6 testcone 01212020 | FORM TP 2024060 MAY/UNE 2024 CARIBBEAN EXAMINATIONS COUNCIL CARIBBEAN SECONDARY EDUCATION CERTIFICATE® EXAMINATION CHEMISTRY Paper 02 - General Proficiency 2 hours 30 minutes 8 READ THE FOLLOWING INSTRUCTIONS CAREFULLY. 1. This paper consists of SIX questions in TWO sections. Answer ALL questions. 2. Write your answers in the spaces provided in this booklet. 3. Do NOT write in the margins. 4, Where appropriate, ALL WORKING MUST BE SHOWN in this booklet. 5. You may use a silent, non-programmable calculator to answer questions. 6. Ifyou need to rewrite any answer and there is not enough space to do so on the original page, you must use the extra lined page(s) provided at the back of this booklet. Remember to draw a line through your original answer. 3 7. Ifyou use the extra page(s), you MUST write the question number clearly in the box provided at the top of the extra page(s) and, where relevant, include the question part beside the answer. DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO. Copyright © 2023 Caribbean Examinations Council All rights reserved. 01212020/MJ/CSEC 2024100 -4- SECTION A Answer ALL questions. DO NOT spend more than 30 minutes on Question 1. 1, Sodium thiosulfate solution (Na,S,O,) reacts with dilute hydrochloric acid to produce sodium chloride solution, sulfur dioxide gas, solid sulfur, and water. To investigate the effect of temperature on the rate of reaction, Paul performed different experiments using sodium thiosulfate and te hydrochloric acid. For each experiment, the same volume and concentration of sodium thiosulfate and dilute hydrochloric acid were reacted but at different temperatures. ‘The temperature was measured at the start of each experiment and the thermometer readings for Experiments 3-7 are shown in Figure 1. °c °c °c °c °c 15 2 | 28 J- 34 |- 36 — pis a [— 927 — 933, F 35 L- Hi3 | 20 - B26 Haz - Bss Experiment 3 Experiment 4 Experiment $ Experiment Experiment 7 Figure 1. Temperature readings (@) Define the term ‘rate of reactio he ate of 2. cheat (2xthow. 4 dhe. asnng wt the omedlfation 4, (witods. 9 pco dude ogc ual. te (1 mark) GO ON TO THE NEXT PAGE 2020/MI/CSEC 2024r » (GES) - (6) (i)_ Write a balanced chemical equation for the reaction between sodium thiosulfate and dilute hydrochloric aci (2 marks) (ii) Describe a test and state the observation that can be used to confirm the presence of the sulfur dioxide gas produced from the reaction. Test Alhw dhe. gas to. pass, dkoudy, ay solddion, ¥ Observation (2 marks) (iii) Determine the mass of sulfur dioxide produced when 50 cm’ of the gas was collected at STP. [RAM. S = 32, O= 16; 1 mole ofa gas occupies 22 400 cm’ at STP.) 2 GO ON TO THE NEXT PAGE | 01212020/MJ/CSEC 2024 kL Hee8 r AG © (@_ In Table 1, record the temperature readings for each of the experiments shown in Figure | on page 4. TABLE 1: THE EFFECT OF TEMPERATURE ON THE RATE OF REACTION Experiment ‘Temperature Time Rate of Reaction Number ec) ©) ey 1 5 9 0.017 2 10 50 0.020 5 bt # pag 4 nS 4 D4 s Mo 15 0-06} 6 33°0 " 0104 7 35'S 10 O10 (S marks) (ii) Calculate, to three decimal places, the rate of reaction for EACH experiment, given that the rate is 1/Time. Record your results in Column 4 of Table 1. (S marks) () —@_Using the axes provided in Figure 2 on page 7, plota graph of rate of reaction versus temperature for Experiments 1-7. Draw a smooth curve through the points. (5 marks) GO ON TO THE NEXT PAGE “nm | 01212020/MJ/CSEC 20240.090] oa EEE 3 g 3 Te. 4 Rate of reaction (s") sd wt tt ~ 0.030 0.020) 0.010) H o s 10 is 20 2s x» 35 40 45 ‘Temperature (°C) Figure 2. Graph of rate of reaction versus temperature GO ON TO THE NEXT PAGE 01212020/MA/CSEC 2024 NN |r . (IE) - Gi) Using the graph you plotted on page 7, explain how the change in temperature affects the rate of the reaction between sodium thiosulfate and hydrochloric acid. fom o to Wyte. es a acadual 10 of (2 marks) ‘Total 25 marks GO ON TO THE NEXT PAGE nema | 01212020/MJ/CSEC 2024r * 7 2. The most stable form of the element oxygen has a mass number of 16 and an atomic number of 8. It.can also exist as a radioactive isotope. (a) Define the following terms. (i) Mass number ) Gil) Isotopes (@ marks) GO ON TO THE NEXT PAGE ml 01212020/MJ/CSEC 2024r » (OES) (b) Use a dot and cross diagram to show the bonding present in oxygen gas. aden kilo fon appa be wd ld x jee ao! onl cn wk ie (3 marks) (©) There are many uses of radioactive isotopes in everyday life. List ANY THREE uses of radioactive isotopes. GO ON TO THE NEXT PAGE, 01212020/MJ/CSEC 2024~ =i (d)__ Carbon burns completely in excess oxygen to produce carbon dioxide. Write a balanced chemical equation, including state symbols, to show this reaction. (@ marks) © ir ted oxygen supply to produce carbon monoxide. Write a balanced Juding state symbols, to show this reaction. 3 G marks) Total 15 marks i GO ON TO THE NEXT PAGE 01212020/MJ/CSEC 2024 NNN _|T -12- 4 (@) Compounds A and B are straight-chain hydrocarbons whose molecular formulas are C,H,, and C,H, , respectively, (i) State ONE natural source of hydrocarbons. Gi) State TWO uses of Compound B. skin Ag (b) —(i)_ Draw the FULLY displayed structure of Compound A. H HHH N= o. nore roe oe it APH HH @ marks) GO ON TO THE NEXT PAGE 01212020/MJ/CSEC 2024Gi) Draw the FULLY displayed structure of Compound B. HH HH UH \ ryopba W-~ o-c-e-e-e eH hypo AH HA WH (2 marks) (©) @)_List ANY FOUR general characteristics of a homologous series. (ii) Deduce the homologous series to which Compounds A and B belong. wo — Cottons GO ON TO THE NEXT PAGE | 01212020/MJ/CSEC 2024r (BES) 5 (a) Compound B (C,H,,) bums completely in oxygen to produce carbon dioxide (CO,) and water (H,O). Write a balanced chemical equation, including state symbols, for this Col 2 ccoi)+ B42 ce (3 marks) Total 15 marks 100 GO ON TO THE NEXT PAGE nnn | 01212020/MJ/CSEC 20247 r aes Be SECTION B Answer ALL questions. 4 Magnesium and lead are metals often found in living things and in the environment. (2) @_Explain metallic metals. (2 marks) (ii) Give the reason why metals conduct electricity in solid form, Teds coadluteletei vt, because, The elt a, Why midbeds Omnductelea idly. (iii) 4 (1 mark) ste ANY TWO harmful effects of lead and its compounds on living things and their environment. (Q marks) GO ON TO THE NEXT PAGE 01212020/MJ/CSEC 2024 | i202 gg gar 7 (>) Acchemistry student conducted a series of experiments using an electrolytic cell to test the conductivity of magnesium chloride. The materials used to set up the apparatus and the student's observations were recorded in Table 2 below. ‘TABLE 2: MATERIALS USED TO SET UP EXPERIMENTS AND OBSERVATIONS Experiment Number Electrodes Used PVC Plastic Electrolyte magnesium chloride Dilute aqueous Bulb ‘Observations at Electrodes Bulb did not light Graphite Dilute aqueous Bulb lit ‘magnesium at the cathode chloride and the anode Platinum Solid Bulb didnot | No visible magnesium | light reaction chloride (Explain why the bulb did not light in Experiments 1 and 3. Experiment 1 tu. bulb did act tid euch shit rol Experiment 3 (01212020/MJ/CSEC 2024 GO ON TO THE NEXT PAGE ElGi) Explain why the bulb lit in Experiment 2. the hie W810. oy Leary th G marks) (iii) State the process that took place in Experiment 2. : vn EAS g (c) Magnesium readily reacts with oxygen in the for this reaction, ie a balanced chemical equation (2 marks) Total 18 marks GO ON TO THE NEXT PAGE MNUNNERERANN J 01212020/MJ/CSEC 2024 leerc 5. (a) (b) . GE8) 5 Proteins and starch are examples of natural polymers which are formed through the process of condensation polymerization. (i) Define the term ‘polymer’. . ‘The manufacture of ethanol makes use of the fermentation process. (i) Define the term ‘fermentation’. ic itetion ig the amicnl cenction in (GB marks) Gi) Write a balanced chemical equation, including state symbols, to show the process offermentation, ——2ymece span @ marks) (01212020/MJ/CSEC 2024 GO ON TO THE NEXT PAGE gg geis - -19- (9 ah J “7] (iii) Draw the FULLY displayed structure of ethanol. o-= x (2 marks) GO ON TO THE NEXT PAGE 01212020/MJ/CSEC 2024(iv) During demonstration of the wine-making process in the school’s food laboratory, ‘technician separated a pure sample of ethanol. However, the flask was not labelled and water was accidentally poured into the sample. Using a line diagram, draw and label the apparatus that could be set up in the chemisty laboratory to obtain the pure ethanol from the contaminated sample. 100 SF eadttond seers with glass beads Feemertotion mixture con contains honol (4 marks) ‘Total 15 marks GO ON TO THE NEXT PAGE | 01212020/MJ/CSEC 2024sss] Sosa b | 6. Alka Seltzer* and Epsom* salt are common remedies used in the Caribbean. Alka Seltzer* is an antacid used to {reat upset stomach and Epsom* salt is used to treat sprains and muscle pain. The “adlive ingredient in Aika Seltzer* is sodium bicarbonate (NaHCO, )and in Epsom* salt, magnesium sulfate, —— (a) Water is called the universal solvent because it dissolves many substances. Epsom® salt and Alka Seltzer* work by dissolving in water. @ Explain why water is a good solvent. (2 marks) Gi) State ANY TWO other compounds that dissolve in water. i 2 marks) GO ON TO THE NEXT PAGE | 01212020/MJ/CSEC 2024 Ir >» (LEIS) 5 (b) Continuous use of Epsom salt in water may cause hardness of water. This does not happen’ with Alka Seltzer®, RE Esa (i) State the type of water hardness caused by dissolving Epsomt salt in water. (mark «i 8 (@ marks) (iii) Explain why boiling the water will not remove the hardness caused by Epsom* salt. M603) ofe- Sable. H Yc Wry ded otic 3 5 GO ON TO THE NEXT PAGE, | 01212020/MJ/CSEC 2024i +2. (iv) Identify TWO salts that cause hardness of water and can be removed by boiling. Collcium, bioxbmite Gu __Magaasuorb' encbenite. th (¥) When used as an antacid, Atka Seltzer neutralizes the hydrochloric acid (HCI) in the stomach. Write a balanced chemical equation, including state symbols, to illustrate this process. Total 15 marks END OF TEST IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON THIS TEST. 01212020/MJ/CSEC 2024 L