Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -1(Adv-2023-P1-Model) Date: 08-05-2024
Time: 09.00Am to 12.00Pm GTA-31 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 AC 2 ACD 3 ABC 4 C 5 C 6 D

7 A 8 0 9 10 10 4 11 4 12 0

13 2 14 C 15 B 16 D 17 D

PHYSICS
18 BC 19 AD 20 BD 21 D 22 A 23 B

24 C 25 5 26 2 27 6 28 5 29 2

30 8 31 B 32 C 33 D 34 B

CHEMISTRY
35 ABD 36 BC 37 ACD 38 C 39 A 40 B

41 B 42 3 43 4 44 2 45 90 46 1

47 6 48 B 49 D 50 D 51 A
 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s

SOLUTIONS
MATHEMATICS
 x  x   x   0; x  0
1. f  x  
 x  x  x  2 x ; x  0
2

 f is continuous and differentiable

0; x  0
Again f '  x   
4 x; x  0
 f '  x  is continuous but not differentiable at x=0
2. z 2  az  a 2  0
 z  a , a 2 (where ' ' is non real of unity)
 locus of z is a pair of rays (since a  0 ) and
arg  z   arg  a   arg   or arg  a   arg  2 
2
  arg  z    also, z  a   a  2  z  a
3
3.  
1  2 2 4  10 and  2  2 2 4  10  

3
 1 1 1 1
4. f  x   x     x   
 2 4 2 2
3/4 1/4
1  1
I   g  x  dx let x  t   I   g  t   dt
1/4
2 1/4 
2

3
 1 1 1   1   1  1 1  1
f  t    t3  t   f  f  t      t3  t    t3  t  
 2 4 2   2   4  4 4  2
 1 1
 g  t    p  t   where p  t   p  t   0
 2 2
1/4
1 1
 I   dt 
1/ 4
2 4
x2 1 2  x 2  1 3  x 2  1
5. The scale triple product of the three given vectors is 2 x 2  1 2x2  1 x2
3x 2  2 x2  4 x2  1

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
1 2 3 1 2 0
  x  1 2 x  1 2 x  1
2 2
x   x  1 2 x  1 2 x  1
2 2 2
x2 (using C3  C3  C2  C1 )
2 2

3x  2 x  4 x  1
2 2 2
3x  2 x  4 5 x  7
2 2 2

1 0 0
  x  1 2 x  1 2 x  3
2 2 2
5x 2 (using C2  C2  2C1 )
3x  2
2
5 x 2
5x  72

  x 2  115 x 4  x 2  21
Vector are non-coplanar  Scalar triple product
 0  x 2  1  0 15 x 4  x 2  21  0   x  1
6.  y   y   2 cos x   y   cos x
1
y  sin x  sin x  sin x    sin x 
3
 sin x   cos x
Number of solution in  0, 2  is 0
Hence total solution is 0.
 both are periodic with period 2
7. n  S  64 C3
Let ‘E’ be the even of selecting 3 squares which from the letter ‘L’
No ways of selecting squares consisting of 4 unit squares  7 C1 7 C1  49
Each square with 4 unit squares forms 4L – shapes consisting of 3 unit squares
 n  E   7  7  4  196
196
 pE  64
C3
 x2 
8. f  x   2 f    f  6  x2 
 2 
 x2 
 f   x   2 f    x  2 xf   6  x 2 
 2
  x2  
 f   x  2x  f    f 6  x2  
  2 
x 
2
2 x 2

f     f   6  x   if  6  x2 
 2  2 
 f   x  is increasing
x2
 6  x2  x2  4
2
 x2 
 f     f   6  x 2   0 where x  2 or x  2
 2
 f   x   0 , when x   2, 0    2,  
 abc  0
9. Since diagonal is a member of both the families so it will pass through 1, 0  and  1,1
Equation of diagonal AC is x  2 y  1  0
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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
Since one of the vertex  3, 2  which does not be on AC, so equation of BD is 2 x  y  4
Point of intersection of AC and BD is P  ,  
9 2
5 5

If vertex B is  3, 2  then vertex D is  ,   also BD 

3 14 12 5
 say d1 
5 5 5
1
Area of rhombus   d1  d 2
2
1  12 5 
   d 2  12 5
2  5 
d 2  10
10. x 2   2  tan   x  1  tan    0
    tan   2 ... 1
   tan   1 ...  2 
From equation (1) + (2)
      3
  1   1  2
Hence either   1  2 and   1  1
then   3,   0
or   1  1 and   1  2
  2 and   1
If   3,   0 then tan   1
3 7
  ,
4 4
If    2,   1 then tan   1
 5
  ,
4 4
3 7  5
Sum      4  4
4 4 4 4
c
11. Normal to hyperbola at t is y   t 2  x  ct  ..... 1
t
It touches xy  c 2
Solving with (1), we get x   t 2  x  ct    c 2  0  t 2 x 2    ct 3  x  c 2  0
c c
t  t 
2

For equal roots, we have   t 3   4t 2  0  1  t 4   4t 4  0

1 2

t  
 t  1  2t  0 or t  1  2t  0
4 2 4 2

2 8 2  8
 t2  or  t 2  1  2 or 1  2
2 2
1  2 ln x  1  3  2 ln x 
12. The given function is y  cot 1    tan  .
 1  2 ln x   1  6 ln x 

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
  
 tan  tan  
4 1  tan   tan  
Let tan   2 ln x, tan   3 so that y  cot 1    tan  

 1  tan tan    1  tan  tan  
 4 
  
 cot 1  tan       tan 1  tan     
 4 
    
               tan 1 3  constant
2 4  4 4
2
d y
 2  0.
dx
 11 a12   1 1  1 1  a11 a12 
a
13. a    
 21 a22   2 1  2 1  a21 a22 
 a11  2a12  a11  a21 .....  i 
a11  a12  2a12  a22 .....  ii 
a21  2a22  2a11  a21
a21  a22  2a12  a22
 From (ii), a11  a22
a21  2a12
 a11a22  a21a21   a11   2  a12 
2 2

 a11  2a12
14.  P f   x   2 x  g  1 , f   x   2
g   x   2 x  f   2  , g   x   2
at x  1, f  1  2  g  1 and g  1  2  f   2 
 f  1  4  f   2 
Q   2 f  x  f  y   f  x  y   f  x  y  .... 1
Replacing x by y and y by x, then
2 f  x f  x  f  y  x  f  y  x .....  2 
From equation (1) and (2), we get f  x  y   f  y  x 
Put y  0 , then differentiate
R f   x   3 x 2  2 xf  1  f   2 
 f  1  3  2 f  1  f   2 
 f  1  f   2   3
 and f   x   6 x  2 f  1
 f   2   12  2 f  1
2 f  1  f   2   12
 S  n  a  b
n 1
 na n 1  nb n 1
15. (P) Put t  2  z
(Q) Put 3t  z
(R) Integrate by part

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1
(S) Put  z
t
1
1
 A4  4 1
16. (P) P    
 B 1 1 1 3 1 6 1
      1 2
4 10 4 10 4 10 4
3 5 C  53 31
(Q) Required probability  15 3 
C3 91
3! 2  3
(R) Required probability  
4  4  4 16
(S) Probability does not change when order of drawn balls changes. So probability of
given question is same as probability of drawing red ball in second position given that
first ball drawn is red. Which is 3/4
10 10
17. (P)   r     r   2    r 2  r  1  1
e 1 r 1

(Q)           8   1 2     2  1  0
4 4 1 1 4

   
(R) N T  1  cos   i sin   2cos cos  i sin   2 cos  ei / 2
2 2 2 2

D r  i 2 sin   i 1  cos    i conjugate of N r   i 2cos  e  i /2
2
   
(S)  2
 3
 ...... 
3 3 3 2

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s

PHYSICS
18. x   1  2   0.1 20 10 6

2 2  106
 2 10 6 m;     10
4000 1010
l '  0.75l0  0.5l0  2 0.75  0.5 l0 cos10
3 l 3 5 3
 l0  0  2 l0     l0
4 2 8  4 2 

19.
sin    sin r , use r  c  90  180 ,
L
t1 
c
2ABn1 Ln 21
t2  
c cn2
Ln1  n1 
t2  t1    1
c  n2 
Ln1
t   n1  n2 
cn2

20.
N  Fm  mg
N  O  Fm  mg
qVB0  mg
mg
V
qB0
 qE 
V   0 t
 m 
m2 g
t 2
q  0 B0
hc
21. eV   

hc
edV  2 d 


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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
hc 6.625 10  3  108  1019
34
V   d  
e 2  300 109  1.6 1019
2

 0.0137 V
F
22. S  2  F   Sr 2
r

23.
(Ladder + Man) system is counterbalanced by block of mass M, Hence Mass of ladder
M   M  m
There is no external force on system and rope tension is same both on the left and right
hand side at every instant
Hence momentum of both sides are also equal
Mv   M  m  v   m  vr  v 
 m 
 v  vr 
 2M 
 Momentum of centre of mass
2M Vcom  Mv  Mv
m
Vcom  vr
2M
24. According to problem disc is melted and recasted into a solid sphere so their volume will
be same.
4
VDisc  VSphere   R 2 Disc t   R 3Sphere
3
 R  4
VDisc  VSphere   R 2 Disc  Disc    R 3Sphere
 6  3
R
 RDisc
3
 8 Rsphere
3
 Rsphere  Disc
2
1
Moment of inertia of disc lDisc  MR 2 Disc  l
2
2
Moment of inertia of sphere lSphere  MR 2 Sphere
5

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
ldisc
lSphere 
5

25.
di
Blv  L
dt
d 2i
Bla  L 2
dt
Bl
 ilB 
L 2
d 2i
m dt
B 2l 2 d 2i
 i 2
Lm dt
B 2l 2
  0.4
mL
2 102
2  102  0.4  A  A  0.05
0.4

26.
BAD  75
tan 75 
BD
AB
 
 BD  2 2  3  7.46cm

Hence DP = 20 cm i.e., the ray emerging from the prism passes through the centre of
curvature of the mirror.
27. We have to find the time at which A N A  B N B
 ln 2   ln 2   Bt  A B t
  4N0e    N0    e  e
  At
 8
 TA   TB 
 A  B  t  ln 8  3  ln 2     t  3ln  2   t  6 min
ln 2 ln 2
 1 2 
28. For observer O1
V  VS V  V / 5 4V
4   
f f 5f
For O2 , there is change of medium. Hence, at the surface of water, keeping frequency
unchanged
V 4V

a w

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s

16V
 w  4a 
5f
0 I
29.
4 R
ln  2 1
Consider a current element at an angle  with the radius OP’ as shown in the figure From
geometry,

r  2 R cos
2


And   90 
2
0 I  Rd  sin 
Now, the magnetic field due to this current element at P is dB 
4 r
   
   /2 I  Rd  sin  90  2  
 B  2 0   
 4  
0 2 R cos
 2 
I
 B  0 ln 2  1
4 R
 
1 1
30. dQ  du  dw
3 2
From 1st law of thermodynamics, dQ  du  dw
R R
dQ  ncdt.C   for Pv n process
 1 1 n
31. PV  nRT
32. Refer Doppler effect theory
F
33. a  4  5a a  0.8 m /s 2
6
F  4.8 N
1 1 1
34.   for lens
v u f
1 1 1
  for mirror
v u f

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s

CHEMISTRY
35. Conceptual
36. Conceptual
37. knet  k1  k2
 Ea2 / RT
Ae  Ea / RT  A1e  Ea / RT  A2 e
Differentiate wA 1
T
 Ea Ea Ea
 k  1 k1  2 k2
R R R
Ea1 k1  Ea2 k2
Ea 
k1  k2
38. Basic strength of the oxide increase in the order Li2O<Na 2O<K 2O<Rb2O<Cs2O. The increase
in basic strength is due to the decrease in I.E. and increase in electropositive character the
melting points of the halides decrease in the order NaF  NaCl  NaBr  Nal , as the size of
the halide ion increases. The decrease in melting point is due to increase in the covalent
character with increase in the size of anion according to Fajan’s rule.
39. Conceptual
40.
Sample 
NaCl
 Precipitate 'A' insoluble chloride  AgCl  + Filtrate  Ba 2+ and Zn 2+ 

Na 2SO4

ppt.'C'insoluble hydroxide  Zn  OH 2  

acqeous
NH3
Filtrate  Zn 2+  +ppt.'B'insolublesulphate  BaSO4 

Ag + +Cl-  AgCl   White  ;3AgCl+Na 3AsO3  Ag3 AsO3   yellow  +3NaCl

Ba 2+ +SO 42  BaSO4   White  :Ba 2  Salts give apple green colour to the Bunsen flame.
Zn 2+ +2NH 3 +2H 2 O  Zn  OH 2   white   2NH 4 
Zn  OH 2   4NH 4  [Zn  NH 3 4 ]2+ +2OH -
O
O O
COOH C

NH N N  CH 2CH 2CH 3

COOH C

O O O

COOH

CH 3CH 2CH 2 NH 2

41. COOH

42. n eq  KMnO 4  =n aq  X n+

n×1=1×3

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 Sri Chaitanya IIT Academy 08-05-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-31_Key& Sol’s
n =3
43. Conceptual
44. Conceptual
E2 k 2  tert - butyl bromide  HO- 
45. =
E2+E1 k 2  tert - butyl broide  HO-  + k1  tert - buyl bromide
E2 7.2  10 5  5.0 36  10 5 36
 5 5
 5 5
  0.90  90%
E2+E1 7.2  10  5.0  4.0  10 36  10  4  10 40
46. 2Kl+O3  H 2O  2KO2  l2  O2
Meg of I 2  Meg of Na 2S2O 3  200  0.1  20
meg 20
m moles of I 2    10
valecy 2
Also millennials of O3 = millennials I2 (mole ration = 1 : 1)
Millennials = 10 of O3
or moles =10 103
P  nRT / v
10  10 3  0.082  273
Po3 
22.4
Po3 %  10 103 100
 1%
47. Isoelectric pH is the pH at which there is no migration of Zwitter ion on passing electric
current
pH  with NaOH  +pH  with HCl 
pH =
2
9.714  2.286
= 6
6
48. Conceptual

49.
50. Conceptual
51. Conceptual

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