Test 3 Amaan
Test 3 Amaan
1 Water is added to a sample of purple powder in a test-tube. The contents of the test-
tube are shaken, then filtered. A blue solid is left on the filter paper. After evaporating
the filtrate, red crystals are left. Which of the following can be deduced from this
analysis?
I
Y- 20 18
z 20 17
A x
B
c z
D None of the above
4 The diagram below shows the arrangement of electrons in the outer shells of the atoms
in the compound LMz.
x Electrons of L
o Electrons of M
L M
A Calcium Fluorine
B Carbon Sulfur
c Orygen Hydrogen
D Sulfur Chlorine
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H H H
I I I
H c c c H
H
How many electrons are not used for bonding?
A ?
B 4
c 6
D I
Beaker Eeaker
P a P a
Porous tbe Po{ol]sh..,e
corta;rdr€ corlainirE
lEtun helun
Experiment I Experiment 2
Experiment 1 Experiment 2
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Solvent front
Compound A '-a
z
Compound B +a'-- v
I x
Start line I
Which statement regarding the paper chromatogram is correct?
8 Which mixture of gases would not change the colour of damp red litmus paper?
10 The pH value of 0.1 mol/dm3 of ethanoic acid is 3.7 whereas the pH value of
0.1 mol/dm3 of nitric acid is 1.
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12 The diagrams show the arrangement of particles in three different physical states
of substance X.
oo o
O
oo
o c
oo o
state I slate 2 state 3
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A +
15 The graph shows the change in temperature with time when ice at -20 'C is
heated to 100 "C.
o P
100
80
Temperature/ 60
.c
40
20
0
MN
-20
L Time /min
Which of the following can be deduced from the graph?
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7
Which of the following gives the correct number of each type of oxide?
17 Which statement explains why sodium chloride, NaC/, has a lower melting point
than magnesium oxide, MgO?
A 't50
B 152
c 153
D 156
,t9 Which of the following salts is incorrectly matched with its method of preparation?
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I
20 Element P has proton number n. lt is virtually unreactive under most conditions. Another
element Q has proton number (n+2). What is the formula of the oxide of Q?
A QO
B QOz
c QzOs
D QOs
H
oH\ I H
H C-
H I il ,
C C\
H N. c'
lt
N\
4C-IJ
g#C**-C* N
I
H-'f',*H
H
What is the total number of electrons shared in all the double bonds shown?
A 2
B 4
c I
D 16
A SOz
B SiOz
c Mgo
D ZnO
A It tums moist red litmus paper blue when dissolved in an organic solvent.
B It reacts with ammonium salt to produce ammonia gas.
c It reacts with alkali to produce salt and water.
D It dissolves in water to give hydrogen ions.
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I
24 The diagram shows the anangement of ions in an ionic crystal.
Which row gives the conect number of protons, neutrons and electrons in a negative
ion of an isotope of R?
26 Which of the following shows the conect property and explanation for graphite?
Property Explanation
Can conduct Each carbon atom only uses 4 electrons in its bonding
A and has I valence electron delocalised.
electricity
B Hard Atoms are held by strong covalent bonds.
High melting and A large amount of energy is required to break the strong
c covalent bonds between the layers of carbon atoms.
boiling points
The layers of carbon atoms have weak forces of
D Soft and slippery
attraction.
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10
2-
2+
I Element L is hydrogen.
ll Element J belongs to Group ll of the Periodic Table.
lll Elements J, K and L are bonded together by ionic bonds only.
A lll only
B I and ll only
c ll and lll only
D All of the above
28 Since the discovery ol gnphene, scientists have been able to convert it to another
material known as graphane (shown below) by attaching one hydrogen atom to each
carbon atom as shown below:
o Hydrogen aloms
o Carbon atoms
Graphane has the same honeycomb structure as graphene, and retains most of its
properties too.
A It is insoluble in water.
B It is very strong and rigid.
c It has a high melting point.
D It is an electrical conductor
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A Carbon monoxide, CO
B Nitrogen dioxide, NOz
c Sulfur dioxide, SOz
D Sulfur trioxide, SO:
32 A student heats some solid ammonium chloride in a test tube as shown in the figure
below.
h€et
What will be the colour change(es) observed?
A Moist blue litmus paper tums red and no further change is observed.
B Moist blue litmus paper tums red first before both litmus tum blue.
c Moist red litmus paper tums blue and no further change is observed.
D Moist red litmus paper turns blue first before both litmus turn red.
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33 Which pair of reagents can be used in the setup shown below to prepare a salt?
Burette
Conical flask
34 Which of the following equations best represents the ionic equation for the reaction
between aqueous lithium carbonate and aqueous silver nitrate?
A Lr+NOt)LiNOs
B Li +Ag')Li'+Ag
c co32- + 2Ag') Ag2Co3
D Cos2- + 4Ag* )
4Ag + Co: + 02-
Mercury can form a crystalline salt with chlorine. The ionic compound has the formula Hg2C/2.
A Hgr'
B Hg"
c Hg22'
D Hg'*
36 What is the total number of electrons in the mercury cation in the compound?
A 158
B 159
c '160
D 162
37 An element X reacts with iron to form two different compounds with the formulae FeX
and Fe2)G.
A5
B7
c8
D9
GESS 3EXP CHEM P1 IUYE 19 CMT
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38 Calcium reacts with water to form calcium hydroxide and hydrogen gas. Which of the
following shows the chemical equation for this reaction?
A Ca+HzO)CaH+OH
B Ca+HzO)CaOH+H
G Ca+(HzO)z)Ca(OH)r+2H
D Ca+2H2O)Ca(OH)z+Hz
39 The diagram shows the pH at which a change in colour occurs for the indicators methyl
orange and methyl red.
red yellow
methyl orange I
2 3 4 6 14
pH
Which pair of solution can likely be distinguished using methyl orange and methyl red?
40 Hydrogen chloride was bubbled into hexane, an organic solvent. This mixture was
added to magnesium metal. However, no visible reaction took place. What is a likely
explanation for this?
END OF PAPER
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2
Section A [50 marksl
Answer ALL the questions in the spacas provided.
(a) is a metal.
[Total: 6]
A2 (a) A student set up the apparatus below to investigate the relative molecular mass of three
unknown gases, A, B, C and Argon as compared to air.
Poaous
containei
filled with air
Water
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(iii) Explain the presence of effervescence in the set-up using gas A and gas B.
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(iv) Why did the student place the container of argon the opposite way compared to the
others?
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(b) The diagram below shows a method used to determine the melting point of a powdered solid,
which melts between 50 'C and 80 'C.
Thermometer
Stirrer
Boiling tube
Water
Powdered
solid
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4
(iD What observation could be made about the thermometer reading when the solid is
melting?
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(iiO Explain why this experiment could not be used to determine the melting point of a solid,
which is between 120 'C and 130'C? Suggest how the experiment could be modified
for this purpose.
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A3 A pure substance Z has a melting point of 120 oC and a boiling point of 190 oC. lt was cooled
in an enclosed container where heat was drawn away at a constant rate.
(a) lf the starting temperature was 200'C and the ending temperature was 100 "C, sketch the
cooling curve, showing how the Temperature/ oC of substance Z changes with Time/ min.
lndicate cleady on the graph below, the starting temperature, ending temperature, melting
and boiling points clearly.
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(b) Mark on the graph, the regions solid, liquid and gas where the substance exists in only one
physical state.
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(c) Mark on the graph the regions P and Q where there are two physical states of matter co-
existing. t1l
P &.................
o .... &.. l2l
191 0C 1200C
121
[Total: 10]
A4 Carbon dioxide can be prepared in the laboratory using the apparatus shown below.
Carbon
dioxide
B
1"1
Hydrochloric acid -l
Marble chips
(Calcium carbonate)
121
(b) State and explain whether the volume of carbon dioxide collected in B is lower, higher or the
same as expected.
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[Total:4]
(a) (i) Write an equation, with state symbols, to show the precipitation of aspirin dlen
hydrochloric acid acts on the soluble sodium salt of aspirin.
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(ii) Explain what the low solubility of aspirin tells you about its strength as an acid.
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(iii) When a person takes the soluble sodium salt of aspirin, the precipitation only occurs in
the stomach. Suggest why.
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(b) An antioxidant is a substance that prevents oxidation from taking place. Ascorbic acid,
CsHsOo, is a common antioxidant used in the food industry to prevent food from oxidising.
When ascorbic acid acts as an antioxidant, it is changed to a new chemical called
dehydroascorbic acid with a formula CoHoOo.
(i) Which atoms are lost when asmrbic acid acts as an antioxidant?
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(ii) Oxidation happens when a substance reacts with oxygen and water in the air. Suggest
how ascorbic acid is able to act as an antioxidant to prevent food from being oxidised.
Ill
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A6 Electrodes A and B from 2 lead-acid batteries are tested to see if they are from the same
manufacturer. ln order to compare the impurities present in the electrodes, samples from the
electrodes were dissolved in a suitable acid and the resulting solutions were
chromatographed, together with solutions containing five known metal ions.
After treating with a locating agent, the chromatograms were as shown below
(a) Based on the above chromatograms, provide a reason why the two electrodes are from
different manufacturers.
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(ii) Add to the diagram above the "spot" for Fe2', which canies an & value of 0.75. t1l
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A7 Table 7.1 below gives some information of six gases. All the volumes are measured at room
temperature and pressure.
Table 7.1
(a) (0 Which of the gases in the above table would diffuse the fastest? Give a reason for your
answer.
12)
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(iii) Hydrogen bromide is a gas at room temperature and pressure. It dissolves in water to
form hydrobromic acid. Describe the bonding in hydrogen bromide and deduce its
boiling point.
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For the reaction of phosphorus with dry chlorine, it is carried out in a fume cupboard.
tll
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(ii) Suggest a reason why the experiment has to be canied out in the fume cupboard.
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(iii) Describe what you would observe when phosphorous trichloride is added to a blue
litmus solution.
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The last question is in the form either/ or and only one of the altematives should be attempted
BE Read the following article about freezing point depression and salting roads during extreme
cold weather.
Adding salt to water lowers the fteezing point below zero. This phenomenon is known as
freezing point depression.
During extreme cold weather in some countries, workers spread salt on the roads. As
snowflakes melt, the salt dissolves in the liquid water. This produces a solution of 'salty
water', which has a lower freelng point than pure snow. As a result, the additional snow
might cool the road, but the temperature will not be cold enough to freeze the salt solution.
Salting is also effective when ice has already formed on roads. The salt causes salt solution
to form on the surface of the ice. Although this is slow in the beginning, the growing solution
continues to dissolve more salt and melt more ice. Passing vehicles also help to speed up
this process. Salting allows drivers to be able to travel more safely on roads during exreme
cold weathers.
The phase diagram above shows how the salt solution concentration affects the freezing
point of water. Table 8.1 shows the effective temperatures for three commonly used salts.
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(a) The phase diagram helps workers determine the mass of salt to be added onto roads.
(D Describe how the freeze point of water is related to the satt solution concentration.
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(ii) Use the phase diagram to determine the freeze point (in 'C) of a salt solution that has
a concentration of 15% by mass of salt.
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(b) ln one sample of salt solution, the concentration was found to be 20% by mass of salt. Draw
in the box below to show how the particles are arranged at a temperature of -5'C.
Water particle
o Salt particle
lll
(c) ln some parts of Alaska, temperatures may drop to -20'C. Name the salt that can be used to
salt the roads effectively.
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(d) ls salting effective in prolonged periods of cold weather? Explain your answer
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(e) The instructions for preparing hydrated crystals of magnesium suJfate are given below:
Add one spatula full of magnesium carbonate to 50 cm3 of dilute sulfuric acid. When it has
reacted, add further amounts until no more maqnesium carbonate will dissolve. Then filter
the mixture. Evaporate the filtrate to about half its volume Allow the filtrate to cool. Filter
off the crystals. Dry them on filter paper.
141
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Bg Boron nitride is found to exist in two possible forms, hexagonal boron nitride and cubic boron
nitride as shown below.
ll
tl o Boron atom
tl
o Nitrogen atom
tl I
ll I
tt I
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(b) Based on the structures shown, explain the difference in one physical property of
hexagonal and cubic boron nitride other than electrical conductivity.
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(c) The melting points of hexagonal boron nitride and two other compounds of nitrogen are
given below.
Melting point / oC
Compound
Hexagonal boron nitride 2973
Aluminium nitride (AN) 2200
Hydrazine (NzHr) 2
(i) Draw the'dot and cross'diagram to represent the bonding in aluminium nitride.
Show only the valence electrons.
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(iD Both hexagonal boron nitride and aluminium nitride have very high melting
points. Explain why, in terms of ths bonding and sauctures, are present in both
substances.
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Either
B1 0 Camphor is a white solid used in some skin ointments. An impure sample of camphor is
found to be contaminated with traces of carbon, iron and iron(lll) oxide. The effects of three
solvents on four substances are shown in Table 10.1 below.
Solubility in dilute
Substance Solubility in ethanol Solubility in water sulfuric acid
Dissolves to give a
Camphor lnsoluble lnsoluble
colourless solution I
Reacts to give a
lron lnsoiuble lnsoluble green solution and a
coloudess gas
Reacts to give a
lron(lll) oxide lnsoluble lnsoluble
brown solution
(a) Use the information in Table 10.1 to explain how to obtain a pure and dry sample of camphor
from the impure sample.
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(b) A mass spectrometer determines the mass of a molecule by measuring the mass-to-charge
ratio (m/z) of its ions. lons are generated by either losing or gaining a charge from a neutral
species. Once ions are formed, they are directed into a mass analyser where they are
separated according to m/z and finally detected. The result is a mass spectrum that can
provide molecular mass and even structural information.
ln 1861, Bunsen and Kirchoff found that rubidium has two naturally orcuning isotopes,
rubidium-8S and rubidium-87. Figure 10.1 below shows the percentage abundance of the
different isotopes of rubidium from a mass spectrum of an analysed rubidium sample.
too
ao
Relatlve
abundance
60
40
20
o
ao a5 90 95
Relative isotopic mass
(0 State one similarity and one difference between the compositions of the nuclei of
the two isotopes of rubidium.
Similarity
Difference
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(iiD lsotopes have different physical properties. State and explain how the density of
rubidium-87 differs from rubidium-85.
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OR
810
(a) In 1991 a Japanese chemist discovered that a layer of graphite could be rolled into a
tube- These tubes, 50,000 times thinner than a human hair, are called carbon
nanotubes, as shown below.
Carbon nanotubes are extremely lightweight and strong. They can conduct electricity
much better than metals. Due io these properties, chemists believe that nanotubes will
have important future uses.
(i) Explain, in terms of struc'ture and bonding, the physical state of carbon
nanotubes at room temperature.
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(iD State one similarity and one difference in the structures between graphite and
carbon nanotube.
Similarity
Difference
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(ii0 Explain, in terms of structure and bonding, if carbon nanotubes are good
conductors of electricity.
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(b) Covalent substances, such as carbon nanotubes and graphite, have giant structures.
Metals too have giant structures.
With the help of a labelled diagram, explain how the bonding and structure in sodium
allow it to conduct electricity.
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END OF PAPER