1 Identification: Acc. To OSHA HCS
1 Identification: Acc. To OSHA HCS
1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Information department: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887
2 Hazard(s) identification
· Classification of the substance or mixture
Gases under Pressure - Compressed gas H280 Contains gas under pressure; may explode if heated.
GHS07
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Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 4 Reactivity = 4
· HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
FIRE 4 Fire = 4
REACTIVITY 4 Reactivity = 4
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
67-63-0 propan-2-ol >10-≤25%
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro >2.5-≤10%
4 First-aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
(Contd. on page 3)
US
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(Contd. of page 2)
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
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Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 15.3 %
VOC content: 15.31 %
1,140.9 g/l / 9.52 lb/gal
Solids content: 0.0 %
· Other information No further relevant information available.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
67-63-0 propan-2-ol 3
· NTP (National Toxicology Program)
None of the ingredients is listed.
(Contd. on page 7)
US
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· OSHA-Ca (Occupational Safety Health Administration)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT, ADR, IMDG, IATA UN1950
· UN proper shipping name
· DOT Aerosols, flammable
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· Transport hazard class(es)
· DOT
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· Label 2.2
· ADR
· Class 2 5F Gases
· Label 2.2
· IMDG, IATA
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15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
67-63-0 propan-2-ol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Hazardous Air Pollutants
None of the ingredients is listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value)
67-63-0 propan-2-ol A4
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
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· Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Wash thoroughly after handling.
Wear eye protection / face protection.
Wear personal protective equipment/face protection.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
Store in accordance with local/regional/national/international regulations.
Protect from sunlight. Store in a well-ventilated place.
Dispose of contents/container in accordance with local/regional/national/international regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact:
· Date of preparation / last revision 08/12/2022 / -
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Unstable Explosives: Explosives – Unstable explosive
Gases under Pressure - Compressed gas: Gases under pressure – Compressed gas
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
US
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Safety Data Sheet
according to WHS Regulations
Printing date 12.08.2022 Revision: 12.08.2022
1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
ProSciTech Pty Ltd
11 Carlton Street, Kirwan QLD 4817 Australia
Telephone Number: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays)
Emergency Contact: (07) 4773 9444 - 8:30am - 5:00pm, Monday to Friday (excluding Public Holidays)
Website: ems.proscitech.com
Emgrid Australia Pty. Ltd.
P.O. Box 118
The Patch VIC 3792
Australia
Tel: 03 9752 1785
Fax: 03 9752 1784
Website: www.emgrid.com.au
· Further information obtainable from: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887
2 Hazard(s) Identification
· Classification of the substance or mixture
Press. Gas C H280 Contains gas under pressure; may explode if heated.
GHS07
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(Contd. of page 1)
· Hazard pictograms
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· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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(Contd. of page 3)
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11 Toxicological Information
· Information on toxicological effects
· Acute toxicity
· LD/LC50 values relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation No irritant effect.
· Serious eye damage/irritation Irritating effect.
· Respiratory or skin sensitisation No sensitising effects known.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
12 Ecological Information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· ADG, IMDG, IATA UN1950
(Contd. on page 7)
AU
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· Class 2 5F Gases.
· Label 2.2
· IMDG, IATA
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· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.2
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Australian Inventory of Industrial Chemicals
All ingredients are listed.
· Standard for the Uniform Scheduling of Medicines and Poisons
None of the ingredients is listed.
· Australia: Priority Existing Chemicals
None of the ingredients is listed.
· GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS).
· Hazard pictograms
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· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact:
· Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosives – Unstable explosive
Press. Gas C: Gases under pressure – Compressed gas
Eye Irritation 2A: Serious eye damage/eye irritation – Category 2A
AU
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Page 1/9
Safety Data Sheet
according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022
1 Identification
· Product identifier
· Trade name: TEFLON SPRAY
· Article number: 72619
· Application of the substance / the mixture Laboratory chemicals
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
· Information department: Product safety department
· Emergency telephone number:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887
2 Hazard identification
· Classification of the substance or mixture
Gases Under Pressure - Compressed Gas H280 Contains gas under pressure; may explode if heated.
GHS07
GHS04 GHS07
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(Contd. of page 1)
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 2
4 Fire = 4
2 4 Reactivity = 4
· HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
FIRE 4 Fire = 4
REACTIVITY 4 Reactivity = 4
3 Composition/Information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
67-63-0 propan-2-ol 10-30% w/w *
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro 1-5% w/w *
* Actual concentration ranges are withheld as a trade secret.
4 First-aid measures
· Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
CA
(Contd. on page 3)
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(Contd. of page 2)
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Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
67-63-0 propan-2-ol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rabbit)
Inhalative LC50/4 h 30 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
67-63-0 propan-2-ol 3
(Contd. on page 6)
CA
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· NTP (National Toxicology Program)
None of the ingredients is listed.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· DOT/TDG, ADR, IMDG, IATA UN1950
· UN proper shipping name
· DOT/TDG Aerosols, flammable
· ADR 1950 Aerosols
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· Transport hazard class(es)
· DOT/TDG (Transport dangerous goods):
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(Contd. of page 6)
· Label 2.2
· ADR
· Class 2 5F Gases
· Label 2.2
· IMDG, IATA
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according to HPR, Schedule 1
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15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
67-63-0 propan-2-ol
· TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
· Canadian substance listings:
· Canadian Domestic Substances List (DSL)
All ingredients are listed.
· Canadian Non-Domestic Substances List (NDSL)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%)
67-63-0 propan-2-ol
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS04 GHS07
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
(Contd. on page 9)
CA
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according to HPR, Schedule 1
Printing date 08/12/2022 Reviewed on 08/12/2022
(Contd. of page 8)
· Contact:
· Date of the latest revision of the safety data sheet 08/12/2022 / -
· Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
CA
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022
exploding bomb
GHS01 GHS07
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according to 1907/2006/EC, Article 31
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(Contd. of page 1)
· Precautionary statements
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P373 DO NOT fight fire when fire reaches explosives.
P380 Evacuate area.
P401 Store in accordance with local/regional/national/international regulations.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 12.08.2022 Revision: 12.08.2022
(Contd. of page 2)
· 5.3 Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
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Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
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· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
· Class 2 5F Gases.
(Contd. on page 7)
GB
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· Label 2.2
· IMDG, IATA
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· Qualifying quantity (tonnes) for the application of lower-tier requirements 10 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50 t
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
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GHS01 GHS07
· Signaalwoord Gevaar
· Gevarenaanduidingen
H200 Instabiele ontplofbare stof.
H229 Houder onder druk: kan open barsten bij verhitting.
H319 Veroorzaakt ernstige oogirritatie.
· Veiligheidsaanbevelingen
P305+P351+P338 BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal
minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
P373 NIET blussen wanneer het vuur de ontplofbare stoffen bereikt.
P380 Evacueren.
P401 Opslaan volgens de plaatselijke/regionale/nationale/internationale voorschriften.
P410+P412 Tegen zonlicht beschermen. Niet blootstellen aan temperaturen boven 50 °C/122 °F.
P501 De inhoud en de verpakking verwerken volgens de plaatselijke/regionale/nationale/
internationale voorschriften.
· 2.3 Andere gevaren
· Resultaten van PBT- en zPzB-beoordeling
· PBT: Niet bruikbaar.
· zPzB: Niet bruikbaar.
RUBRIEK 4: Eerstehulpmaatregelen
· 4.1 Beschrijving van de eerstehulpmaatregelen
· Algemene informatie:
Het is mogelijk dat vergiftigingssymptomen pas na vele uren optreden. Om deze reden is medische controle
gedurende minstens 48 uur na een ongeval noodzakelijk.
· Na het inademen:
Frisse lucht toedienen, eventueel beademing, warmte. Wanneer de klachten niet ophouden, een arts raadplegen.
Bij bewusteloosheid ligging en vervoer in stabiele zijligging.
· Na huidcontact: Over het algemeen is het produkt niet prikkelend voor de huid
· Na oogcontact:
De ogen gedurende verscheidene minuten onder stromend water afspoelen terwijl de oogspleet geopend blijft. Bij
aanhoudende klachten een dokter raadplegen.
· Na inslikken: Als de klachten niet minderen, een arts raadplegen
· 4.2 Belangrijkste acute en uitgestelde symptomen en effecten Geen verdere relevante informatie verkrijgbaar.
(Vervolg op blz. 3)
NL
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RUBRIEK 5: Brandbestrijdingsmaatregelen
· 5.1 Blusmiddelen
· Geschikte blusmiddelen:
CO2, bluspoeder of waterstraal. Grotere brand met waterstraal bestrijden of met schuim, dat tegen alcohol
bestand is.
· 5.2 Speciale gevaren die door de stof of het mengsel worden veroorzaakt
Geen verdere relevante informatie verkrijgbaar.
· 5.3 Advies voor brandweerlieden
· Speciale beschermende kleding: Ademhalingstoestel aantrekken.
RUBRIEK 6: Maatregelen bij het accidenteel vrijkomen van de stof of het mengsel
· 6.1 Persoonlijke voorzorgsmaatregelen, beschermingsmiddelen en noodprocedures Niet nodig.
· 6.2 Milieuvoorzorgsmaatregelen: Niet in de riolering/het oppervlaktewater/het grondwater laten terechtkomen.
· 6.3 Insluitings- en reinigingsmethoden en -materiaal:
Besmet materiaal zoals afval volgens punt 13 verwijderen.
Voor voldoende ventilatie zorgen.
· 6.4 Verwijzing naar andere rubrieken
Informatie inzake veilig gebruik - zie hoofdstuk 7.
Informatie inzake persoonlijke beschermingsuitrusting - zie hoofdstuk 8.
Informatie inzake berging - zie hoofdstuk 13.
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· Ontstekingstemperatuur: 425 °C
· Ontledingstemperatuur: Niet bepaald.
· Zelfontbrandingstemperatuur: Het produkt ontbrandt niet uit zichzelf.
· Ontploffingseigenschappen: Ontplofbaar met en zonder lucht.
· Ontploffingsgrenzen:
Onderste: 2 Vol %
Bovenste: 12 Vol %
· Dampspanning bij 25 °C: 5.515,8 hPa
· Dichtheid bij 20 °C: 1,25 g/cm³
· Relatieve dichtheid Niet bepaald.
· Dampdichtheid Niet bepaald.
· Verdampingssnelheid Niet bruikbaar.
· Oplosbaarheid in/mengbaarheid met
Water: Niet resp. gering mengbaar.
· Verdelingscoëfficiënt: n-octanol/water: Niet bepaald.
· Viscositeit
Dynamisch: Niet bepaald.
Kinematisch: Niet bepaald.
· Oplosmiddelgehalte:
Organisch oplosmiddel: 15,3 %
VOC (EG) 96,94 %
Gehalte aan vaste bestanddelen: 0,0 %
· 9.2 Overige informatie Geen verdere relevante informatie verkrijgbaar.
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· 14.3 Transportgevarenklasse(n)
· ADR
· klasse 2 5F Gassen
· Etiket 2.2
· IMDG, IATA
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GHS07
GHS01 GHS07
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(suite de la page 1)
· Conseils de prudence
P305+P351+P338 EN CAS DE CONTACT AVEC LES YEUX: Rincer avec précaution à l'eau pendant plusieurs
minutes. Enlever les lentilles de contact si la victime en porte et si elles peuvent être
facilement enlevées. Continuer à rincer.
P373 NE PAS combattre l'incendie lorsque le feu atteint les explosifs.
P380 Évacuer la zone.
P401 Stocker conformément à la réglementation locale/régionale/nationale/internationale.
P410+P412 Protéger du rayonnement solaire. Ne pas exposer à une température supérieure à 50 °C/122
°F.
P501 Éliminer le contenu/récipient conformément à la réglementation locale/régionale/nationale/
internationale.
· 2.3 Autres dangers
· Résultats des évaluations PBT et vPvB
· PBT: Non applicable.
· vPvB: Non applicable.
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· 5.2 Dangers particuliers résultant de la substance ou du mélange
Pas d'autres informations importantes disponibles.
· 5.3 Conseils aux pompiers
· Equipement spécial de sécurité: Porter un appareil de protection respiratoire.
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(suite de la page 5)
· Sensibilisation respiratoire ou cutanée
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Indications toxicologiques complémentaires:
· Effets CMR (cancérogène, mutagène et toxique pour la reproduction)
· Mutagénicité sur les cellules germinales
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Cancérogénicité Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité pour la reproduction
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité spécifique pour certains organes cibles - exposition unique
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Toxicité spécifique pour certains organes cibles - exposition répétée
Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
· Danger par aspiration Compte tenu des données disponibles, les critères de classification ne sont pas remplis.
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· Classe 2 5F Gaz.
· Étiquette 2.2
· IMDG, IATA
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(suite de la page 8)
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosibles – Explosible instable
Aerosol 3: Aérosols – Catégorie 3
Flam. Liq. 2: Liquides inflammables – Catégorie 2
Eye Irrit. 2: Lésions oculaires graves/irritation oculaire – Catégorie 2
STOT SE 3: Toxicité spécifique pour certains organes cibles (exposition unique) – Catégorie 3
FR
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GHS01 GHS07
· Signalwort Gefahr
· Gefahrenhinweise
H200 Instabil, explosiv.
H229 Behälter steht unter Druck: kann bei Erwärmung bersten.
H319 Verursacht schwere Augenreizung.
· Sicherheitshinweise
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen.
Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P373 KEINE Brandbekämpfung, wenn das Feuer explosive Stoffe/Gemische/Erzeugnisse erreicht.
P380 Umgebung räumen.
P401 Gemäß örtlicher/regionaler/nationaler/internationaler Vorschrift lagern.
P410+P412 Vor Sonnenbestrahlung schützen. Nicht Temperaturen über 50 °C/122 °F aussetzen.
P501 Entsorgung des Inhalts / des Behälters gemäß den örtlichen / regionalen / nationalen/
internationalen Vorschriften.
· 2.3 Sonstige Gefahren
· Ergebnisse der PBT- und vPvB-Beurteilung
· PBT: Nicht anwendbar.
· vPvB: Nicht anwendbar.
ABSCHNITT 4: Erste-Hilfe-Maßnahmen
· 4.1 Beschreibung der Erste-Hilfe-Maßnahmen
· Allgemeine Hinweise:
Vergiftungssymptome können erst nach vielen Stunden auftreten, deshalb ärztliche Überwachung mindestens 48
Stunden nach einem Unfall.
· Nach Einatmen:
Frischluftzufuhr, gegebenenfalls Atemspende, Wärme. Bei anhaltenden Beschwerden Arzt konsultieren.
Bei Bewusstlosigkeit Lagerung und Transport in stabiler Seitenlage.
· Nach Hautkontakt: Im allgemeinen ist das Produkt nicht hautreizend.
· Nach Augenkontakt:
Augen mehrere Minuten bei geöffnetem Lidspalt unter fließendem Wasser spülen. Bei anhaltenden Beschwerden
Arzt konsultieren.
(Fortsetzung auf Seite 3)
DE
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25 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton
· Zusätzliche Hinweise: Als Grundlage dienten die bei der Erstellung gültigen Listen.
· 8.2 Begrenzung und Überwachung der Exposition
· Persönliche Schutzausrüstung:
· Allgemeine Schutz- und Hygienemaßnahmen:
Von Nahrungsmitteln, Getränken und Futtermitteln fernhalten.
Beschmutzte, getränkte Kleidung sofort ausziehen.
Vor den Pausen und bei Arbeitsende Hände waschen.
Berührung mit den Augen vermeiden.
Berührung mit den Augen und der Haut vermeiden.
· Atemschutz:
Bei kurzzeitiger oder geringer Belastung Atemfiltergerät; bei intensiver bzw. längerer Exposition
umluftunabhängiges Atemschutzgerät verwenden.
· Handschutz:
Das Handschuhmaterial muss undurchlässig und beständig gegen das Produkt / den Stoff / die Zubereitung sein.
Aufgrund fehlender Tests kann keine Empfehlung zum Handschuhmaterial für das Produkt / die Zubereitung / das
Chemikaliengemisch abgegeben werden.
Auswahl des Handschuhmaterials unter Beachtung der Durchbruchzeiten, Permeationsraten und der
Degradation.
· Handschuhmaterial
Die Auswahl eines geeigneten Handschuhs ist nicht nur vom Material, sondern auch von weiteren
Qualitätsmerkmalen abhängig und von Hersteller zu Hersteller unterschiedlich. Da das Produkt eine Zubereitung
aus mehreren Stoffen darstellt, ist die Beständigkeit von Handschuhmaterialen nicht vorausberechenbar und muß
deshalb vor dem Einsatz überprüft werden.
· Durchdringungszeit des Handschuhmaterials
Die genaue Durchbruchzeit ist beim Schutzhandschuhhersteller zu erfahren und einzuhalten.
(Fortsetzung auf Seite 5)
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· Klasse 2 5F Gase
· Gefahrzettel 2.2
· IMDG, IATA
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GHS07
GHS01 GHS07
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IT
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· Avvertenza Pericolo
· Indicazioni di pericolo
H200 Esplosivo instabile.
H229 Contenitore pressurizzato: può esplodere se riscaldato.
H319 Provoca grave irritazione oculare.
· Consigli di prudenza
P305+P351+P338 IN CASO DI CONTATTO CON GLI OCCHI: sciacquare accuratamente per parecchi minuti.
Togliere le eventuali lenti a contatto se è agevole farlo. Continuare a sciacquare.
P373 NON utilizzare mezzi estinguenti se l'incendio raggiunge materiali esplosivi.
P380 Evacuare la zona.
P401 Conservare secondo i regolamenti locali/regionali/nazionali/internazionali.
P410+P412 Proteggere dai raggi solari. Non esporre a temperature superiori a 50 °C/122 °F.
P501 Smaltire il prodotto/recipiente in conformità con le disposizioni locali / regionali / nazionali /
internazionali.
· 2.3 Altri pericoli
· Risultati della valutazione PBT e vPvB
· PBT: Non applicabile.
· vPvB: Non applicabile.
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· Componenti con valori limite biologici:
67-63-0 2-propanolo
IBE 40 mg/l
Campioni: urine
Momento del prelievo: f.t.f.s.l
Indicatore biologico: acetone
· Ulteriori indicazioni: Le liste valide alla data di compilazione sono state usate come base.
· 8.2 Controlli dell'esposizione
· Mezzi protettivi individuali:
· Norme generali protettive e di igiene del lavoro:
Tenere lontano da cibo, bevande e foraggi.
Togliere immediatamente gli abiti contaminati.
Lavarsi le mani prima dell'intervallo o a lavoro terminato.
Evitare il contatto con gli occhi.
Evitare il contatto con gli occhi e la pelle.
· Maschera protettiva:
Nelle esposizioni brevi e minime utilizzare la maschera; nelle esposizioni più intense e durature indossare
l'autorespiratore.
· Guanti protettivi:
Il materiale dei guanti deve essere impermeabile e stabile contro il prodotto/ la sostanza/ la formulazione.
A causa della mancanza di tests non può essere consigliato alcun tipo di materiale per i guanti con cui
manipolare il prodotto / la formulazione / la miscela di sostanze chimiche.
Scelta del materiale dei guanti in considerazione dei tempi di passaggio, dei tassi di permeazione e della
degradazione.
· Materiale dei guanti
La scelta dei guanti adatti non dipende soltanto dal materiale bensí anche da altre caratteristiche di qualità
variabili da un produttore a un altro. Poiché il prodotto rappresenta una formulazione di più sostanze, la stabilità
dei materiali dei guanti non è calcolabile in anticipo e deve essere testata prima dell'impiego
· Tempo di permeazione del materiale dei guanti
Richiedere dal fornitore dei guanti il tempo di passaggio preciso il quale deve essere rispettato.
· Occhiali protettivi:
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· Valori LD/LC50 rilevanti per la classificazione:
67-63-0 2-propanolo
Orale LD50 5.045 mg/kg (rat)
Cutaneo LD50 12.800 mg/kg (rabbit)
Per inalazione LC50/4 h 30 mg/l (rat)
· Irritabilità primaria:
· Corrosione/irritazione cutanea Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Lesioni oculari gravi/irritazioni oculari gravi
Provoca grave irritazione oculare.
· Sensibilizzazione respiratoria o cutanea
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Ulteriori dati tossicologici:
· Effetti CMR (cancerogenicità, mutagenicità e tossicità per la riproduzione)
· Mutagenicità delle cellule germinali
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Cancerogenicità Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità per la riproduzione Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità specifica per organi bersaglio (STOT) - esposizione singola
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Tossicità specifica per organi bersaglio (STOT) - esposizione ripetuta
Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
· Pericolo in caso di aspirazione Basandosi sui dati disponibili i criteri di classificazione non sono soddisfatti.
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Scheda di dati di sicurezza
ai sensi del regolamento 1907/2006/CE, Articolo 31
Stampato il: 12.08.2022 Revisione: 12.08.2022
(Segue da pagina 6)
· Classe 2 5F Gas
· Etichetta 2.2
· IMDG, IATA
55.0.4
Pagina: 8/9
Scheda di dati di sicurezza
ai sensi del regolamento 1907/2006/CE, Articolo 31
Stampato il: 12.08.2022 Revisione: 12.08.2022
(Segue da pagina 7)
· Categoria di trasporto 2
· Codice di restrizione in galleria D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOL, 2.2
55.0.4
Pagina: 9/9
Scheda di dati di sicurezza
ai sensi del regolamento 1907/2006/CE, Articolo 31
Stampato il: 12.08.2022 Revisione: 12.08.2022
(Segue da pagina 8)
H336 Può provocare sonnolenza o vertigini.
· Abbreviazioni e acronimi:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Esplosivi – Esplosivo instabile
Aerosol 3: Aerosol – Categoria 3
Flam. Liq. 2: Liquidi infiammabili – Categoria 2
Eye Irrit. 2: Gravi lesioni oculari/irritazione oculare – Categoria 2
STOT SE 3: Tossicità specifica per organi bersaglio (esposizione singola) – Categoria 3
IT
55.0.4
쪽: 1/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
1 화학제품과 회사에 관한 정보
· 제품 식별자
· 제품명: TEFLON SPRAY
· 상품번호: 72619
· 해당 순물질이나 혼합물의 관련 하위용도 및 사용금지용도
· 제품의 권고 용도와 사용상의 제한: TEFLON SPRAY
· 제품의 권고 용도와 사용상의 제한: 실 험 실 화 학품
· 안전데이터표(Safety Data Sheet)내 공급업체 관련 상세 정보
· 제조자/수입자/유통업자 정보:
Electron Microscopy Sciences
1560 Industry Road
USA-Hatfield, PA 19440
Tel: 215-412-8400 Fax: 215-412-8450
email: [email protected]
www.emsdiasum.com
Samchang Commercial Co., Ltd.
Yeo Eui Do
PO Box 1110
Seoul, Korea
Tel: 82 2 703 3040
Fax: 82 2 717 3298
----------------------------------------------------------
Daedok Science, Co. Ltd.
34141 E10 Korea Advanced Institute of Science
Guseong-Dong, Yuseong-gu, Daejeon,
Korea
Phone: 82 42 710 2091
Fax: 82 42 367 0005
Website: www.labsmro.com
· 추가적인 정보 획득 가능: Product safety department
· 비상연락 전화번호:
ChemTrec 1-800-424-9300 Contract CCN7661
1-703-527-3887
2 유해성·위험성
· 순물질 또는 혼합물의 분류
폭발
55.0.4
쪽: 2/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(1 쪽부터계속)
· GHS 그림문자
GHS01 GHS07
· 신호어 위험
· 유해·위험문구
불안정한 폭발성 물질
압력용기: 가열하면 터질 수 있음
눈에 심한 자극을 일으킴
· 예방조치문구
눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
화염이 폭발성 물질에 도달하면 불을 끄려 하지 마시오.
주변 지역의 사람을 대피시키시오.
현지/지역/국가/국제 규정에 따라서 보관 하기
직사광선을 피하고 50℃ 이상의 온도에 노출시키지 마시오.
(지방/지역/국가/국제 규정에 따라) 에 내용물/용기를 폐기하시오.
· 기타 유해성
· PBT(잔류성, 생물농축성, 독성 물질) 및 vPvB(고 잔류성, 고 생물농축성 물질) 평가 결과
· PBT(잔류성, 생물농축성, 독성 물질): 해당사항 없음.
· vPvB(고 잔류성, 고 생물농축성 물질): 해당사항 없음.
3 구성성분의 명칭 및 함유량
· 화 학 적 특 성: 혼합물
· 설명: 무해한 첨 가 물 이 함유된 아래에 열 거 된 물 질 로 만 들 어 진 혼 합 물.
· 위 험 요소:
811-97-2 1,1,1,2-tetrafluoroethane >50-≤100%
67-63-0 propan-2-ol >10-≤25%
인화성 액체 – 구분2, H225; 심한 눈 손상성/눈 자극성 – 구분 2, H319; 특정표적장기 독성
- 1회 노출– 구분3, H336
4 응급조치 요령
· 응급조치요령 내용
· 일 반 적 정보:
중 독 증 상 은 몇 시 간이 지난 뒤에 발생할 수 있다. 따라서 사고가 발 생 한 후에 적 어 도 48 시 간동안은 의료진의 관찰을 받
아 야 한 다.
· 흡입했을 때:
신 선 한 공 기를 쐬고 , 필요할 경우에는 산 소 호 흡 기의 도움을 받는다 . 환자를 따뜻하게 하고 , 증상이 지속될 경우에는
의료진의 도움을 구한다.
환자가 의식을 잃었을 경우에는 안전한 자세에서 환자를 운반한다.
· 피부에 접촉했을 때: 일 반 적 으 로 이 제품은 피 부 에 자 극 적 이 지 않 다.
· 눈에 들어갔을 때: 흐르는 물에 눈을 몇분동안 씻어내고나서, 증상이 지속될 경우에는 의사와 상담한 다
· 먹었을 때: 증상이 지 속될 경우에는 의사와 상 담 한 다.
· 기타 의사의 주의사항:
· 가장 중요한 급∙만성 증상 및 영향 추가적인 정보가 존재하지 않습니다.
(3 쪽에계속)
KR
55.0.4
쪽: 3/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(2 쪽부터계속)
· 즉각적인 의료처치 및 특별치료가 필요함을 시사하는 징후 추가적인 정보가 존재하지 않습니다.
5 폭발·화재시 대처방법
· 소화제
· 적절한 소화제:
이 산 화 탄 소, 진 화 용 석 회 가 루 또 는 물 방 사를 사용하고, 더 큰 화재는 물 을 분 사 하 거 나 알 코 올 이 함 유 된 거 품 으
로 끈 다.
· 본 화학물질이나 혼합물에서 발생하는 특별 유해성 추가적인 정보가 존재하지 않습니다.
· 소방관에 대한 권고사항
· 화재 진압 시 착용할 보호구 및 예방조치: 호흡보호장비설치.
6 누출 사고 시 대처방법
· 개인적 예방조치, 보호장비 및 응급처치 절차 필요없음.
· 환경 관련 예방조치: 하수도망/해수면위의물/지하수로도달하지않게한다.
· 밀폐 및 정화 방법과 소재:
항목 13에 따라 오염된 물질을 쓰레기로 처분한다.
충분한 환기가 되도록 한다.
· 타 섹션 참조
안 전 관 리 에 대한 정보는 제7 장 을 참고하시오.
개 인 보 호 장 비에 대한 정보는 제8 장 을 참고하시 오.
쓰 레 기 처 리 에 대한 정보는 제13 장 을 참고하시 오.
7 취급 및 저장방법
· 취급:
· 안전 취급을 위한 예방조치 작업장에서는통풍이잘되고/습기제거가잘되게주의한다.
· 화재 및 폭발 사고 예방대책에 관한 정보:
열로부터보호한다.
용기는압축되어있다. 태양광선이나 50°C 이상의온도로부터보호한다. 역시사용후에는강제적으로개봉하거나소각시키지않는다 .
화염에가까이하거나타고있는물건에분사하지않는다 .
· 혼합위험성 등 안전 저장 조건
· 보관:
· 안전한 저장 방법: 압력가스상자보관에관한관청의지시에주의해야한다 .
· 하나의 공동 보관 시설에 대한 보관 관련 정보: 필 요없음
· 보 관 조 건 에 관 한 추가적인 정보:
용기를새지않게밀폐한채보관한다.
열이나직사광선으로부터보호한다.
· 구체적 최종 사용자 추가적인 정보가 존재하지 않습니다.
8 노출방지 및 개인보호구
· 첨단시설 디자인에 대한 추가정보: 더 이 상 의 자료는 없음. 항 목 7 을 참고하시 오.
· 통제 변수
· 화학물질의 노출기준, 생물학적 노출기준 등:
811-97-2 1,1,1,2-tetrafluoroethane
WEEL (US) 장기간의값: 1000 ppm
(4 쪽에계속)
KR
55.0.4
쪽: 4/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(3 쪽부터계속)
67-63-0 propan-2-ol
OELV (KR) 단기간의값: 400 ppm
장기간의값: 200 ppm
PEL (US) 장기간의값: 980 mg/m³, 400 ppm
REL (US) 단기간의값: 1225 mg/m³, 500 ppm
장기간의값: 980 mg/m³, 400 ppm
TLV (US) 단기간의값: 400 ppm
장기간의값: 200 ppm
BEI, A4
· 생물학적 허용값을 갖는 원료:
67-63-0 propan-2-ol
BEI (US) 40 mg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Acetone (background, nonspecific)
· 추 가 정보: 제 조 할 당시에 유 효 한 목 록을 기초로 사용했다.
· 노출 통제
· 개인 보호구
· 일반적보호조치및위생조치:
식 료 품, 음 료 수와 사 료 로 부 터 멀 리 떨 어 뜨 려 놓 는 다.
더 러 워 지 거 나 음 료 수 가 묻 은 옷 은 즉 시 탈의한다.
휴 식 전 이 나 작업이 끝날때마다 손을 씻는다.
눈과의 접 촉 을 피 한 다.
눈 과 피 부와의 접 촉 은 피 한 다.
· 호흡기 보호:
단 시 간 또 는 경 미 한 오 염 의 경 우에는 호 흡 여 과 기 를 사 용 한 다. 심각한 또 는 장 기 간 노 출시에 는 호 흡 보 호 장 비
를 사 용 한 다.
· 손 보호:
장갑재질은제품 / 원료 / 조제를투과시키지않아야하고, 내구성이있어야한다.
테 스 트 를 하 지 않 았기 때문에 제 품 / 조 제 / 화 학 혼 합 물에 적합한 장갑재질에 대한 추천이 없다.
투과 시 간, 침 투 율 과 저하를 고 려해서 장 갑 재 료를 선택한다.
· 장갑의재료
적합한장갑의선정은재질차이뿐아니라품질기준의차이도고려하여이루어져야하고제조업종에따라서도다르게선정되어야한다 .
제품은다양한재료로부터의조제로이루어지는것이기때문에 , 장갑재질의안정성은사전에예측되어질수있는것이아니고 ,
반드시사용전에 (그안전성이) 체크되어져야한다.
· 장 갑 재 료 의 투과시 간 정확한관통시간은보호장갑제조자에의하여인지되고 , 준수되어야한다.
· 눈 보호:
꽉조이는보안경
9 물리화학적 특성
· 기본 물리 및 화학적 특성에 대한 정보
· 일반정보
· 외형
물리적 상태: 에어로졸
색: 하얀
(5 쪽에계속)
KR
55.0.4
쪽: 5/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(4 쪽부터계속)
· 냄새: 에테르종류의
· 후각역치 알맞지않다.
· pH 의경우 20 °C: 7
· 상태변화
녹는점/어는점: 맞지않는
초기 끓는점과 끓는점 범위: 82 °C
· 인화점: 12 °C
· 인화성(고체, 기체): 해당사항 없음.
· 점화온도: 425 °C
· 분해 온도: 알맞지않다.
· 자기점화: 이제품은자연발화성이없다.
· 폭발위험: 공기가있던없던폭발가능성이있는
· 인화 또는 폭발 범위의 상한/하한
아래로: 2 Vol %
위로: 12 Vol %
· 증기압 의경우 25 °C: 5,515.8 hPa
· 밀도 의경우 20 °C: 1.25 g/cm³
· 비중: 알맞지않다.
· 증기밀도: 알맞지않다.
· 증발 속도: 해당사항 없음.
· 용해도:
물: 각각의경우에따라서는거의혼합할수없는
· 점도:
역학성: 알맞지않다.
동점성: 알맞지않다.
· 용매내용물
유기용매: 15.3 %
VOC (EU) 96.94 %
고체의 함량: 0.0 %
· 기타 정보 추가적인 정보가 존재하지 않습니다.
10 안정성 및 반응성
· 반응성 추가적인 정보가 존재하지 않습니다.
· 화학적 안정성
· 화학적 안정성 및 유해 반응의 가능성 / 피해야 할 조건: 규정에따라사용할경우해체는없다
· 유해반응 가능성 위험한반응으로는알려지지않았다.
· 피해야 할 조건 추가적인 정보가 존재하지 않습니다.
· 혼합 금지 물질: 추가적인 정보가 존재하지 않습니다.
· 유해분해물질: 위험성있는분해물들은알려지지않았다.
KR
(6 쪽에계속)
55.0.4
쪽: 6/9
물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(5 쪽부터계속)
11 독성에 관한 정보
· 독성학적 영향에 대한 정보
· 급성 독성:
· LD/LC50-수치에 따른 분류:
67-63-0 propan-2-ol
구강의 LD50 5,045 mg/kg (rat)
피부의 LD50 12,800 mg/kg (rabbit)
흡입의 LC50/4 h 30 mg/l (rat)
· 일차적 자극 효과:
· 피부 부식성 또는 자극성: 무자극
· 심한 눈 손상 또는 자극성: 자극
· 감각화: 민감한영향이없는것으로알려져있다.
· 추 가 적 인 독성에 관한 정보:
이제품은유럽공동체의공동분류원칙의합법적인절차에근거하여최근에발효된원고에서아래위험들의사전준비에대하여제시하고있
다.
건강에해로운
자극적인
12 환경에 미치는 영향
· 독성
· 수생독성: 추가적인 정보가 존재하지 않습니다.
· 지속성 및 분해성 추가적인 정보가 존재하지 않습니다.
· 환 경 시스템에서의 행 동:
· 생물농축 잠재성 추가적인 정보가 존재하지 않습니다.
· 토양내 이동성 추가적인 정보가 존재하지 않습니다.
· 추가적인 생태학 정보:
· 일반 특징:
수질오염등급 1 (자체등급분류): 약하게수질오염이된
희석시키지않은채대량으로지하수나 , 하천으로그리고하수도망에도달하지않게한다 .
· PBT(잔류성, 생물농축성, 독성 물질) 및 vPvB(고 잔류성, 고 생물농축성 물질) 평가 결과
· PBT(잔류성, 생물농축성, 독성 물질): 해당사항 없음.
· vPvB(고 잔류성, 고 생물농축성 물질): 해당사항 없음.
· 기타 부작용 추가적인 정보가 존재하지 않습니다.
13 폐기시 주의사항
· 폐기물 처리 방법
· 권고: 생활쓰레기와함께처리되어서는안된다. 하수도망으로유입되서는안된다.
· 비위생적 포장:
· 권고: 당국의지침에입각한쓰레기처리.
14 운송에 필요한 정보
· 유엔 번호
· ADR, IMDG, IATA UN1950
(7 쪽에계속)
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물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(6 쪽부터계속)
· UN 적정 선적명
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 교통 위험 클래스
· ADR
· 등급 2 5F 가스
· 위험물 라벨 2.2
· IMDG, IATA
· Class 2.2 가스
· Label 2.2
· 용기등급
· ADR, IMDG, IATA 누락되다
· 운 송/추가 정보:
· ADR
· 한정 수량 (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· 운송 구분 2
· 터널 제한 코드 D
(8 쪽에계속)
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물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(7 쪽부터계속)
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "모범 규제": UN 1950 AEROSOLS, 2.2
15 법적 규제현황
· 산업안전보건법에 의한 규제:
· 제조 등 금지물질:
어떠한내용물도목록화되어있지않다
· 허가대상물질:
어떠한내용물도목록화되어있지않다
· 관리대상유해물질:
67-63-0 propan-2-ol
· 작업환경측정 대상 유해인자
67-63-0 propan-2-ol 1A79
· 특수건강진단 대상 유해인자
67-63-0 propan-2-ol 1A74
· 해당 순물질 또는 혼합물에 대한 안전, 보건 및 환경 규제/법률 추가적인 정보가 존재하지 않습니다.
· Korean Existing Chemical Inventory
811-97-2 1,1,1,2-tetrafluoroethane KE-33426
67-63-0 propan-2-ol KE-29363
65530-85-0 Poly-TFE, Alpha-(cyclohexylmethyl)-omega-hydro KE-09252
· 화학물질관리법
· 사고대비물질
어떠한내용물도목록화되어있지않다
· 금지물질
어떠한내용물도목록화되어있지않다
· 제한물질
어떠한내용물도목록화되어있지않다
· 유독물질
어떠한내용물도목록화되어있지않다
· 허가물질
어떠한내용물도목록화되어있지않다
· 위험물안전관리법 (위험물 및 지정수량) 제 4: 400 리터
· 등록 또는 신고 면제대상 화학물질
어떠한내용물도목록화되어있지않다
· 중점관리물질(제2조 관련)
어떠한내용물도목록화되어있지않다
· GHS 라벨 요소 본 제품은 화학물질의 분류 및 표기에 관한 국제조화시스템(GHS)에 따라 분류 및 표기되었습니다.
(9 쪽에계속)
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물질안전보건자료
GHS에 따라
인쇄일자: 2022.08.12 개정: 2022.08.12
(8 쪽부터계속)
· GHS 그림문자
GHS01 GHS07
· 신호어 위험
· 유해·위험문구
불안정한 폭발성 물질
압력용기: 가열하면 터질 수 있음
눈에 심한 자극을 일으킴
· 예방조치문구
눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
화염이 폭발성 물질에 도달하면 불을 끄려 하지 마시오.
주변 지역의 사람을 대피시키시오.
현지/지역/국가/국제 규정에 따라서 보관 하기
직사광선을 피하고 50℃ 이상의 온도에 노출시키지 마시오.
(지방/지역/국가/국제 규정에 따라) 에 내용물/용기를 폐기하시오.
· 화학물질 안전성 평가: 화학물질 안전성 평가가 수행되지 않음
16 그 밖의 참고사항
이보고는우리지식에대한오늘날의상태에대하여평가하고있다 ,
하지만이보고서는생산특성에관한보증은기술하지않았으며계약적인법률관계에기반을두고있지도않다
· 담당자:
· 최초 작성일자: 2022.08.12
· 개정 횟수 및 최종 개정일자: 1 / 2022.08.12
· 약어와 두문자어:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
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GHS07
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· Pictogramas de peligro
GHS01 GHS07
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· 4.3 Indicación de toda atención médica y de los tratamientos especiales que deban dispensarse inmediatamente
No existen más datos relevantes disponibles.
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· Componentes con valores límite admisibles que deben controlarse en el puesto de trabajo:
67-63-0 2-propanol
LEP Valor de corta duración: 1000 mg/m³, 400 ppm
Valor de larga duración: 500 mg/m³, 200 ppm
VLB, s
· Componentes con valores límite biológicos:
67-63-0 2-propanol
VLB 40 mg/l
Muestra: orina
Momento de Muestero: Final de la semana laboral
Indicador Biológico: Acetona
· Indicaciones adicionales: Como base se han utilizado las listas vigentes en el momento de la elaboración.
· 8.2 Controles de la exposición
· Equipo de protección individual:
· Medidas generales de protección e higiene:
Mantener alejado de alimentos, bebidas y alimentos para animales.
Quitarse de inmediato la ropa ensuciada o impregnada.
Lavarse las manos antes de las pausas y al final del trabajo.
Evitar el contacto con los ojos.
Evitar el contacto con los ojos y la piel.
· Protección respiratoria:
Si la exposición va a ser breve o de poca intensidad, colocarse una máscara respiratoria. Para una exposición
más intensa o de mayor duración, usar un aparato de respiración autónomo.
· Protección de manos:
El material del guante deberá ser impermeable y resistente al producto / substancia / preparado.
Ante la ausencia de tests específicos, no se puede recomendar ningún material específico para guantes de
protección contra el producto / preparado / mezcla de substancias químicas.
Selección del material de los guantes en función de los tiempos de rotura, grado de permeabilidad y degradación.
· Material de los guantes
La elección del guante adecuado no depende únicamente del material, sino también de otras características de
calidad, que pueden variar de un fabricante a otro. Teniendo en cuenta que el producto está fabricado a partir de
diferentes materiales, su calidad no puede ser avaluada de antemano, de modo que los guantes deberán ser
controlados antes de su utilización.
· Tiempo de penetración del material de los guantes
El tiempo de resistencia a la penetración exacto deberá ser pedido al fabricante de los guantes. Este tiempo debe
ser respetado.
· Protección de ojos:
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· Clase 2 5F Gases
· Etiqueta 2.2
· IMDG, IATA
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· Frases relevantes
H225 Líquido y vapores muy inflamables.
H319 Provoca irritación ocular grave.
H336 Puede provocar somnolencia o vértigo.
· Abreviaturas y acrónimos:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Unst. Expl.: Explosivos – Explosivo inestable
Aerosol 3: Aerosoles – Categoría 3
Flam. Liq. 2: Líquidos inflamables – Categoría 2
Eye Irrit. 2: Lesiones oculares graves o irritación ocular – Categoría 2
STOT SE 3: Toxicidad específica en determinados órganos ( exposición única) – Categoría 3
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