SAFETY DATA SHEET
SDS Number: SDS-70628 Version No: 003
Revision Date/Version No:08-02-2024 /3/3.2.2
1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE
COMPANY / UNDERTAKING
Product Name: HI-VINYL 1102 CF ETCHING PRIMER DARK
GREEN
Intended Use: Solvent-Based Protective Coating
Manufacturer: Nippon Paint (S) Co. Pte Ltd
No. 1 First Lok Yang Road
Jurong Singapore 629728
Emergency Phone Number: (65) 6 265 5355
Fax Numbers: (65) 6 264 1603
2. HAZARDS IDENTIFICATION
GHS Classification:
Physical Hazard
Flammable Hazard Category 2
Health Hazard
Skin corrosion/irritation Category 2
Serious eye damage/irritation Category 1
Specific target organ toxicity:
- Single exposure Category 3
Environmental Hazard
Not classified as an environmental hazard under GHS criteria
GHS Pictogram
Signal Word
Danger
Hazard statements
H225: Highly flammable liquid and vapour
H315: Causes skin irritation
H318: Causes serious eye damage
H335: May cause respiratory irritation
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H336: May cause drowsiness or dizziness
Precautionary statements
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
P233: Keep container tightly closed
P240: Ground/bond container and receiving equipment
P241: Use explosion-proof electrical/ventilating/light/equipment
P242: Use only non-sparking tools
P243: Take precautionary measures against static discharge
P261: Avoid breathing dust/fume/gas/mist/vapours/spray
P264: Wash hands thoroughly after handling
P271: Use only outdoors or in a well-ventilated area
P280: Wear protective gloves/protective clothing/eye protection/face protection
Response
P310: Immediately call a POISON CENTER or doctor/physician
P312: Call a POISON CENTER or doctor/physician if you feel unwell
P321: Specific treatment (see Section 4 of SDS)
P362: Take off contaminated clothing and wash before reuse
P302+352: IF ON SKIN: Wash with soap and water
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing
P332+313: If skin irritation occurs: Get medical advice/attention
P370+378: In case of fire: Use appropriate media for extinction
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower
P305+351+338: IF IN EYES: Rinse continuously with water for several minutes. Remove contact
lenses if present and easy to do – continue rinsing
Storage
P405: Store locked up
P403+233: Store in a well ventilated place. Keep container tightly closed
P403+235: Store in a well ventilated place. Keep cool
Disposal
P501: Dispose of contents/container to appropriate waste site or reclaimer in accordance with local
or national regulations
3. COMPOSITION / INFORMATION ON INGREDIENTS
Substances CAS No. %
2-Propanol 67-63-0 18-40
Xylene 1330-20-7 11-24
1-Butanol 71-36-3 8-17
Vinyl butyral polymer 63148-65-2 3-7
Methyl isobutyl ketone 108-10-1 2-4
Substances determined to be non-hazardous - Balance
100%
4. FIRST-AID MEASURES
INHALATION
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Move person to fresh air and call for medical assistance immediately.
If not breathing, give artificial respiration, if breathing is difficult, give oxygen. Keep at rest.
SKIN CONTACT
In case of contact, immediately flush skin with large amounts of water and soap while
removing contaminated clothing and shoes.
If irritation persists, get medical attention.
EYE CONTACT
Immediately flush eyes with large amounts of water until irritation subsides.
Remove contact lens.
Obtain medical attention, preferably by an ophthalmologist, immediately.
INGESTION
DO NOT induce vomiting unless directed to do so by a medical personnel. Never give
anything by mouth to an unconscious person. Keep at rest. Get medical attention immediately.
5. FIRE FIGHTING MEASURES
SUITABLE FIRE EXTINGUISHING MEDIA
Alcohol - resistant foam, Carbon dioxide, or dry chemical type.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL
Combustion products may include and are not limited to: Carbon monoxide and Carbon
dioxide.
SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS
Wear full protective clothing and NIOSH - approved self - contained breathing apparatus.
Use water spray to cool fire - exposed surfaces and to protect personnel. If a leak or spill has
not ignited, use water spray to disperse the vapours.
If possible, isolate product from heat, electrical equipments, sparks and open flames.
Avoid spraying water directly into storage containers.
Closed containers may explode when exposed to extreme heat.
Avoid spreading burning liquid with water, isolate liquid.
Do not allow runoff from fire fighting to enter drains or watercourses.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURE
Wear appropriate protective equipment, e.g. respirators, eye protection, gloves and safety
shoes.
Avoid substance contact with eyes. Do not inhale vapours.
Ensure supply of fresh air in enclosed rooms.
ENVIRONMENTAL PRECAUTIONS
Eliminate sources of ignition.
Keep public away.
Contain spilled liquid with sand or other non-combustible absorbent materials.
Wash area and prevent runoff into drains and sewerage system.
Advise authorities if substance has entered a watercourse or sewer or has contaminated soil
or vegetation.
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METHODS AND MATERIALS FOR CONTAINMENTS AND CLEANING UP
Clean up all spills immediately.
Absorb spill with absorbent and inert material, then place in container.
Disposal in accordance to local/national regulations.
7. HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING
Use appropriate personal protective equipment
Keep out of reach of children.
Handle containers with care. Open slowly in order to control possible pressure release.
Do not pressurize containers.
Do not ingest. Do not breathe in gas/fumes/vapour. Avoid contact with skin and eyes.
For personal protection, see section 8.
Use only in areas from which all naked lights and other sources of ignition have been
excluded.
Take precautionary measures against static discharge
Protect from frost and extremes of temperature
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILTIES
Keep containers tightly closed
Containers that are opened should be properly resealed and kept upright to prevent leakage.
Store in cool, dry and well - ventilated place at temperature between 20°C to 40°C away from
heat and sources of ignition
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
CONTROL PARAMETERS/OCCUPATIONAL LIMITS
ACGIH TLV-TWA OSHA PEL-TWA
Substances
ppm mg/m3 ppm mg/m3
2-Propanol 200 - 400 980.00
Xylene 100 434.00 - -
1-Butanol - - - -
Vinyl butyral polymer - - - -
Methyl isobutyl ketone 50 - - -
APPROPRIATE ENGINEERING CONTROL MEASURES
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations
of vapours below their respective occupational exposure limits.
Ensure eyewash stations and safety showers are close to the workstation location.
PERSONAL PROTECTION
Respiratory Protection: Use of NIOSH - approved respirators with organic vapour
cartridges is recommended.
Hand Protection: Use of solvent resistance type or chemical resistant type of
protective gloves is recommended.
Eye Protection: Use of safety glasses or goggles with side shields is
recommended.
Skin / Body Protection: Wear chemical resistant clothes and safety shoes when
handling product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Odour : Aromatic hydrocarbon odour
Odour threshold : Not available
pH : Not available
Melting point/freezing point : Not available
Initial boiling point and boiling range : Between 82 and 182 °C
Flash point : 12 °C
Evaporation rate : Not available
Flammability (solid, gas) : Not applicable
Lower flammability or explosive limit : 1.1 % by vol
Upper flammability or explosive limit : 12 % by vol
Vapour pressure : Not available
Vapour density : > 1.00 (Vapour is heavier than air)
Relative density : Not available
Solubility : Not Miscible in water
Partition coefficient : Not available
Auto-ignition temperature : > 230 °C
Decomposition temperature : Not available
Viscosity : 53 - 57 KU
10. STABILITY AND REACTIVITY
REACTIVITY
No dangerous reaction known under condition of normal use
CHEMICAL STABILITY
The product is stable under recommended storage and handling conditions. (see section7)
POSSIBILITY OF HAZARDOUS REACTION
Under normal conditions of storage and use, hazardous reaction will not occur
CONDITIONS TO AVOID
Keep away from oxidising agents, strongly alkaline and strongly acidic materials in order to
avoid exothermic reactions. Avoid all possible sources of ignition (spark or flame). Do not
pressurize, cut, weld, braze, drill, grind or expose containers to heat or sources of ignition
HAZARDOUS DECOMPOSITION PRODUCTS
When exposed to high temperatures may produce hazardous decomposition products such as
carbon monoxide, carbon dioxide, oxides of nitrogen and smoke.
11. TOXICOLOGICAL INFORMATION
There is no data available on the product itself.
Toxicological information of substances:
Acute oral toxicity
Harmful if swallowed
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Substances Oral LD50(Rat), mg/kg
2-Propanol 5045
Xylene 4300
1-Butanol 790
Vinyl butyral polymer Data not available
Methyl isobutyl ketone 2080
Acute dermal/skin toxicity
May be harmful if in contact with skin
Substances Dermal LD50 (Rabbit), mg/kg
2-Propanol 12800
Xylene 1700
1-Butanol 3400
Vinyl butyral polymer Data not available
Methyl isobutyl ketone 16000
Acute inhalation toxicity
Vapour concentrations above the recommended exposure levels may be irritating to the eyes and
the respiratory tract, may cause headaches and dizziness, could be anesthetic and may have other
central nervous system effects.
Substances Inhalation Vapor LC50 (Rat), mg/L/4hr
2-Propanol 16000
Xylene 5000
1-Butanol 8000
Vinyl butyral polymer Data not available
Methyl isobutyl ketone 16.4
Skin corrosion or irritation
Causes skin irritation. Frequent or prolonged contact may dry the skin, leading to discomfort and
dermatitis.
Serious eye damage or irritation
May be an eye irritant
Respiratory or skin sensitisation
Vapour concentrations above the recommended exposure levels may be irritating to the eyes and
the respiratory tract
Germ cell mutagenicity
No information available on the product
Carcinogenicity
Titanium Dioxide
The International Agency for Research on Cancer (IARC) has classified Titanium Dioxide as
possibly carcinogenic to humans (Group 2B) based on inadequate evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals
Reproductive toxicity
No information available on the product
Specific Target Organ Toxicity (STOT)-single exposure
No information available on the product
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Specific Target Organ Toxicity (STOT)-repeated exposure
No information available on the product
Asphyxiation hazard
May be harmful if swallowed and enters airways
12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity -No data available
Persistence and degradability
Biodegradation -No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Result of PBT and vPvB assessment
No data available
Other adverse effects
There is no ecotoxicological test data available on the product itself.
The product should not be allowed to enter drains or water courses.
13. DISPOSAL CONSIDERATIONS
The product should not be allowed to enter drains and watercourses.
Preferred methods of waste disposal are incineration or biological treatment in federal/state
approved facility. Empty containers should be recycled or disposed through an approved waste
management facility or licensed contractor.
All federal, state and local environmental regulations shall be observed.
14. TRANSPORT INFORMATION
Transport to be in accordance with ADR/RID for road/rail, IMDG for sea and IATA for Air.
LAND TRANSPORT
Classified as Dangerous Goods by the criteria of the European Agreement concerning the
international carriage of Dangerous Goods (ADR) by Road & Regulations concerning the
international carriage of Dangerous goods (RID) by Rail.
UN Number: 1263
Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish,
polish, liquid filler and liquid lacquer base) or PAINT RELATED
MATERIAL (including paint thinning or reducing compound)
Class: 3
Subsidary Risk(s): -
Packaging Group: II
SEA TRANSPORT
Classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods
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Code (IMDG Code) for transport of Sea.
UN Number: 1263
Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish,
polish, liquid filler and liquid lacquer base) or PAINT RELATED
MATERIAL (including paint thinning or reducing compound)
Class: 3
Subsidary Risk(s): -
Packaging Group: II
Marine Pollutant No
SEA (ANNEX II OF MARPOL 73/78 AND THE IBC CODE)
Not applicable
AIR TRANSPORT
Classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA)
Dangerous Goods Regulations for transport by Air
UN Number: 1263
Proper shipping name: PAINT (including paint, lacquer, enamel, stain, shellac, varnish,
polish, liquid filler and liquid lacquer base) or PAINT RELATED
MATERIAL (including paint thinning or reducing compound)
Class: 3
Subsidary Risk(s): -
Packaging Group: II
15. REGULATORY INFORMATION
Applicable national regulations:
Standards on Hazard communication for hazardous chemicals and dangerous goods
- SS 586: Part 1: 2021-Transport and storage of dangerous goods
- SS 586: Part 2: 2014-GHS of classification and labelling of chemicals
- SS 586: Part 3: 2008(2014)-Preparation of safety data sheet
MOM: Workplace Safety and Health Act & Workplace Safety and Health (General Provisions)
Regulations
- This product is subject to SDS, labelling, PEL and other requirements in the
Acts/Regulations.
NEA: Environmental Protection and Management Act & Environmental Protection and
Management (Hazardous Substances) Regulations
- This product is not subject to control under this Acts/Regulations.
SCDF: Fire Safety Act & Fire Safety (Petroleum and Flammable Materials) Regulations
- This product is subject to the requirement of this Acts/Regulations.
SPF: The Arms and Explosive Act, the Arms and Explosives (Explosives) Rules, and the Arms
and Explosives (Explosive Precursors) Rules
- This product is not subject to the requirement of this Acts/Regulations.
16. OTHER INFORMATION
Revision Date/Version No.: 08-02-2024 /3/3.2.2
History
Previous Revision Date /Version No.: 04-11-2022 /3/3.1.1
Abbreviation
ACGIH American Conference of Governmental Industrial Hygienists
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TLV Threshold limit value
TWA Time-Weighted Average
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
LD50 Lethal Dose
LC50 Median lethal concentration
IARC International Agency for Research in Cancer
Disclaimer
To the best of our knowledge, the information contained herein is accurate. However, the
information is provided without any representation or warranty, expressed or implied, regarding its
accuracy or completeness. Since the conditions of handling, storage, use and disposal are beyond
our control and may be beyond our knowledge, for this and other reasons, we make no guarantee
of results and assume no liability for damages incurred by the use of this product. Please be
reminded that all chemicals may present unknown health hazards and should be used with caution.
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