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Thinner #2 MSDS

This safety data sheet provides information on a thinner product. It contains toluene and butanone as hazardous ingredients. The document outlines handling, storage, exposure, and disposal information and recommends personal protective equipment when working with the product.

Uploaded by

Sudhanshu Kumar
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© © All Rights Reserved
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0% found this document useful (0 votes)
211 views10 pages

Thinner #2 MSDS

This safety data sheet provides information on a thinner product. It contains toluene and butanone as hazardous ingredients. The document outlines handling, storage, exposure, and disposal information and recommends personal protective equipment when working with the product.

Uploaded by

Sudhanshu Kumar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 10

Date Printed: 24/06/2020 Product: 0010T0002S

Safety Data Sheet according to


Regulation (EC) 'No. 2015/830

SECTION 1: Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0010T0002S Revision Date: 24/06/2020

Product Name: THINNER #2 Supersedes Date: New SDS

1.2 Relevant identified uses of the Thinner for industrial coatings - Industrial use.
substance or mixture and uses
advised against

1.3 Details of the supplier of the safety data sheet


Importer: None

Manufacturer: StonCor Middle East L.L.C.


Plot # B518, Al Quoz Industrial Area 3
P.O. Box: 3034
Dubai, U.A.E.

Regulatory / Technical Information:


+971 4 347 0460
+971 4 347 0242 (fax)

Rivero, Melody - [email protected]


Datasheet Produced by:

1.4 Emergency telephone number: CHEMTREC +1 703 5273887 (Outside US)


+ 971 55 781 7362(Sarvar Ansari- Regional
Technical Manager)
+ 971 50 293 4945 (C M Selvan - Regional
Operations Manager)

SECTION 2: Hazard Identification

2.1 Classification of the substance or mixture

Classification according to Classification, Labeling & Packaging Regulation (EC) 1272/2008

HAZARD STATEMENTS

Flammable Liquid, category 2 H225


Skin Irritation, category 2 H315
Eye Irritation, category 2 H319

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Date Printed: 24/06/2020 Product: 0010T0002S

STOT, single exposure, category 3, NE H336


Reproductive Toxicity, category 2 H361
STOT, repeated exposure, category 2 H373
2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label


Butanone, Toluene
HAZARD STATEMENTS

Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.


Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Reproductive Toxicity, category 2 H361 Suspected of damaging fertility or the unborn child.
STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated
exposure.
PRECAUTION PHRASES
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P235 Keep cool.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
2.3 Other hazards
No Information

Results of PBT and vPvB assessment:


The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

SECTION 3: Composition/Information On Ingredients


3.2 Mixtures
Hazardous Ingredients
CAS-No. EINEC No. Name According to EEC %
108-88-3 203-625-9 Toluene 75-100
78-93-3 201-159-0 Butanone 10 - <25

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Date Printed: 24/06/2020 Product: 0010T0002S

CAS-No. REACH Reg No. CLP Symbols CLP Hazard Statements M-Factors
108-88-3 GHS02-GHS07-GHS08 H225-304-315-336-361-373
78-93-3 GHS02-GHS07 H225-319-336

Additional Information: The text for CLP Hazard Statements shown above (if any) is given in Section 16.

SECTION 4: First-aid Measures


4.1 Description of First Aid Measures
GENERAL NOTES: When symptoms persist or in all cases of doubt seek medical advice.
AFTER INHALATION: Move to fresh air.
AFTER SKIN CONTACT: Use a mild soap if available. Wash off immediately with soap and plenty of water while removing
all contaminated clothes and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove
contact lenses. If eye irritation persists, consult a specialist.
AFTER INGESTION: Gently wipe or rinse the inside of the mouth with water. Give small amounts of water to drink. Do NOT
induce vomiting. Never give anything by mouth to an unconscious person.
Self protection of the first aider:
No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid
to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

No Information
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.

SECTION 5: Fire-fighting Measures


5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam
FOR SAFETY REASONS NOT TO BE USED: Alcohol, Alcohol based solutions, any other media not listed above. Do not
use a solid water stream as it may scatter and spread fire.

5.2 Special hazards arising from the substance or mixture


No Information

5.3 Advice for firefighters


Flash back possible over considerable distance. In the event of fire, wear self-contained breathing apparatus. Do not use a
solid water stream as it may scatter and spread fire. Hazardous decomposition products formed under fire conditions. Collect
contaminated fire extinguishing water separately. This must not be discharged into drains. Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide.

SECTION 6: Accidental Release Measures


6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Use personal protective equipment. Remove all sources of ignition.
6.2 Environmental precautions
Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).

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Date Printed: 24/06/2020 Product: 0010T0002S

6.4 Reference to other sections

FURTHER INSTRUCTIONS: Please refer to EU disposal requirements or country specific disposal requirements for this
material. See Section 13 for further information.

SECTION 7: Handling and Storage


7.1 Precautions for safe handling

Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Vapours may form
explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure limits. Electrical equipment should be protected to the appropriate
standard. Preparation may charge electrostatically: always use earthing leads when transferring from one container to
another. Use only in area provided with appropriate exhaust ventilation. Provide sufficient air exchange and/or exhaust in
work rooms. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded.
Wear personal protective equipment. Do not breathe vapours or spray mist. Use only explosion-proof equipment. Keep
away from sources of ignition - No smoking.
Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities
CONDITIONS TO AVOID: Direct sources of heat.
STORAGE CONDITIONS: Store in original container. Keep locked up or in an area accessible only to qualified or authorised
persons. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
7.3 Specific end use(s)

No specific advice for end use available.

SECTION 8: Exposure Controls/Personal Protection

8.1 Control parameters

Ingredients with Occupational Exposure Limits


(EU)

Name CAS-No. LTEL ppm STEL ppm STEL mg/m3 LTEL mg/m3
Toluene 108-88-3 50 100 384 192
Butanone 78-93-3 200 300 900 600

Name CAS-No. OEL Note

Toluene 108-88-3

Butanone 78-93-3

FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: Respirator with a vapor filter.
EYE PROTECTION: Tightly fitting safety goggles.
HAND PROTECTION: Rubber or plastic gloves. Take note of the information given by the producer concerning permeability
and break through times, and of special workplace conditions (mechanical strain, duration of contact). Long sleeved clothing.
Remove and wash contaminated clothing before re-use.
OTHER PROTECTIVE EQUIPMENT: No Information
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

Page 4 / 10
Date Printed: 24/06/2020 Product: 0010T0002S

Chemical Name:
EC No.: CAS-No.:

DNELs - Derived no effect level

Workers Consumers
Route of Acute effect Acute effects Chronic Chronic effects Acute effect Acute effects Chronic Chronic effects
Exposure local systemic effects local systemic local systemic effects local systemic
Oral Not required
Inhalation
Dermal
PNEC's - Predicted no effect concentration
Environmental protection target PNEC
Fresh water
Fresh water sediments
Marine water
Marine sediments
Food chain
Microorganisms in sewage treatment
soil (agricultural)
Air

SECTION 9: Physical and Chemical Properties


9.1 Information on basic physical and chemical properties
Appearance: Clear Liquid
Physical State Liquid
Odor Solvent
Odor threshold Not determined
pH Not determined
Melting point / freezing point (°C) Not determined
Boiling point/range (°C) 78 - 111
Flash Point, (°C) -4
Evaporation rate Slower Than Ether
Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 1.3 - 10.1


limits
Vapour Pressure 36.3
Vapour density Heavier Than Air
Relative density Not determined
Solubility in / Miscibility with water Not determined
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties

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Date Printed: 24/06/2020 Product: 0010T0002S

Not determined

9.2 Other information


VOC Content g/l: 850.00

Specific Gravity (g/cm3) 0.850

SECTION 10: Stability and Reactivity


10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under recommended storage conditions. Risk of ignition.
10.3 Possibility of hazardous reactions
No Information
10.4 Conditions to avoid
Direct sources of heat.
10.5 Incompatible materials
Strong oxidizing agents.

10.6 Hazardous decomposition products


Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

SECTION 11: Toxicological Information


11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: No information available.
Inhalation LC50: No information available.

Irritation: No information available.

Corrosivity: No information available.

Sensitization: No information available.

Repeated dose toxicity: No information available.

Carcinogenicity: No information available.

Mutagenicity: No information available.

Toxicity for reproduction: No information available.

STOT-single exposure: No information available.

STOT-repeated exposure: No information available.

Aspiration hazard: No information available.

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Page 6 / 10
Date Printed: 24/06/2020 Product: 0010T0002S

CAS-No. Name According to EEC Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist LC50

5000 mg/kg rat


8000 ppm/4 hrs,
108-88-3 Toluene oral, 14000 mg/kg
rat, inhalation
0.000 0.000
rabbit dermal
5000 ppm / 1
2737 mg/kg rat,
78-93-3 Butanone oral
hour rat, 0.000 0.000
inhalation

Additional Information:
No Information

SECTION 12: Ecological Information


12.1 Toxicity:

EC50 48hr (Daphnia): No information


IC50 72hr (Algae): No information
LC50 96hr (fish): No information

12.2 Persistence and degradability: No information

12.3 Bioaccumulative potential: No information

12.4 Mobility in soil: No information

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: No information

CAS-No. Name According to EEC EC50 48hr IC50 72hr LC50 96hr

108-88-3 Toluene No information No information


78-93-3 Butanone No information No information

SECTION 13: Disposal Considerations


13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Empty containers should be taken to an approved waste handling site for
recycling or disposal.
European Waste Code: 140603
Packaging Waste Code: 150110

Page 7 / 10
Date Printed: 24/06/2020 Product: 0010T0002S

SECTION 14: Transport Information


14.1 UN number UN 1263
14.2 UN proper shipping name Paint Related Material
Technical name Not applicable
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard Not applicable
14.4 Packing group II
14.5 Environmental hazards Unknown
14.6 Special precautions for user Unknown
EmS-No.: F-E , S-E

14.7 Transport in bulk according to Annex II Unknown


of MARPOL 73/78 and the IBC code

SECTION 15: Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

National Regulations:

Denmark Product Registration Number: Not available

Danish MAL Code: Not available

Danish MAL Code - Mixture: Not available

Sweden Product Registration Number: Not available

Norway Product Registration Number: Not available

Germany WGK Class: Not available

Covered by Directive 2012/18/EC (Seveso III): Not applicable

Restrictions to product or to substances according


to Annex XVII, Regulation (CE) 1907/2006: Not applicable

Annex XIV - Authorisation List:


CAS-No. Name According to EEC

Not Applicable

SVHC - Substances of very high concern (Candidate List):

CAS-No. Name According to EEC

Not Applicable

15.2 Chemical Safety Assessment:


No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

SECTION 16: Other Information

Page 8 / 10
Date Printed: 24/06/2020 Product: 0010T0002S

Text for CLP Hazard Statements shown in Section 3 describing each ingredient:

H225 Highly flammable liquid and vapour.


H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Reasons for revision
No Information

List of References:

This Safety Data Sheet was compiled with data and information from the following sources:

The Ariel Regulatory Database provided by the 3E Corporation in Copenhagen, Denmark;


European Union Commission Regulation No. 1907/2006 on REACH as amended within Commission Regulation
(EU) 2015/830;
European Union (EC) Regulation No. 1272/2008 on the classification, labelling and packaging of
substances and mixtures (CLP Regulation) and subsequent technical progress adaptations (ATP);
EU Council Decision 2000/532/EC and its Annex entitled "List of Wastes".

Acronym & Abbreviation Key:

CLP Classification, Labeling & Packaging Regulation


EC European Commission
EU European Union
US United States
CAS Chemical Abstract Service
EINECS European Inventory of Existing Chemical Substances
REACH Registration, Evaluation, Authorization of Chemicals Regulation
GHS Globally Harmonized System of Classification and Labeling of Chemicals
LTEL Long term exposure limit
STEL Short term exposure limit
OEL Occupational exposure limit
ppm Parts per million
mg/m3 Milligrams per cubic meter
TLV Threshold Limit Value
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety & Health Administration
PEL Permissible Exposure Limits
VOC Volatile organic compounds
g/l Grams per liter
mg/kg Milligrams per kilogram
N/A Not applicable
LD50 Lethal dose at 50%
LC50 Lethal concentration at 50%
EC50 Half maximal effective concentration
IC50 Half maximal inhibitory concentration
PBT Persistent bioaccumulative toxic chemical
vPvB Very persistent and very bioaccumulative
EEC European Economic Community
ADR International Transport of Dangerous Goods by Road
RID International Transport of Dangerous Goods by Rail
UN United Nations
IMDG International Maritime Dangerous Goods Code
IATA International Air Transport Association

Page 9 / 10
Date Printed: 24/06/2020 Product: 0010T0002S
MARPOL International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978
IBC International Bulk Container
RTI Respiratory Tract Irritation
NE Narcotic Effects

For further information, please contact: Technical Services Department

The information on this sheet corresponds to our present knowledge. It is not a specification and
it does not guarantee specific properties. The information is intended to provide general
guidance as to health and safety based upon our knowledge of the handling, storage, and use of the
product. It is not applicable to unusual or non-standard uses of the product or where instructions
and recommendations are not followed.

Page 10 / 10

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