(suite de la page 3)

· 8.2 Contrôles de l'exposition


· Equipement de protection individuel:
· Mesures générales de protection et d'hygiène:
Tenir à l'écart des produits alimentaires, des boissons et de la nourriture pour animaux.
Retirer immédiatement les vêtements souillés ou humectés.
Se laver les mains avant les pauses et en fin de travail.
Eviter tout contact avec les yeux.
Eviter tout contact avec les yeux et avec la peau.
· Protection respiratoire:
En cas d'exposition faible ou de courte durée, utiliser un filtre respiratoire; en cas d'exposition intense ou
durable, utiliser un appareil de respiration indépendant de l'air ambiant.
· Protection des mains:
Le matériau des gants doit être imperméable et résistant au produit / à la substance / à la préparation.
À cause du manque de tests, aucune recommandation pour un matériau de gants pour le produit / la préparation /
le mélange de produits chimiques ne peut être donnée.
Choix du matériau des gants en fonction des temps de pénétration, du taux de perméabilité et de la dégradation.
· Matériau des gants
Le choix de gants appropriés dépend non seulement du matériau, mais aussi d'autres critères de qualité qui
peuvent varier d'un fabricant à l'autre. Puisque le produit représente une préparation composée de plusieurs
substances, la résistance des matériaux des gants ne peut pas être calculée à l'avance et doit, alors, être contrôlée
avant l'utilisation.
· Temps de pénétration du matériau des gants
Le temps de pénétration exact est à déterminer par le fabricant des gants de protection et à respecter.
· Protection des yeux:

Lunettes de protection hermétiques

RUBRIQUE 9: Propriétés physiques et chimiques


· 9.1 Informations sur les propriétés physiques et chimiques essentielles
· Indications générales
· Aspect:
Forme: Aérosol
Couleur: Blanc
· Odeur: Genre éther
· Seuil olfactif: Non déterminé.
· valeur du pH à 20 °C: 7
· Changement d'état
Point de fusion/point de congélation: Non déterminé.
Point initial d'ébullition et intervalle d'ébullition: 82 °C
· Point d'éclair 12 °C
· Inflammabilité (solide, gaz): Non applicable.
· Température d'inflammation: 425 °C
· Température de décomposition: Non déterminé.
· Température d'auto-inflammabilité: Le produit ne s'enflamme pas spontanément.
(suite page 5)
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(suite de la page 4)

· Propriétés explosives: Danger d'explosion en contact ou sans contact avec l'air.


· Limites d'explosion:
Inférieure: 2 Vol %
Supérieure: 12 Vol %
· Pression de vapeur à 25 °C: 5.515,8 hPa
· Densité à 20 °C: 1,25 g/cm³
· Densité relative Non déterminé.
· Densité de vapeur: Non déterminé.
· Taux d'évaporation: Non applicable.
· Solubilité dans/miscibilité avec
l'eau: Pas ou peu miscible
· Coefficient de partage: n-octanol/eau: Non déterminé.
· Viscosité:
Dynamique: Non déterminé.
Cinématique: Non déterminé.
· Teneur en solvants:
Solvants organiques: 15,3 %
VOC (CE) 96,94 %
Teneur en substances solides: 0,0 %
· 9.2 Autres informations Pas d'autres informations importantes disponibles.

RUBRIQUE 10: Stabilité et réactivité


· 10.1 Réactivité Pas d'autres informations importantes disponibles.
· 10.2 Stabilité chimique
· Décomposition thermique/conditions à éviter: Pas de décomposition en cas d'usage conforme.
· 10.3 Possibilité de réactions dangereuses Aucune réaction dangereuse connue.
· 10.4 Conditions à éviter Pas d'autres informations importantes disponibles.
· 10.5 Matières incompatibles: Pas d'autres informations importantes disponibles.
· 10.6 Produits de décomposition dangereux: Pas de produits de décomposition dangereux connus

RUBRIQUE 11: Informations toxicologiques


· 11.1 Informations sur les effets toxicologiques
· Toxicité aiguë Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Valeurs LD/LC50 déterminantes pour la classification:
67-63-0 propane-2-ol
Oral LD50 5.045 mg/kg (rat)
Dermique LD50 12.800 mg/kg (lapin)
Inhalatoire LC50/4 h 30 mg/l (rat)
· Effet primaire d'irritation:
· Corrosion cutanée/irritation cutanée
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Lésions oculaires graves/irritation oculaire
Provoque une sévère irritation des yeux.
(suite page 6)
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(suite de la page 5)
· Sensibilisation respiratoire ou cutanée
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Indications toxicologiques complémentaires:
· Effets CMR (cancérogène, mutagène et toxique pour la reproduction)
· Mutagénicité sur les cellules germinales
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Cancérogénicité Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité pour la reproduction
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité spécifique pour certains organes cibles - exposition unique
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité spécifique pour certains organes cibles - exposition répétée
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Danger par aspiration Compte tenu des données disponibles, les critères de classification ne sont pas remplis.

RUBRIQUE 12: Informations écologiques


· 12.1 Toxicité
· Toxicité aquatique: Pas d'autres informations importantes disponibles.
· 12.2 Persistance et dégradabilité Pas d'autres informations importantes disponibles.
· 12.3 Potentiel de bioaccumulation Pas d'autres informations importantes disponibles.
· 12.4 Mobilité dans le sol Pas d'autres informations importantes disponibles.
· Autres indications écologiques:
· Indications générales:
Catégorie de pollution des eaux 1 (D) (Classification propre): peu polluant
Ne pas laisser le produit, non dilué ou en grande quantité, pénétrer la nappe phréatique, les eaux ou les
canalisations.
· 12.5 Résultats des évaluations PBT et VPVB
· PBT: Non applicable.
· vPvB: Non applicable.
· 12.6 Autres effets néfastes Pas d'autres informations importantes disponibles.

RUBRIQUE 13: Considérations relatives à l’élimination


· 13.1 Méthodes de traitement des déchets
· Recommandation: Ne doit pas être évacué avec les ordures ménagères. Ne pas laisser pénétrer dans les égouts.
· Emballages non nettoyés:
· Recommandation: Evacuation conformément aux prescriptions légales.

RUBRIQUE 14: Informations relatives au transport


· 14.1 Numéro ONU
· ADR, IMDG, IATA UN1950
· 14.2 Désignation officielle de transport de l'ONU
· ADR 1950 AÉROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
(suite page 7)
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Nom du produit: TEFLON SPRAY

(suite de la page 6)

· 14.3 Classe(s) de danger pour le transport


· ADR

· Classe 2 5F Gaz.
· Étiquette 2.2
· IMDG, IATA

· Class 2.2 Gaz.


· Label 2.2
· 14.4 Groupe d'emballage
· ADR, IMDG, IATA néant
· 14.5 Dangers pour l'environnement: Non applicable.
· 14.6 Précautions particulières à prendre par
l'utilisateur Attention: Gaz.
· Numéro d'identification du danger (Indice Kemler): -
· No EMS: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1
litre: Category A. For AEROSOLS with a capacity above
1 litre: Category B. For WASTE AEROSOLS: Category
C, Clear of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1
litre:
Segregation as for class 9. Stow "separated from" class
1 except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· 14.7 Transport en vrac conformément à l'annexe II de
la convention Marpol et au recueil IBC Non applicable.
· Indications complémentaires de transport:
· ADR
· Quantités limitées (LQ) 1L
· Quantités exceptées (EQ) Code: E0
Non autorisé en tant que quantité exceptée
· Catégorie de transport 2
· Code de restriction en tunnels D
· IMDG
· Limited quantities (LQ) 1L
(suite page 8)
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Nom du produit: TEFLON SPRAY

(suite de la page 7)

· Excepted quantities (EQ) Code: E0


Not permitted as Excepted Quantity
· "Règlement type" de l'ONU: UN 1950 AÉROSOLS, 2.2

RUBRIQUE 15: Informations relatives à la réglementation


· 15.1 Réglementations/législation particulières à la substance ou au mélange en matière de sécurité, de santé et
d'environnement
· Directive 2012/18/UE
· Substances dangereuses désignées - ANNEXE I Aucun des composants n’est compris.
· Catégorie SEVESO P1a EXPLOSIBLES
· Quantité seuil (tonnes) pour l'application des exigences relatives au seuil bas 10 t
· Quantité seuil (tonnes) pour l'application des exigences relatives au seuil haut 50 t
· RÈGLEMENT (CE) N° 1907/2006 ANNEXE XVII Conditions de limitation: 3
· Directive 2011/65/UE relative à la limitation de l’utilisation de certaines substances dangereuses dans les
équipements électriques et électroniques – Annexe II
Aucun des composants n’est compris.
· RÈGLEMENT (UE) 2019/1148
· Annexe I - PRÉCURSEURS D’EXPLOSIFS FAISANT L’OBJET DE RESTRICTIONS (Valeur limite
maximale aux fins de l’octroi d’une licence en vertu de l’article 5, paragraphe 3)
Aucun des composants n’est compris.
· Annexe II - PRÉCURSEURS D’EXPLOSIFS DEVANT FAIRE L’OBJET D’UN SIGNALEMENT
Aucun des composants n’est compris.
· Règlement (CE) n° 273/2004 relatif aux précurseurs de drogues
Aucun des composants n’est compris.
· Règlement (CE) n° 111/2005 fixant des règles pour la surveillance du commerce des précurseurs des drogues
entre la Communauté et les pays tiers
Aucun des composants n’est compris.
· 15.2 Évaluation de la sécurité chimique: Une évaluation de la sécurité chimique n'a pas été réalisée.

RUBRIQUE 16: Autres informations


Ces indications sont fondées sur l'état actuel de nos connaissances, mais ne constituent pas une garantie quant
aux propriétés du produit et ne donnent pas lieu à un rapport juridique contractuel.
· Phrases importantes
H225 Liquide et vapeurs très inflammables.
H319 Provoque une sévère irritation des yeux.
H336 Peut provoquer somnolence ou vertiges.
· Acronymes et abréviations:
ADR: Accord relatif au transport international des marchandises dangereuses par route
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
(suite page 9)
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(suite de la page 8)
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosibles – Explosible instable
Aerosol 3: Aérosols – Catégorie 3
Flam. Liq. 2: Liquides inflammables – Catégorie 2
Eye Irrit. 2: Lésions oculaires graves/irritation oculaire – Catégorie 2
STOT SE 3: Toxicité spécifique pour certains organes cibles (exposition unique) – Catégorie 3
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ABSCHNITT 1: Bezeichnung des Stoffs beziehungsweise des Gemischs und des


Unternehmens
· 1.1 Produktidentifikator
· Handelsname: TEFLON SPRAY
· Artikelnummer: 72619
· UFI: D941-60F6-W00Y-QC3W
· 1.2 Relevante identifizierte Verwendungen des Stoffs oder Gemischs und Verwendungen, von denen abgeraten
wird
Keine weiteren relevanten Informationen verfügbar.
· Verwendung des Stoffes / des Gemisches Laborchemikalien
· 1.3 Einzelheiten zum Lieferanten, der das Sicherheitsdatenblatt bereitstellt
· Hersteller/Lieferant:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Science Services GmbH
Unterhachinger Str. 75
81737 München Germany

Tel: +49(0)89 18 93 668-0


[email protected]

Deutschland: +49 (0)89 19240, 24h Giftnotruf Munchen, www toxinfo.org


Osterreich: +43 1406 43 43, Gesundheit Osterreich GmbH, 24 h
· Auskunftgebender Bereich: Product safety department
· 1.4 Notrufnummer:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

ABSCHNITT 2: Mögliche Gefahren


· 2.1 Einstufung des Stoffs oder Gemischs
· Einstufung gemäß Verordnung (EG) Nr. 1272/2008

GHS01 explodierende Bombe

Unst. Expl. H200 Instabil, explosiv.

GHS07

Eye Irrit. 2 H319 Verursacht schwere Augenreizung.


Aerosol 3 H229 Behälter steht unter Druck: kann bei Erwärmung bersten.
· 2.2 Kennzeichnungselemente
· Kennzeichnung gemäß Verordnung (EG) Nr. 1272/2008
Das Produkt ist gemäß CLP-Verordnung eingestuft und gekennzeichnet.
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· Gefahrenpiktogramme

GHS01 GHS07

· Signalwort Gefahr
· Gefahrenhinweise
H200 Instabil, explosiv.
H229 Behälter steht unter Druck: kann bei Erwärmung bersten.
H319 Verursacht schwere Augenreizung.
· Sicherheitshinweise
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen.
Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P373 KEINE Brandbekämpfung, wenn das Feuer explosive Stoffe/Gemische/Erzeugnisse erreicht.
P380 Umgebung räumen.
P401 Gemäß örtlicher/regionaler/nationaler/internationaler Vorschrift lagern.
P410+P412 Vor Sonnenbestrahlung schützen. Nicht Temperaturen über 50 °C/122 °F aussetzen.
P501 Entsorgung des Inhalts / des Behälters gemäß den örtlichen / regionalen / nationalen/
internationalen Vorschriften.
· 2.3 Sonstige Gefahren
· Ergebnisse der PBT- und vPvB-Beurteilung
· PBT: Nicht anwendbar.
· vPvB: Nicht anwendbar.

ABSCHNITT 3: Zusammensetzung/Angaben zu Bestandteilen


· 3.2 Chemische Charakterisierung: Gemische
· Beschreibung: Gemisch aus nachfolgend angeführten Stoffen mit ungefährlichen Beimengungen.
· Gefährliche Inhaltsstoffe:
CAS: 811-97-2 1,1,1,2-Tetrafluorethan >50-≤100%
EINECS: 212-377-0 Stoff, für den ein gemeinschaftlicher Grenzwert für die Exposition am
Arbeitsplatz gilt
CAS: 67-63-0 Propan-2-ol >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Zusätzliche Hinweise: Der Wortlaut der angeführten Gefahrenhinweise ist dem Abschnitt 16 zu entnehmen.

ABSCHNITT 4: Erste-Hilfe-Maßnahmen
· 4.1 Beschreibung der Erste-Hilfe-Maßnahmen
· Allgemeine Hinweise:
Vergiftungssymptome können erst nach vielen Stunden auftreten, deshalb ärztliche Überwachung mindestens 48
Stunden nach einem Unfall.
· Nach Einatmen:
Frischluftzufuhr, gegebenenfalls Atemspende, Wärme. Bei anhaltenden Beschwerden Arzt konsultieren.
Bei Bewusstlosigkeit Lagerung und Transport in stabiler Seitenlage.
· Nach Hautkontakt: Im allgemeinen ist das Produkt nicht hautreizend.
· Nach Augenkontakt:
Augen mehrere Minuten bei geöffnetem Lidspalt unter fließendem Wasser spülen. Bei anhaltenden Beschwerden
Arzt konsultieren.
(Fortsetzung auf Seite 3)
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· Nach Verschlucken: Bei anhaltenden Beschwerden Arzt konsultieren.
· 4.2 Wichtigste akute und verzögert auftretende Symptome und Wirkungen
Keine weiteren relevanten Informationen verfügbar.
· 4.3 Hinweise auf ärztliche Soforthilfe oder Spezialbehandlung
Keine weiteren relevanten Informationen verfügbar.

ABSCHNITT 5: Maßnahmen zur Brandbekämpfung


· 5.1 Löschmittel
· Geeignete Löschmittel:
CO2, Löschpulver oder Wassersprühstrahl. Größeren Brand mit Wassersprühstrahl oder alkoholbeständigem
Schaum bekämpfen.
· 5.2 Besondere vom Stoff oder Gemisch ausgehende Gefahren
Keine weiteren relevanten Informationen verfügbar.
· 5.3 Hinweise für die Brandbekämpfung
· Besondere Schutzausrüstung: Atemschutzgerät anlegen.

ABSCHNITT 6: Maßnahmen bei unbeabsichtigter Freisetzung


· 6.1 Personenbezogene Vorsichtsmaßnahmen, Schutzausrüstungen und in Notfällen anzuwendende Verfahren
Nicht erforderlich.
· 6.2 Umweltschutzmaßnahmen: Nicht in die Kanalisation/Oberflächenwasser/Grundwasser gelangen lassen.
· 6.3 Methoden und Material für Rückhaltung und Reinigung:
Kontaminiertes Material als Abfall nach Abschnitt 13 entsorgen.
Für ausreichende Lüftung sorgen.
· 6.4 Verweis auf andere Abschnitte
Informationen zur sicheren Handhabung siehe Abschnitt 7.
Informationen zur persönlichen Schutzausrüstung siehe Abschnitt 8.
Informationen zur Entsorgung siehe Abschnitt 13.

ABSCHNITT 7: Handhabung und Lagerung


· 7.1 Schutzmaßnahmen zur sicheren Handhabung Für gute Belüftung/Absaugung am Arbeitsplatz sorgen.
· Hinweise zum Brand- und Explosionsschutz:
Vor Hitze schützen.
Behälter steht unter Druck. Vor Sonnenbestrahlung und Temperaturen über 50°C (z.B. durch Glühlampen)
schützen. Auch nach Gebrauch nicht gewaltsam öffnen oder verbrennen.
Nicht gegen Flamme oder auf glühenden Gegenstand sprühen.
· 7.2 Bedingungen zur sicheren Lagerung unter Berücksichtigung von Unverträglichkeiten
· Lagerung:
· Anforderung an Lagerräume und Behälter:
Die behördlichen Vorschriften für das Lagern von Druckgaspackungen sind zu beachten.
· Zusammenlagerungshinweise: Nicht erforderlich.
· Weitere Angaben zu den Lagerbedingungen:
Behälter dicht geschlossen halten.
Vor Hitze und direkter Sonnenbestrahlung schützen.
· Lagerklasse:
· Klassifizierung nach Betriebssicherheitsverordnung (BetrSichV): -
(Fortsetzung auf Seite 4)
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· 7.3 Spezifische Endanwendungen Keine weiteren relevanten Informationen verfügbar.

ABSC HNITT 8: Begrenzu ng und Üb erwachung der Expo sition/Pers önliche


Schutzausrüstungen
· 8.1 Zu überwachende Parameter
· Zusätzliche Hinweise zur Gestaltung technischer Anlagen: Keine weiteren Angaben, siehe Abschnitt 7.
· Bestandteile mit arbeitsplatzbezogenen, zu überwachenden Grenzwerten:
811-97-2 1,1,1,2-Tetrafluorethan
AGW Langzeitwert: 4200 mg/m³, 1000 ml/m³
8(II);DFG, Y
67-63-0 Propan-2-ol
AGW Langzeitwert: 500 mg/m³, 200 ml/m³
2(II);DFG, Y
· Bestandteile mit biologischen Grenzwerten:
67-63-0 Propan-2-ol
BGW 25 mg/l
Untersuchungsmaterial: Vollblut
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton

25 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton
· Zusätzliche Hinweise: Als Grundlage dienten die bei der Erstellung gültigen Listen.
· 8.2 Begrenzung und Überwachung der Exposition
· Persönliche Schutzausrüstung:
· Allgemeine Schutz- und Hygienemaßnahmen:
Von Nahrungsmitteln, Getränken und Futtermitteln fernhalten.
Beschmutzte, getränkte Kleidung sofort ausziehen.
Vor den Pausen und bei Arbeitsende Hände waschen.
Berührung mit den Augen vermeiden.
Berührung mit den Augen und der Haut vermeiden.
· Atemschutz:
Bei kurzzeitiger oder geringer Belastung Atemfiltergerät; bei intensiver bzw. längerer Exposition
umluftunabhängiges Atemschutzgerät verwenden.
· Handschutz:
Das Handschuhmaterial muss undurchlässig und beständig gegen das Produkt / den Stoff / die Zubereitung sein.
Aufgrund fehlender Tests kann keine Empfehlung zum Handschuhmaterial für das Produkt / die Zubereitung / das
Chemikaliengemisch abgegeben werden.
Auswahl des Handschuhmaterials unter Beachtung der Durchbruchzeiten, Permeationsraten und der
Degradation.
· Handschuhmaterial
Die Auswahl eines geeigneten Handschuhs ist nicht nur vom Material, sondern auch von weiteren
Qualitätsmerkmalen abhängig und von Hersteller zu Hersteller unterschiedlich. Da das Produkt eine Zubereitung
aus mehreren Stoffen darstellt, ist die Beständigkeit von Handschuhmaterialen nicht vorausberechenbar und muß
deshalb vor dem Einsatz überprüft werden.
· Durchdringungszeit des Handschuhmaterials
Die genaue Durchbruchzeit ist beim Schutzhandschuhhersteller zu erfahren und einzuhalten.
(Fortsetzung auf Seite 5)
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· Augenschutz:

Dichtschließende Schutzbrille

ABSCHNITT 9: Physikalische und chemische Eigenschaften


· 9.1 Angaben zu den grundlegenden physikalischen und chemischen Eigenschaften
· Allgemeine Angaben
· Aussehen:
Form: Aerosol
Farbe: Weiß
· Geruch: Etherartig
· Geruchsschwelle: Nicht bestimmt.
· pH-Wert bei 20 °C: 7
· Zustandsänderung
Schmelzpunkt/Gefrierpunkt: Nicht bestimmt.
Siedebeginn und Siedebereich: 82 °C
· Flammpunkt: 12 °C
· Entzündbarkeit (fest, gasförmig): Nicht anwendbar.
· Zündtemperatur: 425 °C
· Zersetzungstemperatur: Nicht bestimmt.
· Selbstentzündungstemperatur: Das Produkt ist nicht selbstentzündlich.
· Explosive Eigenschaften: Mit und ohne Luft explosionsfähig.
· Explosionsgrenzen:
Untere: 2 Vol %
Obere: 12 Vol %
· Dampfdruck bei 25 °C: 5.515,8 hPa
· Dichte bei 20 °C: 1,25 g/cm³
· Relative Dichte Nicht bestimmt.
· Dampfdichte Nicht bestimmt.
· Verdampfungsgeschwindigkeit Nicht anwendbar.
· Löslichkeit in / Mischbarkeit mit
Wasser: Nicht bzw. wenig mischbar.
· Verteilungskoeffizient: n-Octanol/Wasser: Nicht bestimmt.
· Viskosität:
Dynamisch: Nicht bestimmt.
Kinematisch: Nicht bestimmt.
· Lösemittelgehalt:
Organische Lösemittel: 15,3 %
VOC (EU) 96,94 %
Festkörpergehalt: 0,0 %
(Fortsetzung auf Seite 6)
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· 9.2 Sonstige Angaben Keine weiteren relevanten Informationen verfügbar.

ABSCHNITT 10: Stabilität und Reaktivität


· 10.1 Reaktivität Keine weiteren relevanten Informationen verfügbar.
· 10.2 Chemische Stabilität
· Thermische Zersetzung / zu vermeidende Bedingungen:
Keine Zersetzung bei bestimmungsgemäßer Verwendung.
· 10.3 Möglichkeit gefährlicher Reaktionen Keine gefährlichen Reaktionen bekannt.
· 10.4 Zu vermeidende Bedingungen Keine weiteren relevanten Informationen verfügbar.
· 10.5 Unverträgliche Materialien: Keine weiteren relevanten Informationen verfügbar.
· 10.6 Gefährliche Zersetzungsprodukte: Keine gefährlichen Zersetzungsprodukte bekannt.

ABSCHNITT 11: Toxikologische Angaben


· 11.1 Angaben zu toxikologischen Wirkungen
· Akute Toxizität Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Einstufungsrelevante LD/LC50-Werte:
67-63-0 Propan-2-ol
Oral LD50 5.045 mg/kg (rat)
Dermal LD50 12.800 mg/kg (rabbit)
Inhalativ LC50/4 h 30 mg/l (rat)
· Primäre Reizwirkung:
· Ätz-/Reizwirkung auf die Haut Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Schwere Augenschädigung/-reizung
Verursacht schwere Augenreizung.
· Sensibilisierung der Atemwege/Haut Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Zusätzliche toxikologische Hinweise:
· CMR-Wirkungen (krebserzeugende, erbgutverändernde und fortpflanzungsgefährdende Wirkung)
· Keimzell-Mutagenität Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Karzinogenität Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Reproduktionstoxizität Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Spezifische Zielorgan-Toxizität bei einmaliger Exposition
Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Spezifische Zielorgan-Toxizität bei wiederholter Exposition
Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.
· Aspirationsgefahr Aufgrund der verfügbaren Daten sind die Einstufungskriterien nicht erfüllt.

ABSCHNITT 12: Umweltbezogene Angaben


· 12.1 Toxizität
· Aquatische Toxizität: Keine weiteren relevanten Informationen verfügbar.
· 12.2 Persistenz und Abbaubarkeit Keine weiteren relevanten Informationen verfügbar.
· 12.3 Bioakkumulationspotenzial Keine weiteren relevanten Informationen verfügbar.
· 12.4 Mobilität im Boden Keine weiteren relevanten Informationen verfügbar.
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· Weitere ökologische Hinweise:
· Allgemeine Hinweise:
Wassergefährdungsklasse 1 (Selbsteinstufung): schwach wassergefährdend
Nicht unverdünnt bzw. in größeren Mengen in das Grundwasser, in Gewässer oder in die Kanalisation gelangen
lassen.
· 12.5 Ergebnisse der PBT- und vPvB-Beurteilung
· PBT: Nicht anwendbar.
· vPvB: Nicht anwendbar.
· 12.6 Andere schädliche Wirkungen Keine weiteren relevanten Informationen verfügbar.

ABSCHNITT 13: Hinweise zur Entsorgung


· 13.1 Verfahren der Abfallbehandlung
· Empfehlung: Darf nicht zusammen mit Hausmüll entsorgt werden. Nicht in die Kanalisation gelangen lassen.
· Ungereinigte Verpackungen:
· Empfehlung: Entsorgung gemäß den behördlichen Vorschriften.

ABSCHNITT 14: Angaben zum Transport


· 14.1 UN-Nummer
· ADR, IMDG, IATA UN1950
· 14.2 Ordnungsgemäße UN-Versandbezeichnung
· ADR 1950 DRUCKGASPACKUNGEN
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transportgefahrenklassen
· ADR

· Klasse 2 5F Gase
· Gefahrzettel 2.2
· IMDG, IATA

· Class 2.2 Gase


· Label 2.2
· 14.4 Verpackungsgruppe
· ADR, IMDG, IATA entfällt
· 14.5 Umweltgefahren: Nicht anwendbar.
· 14.6 Besondere Vorsichtsmaßnahmen für den
Verwender Achtung: Gase
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· Nummer zur Kennzeichnung der Gefahr (Kemler-


Zahl): -
· EMS-Nummer: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· 14.7 Massengutbeförderung gemäß Anhang II des
MARPOL-Übereinkommens und gemäß IBC-Code Nicht anwendbar.
· Transport/weitere Angaben:
· ADR
· Begrenzte Menge (LQ) 1L
· Freigestellte Mengen (EQ) Code: E0
In freigestellten Mengen nicht zugelassen
· Beförderungskategorie 2
· Tunnelbeschränkungscode D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 DRUCKGASPACKUNGEN, 2.2

ABSCHNITT 15: Rechtsvorschriften


· 15.1 Vorschriften zu Sicherheit, Gesundheits- und Umweltschutz/spezifische Rechtsvorschriften für den Stoff
oder das Gemisch
· Richtlinie 2012/18/EU
· Namentlich aufgeführte gefährliche Stoffe - ANHANG I Keiner der Inhaltsstoffe ist enthalten.
· Seveso-Kategorie P1a EXPLOSIVE STOFFE
· Mengenschwelle (in Tonnen) für die Anwendung in Betrieben der unteren Klasse 10 t
· Mengenschwelle (in Tonnen) für die Anwendung in Betrieben der oberen Klasse 50 t
· VERORDNUNG (EG) Nr. 1907/2006 ANHANG XVII Beschränkungsbedingungen: 3
· Richtlinie 2011/65/EU zur Beschränkung der Verwendung bestimmter gefährlicher Stoffe in Elektro- und
Elektronikgeräten – Anhang II
Keiner der Inhaltsstoffe ist enthalten.
· VERORDNUNG (EU) 2019/1148
· Anhang I - BESCHRÄNKTE AUSGANGSSTOFFE FÜR EXPLOSIVSTOFFE (Oberer
Konzentrationsgrenzwert für eine Genehmigung nach Artikel 5 Absatz 3)
Keiner der Inhaltsstoffe ist enthalten.
(Fortsetzung auf Seite 9)
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Sicherheitsdatenblatt
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Handelsname: TEFLON SPRAY

(Fortsetzung von Seite 8)


· Anhang II - MELDEPFLICHTIGE AUSGANGSSTOFFE FÜR EXPLOSIVSTOFFE
Keiner der Inhaltsstoffe ist enthalten.
· Verordnung (EG) Nr. 273/2004 betreffend Drogenausgangsstoffe
Keiner der Inhaltsstoffe ist enthalten.
· Verordnung (EG) Nr. 111/2005 zur Festlegung von Vorschriften für die Überwachung des Handels mit
Drogenaustauschstoffen zwischen der Gemeinschaft und Drittländern
Keiner der Inhaltsstoffe ist enthalten.
· Nationale Vorschriften:
· Technische Anleitung Luft:
Klasse Anteil in %
NK 15,3

· Wassergefährdungsklasse: WGK 1 (Selbsteinstufung): schwach wassergefährdend.


· 15.2 Stoffsicherheitsbeurteilung: Eine Stoffsicherheitsbeurteilung wurde nicht durchgeführt.

ABSCHNITT 16: Sonstige Angaben


Die Angaben stützen sich auf den heutigen Stand unserer Kenntnisse, sie stellen jedoch keine Zusicherung von
Produkteigenschaften dar und begründen kein vertragliches Rechtsverhältnis.
· Relevante Sätze
H225 Flüssigkeit und Dampf leicht entzündbar.
H319 Verursacht schwere Augenreizung.
H336 Kann Schläfrigkeit und Benommenheit verursachen.
· Abkürzungen und Akronyme:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosive Stoffe/Gemische und Erzeugnisse mit Explosivstoff – Instabil, explosiv
Aerosol 3: Aerosole – Kategorie 3
Flam. Liq. 2: Entzündbare Flüssigkeiten – Kategorie 2
Eye Irrit. 2: Schwere Augenschädigung/Augenreizung – Kategorie 2
STOT SE 3: Spezifische Zielorgan-Toxizität (einmalige Exposition) – Kategorie 3
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SEZIONE 1: Identificazione della sostanza o della miscela e della società/impresa


· 1.1 Identificatore del prodotto
· Denominazione commerciale: TEFLON SPRAY
· Articolo numero: 72619
· UFI: D941-60F6-W00Y-QC3W
· 1.2 Usi identificati pertinenti della sostanza o della miscela e usi sconsigliati
Non sono disponibili altre informazioni.
· Utilizzazione della Sostanza / del Preparato Prodotti chimici per laboratorio
· 1.3 Informazioni sul fornitore della scheda di dati di sicurezza
· Produttore/fornitore:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Societa Italiana Chimici
Via Rio Nell Ellba 140
00138 Rome, Italy
Tel: 39 06 8800211
Fax: 39 30 06 8815313
Web: www.sichim.com
· Informazioni fornite da: Product safety department
· 1.4 Numero telefonico di emergenza:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

SEZIONE 2: Identificazione dei pericoli


· 2.1 Classificazione della sostanza o della miscela
· Classificazione secondo il regolamento (CE) n. 1272/2008

GHS01 bomba che esplode

Unst. Expl. H200 Esplosivo instabile.

GHS07

Eye Irrit. 2 H319 Provoca grave irritazione oculare.


Aerosol 3 H229 Contenitore pressurizzato: può esplodere se riscaldato.
· 2.2 Elementi dell'etichetta
· Etichettatura secondo il regolamento (CE) n. 1272/2008
Il prodotto è classificato ed etichettato conformemente al regolamento CLP.
· Pittogrammi di pericolo

GHS01 GHS07

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(Segue da pagina 1)
· Avvertenza Pericolo
· Indicazioni di pericolo
H200 Esplosivo instabile.
H229 Contenitore pressurizzato: può esplodere se riscaldato.
H319 Provoca grave irritazione oculare.
· Consigli di prudenza
P305+P351+P338 IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti.
Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
P373 NON utilizzare mezzi estinguenti se l'incendio raggiunge materiali esplosivi.
P380 Evacuare la zona.
P401 Conservare secondo i regolamenti locali/regionali/nazionali/internazionali.
P410+P412 Proteggere dai raggi solari. Non esporre a temperature superiori a 50 °C/122 °F.
P501 Smaltire il prodotto/recipiente in conformità con le disposizioni locali / regionali / nazionali /
internazionali.
· 2.3 Altri pericoli
· Risultati della valutazione PBT e vPvB
· PBT: Non applicabile.
· vPvB: Non applicabile.

SEZIONE 3: Composizione/informazioni sugli ingredienti


· 3.2 Caratteristiche chimiche: Miscele
· Descrizione: Miscela delle seguenti sostanze con additivi non pericolosi.
· Sostanze pericolose:
CAS: 67-63-0 2-propanolo >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Ulteriori indicazioni: Il testo dell'avvertenza dei pericoli citati può essere appreso dal capitolo 16

SEZIONE 4: Misure di primo soccorso


· 4.1 Descrizione delle misure di primo soccorso
· Indicazioni generali:
I sintomi di avvelenamento possono comparire dopo molte ore, per tale motivo è necessaria la sorveglianza di un
medico nelle 48 ore successive all'incidente.
· Inalazione:
Portare in zona ben areata, praticare eventualmente la respirazione artificiale, tenere al caldo. Se i disturbi
persistono consultare il medico.
Se il soggetto è svenuto provvedere a tenerlo durante il trasporto in posizione stabile su un fianco.
· Contatto con la pelle: Generalmente il prodotto non è irritante per la pelle.
· Contatto con gli occhi:
Lavare con acqua corrente per diversi minuti tenendo le palpebre ben aperte Se persiste il dolore consultare il
medico.
· Ingestione: Se il dolore persiste consultare il medico.
· 4.2 Principali sintomi ed effetti, sia acuti che ritardati Non sono disponibili altre informazioni.
· 4.3 Indicazione dell'eventuale necessità di consultare immediatamente un medico e di trattamenti speciali
Non sono disponibili altre informazioni.
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(Segue da pagina 2)

SEZIONE 5: Misure antincendio


· 5.1 Mezzi di estinzione
· Mezzi di estinzione idonei:
CO2, polvere o acqua nebulizzata. Estinguere gli incendi di grosse dimensioni con acqua nebulizzata o con
schiuma resistente all'alcool.
· 5.2 Pericoli speciali derivanti dalla sostanza o dalla miscela Non sono disponibili altre informazioni.
· 5.3 Raccomandazioni per gli addetti all'estinzione degli incendi
· Mezzi protettivi specifici: Indossare il respiratore.

SEZIONE 6: Misure in caso di rilascio accidentale


· 6.1 Precauzioni personali, dispositivi di protezione e procedure in caso di emergenza Non necessario.
· 6.2 Precauzioni ambientali: Impedire infiltrazioni nella fognatura/nelle acque superficiali/nelle acque freatiche.
· 6.3 Metodi e materiali per il contenimento e per la bonifica:
Smaltimento del materiale contaminato conformemente al punto 13.
Provvedere ad una sufficiente areazione.
· 6.4 Riferimento ad altre sezioni
Per informazioni relative ad un manipolazione sicura, vedere capitolo 7.
Per informazioni relative all'equipaggiamento protettivo ad uso personale vedere Capitolo 8.
Per informazioni relative allo smaltimento vedere Capitolo 13.

SEZIONE 7: Manipolazione e immagazzinamento


· 7.1 Precauzioni per la manipolazione sicura Accurata ventilazione/aspirazione nei luoghi di lavoro.
· Indicazioni in caso di incendio ed esplosione:
Proteggere dal calore.
Recipiente sotto pressione. Proteggere dai raggi solari e non esporre a una temperatura superiore ai 50°C, per
esempio da lampade ad incandescenza. Non perforare né bruciare neppure dopo l'uso.
Non vaporizzare su una fiamma o su corpo incandescente.
· 7.2 Condizioni per lo stoccaggio sicuro, comprese eventuali incompatibilità
· Stoccaggio:
· Requisiti dei magazzini e dei recipienti:
Osservare le disposizioni amministrative relative allo stoccaggio di spray.
· Indicazioni sullo stoccaggio misto: Non necessario.
· Ulteriori indicazioni relative alle condizioni di immagazzinamento:
Mantenere i recipienti ermeticamente chiusi.
Proteggere dal calore e dai raggi diretti del sole.
· 7.3 Usi finali particolari Non sono disponibili altre informazioni.

SEZIONE 8: Controllo dell’esposizione/protezione individuale


· 8.1 Parametri di controllo
· Ulteriori indicazioni sulla struttura di impianti tecnici: Nessun dato ulteriore, vedere punto 7.
· Componenti i cui valori limite devono essere tenuti sotto controllo negli ambienti di lavoro:
67-63-0 2-propanolo
TWA Valore a breve termine: 983 mg/m³, 400 ppm
Valore a lungo termine: 492 mg/m³, 200 ppm
A4
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(Segue da pagina 3)
· Componenti con valori limite biologici:
67-63-0 2-propanolo
IBE 40 mg/l
Campioni: urine
Momento del prelievo: f.t.f.s.l
Indicatore biologico: acetone
· Ulteriori indicazioni: Le liste valide alla data di compilazione sono state usate come base.
· 8.2 Controlli dell'esposizione
· Mezzi protettivi individuali:
· Norme generali protettive e di igiene del lavoro:
Tenere lontano da cibo, bevande e foraggi.
Togliere immediatamente gli abiti contaminati.
Lavarsi le mani prima dell'intervallo o a lavoro terminato.
Evitare il contatto con gli occhi.
Evitare il contatto con gli occhi e la pelle.
· Maschera protettiva:
Nelle esposizioni brevi e minime utilizzare la maschera; nelle esposizioni più intense e durature indossare
l'autorespiratore.
· Guanti protettivi:
Il materiale dei guanti deve essere impermeabile e stabile contro il prodotto/ la sostanza/ la formulazione.
A causa della mancanza di tests non può essere consigliato alcun tipo di materiale per i guanti con cui
manipolare il prodotto / la formulazione / la miscela di sostanze chimiche.
Scelta del materiale dei guanti in considerazione dei tempi di passaggio, dei tassi di permeazione e della
degradazione.
· Materiale dei guanti
La scelta dei guanti adatti non dipende soltanto dal materiale bensí anche da altre caratteristiche di qualità
variabili da un produttore a un altro. Poiché il prodotto rappresenta una formulazione di più sostanze, la stabilità
dei materiali dei guanti non è calcolabile in anticipo e deve essere testata prima dell'impiego
· Tempo di permeazione del materiale dei guanti
Richiedere dal fornitore dei guanti il tempo di passaggio preciso il quale deve essere rispettato.
· Occhiali protettivi:

Occhiali protettivi a tenuta

SEZIONE 9: Proprietà fisiche e chimiche


· 9.1 Informazioni sulle proprietà fisiche e chimiche fondamentali
· Indicazioni generali
· Aspetto:
Forma: Aerosol
Colore: Bianco
· Odore: Simile all'etere
· Soglia olfattiva: Non definito.
· valori di pH a 20 °C: 7
· Cambiamento di stato
Punto di fusione/punto di congelamento: Non definito.
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(Segue da pagina 4)

Punto di ebollizione iniziale e intervallo di


ebollizione: 82 °C
· Punto di infiammabilità: 12 °C
· Infiammabilità (solidi, gas): Non applicabile.
· Temperatura di accensione: 425 °C
· Temperatura di decomposizione: Non definito.
· Temperatura di autoaccensione: Prodotto non autoinfiammabile.
· Proprietà esplosive: Esplosivo a contatto o senza contatto con l'aria.
· Limiti di infiammabilità:
Inferiore: 2 Vol %
Superiore: 12 Vol %
· Tensione di vapore a 25 °C: 5.515,8 hPa
· Densità a 20 °C: 1,25 g/cm³
· Densità relativa Non definito.
· Densità di vapore: Non definito.
· Velocità di evaporazione Non applicabile.
· Solubilità in/Miscibilità con
acqua: Poco e/o non miscibile.
· Coefficiente di ripartizione: n-ottanolo/acqua: Non definito.
· Viscosità:
Dinamica: Non definito.
Cinematica: Non definito.
· Tenore del solvente:
Solventi organici: 15,3 %
VOC (CE) 96,94 %
Contenuto solido: 0,0 %
· 9.2 Altre informazioni Non sono disponibili altre informazioni.

SEZIONE 10: Stabilità e reattività


· 10.1 Reattività Non sono disponibili altre informazioni.
· 10.2 Stabilità chimica
· Decomposizione termica/ condizioni da evitare: Il prodotto non si decompone se utilizzato secondo le norme.
· 10.3 Possibilità di reazioni pericolose Non sono note reazioni pericolose.
· 10.4 Condizioni da evitare Non sono disponibili altre informazioni.
· 10.5 Materiali incompatibili: Non sono disponibili altre informazioni.
· 10.6 Prodotti di decomposizione pericolosi: Non sono noti prodotti di decomposizione pericolosi.

SEZIONE 11: Informazioni tossicologiche


· 11.1 Informazioni sugli effetti tossicologici
· Tossicità acuta Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
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(Segue da pagina 5)
· Valori LD/LC50 rilevanti per la classificazione:
67-63-0 2-propanolo
Orale LD50 5.045 mg/kg (rat)
Cutaneo LD50 12.800 mg/kg (rabbit)
Per inalazione LC50/4 h 30 mg/l (rat)
· Irritabilità primaria:
· Corrosione/irritazione cutanea Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Lesioni oculari gravi/irritazioni oculari gravi
Provoca grave irritazione oculare.
· Sensibilizzazione respiratoria o cutanea
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Ulteriori dati tossicologici:
· Effetti CMR (cancerogenicità, mutagenicità e tossicità per la riproduzione)
· Mutagenicità delle cellule germinali
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Cancerogenicità Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità per la riproduzione Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità specifica per organi bersaglio (STOT) - esposizione singola
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità specifica per organi bersaglio (STOT) - esposizione ripetuta
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Pericolo in caso di aspirazione Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.

SEZIONE 12: Informazioni ecologiche


· 12.1 Tossicità
· Tossicità acquatica: Non sono disponibili altre informazioni.
· 12.2 Persistenza e degradabilità Non sono disponibili altre informazioni.
· 12.3 Potenziale di bioaccumulo Non sono disponibili altre informazioni.
· 12.4 Mobilità nel suolo Non sono disponibili altre informazioni.
· Ulteriori indicazioni in materia ambientale:
· Ulteriori indicazioni:
Pericolosità per le acque classe 1 (D) (Autoclassificazione): poco pericoloso
Non immettere nelle acque freatiche, nei corsi d'acqua o nelle fognature non diluito o in grandi quantità.
· 12.5 Risultati della valutazione PBT e vPvB
· PBT: Non applicabile.
· vPvB: Non applicabile.
· 12.6 Altri effetti avversi Non sono disponibili altre informazioni.

SEZIONE 13: Considerazioni sullo smaltimento


· 13.1 Metodi di trattamento dei rifiuti
· Consigli: Non smaltire il prodotto insieme ai rifiuti domestici Non immettere nelle fognature.
· Imballaggi non puliti:
· Consigli: Smaltimento in conformità con le disposizioni amministrative.
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(Segue da pagina 6)

SEZIONE 14: Informazioni sul trasporto


· 14.1 Numero ONU
· ADR, IMDG, IATA UN1950
· 14.2 Nome di spedizione dell'ONU
· ADR 1950 AEROSOL
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Classi di pericolo connesso al trasporto
· ADR

· Classe 2 5F Gas
· Etichetta 2.2
· IMDG, IATA

· Class 2.2 Gas


· Label 2.2
· 14.4 Gruppo di imballaggio
· ADR, IMDG, IATA non applicabile
· 14.5 Pericoli per l'ambiente: Non applicabile.
· 14.6 Precauzioni speciali per gli utilizzatori Attenzione: Gas
· N° identificazione pericolo (Numero Kemler): -
· Numero EMS: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· 14.7 Trasporto di rinfuse secondo l'allegato II di
MARPOL ed il codice IBC Non applicabile.
· Trasporto/ulteriori indicazioni:
· ADR
· Quantità limitate (LQ) 1L
· Quantità esenti (EQ) Codice: E0
Vietato al trasporto in quantità esente
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(Segue da pagina 7)

· Categoria di trasporto 2
· Codice di restrizione in galleria D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOL, 2.2

SEZIONE 15: Informazioni sulla regolamentazione


· 15.1 Disposizioni legislative e regolamentari su salute, sicurezza e ambiente specifiche per la sostanza o la
miscela
· Direttiva 2012/18/UE
· Sostanze pericolose specificate - ALLEGATO I Nessuno dei componenti è contenuto.
· Categoria Seveso P1a ESPLOSIVI
· Quantità limite (tonnellate) ai fini dell'applicazione dei requisiti di soglia inferiore 10 t
· Quantità limite (tonnellate) ai fini dell'applicazione dei requisiti di soglia superiore 50 t
· REGOLAMENTO (CE) n. 1907/2006 ALLEGATO XVII Restrizioni: 3
· Direttiva 2011/65/UE sulla restrizione dell’uso di determinate sostanze pericolose nelle apparecchiature
elettriche ed elettroniche - Allegato II
Nessuno dei componenti è contenuto.
· REGOLAMENTO (UE) 2019/1148
· Allegato I - PRECURSORI DI ESPLOSIVI SOGGETTI A RESTRIZIONI (Valore limite superiore ai fini della
concessione di licenze a norma dell’articolo 5, paragrafo 3)
Nessuno dei componenti è contenuto.
· Allegato II - PRECURSORI DI ESPLOSIVI SOGGETTI A SEGNALAZIONE
Nessuno dei componenti è contenuto.
· Regolamento (CE) n. 273/2004 relativo ai precursori di droghe
Nessuno dei componenti è contenuto.
· Regolamento (CE) N. 111/2005 recante norme per il controllo del commercio dei precursori di droghe tra la
Comunità e i paesi terzi
Nessuno dei componenti è contenuto.
· Disposizioni nazionali:
· Istruzione tecnica aria:
Classe quota in %
NC 15,3
· 15.2 Valutazione della sicurezza chimica: Una valutazione della sicurezza chimica non è stata effettuata.

SEZIONE 16: Altre informazioni


I dati sono riportati sulla base delle nostre conoscenze attuali, non rappresentano tuttavia alcuna garanzia delle
caratteristiche del prodotto e non motivano alcun rapporto giuridico contrattuale.
· Frasi rilevanti
H225 Liquido e vapori facilmente infiammabili.
H319 Provoca grave irritazione oculare.
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(Segue da pagina 8)
H336 Può provocare sonnolenza o vertigini.
· Abbreviazioni e acronimi:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Esplosivi – Esplosivo instabile
Aerosol 3: Aerosol – Categoria 3
Flam. Liq. 2: Liquidi infiammabili – Categoria 2
Eye Irrit. 2: Gravi lesioni oculari/irritazione oculare – Categoria 2
STOT SE 3: Tossicità specifica per organi bersaglio (esposizione singola) – Categoria 3
IT

55.0.4
쪽: 1/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

1 화학제품과 회사에 관한 정보
· 제품 식별자
· 제품명: TEFLON SPRAY
· 상품번호: 72619
· 해당 순물질이나 혼합물의 관련 하위용도 및 사용금지용도
· 제품의 권고 용도와 사용상의 제한: TEFLON SPRAY
· 제품의 권고 용도와 사용상의 제한: 실 험 실 화 학품
· 안전데이터표(Safety Data Sheet)내 공급업체 관련 상세 정보
· 제조자/수입자/유통업자 정보:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Samchang Commercial Co., Ltd.
Yeo Eui Do
PO Box 1110
Seoul, Korea
Tel: 82 2 703 3040
Fax: 82 2 717 3298
----------------------------------------------------------
Daedok Science, Co. Ltd.
34141 E10 Korea Advanced Institute of Science
Guseong-Dong, Yuseong-gu, Daejeon,
Korea
Phone: 82 42 710 2091
Fax: 82 42 367 0005
Website: www.labsmro.com
· 추가적인 정보 획득 가능: Product safety department
· 비상연락 전화번호:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

2 유해성·위험성
· 순물질 또는 혼합물의 분류

폭발

폭발성 물질 – 불안정한 폭발성 물질 H200 불안정한 폭발성 물질

심한 눈 손상성/눈 자극성 – 구분2A H319 눈에 심한 자극을 일으킴


에어로졸 – 구분3 H229 압력용기: 가열하면 터질 수 있음
· 라벨표기 요소
· GHS 라벨 요소 본 제품은 화학물질의 분류 및 표기에 관한 국제조화시스템(GHS)에 따라 분류 및 표기되었습니다.
(2 쪽에계속)
KR

55.0.4
쪽: 2/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(1 쪽부터계속)
· GHS 그림문자

GHS01 GHS07

· 신호어 위험
· 유해·위험문구
불안정한 폭발성 물질
압력용기: 가열하면 터질 수 있음
눈에 심한 자극을 일으킴
· 예방조치문구
눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
화염이 폭발성 물질에 도달하면 불을 끄려 하지 마시오.
주변 지역의 사람을 대피시키시오.
현지/지역/국가/국제 규정에 따라서 보관 하기
직사광선을 피하고 50℃ 이상의 온도에 노출시키지 마시오.
(지방/지역/국가/국제 규정에 따라) 에 내용물/용기를 폐기하시오.
· 기타 유해성
· PBT(잔류성, 생물농축성, 독성 물질) 및 vPvB(고 잔류성, 고 생물농축성 물질) 평가 결과
· PBT(잔류성, 생물농축성, 독성 물질): 해당사항 없음.
· vPvB(고 잔류성, 고 생물농축성 물질): 해당사항 없음.

3 구성성분의 명칭 및 함유량
· 화 학 적 특 성: 혼합물
· 설명: 무해한 첨 가 물 이 함유된 아래에 열 거 된 물 질 로 만 들 어 진 혼 합 물.
· 위 험 요소:
811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
67-63-0 propan-2-ol >10-≤25%
인화성 액체 – 구분2, H225; 심한 눈 손상성/눈 자극성 – 구분 2, H319; 특정표적장기 독성
- 1회 노출– 구분3, H336

4 응급조치 요령
· 응급조치요령 내용
· 일 반 적 정보:
중 독 증 상 은 몇 시 간이 지난 뒤에 발생할 수 있다. 따라서 사고가 발 생 한 후에 적 어 도 48 시 간동안은 의료진의 관찰을 받
아 야 한 다.
· 흡입했을 때:
신 선 한 공 기를 쐬고 , 필요할 경우에는 산 소 호 흡 기의 도움을 받는다 . 환자를 따뜻하게 하고 , 증상이 지속될 경우에는
의료진의 도움을 구한다.
환자가 의식을 잃었을 경우에는 안전한 자세에서 환자를 운반한다.
· 피부에 접촉했을 때: 일 반 적 으 로 이 제품은 피 부 에 자 극 적 이 지 않 다.
· 눈에 들어갔을 때: 흐르는 물에 눈을 몇분동안 씻어내고나서, 증상이 지속될 경우에는 의사와 상담한 다
· 먹었을 때: 증상이 지 속될 경우에는 의사와 상 담 한 다.
· 기타 의사의 주의사항:
· 가장 중요한 급∙만성 증상 및 영향 추가적인 정보가 존재하지 않습니다.
(3 쪽에계속)
KR

55.0.4
쪽: 3/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(2 쪽부터계속)
· 즉각적인 의료처치 및 특별치료가 필요함을 시사하는 징후 추가적인 정보가 존재하지 않습니다.

5 폭발·화재시 대처방법
· 소화제
· 적절한 소화제:
이 산 화 탄 소, 진 화 용 석 회 가 루 또 는 물 방 사를 사용하고, 더 큰 화재는 물 을 분 사 하 거 나 알 코 올 이 함 유 된 거 품 으
로 끈 다.
· 본 화학물질이나 혼합물에서 발생하는 특별 유해성 추가적인 정보가 존재하지 않습니다.
· 소방관에 대한 권고사항
· 화재 진압 시 착용할 보호구 및 예방조치: 호흡보호장비설치.

6 누출 사고 시 대처방법
· 개인적 예방조치, 보호장비 및 응급처치 절차 필요없음.
· 환경 관련 예방조치: 하수도망/해수면위의물/지하수로도달하지않게한다.
· 밀폐 및 정화 방법과 소재:
항목 13에 따라 오염된 물질을 쓰레기로 처분한다.
충분한 환기가 되도록 한다.
· 타 섹션 참조
안 전 관 리 에 대한 정보는 제7 장 을 참고하시오.
개 인 보 호 장 비에 대한 정보는 제8 장 을 참고하시 오.
쓰 레 기 처 리 에 대한 정보는 제13 장 을 참고하시 오.

7 취급 및 저장방법
· 취급:
· 안전 취급을 위한 예방조치 작업장에서는통풍이잘되고/습기제거가잘되게주의한다.
· 화재 및 폭발 사고 예방대책에 관한 정보:
열로부터보호한다.
용기는압축되어있다. 태양광선이나 50°C 이상의온도로부터보호한다. 역시사용후에는강제적으로개봉하거나소각시키지않는다 .
화염에가까이하거나타고있는물건에분사하지않는다 .

· 혼합위험성 등 안전 저장 조건
· 보관:
· 안전한 저장 방법: 압력가스상자보관에관한관청의지시에주의해야한다 .
· 하나의 공동 보관 시설에 대한 보관 관련 정보: 필 요없음
· 보 관 조 건 에 관 한 추가적인 정보:
용기를새지않게밀폐한채보관한다.
열이나직사광선으로부터보호한다.
· 구체적 최종 사용자 추가적인 정보가 존재하지 않습니다.

8 노출방지 및 개인보호구
· 첨단시설 디자인에 대한 추가정보: 더 이 상 의 자료는 없음. 항 목 7 을 참고하시 오.
· 통제 변수
· 화학물질의 노출기준, 생물학적 노출기준 등:
811-97-2 1,1,1,2-tetrafluoroethane
WEEL (US) 장기간의값: 1000 ppm
(4 쪽에계속)
KR

55.0.4
쪽: 4/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(3 쪽부터계속)
67-63-0 propan-2-ol
OELV (KR) 단기간의값: 400 ppm
장기간의값: 200 ppm
PEL (US) 장기간의값: 980 mg/m³, 400 ppm
REL (US) 단기간의값: 1225 mg/m³, 500 ppm
장기간의값: 980 mg/m³, 400 ppm
TLV (US) 단기간의값: 400 ppm
장기간의값: 200 ppm
BEI, A4
· 생물학적 허용값을 갖는 원료:
67-63-0 propan-2-ol
BEI (US) 40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
· 추 가 정보: 제 조 할 당시에 유 효 한 목 록을 기초로 사용했다.
· 노출 통제
· 개인 보호구
· 일반적보호조치및위생조치:
식 료 품, 음 료 수와 사 료 로 부 터 멀 리 떨 어 뜨 려 놓 는 다.
더 러 워 지 거 나 음 료 수 가 묻 은 옷 은 즉 시 탈의한다.
휴 식 전 이 나 작업이 끝날때마다 손을 씻는다.
눈과의 접 촉 을 피 한 다.
눈 과 피 부와의 접 촉 은 피 한 다.
· 호흡기 보호:
단 시 간 또 는 경 미 한 오 염 의 경 우에는 호 흡 여 과 기 를 사 용 한 다. 심각한 또 는 장 기 간 노 출시에 는 호 흡 보 호 장 비
를 사 용 한 다.
· 손 보호:
장갑재질은제품 / 원료 / 조제를투과시키지않아야하고, 내구성이있어야한다.
테 스 트 를 하 지 않 았기 때문에 제 품 / 조 제 / 화 학 혼 합 물에 적합한 장갑재질에 대한 추천이 없다.
투과 시 간, 침 투 율 과 저하를 고 려해서 장 갑 재 료를 선택한다.
· 장갑의재료
적합한장갑의선정은재질차이뿐아니라품질기준의차이도고려하여이루어져야하고제조업종에따라서도다르게선정되어야한다 .
제품은다양한재료로부터의조제로이루어지는것이기때문에 , 장갑재질의안정성은사전에예측되어질수있는것이아니고 ,
반드시사용전에 (그안전성이) 체크되어져야한다.
· 장 갑 재 료 의 투과시 간 정확한관통시간은보호장갑제조자에의하여인지되고 , 준수되어야한다.
· 눈 보호:

꽉조이는보안경

9 물리화학적 특성
· 기본 물리 및 화학적 특성에 대한 정보
· 일반정보
· 외형
물리적 상태: 에어로졸
색: 하얀
(5 쪽에계속)
KR

55.0.4
쪽: 5/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(4 쪽부터계속)

· 냄새: 에테르종류의
· 후각역치 알맞지않다.

· pH 의경우 20 °C: 7
· 상태변화
녹는점/어는점: 맞지않는
초기 끓는점과 끓는점 범위: 82 °C
· 인화점: 12 °C
· 인화성(고체, 기체): 해당사항 없음.

· 점화온도: 425 °C
· 분해 온도: 알맞지않다.

· 자기점화: 이제품은자연발화성이없다.

· 폭발위험: 공기가있던없던폭발가능성이있는

· 인화 또는 폭발 범위의 상한/하한
아래로: 2 Vol %
위로: 12 Vol %
· 증기압 의경우 25 °C: 5,515.8 hPa
· 밀도 의경우 20 °C: 1.25 g/cm³
· 비중: 알맞지않다.
· 증기밀도: 알맞지않다.
· 증발 속도: 해당사항 없음.

· 용해도:
물: 각각의경우에따라서는거의혼합할수없는

· n 옥탄올/물 분배계수: 알맞지않다.

· 점도:
역학성: 알맞지않다.
동점성: 알맞지않다.

· 용매내용물
유기용매: 15.3 %
VOC (EU) 96.94 %
고체의 함량: 0.0 %
· 기타 정보 추가적인 정보가 존재하지 않습니다.

10 안정성 및 반응성
· 반응성 추가적인 정보가 존재하지 않습니다.
· 화학적 안정성
· 화학적 안정성 및 유해 반응의 가능성 / 피해야 할 조건: 규정에따라사용할경우해체는없다
· 유해반응 가능성 위험한반응으로는알려지지않았다.
· 피해야 할 조건 추가적인 정보가 존재하지 않습니다.
· 혼합 금지 물질: 추가적인 정보가 존재하지 않습니다.
· 유해분해물질: 위험성있는분해물들은알려지지않았다.
KR
(6 쪽에계속)

55.0.4
쪽: 6/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(5 쪽부터계속)

11 독성에 관한 정보
· 독성학적 영향에 대한 정보
· 급성 독성:
· LD/LC50-수치에 따른 분류:
67-63-0 propan-2-ol
구강의 LD50 5,045 mg/kg (rat)
피부의 LD50 12,800 mg/kg (rabbit)
흡입의 LC50/4 h 30 mg/l (rat)
· 일차적 자극 효과:
· 피부 부식성 또는 자극성: 무자극
· 심한 눈 손상 또는 자극성: 자극
· 감각화: 민감한영향이없는것으로알려져있다.
· 추 가 적 인 독성에 관한 정보:
이제품은유럽공동체의공동분류원칙의합법적인절차에근거하여최근에발효된원고에서아래위험들의사전준비에대하여제시하고있
다.
건강에해로운
자극적인

12 환경에 미치는 영향
· 독성
· 수생독성: 추가적인 정보가 존재하지 않습니다.
· 지속성 및 분해성 추가적인 정보가 존재하지 않습니다.
· 환 경 시스템에서의 행 동:
· 생물농축 잠재성 추가적인 정보가 존재하지 않습니다.
· 토양내 이동성 추가적인 정보가 존재하지 않습니다.
· 추가적인 생태학 정보:
· 일반 특징:
수질오염등급 1 (자체등급분류): 약하게수질오염이된
희석시키지않은채대량으로지하수나 , 하천으로그리고하수도망에도달하지않게한다 .
· PBT(잔류성, 생물농축성, 독성 물질) 및 vPvB(고 잔류성, 고 생물농축성 물질) 평가 결과
· PBT(잔류성, 생물농축성, 독성 물질): 해당사항 없음.
· vPvB(고 잔류성, 고 생물농축성 물질): 해당사항 없음.
· 기타 부작용 추가적인 정보가 존재하지 않습니다.

13 폐기시 주의사항
· 폐기물 처리 방법
· 권고: 생활쓰레기와함께처리되어서는안된다. 하수도망으로유입되서는안된다.
· 비위생적 포장:
· 권고: 당국의지침에입각한쓰레기처리.

14 운송에 필요한 정보
· 유엔 번호
· ADR, IMDG, IATA UN1950
(7 쪽에계속)
KR

55.0.4
쪽: 7/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(6 쪽부터계속)

· UN 적정 선적명
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 교통 위험 클래스
· ADR

· 등급 2 5F 가스
· 위험물 라벨 2.2
· IMDG, IATA

· Class 2.2 가스
· Label 2.2
· 용기등급
· ADR, IMDG, IATA 누락되다

· 환경적 유해물질: 해당사항 없음.

· 이용자 특별 예방조치 경고: 가스


· 위험 코드: -
· EMS-번호: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of
living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
· MARPOL73/78(선박으로부터의 해양오염방지협약)
부속서2 및 IBC Code(국제선적화물코드)에 따른
벌크(bulk) 운송 해당사항 없음.

· 운 송/추가 정보:
· ADR
· 한정 수량 (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· 운송 구분 2
· 터널 제한 코드 D
(8 쪽에계속)
KR

55.0.4
쪽: 8/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(7 쪽부터계속)

· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "모범 규제": UN 1950 AEROSOLS, 2.2

15 법적 규제현황
· 산업안전보건법에 의한 규제:
· 제조 등 금지물질:
어떠한내용물도목록화되어있지않다

· 허가대상물질:
어떠한내용물도목록화되어있지않다

· 관리대상유해물질:
67-63-0 propan-2-ol
· 작업환경측정 대상 유해인자
67-63-0 propan-2-ol 1A79
· 특수건강진단 대상 유해인자
67-63-0 propan-2-ol 1A74
· 해당 순물질 또는 혼합물에 대한 안전, 보건 및 환경 규제/법률 추가적인 정보가 존재하지 않습니다.
· Korean Existing Chemical Inventory
811-97-2 1,1,1,2-tetrafluoroethane KE-33426
67-63-0 propan-2-ol KE-29363
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro KE-09252
· 화학물질관리법
· 사고대비물질
어떠한내용물도목록화되어있지않다

· 금지물질
어떠한내용물도목록화되어있지않다

· 제한물질
어떠한내용물도목록화되어있지않다

· 유독물질
어떠한내용물도목록화되어있지않다

· 허가물질
어떠한내용물도목록화되어있지않다
· 위험물안전관리법 (위험물 및 지정수량) 제 4: 400 리터
· 등록 또는 신고 면제대상 화학물질
어떠한내용물도목록화되어있지않다

· ‘21년까지 등록하여야 할 암, 돌연변이, 생식능력 이상을 일으키거나 일으킬 우려가 있는 기존화학물질


어떠한내용물도목록화되어있지않다

· 중점관리물질(제2조 관련)
어떠한내용물도목록화되어있지않다
· GHS 라벨 요소 본 제품은 화학물질의 분류 및 표기에 관한 국제조화시스템(GHS)에 따라 분류 및 표기되었습니다.
(9 쪽에계속)
KR

55.0.4
쪽: 9/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12

제품명: TEFLON SPRAY

(8 쪽부터계속)
· GHS 그림문자

GHS01 GHS07

· 신호어 위험
· 유해·위험문구
불안정한 폭발성 물질
압력용기: 가열하면 터질 수 있음
눈에 심한 자극을 일으킴
· 예방조치문구
눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
화염이 폭발성 물질에 도달하면 불을 끄려 하지 마시오.
주변 지역의 사람을 대피시키시오.
현지/지역/국가/국제 규정에 따라서 보관 하기
직사광선을 피하고 50℃ 이상의 온도에 노출시키지 마시오.
(지방/지역/국가/국제 규정에 따라) 에 내용물/용기를 폐기하시오.
· 화학물질 안전성 평가: 화학물질 안전성 평가가 수행되지 않음

16 그 밖의 참고사항
이보고는우리지식에대한오늘날의상태에대하여평가하고있다 ,
하지만이보고서는생산특성에관한보증은기술하지않았으며계약적인법률관계에기반을두고있지도않다

· 담당자:
· 최초 작성일자: 2022.08.12
· 개정 횟수 및 최종 개정일자: 1 / 2022.08.12
· 약어와 두문자어:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
KR

55.0.4
página: 1/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

SECCIÓN 1: Identificación de la sustancia o la mezcla y de la sociedad o la empresa


· 1.1 Identificador del producto
· Nombre comercial: TEFLON SPRAY
· Número del artículo: 72619
· UFI: D941-60F6-W00Y-QC3W
· 1.2 Usos pertinentes identificados de la sustancia o de la mezcla y usos desaconsejados
No existen más datos relevantes disponibles.
· Utilización del producto / de la elaboración Sustancias químicas de laboratorio
· 1.3 Datos del proveedor de la ficha de datos de seguridad
· Fabricante/distribuidor:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Aname
C/ Perez Galdos no. 2
28693 Quijorna
Madrid, Spain
Tel: +34.91.816.89.50
Fax: +34.91.816.85.94
email: [email protected]
· Área de información: Product safety department
· 1.4 Teléfono de emergencia:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887

SECCIÓN 2: Identificación de los peligros


· 2.1 Clasificación de la sustancia o de la mezcla
· Clasificación con arreglo al Reglamento (CE) n° 1272/2008

GHS01 bomba explotando

Unst. Expl. H200 Explosivo inestable.

GHS07

Eye Irrit. 2 H319 Provoca irritación ocular grave.


Aerosol 3 H229 Recipiente a presión: Puede reventar si se calienta.
· 2.2 Elementos de la etiqueta
· Etiquetado con arreglo al Reglamento (CE) n° 1272/2008
El producto se ha clasificado y etiquetado de conformidad con el reglamento CLP.
( se continua en página 2 )
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página: 2/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 1 )
· Pictogramas de peligro

GHS01 GHS07

· Palabra de advertencia Peligro


· Indicaciónes de peligro
H200 Explosivo inestable.
H229 Recipiente a presión: Puede reventar si se calienta.
H319 Provoca irritación ocular grave.
· Consejos de prudencia
P305+P351+P338 EN CASO DE CONTACTO CON LOS OJOS: Enjuagar con agua cuidadosamente durante
varios minutos. Quitar las lentes de contacto cuando estén presentes y pueda hacerse con
facilidad. Proseguir con el lavado.
P373 NO luchar contra el incendio cuando el fuego llega a los explosivos.
P380 Evacuar la zona.
P401 Almacenar conforme a la reglamentación local/regional/nacional/internacional.
P410+P412 Proteger de la luz del sol. No exponer a temperaturas superiores a 50 °C/122 °F.
P501 Eliminar el contenido o el recipiente conforme a la reglamentación local/regional/nacional/
internacional.
· 2.3 Otros peligros
· Resultados de la valoración PBT y mPmB
· PBT: No aplicable.
· mPmB: No aplicable.

SECCIÓN 3: Composición/información sobre los componentes


· 3.2 Caracterización química: Mezclas
· Descripción: Mezcla formada por las substancias especificadas a continuación con adiciones no peligrosas.
· Componentes peligrosos:
CAS: 67-63-0 2-propanol >10-≤25%
EINECS: 200-661-7 Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
· Indicaciones adicionales: El texto de los posibles riesgos aquí indicados se puede consultar en el capítulo 16.

SECCIÓN 4: Primeros auxilios


· 4.1 Descripción de los primeros auxilios
· Instrucciones generales:
Los síntomas de intoxicación pueden presentarse después de muchas horas, por lo que se requiere una
supervisión médica durante un mínimo de 48 horas después del accidente.
· En caso de inhalación del producto:
Suministrar aire fresco; eventualmente hacer respiración artificial, calor. Si los trastornos persisten, consultar al
médico.
Las personas desmayadas deben tenderse y transportarse de lado con la suficiente estabilidad.
· En caso de contacto con la piel: Por regla general, el producto no irrita la piel.
· En caso de con los ojos:
Limpiar los ojos abiertos durante varios minutos con agua corriente. En caso de trastornos persistentes consultar
un médico.
· En caso de ingestión: Consultar un médico si los trastornos persisten.
· 4.2 Principales síntomas y efectos, agudos y retardados No existen más datos relevantes disponibles.
( se continua en página 3 )
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página: 3/9
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según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 2 )
· 4.3 Indicación de toda atención médica y de los tratamientos especiales que deban dispensarse inmediatamente
No existen más datos relevantes disponibles.

SECCIÓN 5: Medidas de lucha contra incendios


· 5.1 Medios de extinción
· Sustancias extintoras apropiadas:
CO2, polvo extintor o chorro de agua rociada. Combatir incendios mayores con chorro de agua rociada o
espuma resistente al alcohol.
· 5.2 Peligros específicos derivados de la sustancia o la mezcla No existen más datos relevantes disponibles.
· 5.3 Recomendaciones para el personal de lucha contra incendios
· Equipo especial de protección: Colocarse la protección respiratoria.

SECCIÓN 6: Medidas en caso de vertido accidental


· 6.1 Precauciones personales, equipo de protección y procedimientos de emergencia No es necesario.
· 6.2 Precauciones relativas al medio ambiente:
Evitar que penetre en la canalización /aguas de superficie /agua subterráneas.
· 6.3 Métodos y material de contención y de limpieza:
Desechar el material contaminado como vertido según item 13.
Asegurar suficiente ventilación.
· 6.4 Referencia a otras secciones
Ver capítulo 7 para mayor información sobre una manipulación segura.
Ver capítulo 8 para mayor información sobre el equipo personal de protección.
Para mayor información sobre cómo desechar el producto, ver capítulo 13.

SECCIÓN 7: Manipulación y almacenamiento


· 7.1 Precauciones para una manipulación segura
Asegurar suficiente ventilación /aspiración en el puesto de trabajo.
· Prevención de incendios y explosiones:
Proteger del calor.
Cuidado: recipiente bajo presión. Protegerlo de la luz solar directa y de temperaturas superiores a 50°C (por
ejemplo bombillas eléctricas). Incluso después de la utilización, no abrirlo con fuerza ni quemarlo.
No rociar sobre llamas o cuerpos incandescentes.
· 7.2 Condiciones de almacenamiento seguro, incluidas posibles incompatibilidades
· Almacenamiento:
· Exigencias con respecto al almacén y los recipientes:
Observar las prescripciones vigentes para el almacenamiento de envases con gas comprimido.
· Normas en caso de un almacenamiento conjunto: No es necesario.
· Indicaciones adicionales sobre las condiciones de almacenamiento:
Mantener el recipiente cerrado herméticamente.
Proteger del calor y de la luz directa del sol.
· 7.3 Usos específicos finales No existen más datos relevantes disponibles.

SECCIÓN 8: Controles de exposición/protección individual


· 8.1 Parámetros de control
· Instrucciones adicionales para el acondicionamiento de instalaciones técnicas:
Sin datos adicionales, ver punto 7.
( se continua en página 4 )
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página: 4/9
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según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 3 )
· Componentes con valores límite admisibles que deben controlarse en el puesto de trabajo:
67-63-0 2-propanol
LEP Valor de corta duración: 1000 mg/m³, 400 ppm
Valor de larga duración: 500 mg/m³, 200 ppm
VLB, s
· Componentes con valores límite biológicos:
67-63-0 2-propanol
VLB 40 mg/l
Muestra: orina
Momento de Muestero: Final de la semana laboral
Indicador Biológico: Acetona
· Indicaciones adicionales: Como base se han utilizado las listas vigentes en el momento de la elaboración.
· 8.2 Controles de la exposición
· Equipo de protección individual:
· Medidas generales de protección e higiene:
Mantener alejado de alimentos, bebidas y alimentos para animales.
Quitarse de inmediato la ropa ensuciada o impregnada.
Lavarse las manos antes de las pausas y al final del trabajo.
Evitar el contacto con los ojos.
Evitar el contacto con los ojos y la piel.
· Protección respiratoria:
Si la exposición va a ser breve o de poca intensidad, colocarse una máscara respiratoria. Para una exposición
más intensa o de mayor duración, usar un aparato de respiración autónomo.
· Protección de manos:
El material del guante deberá ser impermeable y resistente al producto / substancia / preparado.
Ante la ausencia de tests específicos, no se puede recomendar ningún material específico para guantes de
protección contra el producto / preparado / mezcla de substancias químicas.
Selección del material de los guantes en función de los tiempos de rotura, grado de permeabilidad y degradación.
· Material de los guantes
La elección del guante adecuado no depende únicamente del material, sino también de otras características de
calidad, que pueden variar de un fabricante a otro. Teniendo en cuenta que el producto está fabricado a partir de
diferentes materiales, su calidad no puede ser avaluada de antemano, de modo que los guantes deberán ser
controlados antes de su utilización.
· Tiempo de penetración del material de los guantes
El tiempo de resistencia a la penetración exacto deberá ser pedido al fabricante de los guantes. Este tiempo debe
ser respetado.
· Protección de ojos:

Gafas de protección herméticas

SECCIÓN 9: Propiedades físicas y químicas


· 9.1 Información sobre propiedades físicas y químicas básicas
· Datos generales
· Aspecto:
Forma: Aerosol
Color: Blanco
· Olor: Etéreo
( se continua en página 5 )
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fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 4 )

· Umbral olfativo: No determinado.


· valor pH a 20 °C: 7
· Cambio de estado
Punto de fusión/punto de congelación: Indeterminado.
Punto inicial de ebullición e intervalo de ebullición: 82 °C
· Punto de inflamación: 12 °C
· Inflamabilidad (sólido, gas): No aplicable.
· Temperatura de ignición: 425 °C
· Temperatura de descomposición: No determinado.
· Temperatura de auto-inflamación: El producto no es autoinflamable.
· Propiedades explosivas: Peligro de explosión, en contacto o sin contacto con el
aire.
· Límites de explosión:
Inferior: 2 Vol %
Superior: 12 Vol %
· Presión de vapor a 25 °C: 5.515,8 hPa
· Densidad a 20 °C: 1,25 g/cm³
· Densidad relativa No determinado.
· Densidad de vapor No determinado.
· Tasa de evaporación: No aplicable.
· Solubilidad en / miscibilidad con
agua: Poco o no mezclable.
· Coeficiente de reparto: n-octanol/agua: No determinado.
· Viscosidad:
Dinámica: No determinado.
Cinemática: No determinado.
· Concentración del disolvente:
Disolventes orgánicos: 15,3 %
VOC (CE) 96,94 %
Contenido de cuerpos sólidos: 0,0 %
· 9.2 Otros datos No existen más datos relevantes disponibles.

SECCIÓN 10: Estabilidad y reactividad


· 10.1 Reactividad No existen más datos relevantes disponibles.
· 10.2 Estabilidad química
· Descomposición térmica / condiciones que deben evitarse: No se descompone al emplearse adecuadamente.
· 10.3 Posibilidad de reacciones peligrosas No se conocen reacciones peligrosas.
· 10.4 Condiciones que deben evitarse No existen más datos relevantes disponibles.
· 10.5 Materiales incompatibles: No existen más datos relevantes disponibles.
· 10.6 Productos de descomposición peligrosos: No se conocen productos de descomposición peligrosos.
ES
( se continua en página 6 )

55.0.4
página: 6/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 5 )

SECCIÓN 11: Información toxicológica


· 11.1 Información sobre los efectos toxicológicos
· Toxicidad aguda A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Valores LD/LC50 (dosis letal /dosis letal = 50%) relevantes para la clasificación:
67-63-0 2-propanol
Oral LD50 5.045 mg/kg (rat)
Dermal LD50 12.800 mg/kg (rabbit)
Inhalatorio LC50/4 h 30 mg/l (rat)
· Efecto estimulante primario:
· Corrosión o irritación cutáneas A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Lesiones o irritación ocular graves
Provoca irritación ocular grave.
· Sensibilización respiratoria o cutánea
A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Indicaciones toxicológicas adicionales:
· Efectos CMR (carcinogenicidad, mutagenicidad y toxicidad para la reproducción)
· Mutagenicidad en células germinales
A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Carcinogenicidad A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Toxicidad para la reproducción A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Toxicidad específica en determinados órganos (STOT) – exposición única
A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Toxicidad específica en determinados órganos (STOT) – exposición repetida
A la vista de los datos disponibles, no se cumplen los criterios de clasificación.
· Peligro de aspiración A la vista de los datos disponibles, no se cumplen los criterios de clasificación.

SECCIÓN 12: Información ecológica


· 12.1 Toxicidad
· Toxicidad acuática: No existen más datos relevantes disponibles.
· 12.2 Persistencia y degradabilidad No existen más datos relevantes disponibles.
· 12.3 Potencial de bioacumulación No existen más datos relevantes disponibles.
· 12.4 Movilidad en el suelo No existen más datos relevantes disponibles.
· Indicaciones medioambientales adicionales:
· Indicaciones generales:
Nivel de riesgo para el agua 1 (autoclasificación): escasamente peligroso para el agua
En estado no diluido o no neutralizado, no dejar que se infiltre en aguas subterráneas, aguas superficiales o en
alcantarillados.
· 12.5 Resultados de la valoración PBT y mPmB
· PBT: No aplicable.
· mPmB: No aplicable.
· 12.6 Otros efectos adversos No existen más datos relevantes disponibles.

SECCIÓN 13: Consideraciones relativas a la eliminación


· 13.1 Métodos para el tratamiento de residuos
· Recomendación: No debe desecharse con la basura doméstica. No debe llegar al alcantarillado.
( se continua en página 7 )
ES

55.0.4
página: 7/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 6 )

· Embalajes sin limpiar:


· Recomendación: Eliminar conforme a las disposiciones oficiales.

SECCIÓN 14: Información relativa al transporte


· 14.1 Número ONU
· ADR, IMDG, IATA UN1950
· 14.2 Designación oficial de transporte de las Naciones Unidas
· ADR 1950 AEROSOLES
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Clase(s) de peligro para el transporte
· ADR

· Clase 2 5F Gases
· Etiqueta 2.2
· IMDG, IATA

· Class 2.2 Gases


· Label 2.2
· 14.4 Grupo de embalaje
· ADR, IMDG, IATA suprimido
· 14.5 Peligros para el medio ambiente: No aplicable.
· 14.6 Precauciones particulares para los usuarios Atención: Gases
· Número de identificación de peligro (Número
Kemler): -
· Número EMS: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear
of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1
except for division 1.4.
For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2.
For WASTE AEROSOLS:
Segregation as for the appropriate subdivision of class 2.
( se continua en página 8 )
ES

55.0.4
página: 8/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 7 )

· 14.7 Transporte a granel con arreglo al anexo II del


Convenio MARPOL y el Código IBC No aplicable.
· Transporte/datos adicionales:
· ADR
· Cantidades limitadas (LQ) 1L
· Cantidades exceptuadas (EQ) Código: E0
No se permite como cantidad exceptuada
· Categoria de transporte 2
· Código de restricción del túnel D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· "Reglamentación Modelo" de la UNECE: UN 1950 AEROSOLES, 2.2

SECCIÓN 15: Información reglamentaria


· 15.1 Reglamentación y legislación en materia de seguridad, salud y medio ambiente específicas para la
sustancia o la mezcla
· Directiva 2012/18/UE
· Sustancias peligrosas nominadas - ANEXO I ninguno de los componentes está incluido en una lista
· Categoría Seveso P1a EXPLOSIVOS
· Cantidad umbral (toneladas) a efectos de aplicación de los requisitos de nivel inferior 10 t
· Cantidad umbral (toneladas) a efectos de aplicación de los requisitos de nivel superior 50 t
· REGLAMENTO (CE) nº 1907/2006 ANEXO XVII Restricciones: 3
· Directiva 2011/65/UE sobre restricciones a la utilización de determinadas sustancias peligrosas en aparatos
eléctricos y electrónicos - Anexo II
ninguno de los componentes está incluido en una lista
· REGLAMENTO (UE) 2019/1148
· Anexo I - PRECURSORES DE EXPLOSIVOS RESTRINGIDOS (Valor límite superior a efectos de la
concesión de licencias con arreglo al artículo 5, apartado 3)
ninguno de los componentes está incluido en una lista
· Anexo II - PRECURSORES DE EXPLOSIVOS NOTIFICABLES
ninguno de los componentes está incluido en una lista
· Reglamento (CE) no 273/2004 sobre precursores de drogas
ninguno de los componentes está incluido en una lista
· Reglamento (CE) N o 111/2005 por el que establecen normas para la vigilancia del comercio de precursores de
drogas entre la Comunidad y terceros países
ninguno de los componentes está incluido en una lista
· 15.2 Evaluación de la seguridad química: Una evaluación de la seguridad química no se ha llevado a cabo.

SECCIÓN 16: Otra información


Los datos se fundan en el estado actual de nuestros conocimientos, pero no constituyen garantía alguna de
cualidades del producto y no generan ninguna relación jurídica contratual.
( se continua en página 9 )
ES

55.0.4
página: 9/9
Ficha de datos de seguridad
según 1907/2006/CE, Artículo 31
fecha de impresión 12.08.2022 Revisión: 12.08.2022

Nombre comercial: TEFLON SPRAY

( se continua en página 8 )

· Frases relevantes
H225 Líquido y vapores muy inflamables.
H319 Provoca irritación ocular grave.
H336 Puede provocar somnolencia o vértigo.
· Abreviaturas y acrónimos:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosivos – Explosivo inestable
Aerosol 3: Aerosoles – Categoría 3
Flam. Liq. 2: Líquidos inflamables – Categoría 2
Eye Irrit. 2: Lesiones oculares graves o irritación ocular – Categoría 2
STOT SE 3: Toxicidad específica en determinados órganos ( exposición única) – Categoría 3
ES

55.0.4

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