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Roundup UltraMAX SDS

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0% found this document useful (0 votes)
250 views11 pages

Roundup UltraMAX SDS

Uploaded by

taufiq hidayat
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 11

Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

SECTION 1: IDENTIFICATION OF THE MATERIAL AND SUPPLIER

1.1 Product identifier


Trade name Roundup UltraMAX® Herbicide
Product code (UVP) 62289447

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Herbicide
1.3 Details of the supplier of the safety data sheet
Supplier Bayer Cropscience Pty Ltd
ABN 87 000 226 022
Level 4, 109 Burwood Rd
Hawthorn 3122
Victoria
Australia
Telephone (03) 9248 6888
Telefax (03) 9248 6800
Responsible Department 1800 804 479 Technical Information Service
Website www.crop.bayer.com.au

1.4 Emergency telephone no.


Emergency telephone no. 1800 033 111 IXOM Operations Pty Ltd

SECTION 2. HAZARDS IDENTIFICATION


2.1 Classification of the substance or mixture
Classification in accordance with Australian GHS Regulation
Chronic aquatic toxicity: Category 2
H411 Toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling according to specific Australian legislation
No hazard label for supply/use required.

2.3 Other hazards


No additional hazards known beside those mentioned.

1/1
Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature

Potassium salt of Glyphosate 698 g/l


Soluble concentrate (SL)
Chemical name CAS-No. Concentration [%]
Potassium salt of glyphosate 70901-12-1 51.16
Other ingredients (non-hazardous) to 100%

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures


If poisoning occurs, immediately contact a doctor or Poisons Information Centre (telephone 13
General advice
11 26), and Move out
follow the advice given. of dangerous
Show area.Data
this Safety PlaceSheet
and transport
to the victim
doctor.in stable position
(lying sideways). Remove contaminated clothing immediately and dispose
of safely.
Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or poison
control center immediately.
Skin contact Wash off immediately with plenty of water for at least 15 minutes. Take off
contaminated clothing and shoes immediately. Get medical attention if
irritation develops and persists.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least
15 minutes. Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye. Get medical attention if irritation develops and
persists.
Ingestion Call a physician or poison control center immediately. Rinse out mouth and
give water in small sips to drink. DO NOT induce vomiting unless directed to
do so by a physician or poison control center. Never give
anything by mouth to an unconscious person. Do not leave victim
unattended.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms To date no symptoms are known.
4.3 Indication of any immediate medical attention and special treatment needed
Risks This product is not a cholinesterase inhibitor.
Treatment Treatment with atropine and oximes is not indicated. Appropriate
supportive and symptomatic treatment as indicated by the patient's
condition is recommended. There is no specific antidote.

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Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

SECTION 5. FIRE FIGHTING MEASURES

5.1 Extinguishing media


Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Unsuitable High volume water jet

5.2 Special hazards In the event of fire the following may be released: Carbon monoxide (CO),
arising from the Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides of phosphorus
substance or mixture
5.3 Advice for firefighters
In the event of fire and/or explosion do not breathe fumes. In the event of fire,
Special protective wear self-contained breathing apparatus.
equipment for firefighters
Contain the spread of the fire-fighting media. Do not allow water to
Further information come into direct contact with the product.

Hazchem Code •3Z

SECTION 6. ACCIDENTAL RELEASE MEASURES


6.1 Personal precautions, protective equipment and emergency procedures
Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Collect and transfer the product into a properly
labelled and tightly closed container. Clean contaminated floors and objects
thoroughly, observing environmental
regulations.

6.4 Reference to other Information regarding safe handling, see section 7.


sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7. HANDLING AND STORAGE


7.1 Precautions for safe handling
Advice on safe handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation.
Hygiene measures Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, using the toilet or
applying cosmetics.
Remove Personal Protective Equipment (PPE) immediately after handling
this product. Remove soiled clothing immediately and clean

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Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

thoroughly before using again. Wash thoroughly and put on clean


clothing. Keep working clothes separately. Garments that cannot be
cleaned must be destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage Store in original container. Store in a cool, dry place and in such a manner as to
areas and containers prevent cross contamination with other crop protection products, fertilizers,
food, and feed. Store in a place accessible by authorized persons only. Reacts
with galvanised steel or unlined mild steel to produce hydrogen, a highly
flammable gas that could explode. Protect from freezing. Partial crystallization
may occur on prolonged storage below the minimum storage temperature.
Freezing will affect the physical condition but will not damage the material.
Thaw and mix before using.

Advice on common storage Keep away from food, drink and animal feedingstuffs.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION


8.1 Control parameters
No known occupational limit values.

8.2 Exposure controls

Respiratory protection Respiratory protection is not required under anticipated


circumstances of exposure.
Respiratory protection should only be used to control residual risk of short
duration activities, when all reasonably practicable steps have been taken to
reduce exposure at source e.g. containment and/or local extract ventilation.
Always follow respirator manufacturer's instructions regarding wearing and
maintenance.

Hand protection Please observe the instructions regarding permeability and breakthrough
time which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the product is used,
such as the danger of cuts, abrasion, and the contact time.
Wash gloves when contaminated. Dispose of when contaminated inside,
when perforated or when contamination on the outside cannot be removed.
Wash hands frequently and always before eating,
drinking, smoking or using the toilet.

Material Nitrile rubber


Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index Class 6
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 5 suit.
If there is a risk of significant exposure, consider a higher protective type
suit.
Wear two layers of clothing wherever possible. Polyester/cotton or

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Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

cotton overalls should be worn under chemical protection suit and


should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.
General protective measures If product is handled while not enclosed, and if contact may occur:
Complete suit protecting against chemicals
In normal use and handling conditions please refer to the label
and/or leaflet. In all other cases the above mentioned
recommendations would apply.

Engineering Controls
Advice on safe handling Avoid contact with skin, eyes and clothing. Ensure adequate ventilation.

SECTION
9.1 9. PHYSICAL
Information AND CHEMICAL
on basic physical PROPERTIES
and chemical properties

Form Liquid, clear, free from foreign matter


Colour blue
Odour odourless
Odour Threshold No data available
pH 4.3 - 4.8 (6.0 %) (23 °C) (deionized water)
Melting point/range No data available
Boiling Point No data available
Flash point does not flash
Flammability Not applicable
Auto-ignition temperature No data available
Thermal decomposition No data available

Minimum ignition energy No data available


Self-accelarating No data available
decomposition temperature
(SADT)
Upper explosion limit No data available
Lower explosion limit No data available
Vapour pressure No data available
Evaporation rate No data available
Relative vapour density No data available
Relative density 1.379
Density ca. 1.37 g/cm³ (20 °C)

Water solubility soluble

5/1
Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

Partition coefficient: n- Potassium salt of glyphosate: log Pow: < -3.2 (25 °C)
octanol/water

Viscosity, dynamic No data available


Viscosity, kinematic No data available
Oxidizing properties No oxidizing properties
Explosivity Not explosive
9.2 Other information Further safety related physical-chemical data are not known.

SECTION 10. STABILITY AND REACTIVITY


10.1 Reactivity Stable under normal conditions.
10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of Reacts with galvanised steel or unlined mild steel to produce hydrogen,
hazardous reactions a highly flammable gas that could explode.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Galvanised steel, Carbon steel, Unlined mild steel
Store only in the original container.

10.6 Hazardous Hazardous products of combustion: see section 5.


decomposition products

SECTION 11. TOXICOLOGICAL INFORMATION


11.1 Information on toxicological effects
Acute oral toxicity LD50 (Rat) > 5,000 mg/kg
Test conducted with a similar formulation.
No mortality.
Acute inhalation toxicity LC50 (Rat) > 0.95 mg/l
Exposure time: 4 h
Highest attainable concentration.
No mortality.
Test conducted with a similar formulation.
Acute dermal toxicity LD50 (Rat) > 4,000 mg/kg
Test conducted with a similar formulation.
No mortality.
Skin corrosion/irritation Slight irritant effect - does not require labelling. (Rabbit)
Test conducted with a similar formulation.
Serious eye damage/eye Slight irritant effect - does not require labelling. (Rabbit)

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Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

irritation Test conducted with a similar formulation.


Respiratory or skin Skin: Non-sensitizing. (Guinea pig) OECD
sensitisation Test Guideline 406, Buehler test Test
conducted with a similar formulation.
Assessment mutagenicity
Potassium salt of glyphosate is not considered mutagenic.
Assessment carcinogenicity
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment toxicity to reproduction
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment developmental toxicity
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – single exposure
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Potassium salt of glyphosate did not cause specific target organ toxicity in experimental animal studies.
Aspiration hazard
Based on available data, the classification criteria are not met.

Information on likely routes of exposure


Harmful if inhaled.
May cause skin irritation.
May cause eye irritation.
Harmful if swallowed.

Early onset symptoms related to exposure


Refer to Section 4

Delayed health effects from exposure


Refer to Section 11

Exposure levels and health effects


Refer to Section 4

Interactive effects
Not known

When specific chemical data is not available


Not applicable

Mixture of chemicals
Refer to Section 2.1
Further information
No further toxicological information is available.

7/1
Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Lepomis macrochirus (Bluegill sunfish)) 5.2 mg/l Test
conducted with a similar formulation.
LC50 (Cyprinus carpio (Carp)) 4.0 mg/l Test
conducted with a similar formulation.
Toxicity to aquatic EC50 (Daphnia (water flea)) 8.0 mg/l Test
invertebrates conducted with a similar formulation.
Toxicity to aquatic plants ErC50 (Raphidocelis subcapitata (freshwater green alga)) 1.4 mg/l Growth
rate; Exposure time: 72 h
Test conducted with a similar formulation.
NOEC (Raphidocelis subcapitata (freshwater green alga)) 0.22 mg/l Growth
rate; Exposure time: 72 h
Test conducted with a similar formulation.
12.2 Persistence and degradability
Biodegradability Potassium salt of glyphosate:
Not readily biodegradable.
Koc Potassium salt of glyphosate: Koc: 884
12.3 Bioaccumulative potential
Bioaccumulation Potassium salt of glyphosate: Bioconcentration factor (BCF) < 1
12.4 Mobility in soil
Mobility in soil Potassium salt of glyphosate: Variable, depends on temperature, soil
type, soil moisture, soil pH and organic matter content.
12.5 Other adverse effects
Additional ecological No further ecological information is available.
information

SECTION 13. DISPOSAL CONSIDERATIONS


Triple-rinse containers before disposal. Add rinsings to spray tank. Do not dispose of undiluted chemicals on site. If
recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, break,
crush, or puncture and deliver empty packaging to an approved waste management facility. If an approved waste
management facility is not available, bury the empty packaging 500 mm below the surface in a disposal pit
specifically marked and set up for this purpose, clear of waterways, desirable vegetation and tree roots, in
compliance with relevant Local, State or Territory government regulations. Do not burn empty containers or
product.
Do not reuse container for any other purpose.

SECTION 14. TRANSPORT INFORMATION


ADG

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Safety Data Sheet

Roundup UltraMAX® Herbicide 1/11


Version 1 / AUS Revision Date: 11.01.2024
102000039925 Print Date: 11.01.2024

UN number 3082
Transport hazard class(es) 9
Subsidiary Risk None
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION)
Hazchem Code •3Z
AU01: Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this
Code when transported by road or rail in;
a) packagings that do not incorporate a receptacle exceeding 500 kg(L); or
b) IBCs

IMDG
UN number 3082
Transport hazard class(es) 9
Subsidiary Risk None
Packaging group III
Marine pollutant YES
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION)
IATA
UN number 3082
Transport hazard class(es) 9
Subsidiary Risk None
Packaging group III
Environm. Hazardous Mark YES
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION )

SECTION 15. REGULATORY INFORMATION


Registered according to the Agricultural and Veterinary Chemicals Code Act 1994
Australian Pesticides and Veterinary Medicines Authority approval number: 68506

SUSMP classification (Poison Schedule)

Schedule 5 (Standard for the Uniform Scheduling of Medicines and Poisons)

SECTION information
Trademark 16. OTHER INFORMATION
Roundup UltraMAX® is a Registered Trademark of the Bayer Group.

Abbreviations and acronyms


ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by

9/1
Safety Data

Roundup UltraMAX® 10/


Herbicide Revision Date: 11.01.2024
Print Date: 11.01.2024

Road
ATE Acute toxicity estimate
AU OEL Australia. OELs. (Adopted National Exposure Standards for Atmospheric
Contaminants in the Occupational Environment)
CAS-Nr. Chemical Abstracts Service number
CEILING Ceiling Limit Value
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
OES BCS OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure
Standard"
PEAK PEAK: Exposure Standard - Peak means a maximum or peak airborne concentration
of a particular substance determined over the shortest analytically practicable period of time
which does not exceed 15 minutes.
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
SK-SEN Skin sensitiser
SKIN_DES SKIN_DES: Skin notation: Absorption through the skin may be a significant source of
exposure.
STEL STEL: Exposure standard - short term exposure limit (STEL): A 15 minute TWA exposure
which should not be exceeded at any time during a working day even if the eight-hour TWA
average is within the TWA exposure standard. Exposures at the STEL should not be longer
than 15 minutes and should not be repeated more than four times per day. There should be at
least 60 minutes between successive exposures at the
STEL.
TWA TWA: Exposure standard - time-weighted average (TWA): The average airborne concentration of
a particular substance when calculated over a normal eight-hour
working day, for a five-day working week.
TWA Time weighted average
UN United Nations
WHO World health organisation

This SDS summarises our best knowledge of the health and safety hazard information of the product and how to
safely handle and use the product in the workplace. Each user should read this SDS and consider the information in
the context of how the product will be handled and used in the workplace including in conjunction with other
products.

10/1
Safety Data

Roundup UltraMAX® 10/


Herbicide Revision Date: 11.01.2024
Print Date: 11.01.2024

Changes since the last version are highlighted in the margin. This version replaces all previous versions.

11/1

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