lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
dM
M 1 M x2
dx1
dM
M 2 M x1
dx1
dV
V1 V x2
dx1
dV
V2 V x1
dx1
V x1V1 x2V2 V E x1V1 x2V2 V
V 110 x1 90 x2 x1 x2 45 x1 25 x2
V 110 x1 90 1 x1 x1 1 x1 45 x1 25 1 x1
V 20 x1 90 x1 x12 20 x1 25
V 90 45 x1 5 x12 20 x13
dV
45 10 x1 60 x12
dx1
dV
dx1
dV
V1 V x2 105.92 0.6*31.4 124.76 cm 3 mol -1
dx1
dV
V2 V x1 105.92 0.4*31.4 93.36 cm3 mol-1
dx1
Updated 4/5/2017 p. 1 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
nV
Vi
ni T , P ,n ji
V x1V1 x2V2 V E x1V1 x2V2 V
V 110 x1 90 x2 x1 x2 45 x1 25 x2
n1n2
nV 110n1 90n2 45n1 25n2
n1 n2
2
nV n1n2 n2 2n1n2
V1 110 45 45n1 25n2
n T , P ,n2 n n
2
n n
2
n n
3
1 1 2 1 2 1 2
V 110 45 x1 x2 45 x1 25 x2 x2 2 x1 x2
V 110 90 x1 x2 1 x1 25 x22 50 x1 x22
V 110 40 x1 x22 25 x22
V1
V x1V1 x2V2
V x1V1 105.92 0.4*124.76
V2 93.36 cm3 mol-1
x2 0.6
Updated 4/5/2017 p. 2 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 3 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 4 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
⋅ − ⋅ ⋅ ⋅ ⋅
Updated 4/5/2017 p. 5 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
H
Updated 4/5/2017 p. 6 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
4 moles
water Enthalpy Change = -25.5 kJ 5 moles 20%
LiCl in
water
1 mol
LiCl
Enthalpy Change
3 moles = -20.8 kJ Enthalpy Change
water 5 moles 20% = -25.5 kJ +20.8 kJ
LiCl in = -4.7 kJ
water 5 moles 20%
1 mol
LiCl in
LiCl
water
1 mole
water
Updated 4/5/2017 p. 7 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 8 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 9 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 10 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
ΔHf -
n Hf (kJ) HfCaCl2
10 -862.74 -66.94
Updated 4/5/2017 p. 11 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
15 -867.85 -72.05
20 -870.06 -74.26
25 -871.07 -75.27
50 -872.91 -77.11
100 -873.82 -78.02
300 -874.79 -78.99
500 -875.13 -79.33
1000 -875.54 -79.74
-66
-68
-70
Hf -HfCaCl2
-72
-74
-76
-78
-80
10 100 1000
ni
Updated 4/5/2017 p. 12 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 13 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 14 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 15 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 16 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 17 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 18 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 19 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 20 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 21 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 22 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
M:
Differentiate:
Updated 4/5/2017 p. 23 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
0
0 0.2 0.4 0.6 0.8 1
-500
-1000
H (kJ/kg)
Hebar1
Hebar2
-1500
H(x1)
-2000
-2500
X1
Updated 4/5/2017 p. 24 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 25 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
3600
3100
2600
r(x1) (kg/h)
2100
1600
1100
600
0 1 2 3 4 5 6
Θ (x1)
Updated 4/5/2017 p. 26 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 27 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
lOMoARcPSD|17166750
SVNAS 8th Edition Annotated Solutions Chapter 11
Updated 4/5/2017 p. 28 of 28
Copyright © McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior
written consent of McGraw-Hill Education.
Downloaded by ?? ? ([email protected])
