Safety Data Sheet

Section 1 - Chemical Product and Company Identification

Product Name: Duralay Liquid

Company Identification:
Reliance Dental Mfg., LLC.
5805 W. 117th Place
Alsip, IL 60803

For Product Information, call: 708-597-6694 For Medical Information, call: 800-535-5053

Section 2 - Hazards Identification

Classification of the substance or mixture

Hazard Class – Physical, Health, environmental Category
Flammable Liquid 2
Skin Corrosion/Irritation 2
Skin sensitizer 1
Specific Target Organ Toxicity - Single Exposure 3
Label Elements - Pictograms, Signal Word, Hazard Statements, Precautionary Statements, & Supplemental Information

Signal Word: Danger

Hazard Statements Precautionary Statements – Prevention, Response, Disposal

H225 Highly flammable liquid and vapor P210 Keep away from heat/sparks/open flames/hot surfaces
-No Smoking
H315 Causes skin irritation P233 Keep container tightly closed
H317 May cause an allergic skin reaction P240 Ground and bond container and receiving equipment
H335 May cause respiratory irritation P241 Use explosion-proof electrical/ventilating/light/…/equipment
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands and exposed skin thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the
workplace
P280 Wear protective gloves/protective clothing/eye protection/face
protection
P312 Call a POISON CENTER or doctor/physician if you feel unwell
P321 Specific treatment (see….on this label)
P362 Take off contaminated clothing and wash before reuse
P363 Wash contaminated clothing before reuse
P302+P352 IF ON SKIN-Wash with soap and water
P303+P361 IF ON SKIN (or hair): Remove/Take off immediately all
+ P353 contaminated clothing. Rinse skin with water/shower
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing
P332+P313 If skin irritation occurs: Get medical advice/attention
P333+P313 If skin irritation or a rash occurs: Get medical advice/attention
P370+P378 In case of fire: Use CO2 for extinction
P405 Store locked up
P403+P233 Store in a well ventilated place. Keep container tightly closed
P403+P235 Store in a well ventilated place. Keep cool
P501 Dispose of contents/container to an authorized disposal facility

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 Section 3 - Composition, Information on Ingredients

Hazardous Components Case No. Percent GHS Ratings

Methyl Methacrylate 80-62-6 90-100 Skin Corrosion/Irritation(H315) 2

Skin Sensitizer(H317) 1
Specific Target Organ
Toxicity-Single Exposure(H335) 3
Aquatic Toxicity(H402) A3
*Component names may have been omitted to protect confidential business information (CBI) in compliance with OSHA GHS HCS§ 1910.1200 Appendix E.

Section 4 - First Aid Measures

General Advice: Provide the SDS to medical personnel for treatment

Inhalation: Remove victim to fresh air. Seek immediate medical attention.

Eye Contact: If product gets in the eyes, flush with lukewarm water for at least 15 minutes. If
irritation occurs, contact a physician.

Skin Contact: Rinse thoroughly with lukewarm water, followed by a thorough washing of the
affected area with soap and water. If irritation, redness or swelling persists, contact
a physician immediately.

Clothing: Remove contaminated clothing, wash thoroughly before reuse.

Ingestion: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an
estimate of the time at which the materials was ingested and the amount of the
substance that was swallowed. Get medical attention immediately.

Section 5 - Fire Fighting Measures

Suitable Extinguishing Media: Chemical (alcohol-resistant) foam, dry chemical or carbon dioxide.
Unsuitable Extinguishing Media: Water spray or water stream may not be effective.
Specific Hazards Arising from the Chemical: High temperatures, inhibitor depletion, accidental
impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating
heat/pressure. Closed containers may rupture or explode during a runaway polymerization. This
product is a flammable liquid. Vapors of this product are heavier than air and may travel to a source of
ignition and flash back to a leaking or open container. Vapor forms an explosive mixture with air.

Hazardous Combustion Products: Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps

other toxic vapors may be released during a fire involving this product.

Special Fire Fighting Procedures: Use a water spray or fog to reduce or direct vapors, and keep
containers cool. Water may not be effective in actually extinguishing a fire involving this product. Do
not enter fire area without proper protection. Fight fire from a safe location. Structural firefighters must
wear SCBA and full protective equipment. Heat/impurities may cause pressure to build and/or rupture
closed containers, spreading fire, increasing risk of burns/injuries.

Protective Equipment and Precautions for Firefighters: Wear self-contained breathing apparatus
for firefighting if necessary. Do not enter fire area without proper protection. Fight fire from a safe
distance/protected location. Heat/impurities may increase temperature/build pressure/rupture closed
containers, spreading fire, increasing risk of burns/injuries. Use water spray to cool unopened containers.
Pressure relief system may plug with solids creating risk of overpressure.

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 Section 6 - Accidental Release Measures

Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions: Before cleaning any spill or leak, individuals must wear appropriate
Personal protective Equipment that is specified is section 8. Deny
entry to all unprotected individuals. Remove any contaminated
clothing and wash thoroughly before reuse.
Environmental Precautions: Extinguish all ignition sources. Keep spills and cleaning runsoffs out
of municipal sewers and open bodies of water. May contaminate
water supplies/be harmful to aquatic organisms. May cause
long-term adverse effects in the aquatic environment. US Regulations
(CERCLA) require reporting spills and releases to soil, water and air in
excess of reportable quantities. The toll free number for the US Coast
Guard National Response Center is (800) 434-8802.

Methods and Material for Containment and Cleaning UP

Methods for Containment: Prevent further leakage or spillage if safe to do so. Dike and contain
spill with inert material (e.g. sand or earth). May contaminate water
supply.
Methods for Cleaning Up: Maximize ventilation (open doors and windows) and secure all sources
of ignition. Use good, local ventilation with a minimum capture
velocity of 100 ft/min (30 m/min) at point of product release. Place
into appropriate closed container(s) for disposal in accordance with
local, state and federal regulations. Wash all affected areas with plenty
of warm water and soap. Clean up materials maybe a RCRA
hazardous waste, a hazardous waste determination should be done by
qualified personnel.

Section 7 - Handling and Storage

Precautions for safe Handling

Advice on Safe Handling: Keep away from heat, sparks, and flame. Keep container closed after
each use. Do NOT use localized heat source such as band heaters to
heat/melt product. Do NOT use steam. Hot boxes or hot rooms are
recommended for heating the product, which can be set at a maximum
temperature of 60°C/140°F. Avoid contact with skin, eyes and
clothing. Use good personal hygiene and housekeeping. After use,
wash hands and exposed skin with soap and water. Do not eat, drink,
or smoke while handling product. Observe precautions found on lavel.
Ground and bond all containers when transferring. Refer
to Section 8 for suggested exposure controls and personal protection.
Observe precautions found on label.

Conditions for Safe Storage, Including any Incompatibilities

Storage Conditions: Store container in a cool, dry location, away from direct sunlight, heat,
sparks, flame, other light sources, or sources of intense heat. Store
in accordance with National Fire Protection Association
recommendations. Check inhibitor levels periodically, adding to the
bulk material if needed. Do not blanket or mix with oxygen-free gas
as it renders the inhibitor ineffective. Vapors are uninhibited and may
form polymers in vents or flame arresters, resulting in blockage of
vents. Product residue may remain in empty containers. Observe all
label precautions until the container is cleaned, reconditioned, or
destroyed.

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Incompatible Materials: Strong oxidizers, strong reducers, free radical initiators, inert gases,
oxygen scavengers.

Section 8 - Exposure Controls, Personal Protection

Chemical Name ACGIH NIOSH OSHA - Final PELs

100 ppm TWA;
50 ppm TWA; 100 ppm TWA;
METHYL METHACRYLATE 410 mg/m3 TWA
100 ppm STEL 410 mg/m3 TWA
1000 ppm IDLH

Engineering Controls: Use local explosion-proof ventilation that is adequate to keep

employee exposure to airborne concentrations below exposure limits.
Please refer to the ACGIH document, Industrial Ventilation, A Manual
of Recommended Practices, most recent edition, for details.

Personnel Protective Equipment (PPE)

Respiratory Protection: A respirator should be worn whenever workplace conditins warrant a
respirators use. None required if airborne concentrations are
maintained below the exposure limit listed above. If necessary, use
only respiratory protection authorized per U.S. OSHA’s requirement in
29 CFR§1910.134 or other appropriate govening standard.

Eye/Face Protection: Wear safety glasses, chemical goggles when splashing is possible,
when dealing with this materials. If necessary, refer to U.S. Osha 29
CFR§1910.133, or other appropriate governing standard. Ensure that
an eyewash station, sink or washbasin is available in case of exposure
to eyes.

Skin and Body Protection Complete suit protecting agains chemicals, the type of protective
equipment must be selected according to the concentration and
amount of the dangerous substance at the specific workplace. Handle
with gloves. Gloves must be inspected prior to use. Use proper
glove removal technique (without touching glove’s outer surface) to avoid
skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full Contact: Splash Contact:

Material: Nitrile rubber Material: Nitrile rubber
Minimum layer thickness: 0.4 mm Minimum layer thickness: 0.11 mm
Break through time: 480 min Break through time: 120 min

General Hygiene Condsiderations: Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling. An eyewash station and a safety shower are recommended.
Food, beverages, and tobacco products should not be carried, stored or consumed where this material is
in use. Wash hands thoroughly before eating, drinking, or smoking.

Section 9 - Physical and Chemical Properties

Appearance: Clear Physical State: Liquid

Odor: Characteristic Flash Point: 54°F, 12°C
Flammable limit (air Volume% : N/A Autoignition Temperature: 421°C
Lower/Upper) Boiling Range (low-high): 101°C
Evaporation Rate: No data available
Specific Gravity: 0.94

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 Section 10 - Stability and Reactivity

Note: Materials listed as stable may become unstable upon depletion of inhibitors (such as mequinol or
hydroquinone), contact the manufacturer for exact levels and instruction on inhibitor maintenance.

Material stability: Stable

Incompatible Materials: Strong oxidizers, strong reducers, free radical initiators, inert gases, oxygen
scavengers. Material has strong solvent properties and can soften paint and rubber.

Hazardous Decomposition Products: Oxides of Carbon

Possibility of Hazardous Reactions: Hazardous polymerization may occur.

Section 11 - Toxicological Information

Mixture Toxicity
Inhalation Toxicity: 4,632 mg/L

Component Toxicity
Routes of Exposure: No data available

Target Organs: Eyes, Skin and Respiratory System

Effects of Overexposure

Product Conponents Listed as Carcinogenic

CAS Number Description % Weight Carcinogen Rating
None No data available

Section 12 - Ecological Information

Component Ecotoxicity
Methyl Methacrylate 96 Hr LC50 Pimephales promelas: 243 - 275 mg/L [flow-through]; 96 Hr
LC50 Pimephales promelas: 125.5 - 190.7 mg/L [static]; 96 Hr LC50 Lepomis
macrochirus: 170 - 206 mg/L [flow-through]; 96 Hr LC50 Lepomis
macrochirus: 153.9 - 341.8 mg/L [static]; 96 Hr LC50 Oncorhynchus
mykiss: >79 mg/L [flowthrough]; 96 Hr LC50 Oncorhynchus mykiss: >79
mg/L [static]; 96 Hr LC50 Poecilia reticulata: 326.4 - 426.9 mg/L [static] 48
Hr EC50 Daphnia magna: 69 mg/L 96 Hr EC50 Pseudokirchneriella
subcapitata: 170 mg/L
Section 13 - Disposal Considerations

Waste Treatment Methods

Disposal of Wastes
When discarded it is a hazardous waste by the EPA under RCRA. The reportable quantity (RQ) for Ethyl
Methacrylate is 1000 pounds (40 CFR Part 302). After addition of excess inhibitor, dispose waste material
in accordance with Federal, State, and Local regulations. It is the responsibility of the generator to
determine at the time of disposal whether the product meets the criteria of a hazardous waste. Comply
with all applicable federal, state and local regulations. Waste disposal options include landfilling solids at
permitted sites. Incinerate in a chemical incinerator equipped with an afterburner and scrubber. Use
registered transporters.

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Contaminated Packaging
Reuse of empty drums or containers is not recommended. Employees should be advised of the potential
hazards, due to residual flammable material, associated with empty containers. Dispose of all empty
containers properly, in accordance with Federal, State and Local regulations

Section 14 - Transport Information

Agency Proper Shipping Name UN Number Packing Group Hazard Class

DOT METHYL METHACRYLATE MONOMER, STABILIZED UN1247 II 3
RQ: 1000lbs
IATA METHYL METHACRYLATE MONOMER, STABILIZED UN1247 II 3
IMDG METHYL METHACRYLATE MONOMER, STABILIZED UN1247 II 3

Section 15 - Regulatory Information

State of California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65): WARNING! This product contains the following chemicals which are listed by the
State of California as carcinogenic or a reproductive toxin: None

SARA 313: Methyl Methacrylate 80-62-6

US State Right-to-Know Regulations: None

Country Regulation All Components Listed

EINECS Yes
SARA Hazard categories Yes
TSCA Inventory Yes

Section 16 - Additional Information

Hazardous Material Information System (HMIS) National Fire Protection Association (NFPA)
Rating HMIS & NFPA Hazard Rating

HEALTH 2 HEALTH 2
FLAMMABILITY 3 FLAMMABILITY 3
PHYSICAL HAZARD 2 INSTABILITY 2
PERSONAL PROTECTION B

HMIS & NFPA Hazard Rating

*= Chronic Health Hazard
0 = INSIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
B = Gloves and Safety Glasses or Chemical Goggles.

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Reliance Dental Mfg. Co. be
liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if user has been advised of the possibility of such
damages.

Revised January 6, 2022

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