ADDITIVE SECONDARY STANDARD

Date of
S.No. Standard Detail Concentration (ppm)
Preparation
1 PP Cast 29.05.18 200, 400, 600, 800, 1000, 1200

2 PP DHT4A 04.05.18 75, 150, 250, 350, 500

SILICA=2000, 2300, 2600, 2900, 3200

3 PP SILICA + SLIP 27.05.18
SLIP=1400, 1700, 1900, 2100, 2500

SILICA=50, 100, 150, 200, 500

PE SILICA + SLIP
4 28.05.18
( LOW )
SLIP=50, 100, 150, 200, 300

SILICA=1000, 1200, 1400, 1600, 1800

PE SILICA + SLIP
5 31.05.18
( HIGH)
SLIP=400, 600, 800, 1000, 1200

6 PP DSTDP 04.06.18 2000, 2500, 3000, 3500, 4000

7 PP MILLARD 10.08.2018 1000, 1500, 1750, 2000, 2250, 2500, 3100

8 PP HPN20E 05.06.18 0, 50, 100, 200, 300, 400

0, 200, 400, 600, 800, 1000, 1200, 1400, 1600, 1800,

9 PE (CAST + I-168 + Znst 13.07.2018
2000, 2200, 2400, 2600, 2800, 3000, 3200
NDARD

Availability

Material

Material

MATERIAL+SPECIMEN

MATERIAL+SPECIMEN

MATERIAL+SPECIMEN

Material

Material

Material

Material
 Additive in PP Plant (AS ON DATED-16.12.15)
Sr.No. Additive Inst. Method name Cal. Point
BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M
1 AO3114
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M

1 I-1010 250, 500, 1000
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M

2 I-168
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

3 Cast BY- XRF PP_Cast_17092015 0 ,200, 243, 400, 500, 600, 1000, 1200

4 DHT4A BY -XRF PP_DHT4A_50815 0,100,200,250,400,600

5 NaBz
BY- XRF SODIUM BENZOATE 27062013 0,500,700,900,1000

6 DST-DP
BY- XRF HD_DSTDP_12112015 0,1000,1500,1800,2100,2500

BY - ELSD (HPLCGMS-90METHOD 05.11.15.M 10,20,50,100,200

7 GMS-90
0,900,1000,1430,1630,1650,1990,2000,2050,
8 Erucamide
BY - FTIR PP EUEECAMIDE 1600-2000PPM.221211-3
2338,2500,2700,3000,3500

9 Silica BY -XRF PP SILICA 140415 0,1500,2000,2300,2600,3000,3500

10
HPN-20E BY - XRF HPN20E_23092015 0,51,68,85,102,250

11
ULTRNOX-627 BY - XRF PP_ULTRANOX627_180813 0,800,1000,1200

0,405,965,1139,1344,1653,1815,1988,2229,2
12
Millard BY -FTIR MILLARD 080814
517
13 Na27 BY -XRF PP_Na27_100912 0,43.4,43.9,50.3,55.2,60.9
 R.T. - 9.1

R.T. - 12.15

R.T. - 26.12

Ca

Mg

Na

R.T 2.10

Region - (1612.83 - 1791.98)

Si

Zn

Region - ( 620.0 - 635.0)

Na
 Additive in SWING Plant (AS ON DATED-16.12.15)
Sr.No. Additive Inst. Method Cal. Point
BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M
1 I-1010
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M

2 I-1330
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M

3 I-1076
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

BY-HPLC-I ADDITIVES SWING PLANT-20µL.04.05.15.M

4 I-168
BY-HPLC-II ADDITIVES SWING PLANT-20µL.09.05.15.M

UV-1 By - FTIR SW(UV8D)080M60U-090113-1 0,500,800,880,950,1100

5

UV-7 By - FTIR Copy OF SW(UV8D)080M60USM080113 0,1800,2400,2590,2790,3000

6

7 SILICA(LOW) By - XRF PE SILICA 040513 0,110,400,800,1300

By - FTIR SW SILICA 150613 0,100,400,800,1300,1700,2000,2240,2350

8 SILICA(HIGH)

By - XRF PE SILICA 240313 0,1300,1700,2000,2240,2500,3000

EURUCAMIDE(LOW) BY - FTIR SWING EURACAMIDE LOW 0,100,150,300,426,620

9

EURUCAMIDE(HIGH) BY - FTIR SW EURACAMIDE 250512 0,350,470,540,640,775,855,950

10

ULTRA SONIC - (if density <0.930) sample take 3.0 - 5.0gm in 50ml n-hexane & sonicate 90min.
For HPLC
For HPLC
IF density > 0.930 ,sample take 3.0 - 5.0gm in 50ml Cyclohexane & reflux 60min
 R.T. - 12.15

R.T. - 13.95

R.T. - 20.02

R.T. - 26.13

1121-1105

Region - ( 1150.37 - 1169.06 -)

Si

Region - (401 - 584)

Si

Region - (1611.94 - 1792)

Region - (1612.83 - 1791.55)

 Additive in HDPE Plant (AS ON DATED-16.12.15)
Sr.No. Additive Inst. Method Cal. Point Region
I-1010 FOR
BY-FTIR HDPE-I1010 040815 0,200,400,600,800,1000,1200,1800, Region - (1695.12 - 1778.10)
010DP45U
1
0,300,310,525,600,700,810,1000,1200,1400,1500,
I-1010 BY-FTIR HDPE_I-1010_new high_10.11.2012 Region - (1775.16-1682.23)
1600,1800,1990,2000,2100,2200,2480,2970

0,250,500,750,1000,1200,1290,1400,1500,1600,1
2 I-168 BY-XRF PE_I168_03012013 P
700,1800,1885,1990, 2085,2480,2975

0,310,500,600,770,800,950,1000,1100,1248,1490,
3 Cast BY-XRF PE_CAST_03012013 Ca
1690,1800,1890, 1985,2090,2480,2970
4 Znst BY-XRF PE_ZnSt 28032015 0,250,500,750,1000,1400 Zn
5 UV-7 FY-FTIR HD new(UV8D) 0,500,1200,1400,1600,1800,2100 1169.06-1150.37
Sr.
Additive Method name Cal. Point Region & RT FUNCTIONAL
No.
GROUP
Additive in PP Plant

ERUCAMIDE 1000,1300,1600,1800,2000,2300,2600,3000, 1612.83 - 1791.98 AMIDE

1

2 ERUCAMIDE 1000,1300,1600,1800,2000,2200,2400,2700 1612.83 - 1791.99 AMIDE

3 C2 CONTENT 0,0.57,1.77,2.75,4.80,10.40,21.80, 650.0 - 800.0 ALKEEN

4 MILLAD 0, 1000, 1500, 1750, 2000 2250, 2500, 3000 620.0 - 635.0 CYCLIC ETHER
5 Millad 0,405,965,1139,1344,1653,1815,1988,2229,2517, 620.0 - 635.0 CYCLIC ETHER
Si=500,1000,1500,2000,2500,3000,3500,4000 401-584 SILICA
6 SILICA & I-168
I-168=200,400,600,800,1000,1200,1400,1600 1180-1200 OXY-PHOSPHROUS
Additive in SW Plant

7 UV-7 0,1200,1400,1600,1800, 1136.89 - 1170.52 NITRO

8 SILICA(HIGH) 0,100,400,800,1300,1700,2000,2240,2350, 401.0 - 584.0 SILICA

9 EURUCAMIDE(LOW) 0,50,100,150,200,250,300,400,700,750,900,1000, 1611.94 - 1792.0 AMIDE

10 EURUCAMIDE(HIGH) 0,350,470,540,640,775,855,950, 1612.83 - 1791.55 AMIDE

Additive in HD Plant
I-1010 FOR
11 0,200,400,600,800,1000,1200,1800, 1695.12 - 1778.10 ESTER + PHENOLIC
010DP45U
0,300,310,525,600,700,810,1000,1200,1400,1500,16
12 I-1010 1775.16-1682.23 ESTER + PHENOLIC
00,1800,1990,2000,2100,2200,2480,2970,

I-1010=400,600,800,1000,1200,1400,1600,1800 1780-1700 ESTER + PHENOLIC

13 I-1010 & I-168
I-168=400,600,800,1000,1200,1400,1600,1800 1220.72-1180 OXY-PHOSPHROUS
14 UV-7 0,500,1200,1400,1600,1800,2100, 1169.06-1150.37 NITRO

Thicknes of film required for C2 % content

% C2 Weight Thickness of film (mm)

< 2 0.5 - 1.0

2.0 - 5.0 0.3 - 0.5

5.0 - 10.0 0.1 - 0.3

10.0 - 25.0 About 0.1

25.0 - 50.0 0.05 - 0.1

> 50.0 ≤ 0.05

 XRF METHODS FOR ADDITIVE ANALYSIS
PLANT ADDITIVE METHOD NAME Calibration Points (PPM)
Cast PP CAST040517 0, 100, 200, 300, 400, 600, 800, 1000, 1200

DHT4A PP DHT4A 110518 0, 75, 150, 250, 350, 500

I-168 PP I-168 091216 0, 200, 400, 600, 800, 1000, 1200, 1400, 1600
PP Znst PP ZNST 23092017 0, 17, 34, 68, 102, 136

DSTDP PP- DSTDP 060317 0, 2000, 2500, 3000, 3500, 4000

SILICA PP SILICA 08062018 2000, 2300, 2600, 2900, 3200

0, 200, 400, 600, 800, 1000, 1200, 1400, 1600,
I-168 PE I 168 091216 1800, 2000, 2200, 2400, 2600,
2800, 3000, 3200

SWING
SILICA MB SW SILICA 2208017 0, 500, 700, 900, 1100, 1300, 1600

SILICA SWING SILICA LOW PPM 290518 0, 50, 100, 150, 200, 500

HPN20E PE HPN20E 091216 0, 50, 60, 70, 80, 90, 100

DSTDP PE DSTDP 260517 1000 ,1500 ,2000 ,2500

HDPE
I-168 PE I 168 091216 0, 200, 400, 600, 800, 1000, 1200, 1400, 1600,
Cast PE CAST 091216 1800, 2000, 2200, 2400, 2600,
2800, 3000, 3200
Znst PE ZNST 28032015
 PREPARED
S.No. STD NAME Concentration (ppm) Availability
DATE

1 PP DSTDP 28.02.17 2000, 2500, 3000, 3500, 4000 Material

PP Cast + DHT4A
2 14.02.17 100, 200, 300, 400, 600, 800 Material
(Same ppm)
PE CAST+ I-168 + Znst 265,500,750,1000,1200,1400,1600,1800,2000,2300,2700 ,
3 04.03.17 SPECIMEN
(Same ppm) 3100
0,200,400,600,800,1000,1200,1500 (UV-7 1700 PPM IN
4 PE I-1010(UV) 26.07.15 MATERIAL+SPECIMEN
ALL STD)
100+100, 500+200 , 800+400, 1100+600, 1400+800,
5 PE SILICA +EURACAMID 06.03.17 Material
1700+1000, 2000+1200, 2500 , 3000
6 PE HPN 20 E 10.05.16 50,60,70,80,90,100 SPECIMEN

9 PE I-1010 07.04.16 0, 200, 400, 600, 800, 1000, 1200, 1400, 1600 MATERIAL+SPECIMEN
0, 200, 500, 800, 1000, 1200, 1400, 1600, 1800, 2000,
10 PP MILLARD 03.04.16 MATERIAL+SPECIMEN
2200, 2500, 3000
11 PP ERUCAMIDE 13.05.17 1000, 1300, 1600, 1800, 2000, 2200, 2400, 2700 FTIR SPECIMENS BY IM
0, 200, 400, 600, 800, 1000, 1200, 1400, 1600, 1800,
12 PE CAST+ I-168+ Znst 08.04.16 MATERIAL+SPECIMEN
2000, 2200, 2400, 2600, 2800, 3000, 3200
200+500, 400+1000, 600+ 1500, 800+2000, 1000+ 2500,
13 PP I-168 + SILICA 05.04.16 MATERIAL+SPECIMEN
1200+3000, 1400+3500, 1600+4000
14 PP SILICA MADHUKON 13.04.16 0,2000,2200,2500,2700,3000 MATERIAL+SPECIMEN

15 PP PEPQ 07.05.16 0, 600, 800, 1000, 1200, 1400 MATERIAL+SPECIMEN

PE I-1010+ I-168 (Same
16 14.12.16 400, 600, 800, 1000, 1200, 1400, 1600, 1800 MATERIAL+SPECIMEN
PPM)
17 PP HPN20E 26.05.16 0, 50, 100, 200, 300, 400 MATERIAL+SPECIMEN

18 PE DSTDP 26.05.17 0, 1000, 1500, 2000, 2500 MATERIAL+SPECIMEN

 STANDARD
STATUS

CIMENS BY IM
 UV 8 (USED IN 042R35U)
ADDITIVE % MIN (4100) MAX (4900)
UV-1 Cuasorb 531 19.55 802 958
UV-7 Tinuvin 622 58.7 2407 2876
AO-6 I-1076 6.2 254 304
AO-8 I-1010 3.15 129 154
AO-9 I-168 12.4 508 608

TINUVIN 783 (USED IN 080M60U)

ADDITIVE % MIN (2500) MAX (3000)

UV-4 Chimassorb 944 50 1250 1500

UV-7 Tinuvin 622 50 1250 1500

Other Additives used in 080M60U Grade (along with Tinuvin 783)

AO-8 I-1010 400 600

AO-9 I-168 800 1200

 TARGET (4500)
880
2642
279
142
558

0U)

TARGET (2750)

1375

1375

with Tinuvin 783)

500

1000
 SW MFI METHODS

S.No. METHOD NAME

1 SW SE MFI<10 6.35/25.4

2 SW SE MFI<10 6.35/6.35

3 [email protected] MFI>10, L = 25.4

I METHODS

GRADE
042R35A, 042R35U, 080M60,
080M60U, 065E24A,
010E52, 010F18S, 010F18A,
012E50, 020F18A, 020F18S

300M24A, 180M50, 500M24A

 XRF PERFORMANCE DETAILS

S.No. ADDITIVE CONCENTRAION (PPM) RESULTS (PPM)

1 PE- I168 1500 1533

2 PP-CAST 1100 1171

3 PP-ZNST 1150 1202

4 PP-DHT4A 500 489

5 PP-DHT4A 350 348

6 PP-CAST 600 603

Sr.No. Additive Factor

1 Zn to Znst 9.67

2 Ca to Cast 15.15

3 Mg to DHT4A 4.87

4 Li to NA 27 90.90

5 Na to Sodium benzoate 6.3

6 S to DSTDP

7 Silicon to Silica

8 HO1506

9 HPN20E
RESULTS (PPM)

1446

1094

1157

346

604