YOUTH ACADEMY

WHATSAPP USAMA KHALID KAMBOH 0347-2782177 (9TH, 10TH) 0342-1016201(11TH, 12TH)

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11TH CHEMISTRY
SOLVED MCQs
YOUTH PAID SERVICE
FOR ALL PUNJAB BOARDS
BY USAMA KHALID KAMBOH
CEO YOUTH ACADEMY
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YOUTH ACADEMY BY USAMA KHALID KAMBOH 0347-2782177

1ST YEAR CHEMISTRY

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Full Book MCQs
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1. Encircle the Correct Option. ‫۔‬ ‫د دا ہ‬ ‫اب‬ ‫ در‬.1

1) The molecule having zero dipole moment is.
a) NH3 b) CHCI3 c) H2O d) BF3

2) If a salt bridge is not used between two half-cells , then the voltage
a) Decreases repidly b) Does not change c) Decreases slowly d) Drops to zero

3) Fractional atomic mass is mainly due to.

a) Mass of atom is in b) Atomic mass is c) Elements mostly consist of d) Atomic mass is average
fraction average mass of isobars isotopes having different masses of isotopes
fractional abundances

4) If the rate equation of a reaction 2A + B products is , rate = k [A]2[B], and A is present in large excess , then order of
reaction is
a) 1 b) 2 c) 3

5) Equilibrium is established during the process of solvent extraction and the phenomenon obeys
a) Distribution law b) Law of mass action c) Le-chatelier's principle

6) Which of the following technique is useful in organic synthesis for separation , purification and identification of products ?
a) Sublimation b) Filtration c) Chromatography d) Solvent extraction

7) A real gas obeying Van der Wall's equation will resemble ideal gas if
a) Both " a " and " b " are b) " a " is small and " b " is c) Both " a " and " b " are d) " a " is large and " b " is
large large small small

8) By adding NH4CI to NH4OH solution. The ionization of NH4OH.

a) Increases b) Decreases c) Remains same d) Increases 100 times

9) When 6d orbital is complete, the entering electron goes into.

a) 7f b) 7s c) 7p d) 7d

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10) Polarizability is responsible for the intermolecular forces and it

a) Increases down the b) Decrease down the group c) Almost remains the d) Increases along a period
group same

11) The relative lowering of vapour pressure is equal to the mole fraction of the solute . The law is known as
a) Ostwald's dilution law b) Vant Hoff's law c) Raoult's law d) Henry's law

12) Rutherford's atomic model failed because of :

a) The atoms did not have a b) It did not account for the c) It did not account for d) There is actually no
nucleus and electrons attraction between protons the stability of the atom space between the nucleus
and neutrons and the electrons

13) The highest temperature at which a substance can exist as liquid state at its critical pressure is
a) Absolute zero b) Critical temperature c) Consulate temperature d) Tranisition temperature

14) Normal temperature and pressure ( STP ) of gas refers to

a) 273 K and 76 mm of Hg b) 273 K and 760 mm of c) 2730 C and 760 mm of d) 2730 C and 76 mm of Hg
Hg Hg

12 22 11

a) Zero b) -6 c) +6 d) 12

16) Iodine is soluble in

a) Water b) CCl4 c) Water and CCl4 d) NaCl

17) 18g glucose is dissolved in 90 g of water. The relative of vapour pressure is equal to
a) 1/5 b) 5.1 c) 1/51 d) 6

18) The bond order of N2 molecule is

a) 1 b) 2 c) 3 d) 4

19) The crystals of Na2SO4 and Na2SeO4 should be

a) Isomorphs of each b) Allotropes c) Polymorphs of each other d) Isomorphs and
other allotropes of each other

20) In most of the reactions the actual yield is ________ than theoretical yield .
a) More b) Less c) None d) Expected yield

21) Partial pressure of oxygen in the lung is

a) 760 torr b) 320 torr c) 159 torr d) 116 torr

22) Which one of the following compound is purified by sublimation.

a) Benzoic acid b) SiO2 c) CS2 d) Nal

23) Bond formed by mutual sharing of electrons is called

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a) Ionic bond b) Co-ordinate covalent c) Covalent bond d) Metallic bond

bond

2(g) + O2(g) 2SO3(g) H = - 188.3 kJ mol-1

a) The value of Kp falls with a b) The value of Kp falls c) Adding V2O5 catalyst d) The value of Kp is
rise in temperature with increasing pressure increases the equilibrium equal to Kc
yield of sulphur trioxide
2

a) 1 b) 2 c) 3 d) 4

26) The locating agent which can not be used to identify colorless components in Chromatography is
a) H2S b) Rubeanic Acid c) Ninhydrim d) HCl

c 2

a) mole-1 dm3 b) mole-2 dm3 c) mole dm-1 d) None of these

28) The strongest acid among Halogen acids is

a) HCl b) HBr c) Hl d) HF

29) The pH of tomatoes is

a) 1.2 b) 4.2 c) 7.2 d) 9.2

30) The London forces becomes stronger if

a) Size of atom is smaller b) Density of molecules is c) Number of atoms in a d) Molecules are homo-
large molecule are large atomic

31) Many elements have fractional atomic masses. This is because

a) The mass of the atom is b) Atomic masses are c) Atomic masses are d) atomic masses are average
itself fractional. average masses of average masses of masses of isotopes
isobars. isotopes. proportional to their relative
abundance.

32) The distillation of liquid under reduced pressure is called.

a) Destructive distillation b) Fractional distillation c) Vaccum distillation d) Simple distillation

33) Which molecule has Sp2 hydridization ?

a) CH4 b) C2H4 c) C2H2 d) C2H6

34) The commonly used unit of pressure by meteoroloqists is.

a) Atmosphere b) Pascal c) Milli bar d) Pound inch-2

35) Equal masses of methane and oxygen are mixed in an empty container at 250C. The fraction of total pressure exerted by
oxygen is.

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a) b) c) d)

a) Allotropic ctystal b) Isomeric crystal c) Liquid crystal d) Isomorphic crystal

a) Atoms of the He gas b) Molecules of solid iodine c) Molecules of CCl4 d) Molecules of NH3

38) Kinetic theory was proposed by

a) Bernoulli b) Coulomb c) Maxwell d) Newton

39) What will be the pH of buffer solution containing ( CH3COOH ) = 1.0M and [ CH3COONa ] = 0.1M : if Ka for acid is
1.85 10-5 ?
a) 4.74 b) 5.74 c) 3.75 d) 3.94

40) Azeotropic mixture cannot be separated into pure components by

a) Distillation b) Vacuum distillation c) Fractional distillation d) Freezing

41) The deviation of a gas from ideal behaviour is maximum at.

a) -100C and 5.0 atm b) 1000C and 2 atm c) -100C and 2.0 d) 00C and 2.0 atm

42) In Mass-volume relationship if we are given with mass of one substance we can calculate ________ of other substance .
a) Mole b) Volume c) Both A & B d) None of these

43) Heat of combustion can be determined by

a) Glass calorimeter b) Copper calorimeter c) Bomb calorimeter d) Heat calorimeter

44) One of the best technique used to measure atomic radii is

a) Spectrometry b) Chromatography c) Potentiometry d) X-ray diffraction

45) A quantum of light energy is called as

a) Proton b) Electron c) Neutron d) Photon

46) The number of fundamental ways of transferring energy into or out of system is
a) One b) Two c) Three d) Four

47) The largest number of molecules are present.

a) 3.6 g of H2O b) 2.8 g of CO c) 4.8 g of C2H5OH d) 5.4 g of N2O5

48) Born Haber cycle is used to calculate the

a) Lattice energy b) Heat of reaction c) Enthalpy change d) Heat of Atomization

49) Crystal of diamond is.

a) Ionic b) Covalent c) Molecular d) Metallic

50) If an endothermic reaction is allowed to take place very rapidly in the air , the temperature of the surrounding air .

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a) First increases then b) Decrease c) Increases d) Remains unchanged

decreases

51) The number of Isotopes of Gold ( Au ) is

a) 1 b) 3 c) 7 d) 11

52) The number of atoms present in 0.1 mole of oxygen gas is.
a) 6.02 × 1022 b) 2 × 6.02 × 1022 c) 3.101 × 1023 d) 9.03 × 1022

53) An azeotropic mixture of two liquids boils at a lower temperature than either of them when
b) It shows positive c) It shows negative d) None of these
deviation from Raoult's law deviation from Raoult's law

54) Which of the given has hydrogen bonding

a) CH3 b) CCl4 c) NH3 d) NaCl

55) A graph obtained from Boyle's law by plotting P versus V at constant T is.
a) A straight line b) A curve with minimum c) A curve with maximum d) A parabolic curve
called isotherm

56) The condition of standard state of a substance can be represented as

a) 700 mm of Hg and 00C b) 1 atm and 00C c) 2 atm and 00C d) 1 atm and 298 K

57) Colligative properties are the properties of :

a) Dilute solution which b) Concentrated solution which c) Both A & B d) None of these
behave as nearly ideal behave as nearly non-ideal
solution solution

58) Name the electrons is given by

a) William Crooks b) J.J Thomson c) Stoney d) Chadwick

59) The milk in nature is

a) Acidic b) Basic c) Neutral d) Normal

60) The least value of reduction potential is for

a) Li+1 b) F2 c) K+1 d) Na+1

61) Sum of pKa and pKb is equal to.

a) 7 b) 9 c) 11 d) 14

62) The natural plasma is extremely hot and it has minimum temperature.
a) 20000C b) 20,0000C c) 30000C d) 30,0000C

63) ______ affects the value of Kc

a) Concertration b) Temperature c) Catalyst d) Pressure

64) De-Broglie equation is represented by.

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a) b) c) d)

65) In azeotropic mixture showing positive deviation from Raoult's law , the volume of the mixture is
a) Slightly more than the b) Slightly less than the c) Equal to the volume of the d) None of these
total volume of the total volume of the components
components components

66) Solvent extraction is a process.

a) Exothermic b) Endothermic c) Equilibrium d) Non-equilibrium

67) The repulsions of electronic clouds of molecules are responsible for the attractive forces among the molecules . These
forces are
a) Dipole-induced dipole b) Instantaneous dipole- c) Ion-dipole forces d) Dipole-dipole forces
forces induced dipole force

68) The partial pressure of oxygen in lungs is.

a) 760 torr b) 210 torr c) 159 torr d) 116 torr

69) The number of lone pair of electrons in ammonium ion is

a) One b) Three c) Two d) Zero

70) For a reversible reaction , if the concentration of a reactant is doubled , then value of equilibrium constant Kc is
a) Halved b) Doubled c) Not changed d) 1/3rd of the original
value

71) At high temperature the gas ionizes and generates free electrons giving a mixture of gas molecules , ions and free
electrons . This collection is called
a) Mixture of gas b) Highly discordered c) Gaseous phase substance d) Plasma
collection of particles

72) Which of the following is the application of Law of conservation of energy ?

a) 1st Law of Thermodynamics b) Born Haber cycle c) Hess's Law d) All of the above

73) Dipole-induced dipole forces are also called

a) London Dispersion Forces b) Hydrogen boinding c) Debye Forces d) Huckel Forces

74) The e / m ratio of cathode rays is ________ to e / m ratio of positive rays .

a) Smaller b) Greater c) Equal d) Opposite

75) The amount of NaOH required to prepare 250 cm3 of 0.1 M . Solution is
a) 1 g b) 10 g c) 2 g d) 6 g

76) If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will
a) Remain unchanged b) Increase four times c) Reduce to 1/4 d) Be doubled

77) What are the number of moles of hydrogen atom in 3.2g of CH4 ? ( Relative atomic mass C = 12 )

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a) 0.2 b) 0.4 c) 0.6 d) 0.8

78) The depression in freezing point can be measured by

a) Landsberger's method b) Backmann's apparatus c) Solubility curves d) Monometric method

79) Which of the following solutions will have the highest boiling point ?
a) 0.1M NaCl b) 0.1M CaCl2 c) 0.1M FeCl3 d) 0.1M Glucose

80) In the nuclear reaction Cu29 66 66 30Zn + x . The " x " is

a) Electron b) Proton c) Neutron d) -radiation

81) Strength of a base can be determined by

a) pKa b) pKb c) pKw d) pOH

82) Which of the following statement is not correct regarding bonding molecular orbitals?
a) Bonding molecular b) Bonding molecular c) Every electron in the d) Bonding molecular
orbitals possess less orbitals have low electron bonding molecular orbitals orbitals are formed when the
energy than atomic density between the two contributes to the attraction electron waves undergo
orbitals from which they nuclei. between atoms. constructive interference.
are formed.

83) Chromatography is the process which involves the distribution of a solute between
a) Two mobile phases b) Two stationary phases c) Two stationary phases d) A stationary phase and
and two mobile phases mobile phase

84) The cell in which electrical energy is converted into chemical energy is called
a) Galvanic cell b) Electrolytic cell c) Fuel cell d) Daniel cell

85) Force of attraction between the atoms are

a) Hydrogen bonding b) London forces c) Debye forces d) Ion dipole forces

86) Which of the following redox reactions is feasible ?

a) Zn(s) + 2Ag+ (aq) b) Zn(s) + 2Ag (aq) c) Zn+2(aq) + 2Ag d) Zn+2(aq) + Ag
Zn+2 (aq) + 2Ag(s) 2Ag+2 (aq) + 2Ag+2(aq) 2Ag+2 Ag(s) (aq) + Zn(s)

87) The electrode potential of standard hydrogen electrode is arbitrarily taken as

a) Positive b) Zero c) Negative d) Vary with situation

88) In the ground state of an atom ,the electrons is present

a) In the nucleus b) In the second shell

89) Partial pressure of O2 in the air is

a) 156 torr b) 157 torr c) 158 torr d) 159 torr

90) For an ideal gas , the compressibility factor is equal to

a) 0.5 b) 1 c) 1.5 d) 2

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91) Rutherford's alpha particle scattering experiment eventually led to the conclusion that
a) Mass and Energy are b) Electrons occupy c) Neutrons are buried deep d) The electrons are present
related space around the nucleus in the nucleus in the nucleus

92) The value of activation energy is primarily determined by

a) Temperature b) Concentration of reactants c) Collision frequency d) Chemical nature of
reactants and products

93) For what value of Kc almost forward reaction is complete ?

a) Kc = 10-35 b) Kc = 1030 c) Kc = 2 d) Kc = zero

94) The bond distance between H - H is

a) 436.45 pm b) 75.4 pm c) 154 pm d) 133 pm

95) For which of the following reaction, the unit of equilibrium constant (Kc) is reciprocal of molar concentration (M-1).
a) 2H2(g) + N2(g) b) H2(g) + I2(g) c) 2NO2(g) N2O4(g) d) N2(g) + O2(g) 2NO(g)
2H3N(g) 2HI(g)

96) For the reaction NaOH + HCl NaCl + H2O , the change in enthalpy is called
a) Heat of reaction b) Heat of neutralizaion c) Heat of formation d) Heat of combustion

97) The allotropes are those solids , which have

a) Same physical properties b) Same physical but c) Same chemical d) Same physical &
different chemical properties chemical properties
properties

98) Behaviour of gas molecules can be understood from the kinetic equation of gases . This equation was given by clausius
and equation is :
b) c) d)
a)

99) The law of mass action was given by.

a) D.C down and P.wage b) Gay-Lussic and C.M c) C.M Goldberg and d) Hendeson and Le-
P.Waage Chatellier's

100) In zero order reaction , the rate is independent of .

a) Temperature of reaction b) Concentration of products c) Concentration of d) None of these
reactants

101) Transition temperature of S8 ( monoclinic ) S8 ( Rhomic ) is

a) 13.20C b) 95.50C c) 1280C d) 1100C

102) The subject matter of thermochemistry is based upon

a) Hess's Law b) Law of sonseervation of c) Born Haber's cycle d) Law of mass action
energy

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103) Which among the following will show anisotropy ?

a) Wood b) Paper c) Glass d) BaCl2

104) The rate at which the solute moves in paper Chromatography depends upon
a) Distribution coefficient b) Boiling point of the c) Distribution law d) Low partial pressures
solvent

105) Dipole moment of CO2 is.

a) 1.25 D b) 1.85 D c) 3.1 D d) Zero

106) Which is not a molecular Ion.

a) He+ b) CH4+ c) NH4+ d) CO+

107) Bohr's model of atom is contradicted by

a) Planck quantum theory b) Heisenberg's uncertainty c) Pauli's exclusion d) Hund's rule
principle principle

108) The most electronegativity atom is

a) N b) Cl c) O d) F

a) Cubic structure of ice b) Empty spaces present c) Change of bond lengths d) Change of bond angles
in the structure of ice

a) Constant pressure b) Constant temperature c) Constant volume d) Constant enthalpy

a) Law of Conservation of b) Law of Conservation of c) Law of Mass d) Distribution Law

Mass Energy Action

a) 9.1095 × 10-31 kg b) 1.675 × 10-27 kg c) 2.67 × 10-27 kg d) 5.35 × 10-27 kg

113) In ethyne molecule the number and nature of bonds are

a) One sigma two pi b) Two sigma one pi c) Three sigma two pi d) Two sigma two pi

114) Which atomic orbital has lowest energy ?

a) 4f b) 5d c) 6p d) 7s

115) In a gaseous reversible reaction in a closed container which is exothermic in nature , as increase in temperature changes
.
a) Pressure of gases b) Kc ( Equilibrium d) Conc. Of reactants only
constant )

116) Which one of the following salt dissolves in water to form a solution with a pH greater than 7 ?

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a) NaCl b) CuSO4 c) Na2CO3 d) NH4Cl

117) The oxidation state of Mn in KMnO4 is

a) +7 b) +6 c) +2 d) +5

118) Solubility of which substance decreases by increasing temperature

a) NaNO3 b) KNO3 c) NaCl d) Ce2( SO4 )3

119) If Solvent front is 10 cm and distance travelled by solute is 1.2 cm , what is its Rf value ?
a) 0.83 b) 0.12 c) 1.2 d) 8.3

120) The number of Na+ ions which surround each Cl- ion in the NaCl crystal lattice is
a) 8 b) 12 c) 6 d) 4

121) NH, shows a maximum boiling point among the hydrides of Vth group elements due to
a) Very small size of b) lone pair of electrons c) Enhanced electronegative d) Pyramidal structure of
nitrogen present on nitrogen. character of nitrogen NH3

122) The net heat change in a chemical reaction is same whether it is brought about in two or more different ways in one or
several steps . It is known as
a) Henry's Law b) Joule's Principle c) Hess's Law d) Law of conservation of
energy

123) Volume occupied by one mole of a gas at STP is called

a) Normal volume b) Molar volume c) Standard volume d) Mean volume

124) Which of the following has smallest size ?

a) Be b) B c) O d) F

125) Which crystal system is found in AgNO3 ?

a) Orthorhombic and b) Cubic and tetragonal c) Cubic and orthorhombic d) Monoclinic and
rhombohedral hexagonal

126) An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. What
are the main ions in the filtrate?
a) Ag+ and NO3- b) Ba+2 and NO3- only c) Ag+ and Ba+2 and d) Ba+2 and NO3- and CI-
NO3-

127) The H-H bond energy in kJ mol-1 is

a) 346 b) 436 c) 463 d) 336

128) Which of the following substances is amorphous in nature ?

a) Sugar b) Graphite c) KCl d) Plastic

129) The molality of toluene ( C6H8 ) solution in benzene is 0.22 . What is the mass of toluene present in 500g of C6H6 ?
a) 267 b) 260 c) 240 d) 10.12

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130) In paper Chromatography the point at which the solvent rises the maximum extent is called
a) Eluent b) Chromatogram c) Solvent front d) Base line

131) In paper Chromatography mobile phase is

a) Gas b) Liquid c) Solid d) Gas + Liquid

132) With increases in 100C temperature , the rate of reaction doubles . This increase in rate of reaction is due to .
a) Decrease in activation b) Decrease in the number c) Increase in activation d) Increase in number of
energy of reaction of collisions between energy of reaction effective collisions
reactant molecules

133) Isotopes differ in

a) Properties Which b) Arrangement of electrons c) Chemical properties d) The extent to which they
depends upon mass in orbitals may be effected in
electromagnetic field

134) If a graph is plotted between temperature on x-axis and volume of the one mole of the gas on y-axis at constant pressure
then a straight line is obtained which hypothetically cuts the temperature axis at
a) 00C b) -273.160C c) -273.16 K d) 300 K

135) Velocity constant is the rate of reaction when the concentrations of reactants are
a) Zero b) Unity c) Two d) Three

136) The volume occupied by 1.4 g of N2 at S.T.P is

a) 2.24 dm3 b) 22.4 dm3 c) 1.12 dm3 d) 112 cm3

137) Velocity constant is the rate of reaction when the concentrations of reactants are
a) Zero b) Unity c) Two d) Three

a) 5.7.kJ / mole b) Less than 57.kJ / c) 57.kJ / mole d) More than 57.kJ / mole
mole

139) Liquids which are practically immiscible

a) H2O + C6H6 b) H2O + HCl c) H2O + C2H5 - OH d) H2O + CH3 - O - CH3

140) One mole of SO2 contains.

a) 6.02 × 1023 atoms of b) 18.1 × 10 Molecules of SO2 c) 6.02× 1023 atoms of d) 4 g of atoms of SO2
oxygen sulphur

141) Plasma consists of mixture of neutral particles , positive ions and

a) Protons b) Electrons c) Neutrons d) Positron

142) Maximum number of electrons is f-subshell is.

a) 2 b) 6 c) 10 d) 14

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143) In _______ technique a solute distribute between two immiscible liquids .

a) Crystallizzation b) Solvent extraction c) Filtration d) Distillation

144) NH3 shows a maximum boiling among the hydrides of V-A group elements due to.
a) Very small size of b) Lone pair of electrons c) Enhanced electronegative d) Pyramidal structure of
nitrogen present on nitrogen character of nitrogen NH3

145) A salt bridge contains

a) Gelatin + HCl b) Gelatin + NaOH c) Gelatin + H2SO4 d) Gelatin + HCl

146) If the electronegativity difference between bonded atom is more than 0.5 but less than 1.7 , the bond will be
a) Ionic b) Non Polar covalent c) Polar covalent d) Co-ordinate covalnet

147) Which of the following formulas is used to calculate the amount of heat change in a chemical reaction .
a) H= E+P V b) E= H+W c) q = m.S . T d) H= E

148) An ideal gas is one which

a) Shows deviation from b) Has attraction between c) Has significant volume of d) Obeys gas laws at all
gas laws molecules the molecules conditions

149) _______ element has highest value of electron affinity .

a) Fluorine c) Bromine d) Iodine

150) The volume occupied by 1.6 g of O2 at S.T.P.

a) 24.4 dm3 b) 2.24 dm3 c) 1.12 dm3 d) 112 dm3
0

a) 3.0 b) 10.0 c) 1.0 d) 7.0

152) Vapour pressure of liquid depends upon.

a) Amount of liquid b) Temperature c) Surface area d) Size of container

153) If 10g of a gas at one atmospheric pressure is cooled from 2730C to 00C at constant volume , its pressure would become
.
a) 1 atm b) 273 atm c) atm d) atm

154) Which one of the following is a vector quantity ?

a) Ionization energy b) Electron affinity c) Dipole moment d) Electronegativity

155) The oxidation state of oxygen in OF2 is

a) -2 b) -1 c) +2 d) +1
-3 -3
2 4

a) 3.0 b) 2.7 c) 2.0 d) 1.5

157) sp3 Hydridization is associated with structure

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a) Linear b) Trigonal c) Tetrahedral d) Octahedral

158) Ice floats on water because

a) The hydrogen bonding in b) Empty spaces are c) Not empty spaces in d) Ice has two-dimensional
ice is stronger than that in present in ice ice structure
water

159) The long chains of amino acids are coiled about one another into a spiral by
a) Ionic bond b) Hydrogen bonding c) Van der Waal's d) Overlapping of orbitals
forces

160) The molar volume of CO2 is maximum at

a) STP b) 127°C and 1 atm c) 0°C and 2 atm d) 273°C and 2 atm

161) The normal colligative properties are the properties of

a) Dilute solutions b) Concentrated solutions c) Substance which are d) Solutions which
which behave ideally which behave nonideally electrolytes deviate from Raoult's Law

162) Half life of a second order reaction in inversely proportional to

a) Initial concentration of b) Initial concentration c) Final concentration of d) Final concentration of
products of reactants reactants products

163) The solubility of sugar in water is due to

b) Hydrogen boning with c) High solvation energy d) High dipole moment of
water water

164) Which of the following will have the same number of molecules at STP?
a) 280 cm3 of CO2 and b) 11.2 dm3 of O2 and 32 g c) 44 g of CO2 and 11.2 d) 28 g of N2 and 5.6 dm3 of
280 cm3 of N2O of O2 dm3 of CO oxygen

165) The existence of an element in more than one form is called

a) Isomorphism b) Allotropy c) Polymorphism d) Symmetry

166) The pattern of inks formed on paper in Chromatography is called

a) Chromatophore b) Chromatogram c) Chromatograph d) Chromatograph
and Chromatogram

167) The strongest bond is

a) C-C b) C=C c) C C d) All are equally strong

168) The overall positive values for cell potential predicts that the process is energetically .
a) Feasible b) Not feasible c) Not possible d) Cannot be predicted

169) Which of the following metals shows hexagonal geometry ?

a) Cu b) Ag c) Zn d) Na

170) The element which has maximum number of unpaired electron is.

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a) Cr24 b) Ca20 c) F26 d) CH29

171) Bohr's atomic model of atom is contradicted by:

d) All of these

172) The transition temperature of KNO3 is

a) 13.20C b) 95.50C c) 1280C d) 32.020C

173) The shape of SnCl2 molecule is

a) Linear b) Angular c) Trigonal planar d) Tetrahedral

174) Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction of total pressure exerted by
oxygen is
a) 1/3 b) 8/9 c) 1/9 d) 16/17

175) Which of the following forces exist in noble gases ?

a) Dipole-dipole forces b) Dipole-induced Dipole c) Iondon dispersion d) Hydrogen bonding
forces

176) The units for kw of H2O are

a) mol dm3 b) mol2 dm-6 c) mol-2 dm-6 d) mol-2 dm-3

177) Chromatography in which the stationary phase is a solid is classified as.

a) Partition Chromatography b) Adsorption Chromatography c) Gas Chromatography d) Thin
layer

178) The crystals which show different physical properties from different directions is called
a) Symmetry b) Polymorphism c) Habit of crystal d) Anisotropy

179) The internal energy of a system is equal to

a) P.E. of the particles b) Kinetic energy of the c) Enthalpy d) Sum of K.E and
particles P.E

180) The carbon atom in C2H4 is

a) Sp3-hydridized b) Sp2-hydridized c) Sp-hydridized d) Not -hydridized

181) The graph between pressure and inverse of volume for a given mass of a gas at constant temperature is
a) Straight line parallel to b) Straight line passing c) Straight line parallel to d) The curve showing the
x-axis through the origin y-axis maximum

182) Which of the following mixtures exhibitsive deviation from Raoult's law and azeotropic mixture with maximum boiling
point ?
a) Acetone + CS2 b) Methanol c) Benzene d) Ethanol + Benzene

183) The free expansion of the gas from high pressure towards the low pressure causes.

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a) Increase of temperature b) Greater number of c) Decrease of d) Decrease of velocities

collisions among the temperature of gas molecules
molecules

184) The atomic radii decrease along the period due to

a) Increase in nuclear b) Increase in electropositivity c) Increase in atomic d) Increase in electron
charge mass affinity

185) The number of atoms present in 0.5 moles of Na is

a) 1.0 × 1023 b) 6.02 × 1023 c) 2.04 × 1023 d) 3.01 × 1023

186) Spectrum of sodium contains two lines in the region

a) Violet region b) Red region c) Greed region d) Yellow region

187) Which pair of gases do not obey Dalton's law of partial pressure ?
a) H2 and O2 b) N2 and O2 c) H2 and O2 d) NH3 and HCl

188) Which of the following techniques can separate organic compound from aqueous solution ?
a) Distillation b) Chromatograph c) Filtration d) Solvent extraction

189) The geometry of ethane is

a) Trigonal planar b) Linear c) V-shaped d) Tetrahedral

190) The ionization constant of pure water ( Kw ) at 250C is

a) 1.8 × 10-16 mole dm-3 b) 1.0 × 10-16 mole dm-3 c) 1.6 × 10-14 mole dm-3 d) 3 × 10-14 mole dm-3

191) Isotopes differ in

a) Number of atoms b) Number of Ptoton c) Number of electron d) Number of neutron

a) Cu will be deposited b) Fe is precipitated out c) No reaction takes d) Cu and Fe both dissolve
down place

a) 2 b) 4 c) 6 d) 8

a) 1 b) c) d)

195) If value of Azimuthal quantum number is 3 , the value of " m " will be
a) +3, +2, +1, 0 , -1, -2, -3 b) +2, +1, 0 , -1, -2 c) 0, 1, 2, 3 d) -1 , 0 , + 1

196) An acidic buffer solutions can bee prepared by mixing.

a) A weak Acid and weak b) A strong Acid and strong c) A strong Acid and weak d) A weak Base and its
Base Base Base Salt with strong acid

197) The most common Solvent used for solvent extraction is

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a) Water b) Ethanol c) Ether d) Carbon tetrachloride

198) Which of the following substances is a sublime material ?

a) Potash alum b) NaCl c) Acetic acid d) Benzoic acid

199) A real gas obeying Van der Waal's equation will resemble ideal gas if.
a) Both A and B are large b) Both A and B are c) A is small and B is large d) A is large and B is small
small or zero

200) The value of ionic product of water at 250C is

a) 0.11 × 10-14 b) 0.30 × 10-14 c) 1 × 10-14 d) 3.0 × 10-14

201) The volume occupied by 1.4g of N2 at S.T.P is

a) 24.4 dm3 b) 22.4 dm3 c) 1.12 dm3 d) 112 dm3

202) The amount of heat absorbed when one mole of gaseous atoms are formed from the element is called enthalpy of
a) Formation b) Reaction c) Combustion d) Atomization

203) The amount of energy released by absorbing electron in the valence shell is
a) Ionization energy b) Electronegativity c) Electron affinity d) Atomic radius

204) The most effective calalyst in contact process is

a) V2O5 b) Platinum c) Both A & B d) None of these

205) Cathode rays are material particles having definite

a) Time period & amplitude b) Wavelength c) Frequency & amplitude d) Mass

206) Ionization of weak acid is expressed in terms of which of the following constants ?
a) Kw b) Kn c) Kp d) Ka

207) Which of the following is not a type of liquid crystal ?

a) Enteric b) Cholesteric c) Smectic d) Nematic

208) The unit of equilibrium constant Kc for the reaction N2 + 3H2 2NH3
a) dm+6 mole-2 b) mole2 dm-6 c) mole dm-3 d) having no units

209) Solvent extraction method is particularly useful technique for separation when the product to be separated is
a) Non-volatile or b) Non-volatile or c) Volatile or thermally d) Volatile or thermally
thermally unstabel thermally stable stable unstable

210) The pH of 10-3 mol dm-3 of an aqueous solution of H2SO4 is

a) 3.0 b) 2.7 c) 2.0 d) 1.5

211) Law of mass action was given by Guldberg and Waag in

a) 1909 b) 1906 c) 1846 d) 1864

212) For a hypothetical reaction A + 2B products , the rate law is rate = k [A] [B]. the order of reactions is

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a) 1 b) 2 c) 3 d) 4

213) Quantum number values for 2p orbitals/subshell are.

a) n = 2 , I = 1 b) n = 1 , I = 0 c) n = 1 , I = 2 d) n = 2 , I = 0

214) The solubility product of AgCI is 2.0 × 10-10 mol2dm-6. The maximum concentration of Ag+ ions is the solution is.
a) 2.0 × 1010 moldm3 b) 1.0 × 1010 moldm3 c) 1.41 × 105 moldm3 d) 4.0 × 1020 moldm3

215) The molecules of CO2 in dry ice from the .

a) Ionic crystals b) Molecular crystals c) Covalent crystals d) Amorphous

216) Which one is not sublimable in laborarory ?

a) NH4Cl b) Benzonic Acid c) Naphthalene d) AlCl3

217) When water freezes at 00C , its density decreases due to

a) Cubic structure of ice b) Empty spaces present c) Change of bond length d) Change of bond angles
in the structure of ice

218) The relation used to calculate root mean square velocity of gases is

a) b) c) d)

219) The nature of positive rays depends upon

a) Nature of electrode b) Nature of residual gas c) Nature of discharge tube d) None of Above

220) The wave number of the light emitted by a certain source is 2 × 10 6 m-1 . The wavelength of this light will be .
a) 500nm b) 500m c) 200nm d) 5 × 107 m

221) Two solutions of NaCl ans KCl are prepared separated by dissolving same amount of solution in water. Which of the
following statement is true for these solutions?
a) KCl solution will have b) Both the solutions have
higher boiling point than different boiling points
NaCL

222) At 1000C a gas has 1 atm . Pressure and 10 dm3 volume . Its volume at S.T.P would be
a) 10 dm3 b) less then 10 dm3 c) More than dm3 d) Cannot be predicted

223) Which substance is not a dehydrating agent?

a) CdCI2 b) CaCI2 c) Silica gel d) P2O5

224) Number of molecules in one dm3 of water is close to

a) 55.6 x 6.02 x 1023 b) c) d)

225) Isotopes differ in

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a) Properties which b) Arrangement of electrons c) Chemical properties d) The extent to which they
depend upon mass in orbitals may be affected in
electromagnetic field

226) When ionic product of a solution is greater than the solubility product at a particular temperature then the solution is said
to be
a) Unsaturated b) Satrurated c) Very dilute d) Super saturate

227) The wave number of the light emitted by a certain source is 2 × 106 m -1. The wavelength of this light
a) 500 nm b) 500 m c) 200 nm d) 5 × 107 m

228) Strength of an acid can determined by

a) pKa b) pKb c) pKw d) pOH

a) 10.5 b) 3.5 c) 8.5 d) 11.5

230) Graphite belongs to the crystal system ?

a) Hexagonal b) Monoclinic c) Cubic d) Tetragonal

231) A filtration process could be very time consuming if it were not aided by a gentle suction, which is developed.
a) If the paper covers the funnel b) If the paper has got c) If the stem of the funnel d) If the paper fits
up to its circumference small sized pores in it is large so that it dips into tightly
the filtrate

232) CH4 gas is maintained at 00C and 1 atm pressure . Its density is 0.714 g/dm3 . What is its density at 0.5 atm and 00C ?
a) 0.714 dm-3 b) 1.428 dm-3 c) 0.35 dm-3 d) 7.14 dm-3

233) In azeotropic mixture showing positive deviation from Raoult's law , the volume of the mixture is .
a) Slightly more then the b) Slightly less then the total c) Equal to the total volume d) None of these
total volume of the volume of the components of the components
components

234) Which of the following has strongest hydrogen bonding ?

a) CH4 b) NH3 c) HF d) HC

235) The maximum number of unpaired electrons are present in

a) Fe = 26 b) Ni = 28 c) Cr = 24 d) Na = 11

236) Isomorphism is present in K2 SO4 and K2CrO4 . These two compounds

a) Show same physical and c) Have difference ration of d) The shapes of both
chemical properties the atoms in them So2- 4 and CrO-2 4

237) How should the conditions be changed to prevent the volume of a given gas from expanding when its mass is increased?

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a) Temperature is b) Temperature is increased c) Temperature and d) Temperature and

lowered and pressure is and pressure is lowered pressure both are lowered pressure both are increased
increased

238) The force which are present between the ions and the polar molecular of the solvent are
a) Dipole-induced dipole b) Ion-dipole forces c) Dipole-dipole forces d) London dispersion forces
forces

239) Palladium has Isotopes.

a) 6 b) 7 c) 8 d) 9

240) An orbital which is spherical and symmetrical is.

a) s-orbital b) p-orbital c) d-orbital d) f-orbital

241) The spectrum of radiation from which particular radiation has been absorbed after passing through absorbing substance
is called
a) Continuous spectrum b) Line absorption c) Line emission spectrum d) Band spectrum
spectrum

242) The nature of positive rays depends on

a) The nature of electrodes b) The nature of discharge c) The nature of residual d) All of these
tube gas

243) The unit of Kc for reaction N2 + O 2NO will be

a) mol/dm3 b) mol-1/dm3 c) mol-2/dm+6 d) No unit

244) The value of radius of first Bohr's orbit of Hydrogen atom is

a) 0.229 × 10-10m b) 0.32 × 10-10m c) 0.429 × 10-10m d) 0.529 × 10-10m

245) The respiration process in the animals depends on the difference of

a) Osmotic pressure b) Partial pressure c) Vapour pressure d) Atmospheric pressure

246) Highest bond order is found in

a) O2 b) O2 -1 c) O2 -2 d) O2 +2

247) The value of the general gas constant R in SI units is

a) 8.3143 kj.K-1 .mole-1 b) 0.00821 dm3.atmK-1 c) 8.3143 JK-1 .mole- d) 62.4 dm3torrK-1 .mole-1
.mole-1 1

248) The Increase in atomic radii in a group is due to

a) Increase in atomic b) Increase in electropositivity c) Increase in number d) Increase in polarizability
mass of shells

249) Freezing point of equimolal aqueous solutions will be minimum for

a) Fructose b) Urea c) Glucose d) NH4Cl

250) 27 g of A1 will react completely with how much mass of O2 to produce Al2O3.

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a) 8 g of oxygen b) 16 g of oxygen c) 32 g of oxygen d) 24 g of oxygen

251) In the ground state of an atom , the electron is present

a) In the nucleus b) Nearest to the nucleus c) In the second shell d) Farthest from the nucleus

252) The number of Isotopes of Cadmium is.

a) 3 b) 4 c) 5 d) 9

253) Which of the following will have highest rate of diffusion?

a) O2 b) CO2 c) NH3 d) SO2

254) H-bonding is maximum

a) Ethanol b) Benzene c) Diethyl ether d) Water

255) The molarity of solution containing 1.5 g urea in 100 cm3 of the solution is
a) 1 molar b) 0.1 molar c) 0.2 molar d) 0.25 molar

256) Those solutions which show positive or negative deviations from Raoult's Law are called.
a) Ideal solutions b) Conjugate solutions c) Non ideal solutions d) Saturated solutions

257) Lyman series is obtained when electron in an atom jumps from higher energy level to
a) Ground level b) 2nd level c) 3rd level d) 4th level

258) Rate of a chemical reaction depends upon

a) The number of fruitful b) The number of fruitless c) The number of total d) The number of molecules
collisions per second collisions per second collisions per second taking part in a chemical
reaction

259) The S.I unit of pressure is.

a) Torr b) mmHg c) Pounds inch-2 d) Nm-2

260) The standard reduction potential of Ag and Zn are + 0.80 and - 0.76V respectively . Which of the following conclusions
can be drawn from the data ?
a) Ag is a poor Oxidizing b) Zn has greater c) Zn will always act as a d) Ag dsplaces Zn from a
agent tendency than Ag to from reducing agent solution containing Zn ion
positively charged ion

261) ____ is king of chemicals .

a) HNO3 b) H2SO4 c) H2O d) HCl

262) The boiling point of water at the top of Mount Everest is.
a) 690C b) 590C c) 830C d) 750C

263) The spectral line obtained when an e- jumps from n = 6 to n = 3 belongs to which series ?
a) Lyman series b) Paschen series c) Balmer series d) Pfund series

264) Common ion effects finds extensive applications in the qualitative analysis and the preparation of

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a) Ammonia b) NaOH c) Buffers d) None of these

265) The highest temperature at which a substance can exist as liquid at its critical pressure is.
a) Absolute zero b) Critical temperature c) Consulate temperature d) Transition temperature

266) In endothermic reactions, the heat content of the.

a) Products is more than b) Reactants is more than c) Both A & B d) Reactants and products
of reactansts that of products are equal

267) Which of the following crystal systems represent the structure of sugar.
a) Triclinic b) Monoclinic c) Cubic d) Tetragonal

268) For which system does the equilibrium constant Kc has units of ( concentration ) -1 ?
a) 3H2 2NH3 b) 2NO2 N2O4 c) H2 + I2 2HI d) 2HF H 2 + F2

269) Density of ice is maximum at 40C due to

a) Empty spaces in b) Lage bond lengths c) Tetrahedral shape of crystal d) Large bond angles
structure of ice if ice

270) The spreading of fragrance of a rose or scent in air is due to.

a) Effusion b) Diffusion c) Osmosis d) Evaporation

271) The range of visible region of spectrum is form

a) 300 - 750 nm b) 400 - 750 nm c) 300 - 650 nm d) 400 - 850 nm

272) The electrode reaction of a voltaic cell can be reversed when

a) Concentration of solutions b) Electrodes are c) Temperature is increase d) External circuit is
is changed interchanged employed to supply the
source of electricity

273) Equal masses of methane and oxygen are mixed in an empty container at 250C. The fraction of total pressure exerted by
oxygen is.

a) b) c) d)

274) Partial pressure of oxygen in the air is.

a) 156 toor b) 157 toor c) 158 toor d) 159 toor

275) One mole of SO2 contains

a) 6.02x1023 atoms of b) 6.02x1023 atoms of c) 18.1 x 1023 molecules of d) 4 gram atoms of SO2
oxygen sulphur SO2

276) Solvent extraction method is a particularly useful technique for separation when the product to be separated is:
a) Non-volatile or b) Non-volatile or c) Volatile or thermally d) Volatile or thermally
thermally unstable thermally stable stable unstable

277) If 5.85 g of NaCl ( Mol , mass 58.5 ) is dissolved in 90 g of H2O , the mole fraction of NaCl will be

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a) 0.01 b) 0.1 c) 0.0196 d) 0.3

278) Geometry of SO2 molecule is

a) Linear b) Angular c) Tetrahedral d) Trigonal pyramidla

279) Most crystals show good cleavage because their atoms , ions and molecules are
a) Arranged in planes b) Spherically symmetrical c) Weakly bounded d) Strongly bounded
together together

280) Silver has _______ isotopes.

a) Nine b) Ten c) Eleven d) Sixteen

281) The iodine present in water can be separated by which one of the following techniques ?
a) Sublimation b) Chromatography c) Filtration d) Solvent extraction

282) Which element has highest ionization potential ?

a) Li b) Be c) B d) C

283) Molarity of pure water is.

a) 1 b) 55.5 c) 18 d) 16

284) According to Bohr's model , the radius of the second orbit is

a) 2 0A b) 2.1 0A c) 2.11 × 10-11 m d) 2.11 × 10-12 m

285) The change in heat energy of a chemical reaction at constant temperature and pressure is called
a) Enthalpy change b) Heat of sublimation c) Bond energy d) Internal energy change

286) The pH of human blood is

a) 7.0 b) 7.4 c) 4.0 d) 6.5

287) The unit of Kc for reaction N2(g) + O2(g) 2NO(g) will be.
a) moles / dm3 b) mole-1 / dm3 c) mole-2 dm+6 d) No unit

288) An ionic compound A+B- is most likely to be formed when

a) The ionization energy A b) The ionization energy c) Both The ionization d) Both The ionization
is high and electron affinity A is low and electron energy A is high and energy A is high and
of B is low affinity of B is high electron affinity of B is high electron affinity of B is low

289) In mass mole relationship if we are given with mass of substance the we can calculate _________ of other substance .
a) Mass b) No. of electron c) Moles d) None of these

290) The H - H bond energy in KJ mole-1 is.

a) 346 b) 436 c) 463 d) 336

291) Enthalpy of neutralization of all the strong acids and strong bases has the same value because

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a) Neutralization leads to the b) Strong acids and bases c) Acids always give d) The net chemical
formation of salt and water. are ionic substances. rise to H+ ions and change involve the
bases always furnish combination of H+ and OH-
OH- ions. ions to form water
292) When 5th orbital is completed then entering electron goes into
a) 6s b) 6p c) 6d d) 6f

293) Which of the following statements is true?

a) Isotopes with even b) Isotopes with odd atomic c) Isotopes with even d) Isotopes with even
atomic masses are masses are comparatively atomic and even atomic atomic and odd atomic
comparatively abundant abundant masses are comparatively masses are comparatively
abundant abundant
294) Which one is not AB4 type molecule according to VSEPR theory ?
a) SO2 b) SO4 2- c) PH3 d) H2S

295) The number of moles of CO2 which contain 8.0 g of oxygen

a) 0.25 b) 0.50 c) 1.0 d) 1.50

296) An ionic compound A+B- is most likely to be formed when

a) The ionization energy of b) The ionization energy c) Both the ionization energy d) Both the ionization
A is high and electron of A is low and electron of A andelectron affinity of energy of A and electron
affinity of B is low. affinity of B is high. B are high. affinity of B are low.

297) The weakest intermolecular forces present in a liquid may be

a) Dipole-induced dipole b) Dipole-dipole forces c) London Dispersion d) Electrostatic forces
force forces between ions in ionic solid

298) The Born-Haber cycle is the best application of law

a) Boyle's law b) Hess's law c) Dalton's law d) Graham law

299) To prepare a buffer with pH close to 9.0 you could use mixture of
a) NH4OH and NH4Cl b) HNO2 and NaNO2 c) CH3COOH and d) H2CO3 and NaHCO3
CH3COONa

300) The volume occupied by 16g of CH4 at S.T.P.

a) 224.14 dm3 b) 22.414 dm3 c) 1.12 dm3 d) 2.24 dm3

301) Which of the following is the mathematical expression of First Law of Thermodynamics ?
a) q = m.S. T b) E = q - PVV c) H= E+P V d) H= E

302) An Angstrom is the unit of

a) Time b) Length c) Mass d) Frequency

303) The synthesis of Ammonia was developed by German chemist .

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a) Bohar b) Le-chaterlier c) F.Haber d) None of these

304) The e/m value for the positive rays is maximum for
b) Helium c) Oxygen d) Nitrogen

305) The oxidation number of chromium in K2Cr2O7 is

a) 4 b) 2 c) 6 d) 3

306) The pH of rain water is

a) 7 b) 7.3 c) 6.2 d) 5.0

307) An orbital which is spherically symmetrical is

a) s-orbital b) p-orbital c) d-orbital d) f-orbital

308) The order of the rate of diffusion of gases NH3, SO2, CI2 and CO2 is.
a) NH3 > SO2 > CI2 > b) NH3 > CO2 > SO2 > c) NH3 >CO2 > CI2 > SO2 d) CI2 > SO2 > CO2> NH3
CO2 CI2

309) Air is a mixture of gases . The molecules of the air are not settled down due to
a) Different molar masses b) Pressure of dust particles d) Collision of gas
in the air molecules

310) ______ is not paramagnetic

a) O2 -2 b) O2 c) N2 -2 d) None of these

311) What is the ratio of volume of 2g of H2 to the volume of 16g CH4 both volumes are at STP
a) 1:8 b) 1:2 c) 1:1 d) 2:1

312) The amount of products calculated from balanced chemical equation represents .
a) Actual yield b) Theoretical yield c) Both A & B d) None of these

313) The optimim temperature for the synthesis of NH3 by Haber's process is.
a) 2000 C b) 3000 C c) 4000 C d) 5000 C

314) The lines of the Balmer series lie in the visible region of the spectrum , but the limiting line , in the series lies in
a) Visible region b) I.R region c) X-Ray region d) U.V. region

315) The density of CH4 at 2 atm pressure at 270C is

a) 26 g dm3 b) 0.26 g dm3 c) 1.3 g dm-3 d) 0.13 g dm-3

316) Formation of a chemical bond takes place when

a) Energy is absorbed b) Forces of repulsion c) Force of attraction are d) Forces of attraction
overcome forces of equal to force of repulsion overcome forces of
attraction repulsion

317) In order to mention the B.P. of water at 1100C, the external pressure should be.

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a) Between 760 torr and b) Between 200 torr and 760 c) 765 torr d) Any value of pressure
1200 torr torr

318) Which of the following gives correct relation.

a) b) c) d)

319) In electro-chemical series , the electrodes are compared with SHE and they are arranged in the decreasing order of
a) Cell voltage b) Reduction potential c) Ionization potential d) Oxidation potential

320) Colligative properties are useful in calculating the

a) Solubility of the b) No . of water molecules of c) Molecular masses of d) Valence of ions
substance crystallization the solute

321) During the process of crystallization, the hot saturated solution.

a) Is cooled very slowly b) Is cooled at moderate c) Is evaporated to get the d) Is mixed with an
to get large sized crystals rate to get medium sized crystals of the product immiscible liquid to get the
crystals pure crystals of the product

322) One dm3 of H2 and one dm3 have same number of molecules at STP , their respective masses are
a) 0.1 g and 4.3 g b) 2 g and 32 g c) 0.0899 g and 1.4384 g d) 4 g and 16 g

323) The number of molecules in one dm3 of water is close to

a) 55.6 × 6.02 × 1023 b) c) d)

324) Mass of electron is

a) 9.1095 × 1031 kg b) 9.1095 × 10-31 kg c) 9.1095 × 10-27 kg d) 9.1095 × 10-31 g

a) Slow b) Fast c) Exothermic d) Endothermic

a) Increases during the c) Decreases as the d) Reaction same

reaction reaction proceeds

a) Electron b) Proton c) Neutron d) -particle

328) Splitting of spectral line when atoms are subjected to strong electric field is
a) Zeeman effect b) Stark effect c) Photoelectric effct d) Compton effect

329) Which of the following has highest percentage ionic character.

a) HCI b) HF c) HBr d) HI

330) The sum of the mole fractions of the components of a solution is equal to
a) Zero b) One c) Two d) Three

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331) Which pair of orbitals is degenerate pair ?

a) sp3 . sp3 b) sp3 . sp2 c) sp . sp2 d) sp3 . sp

332) The Lightest value of Lattice energy is for which one of these ionic compounds.
a) NaI b) NaF c) NaBr d) NaCI

333) The product PV of a gas is a unit of

a) Force b) Entropy c) Work d) Impulse

334) 1 dm3 of O2 at STP contains

a) 6.02 × 1023 molecules b) 0.602 × 1023 molecules c) 0.602 × 1022 molecules d)

335) When Non-spontaneous redox reaction is carried out by using the electrical current , then the process is called
a) Decomposition of the b) Electrolysis c) Hydrolysis d) Exothermic process
substances

336) Calorie is equivalent to

a) 0.4184J b) 41.84J c) 4.184J d) 418.4J

337) Which of the following will have the same number of molecules at STP ?
a) 280 cm3 of CO2 and b) 44 g of CO2 and 11.2 c) 1 dm3 of O2 and 32 g of d) 28 g of N2 and 5 dm3 of
280 cm3 of N2O dm3 of CO O2 O2

338) Shielding effect of the inner electrons is responsible for

a) Increasing electron b) Increasing Ionization c) Decreasing Ionization d) Electro Negativity
affinity energy energy

339) Which is not used as drying agent in a desiccator?

a) CaCI2 b) NaCI c) P2S5 d) Silica gel

340) Heisenberg's uncertainty principle is not applicable to

a) Electron b) Proton c) Neutron d) A dust particle

341) Upper-consulate temperature for water- phenol system is.

a) 1500 C b) 65.90 C c) 1200 C d) 1300 C

a) dm-6 mole2 s-1 b) dm3 mole s-1 c) dm6 mole-2s-1 d) dm3 mole-1 s-1

343) One of the following substances does not undergo sublimation .

a) KMnO4 b) Naphthalene c) NH4Cl d) Iodine

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a) Spectrum of " H " atom b) Spectrum of atom or c) Spectrum of H2 d) Spectrum of multi
-
only ion containing one e only molecule electronic atoms

345) Which of the following has highest mass at S.T.P ?

a) 6.02 × 1022 molecules of b) 2 moles of CH4 c) 0.1 g mole of N2O d) 22.4 dm3 of CO2 at .
CO2 S.T.P.

346) Which of the hydrogen halide has the highest percentage of ionic character?
a) HCI b) HBr c) HF d) HI

347) Which of the hydrogen halides has the highest percentage of ionic character?
a) HCl b) HBr c) HF d) Hl

348) Which of the following statement is contray to the first law of thermodynamics ?
a) Energy can neither be b) One from of energy can c) Continuous production d) In an adiabatic process ,
created nor be destroyed be transferred into an of mechanical work without the work done is independent
equivalent amount of other supplying an equivalent of its path
kind of energy amount of heat is possible

349) Mathematical expression of compressibility factor is

a) b) c) d)

350) The mass of two moles of electrons is.

a) 1.10 mg b) 1.008 mg c) 0.184 mg d) 1.673 mg

351) In AI2O3 , the ratio between the ions is.

a) 1:2 b) 2:1 c) 2:3 d) 3:2

352) More ideal gas at room temperature is

a) CO2 b) NH3 c) SO2 d) N2

353) Haemoglobin is a Marco Molecule and consists of approximately atoms.

a) 5,000 b) 10,000 c) 68,000 d) 15,000

354) Pressure remaining constant , at which temperature the volume of a gas will becomes twice of what it is at 00C ?
a) 546 C b) 200 C c) 546 K d) 273 K

355) The largest number of molecules are present in

a) 3.6g of H2O b) 4.8g of C2H5OH c) 2.8g of CO d) 5.4g of N2O5

356) The process in which liquid can be made to boil at low temperature in known as ........... distillation.
a) Simple b) Thermal c) Steam d) Vaccum

357) Splitting of spectral lines when atoms are subtracted to strong electric field is called?
a) Zeeman effect b) Stark effect c) Photoelectric effect d) Compton effect

358) Hydrolysis of Tertiary butyl bromide has order of reaction

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a) First order b) Pseudo first order c) Second order d) Third order

359) An ionic compound will dissolve in water only if

a) Hydration Energy < b) Lattice energy c) Bond energy in low d) Bond energy in high
Lattice energy < Hydration Energy

360) The unit of the rate constant is same as that of the rate of reaction in .
a) First order reaction b) Zero order reaction c) Second order reaction d) Third order reaction

361) The net heat change in a chemical reaction is same,whether it is brought about in two or more different ways in one or
several steps. It is known as
a) Henry’s law b) Hess’s law c) Joule’s principle d) Law of conservation of
energy

362) Azimuthal quantum number gives us the information about

a) Size of orbital b) Shape of orbital c) Structure of orbital d) Spin of electron

363) The temperature of natural plasma is about

a) 20,0000C b) 10,0000C c) 50,0000C d) 10000C

364) The electron in a subshell is filled according to formula.

a) 2n2 b) 2(2I + 1) c) (2I + 1) d) None of these

365) The number of moles of CO2, which contain 8.0 of oxygen.

a) 0.25 b) 0.15 c) 0.35 d) 1.45

366) A redox reaction is

a) Ion combination reaction b) Proton transfer c) Electron transfer d) Proton combination
reaction reaction reaction

367) Pressure remaining constant, at which temperature the volume of a gas will become twice of what it is at 0°C.
a) 546°C b) 200°C c) 546K d) 273K

368) _________ molecule has zero dipole moment.

a) CO b) H2S c) SO2 d) CH4

369) Which salt when dissolved in water forms a solution with a pH greater than 7
a) NaCl b) CuSO4 c) Na2CO3 d) NH4Cl

370) Strong the oxidizing agent , greater is the .

a) Oxidation potential b) Redox potential c) Reduction potential d) E.M.F of cell

371) If Kc of reaction is very large , it indicates that equilibrium occurs.

a) At a low product b) With the help of c) At a high product
concentration catalyst concentration

372) The values of Kw of water at 250C is

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a) 0.11 × 10-14 b) 0.30 × 10-14 c) 1.0 × 10-14 d) 7.5 × 10-14

373) Positive rays were discovered by

a) Goldstein b) Rutherford c) J.J Thomson d) William Crookes

374) Nickle has Isotopes.

a) 3 b) 5 c) 6 d) 11

375) Ionic solids are characterized by.

a) Low melting point b) Good conductivity in solid c) High vapours pressure d) Solubility in polar
state solvent

376) The cathodic reaction in the electrolysis of dil . H2SO4 with Pt electrodes is .
a) Reduction b) Oxidation c) Both oxidation and d) Neither oxidation and
reduction reduction

377) For HF molecule obs is 1.90 D ; ioni is 4.4 D . The percentage ionic character of HF molecule is.

a) 100% b) 80% c) 57% d) 43%

378) Crystals can be classified into

a) 7 crystal systems b) 4 crystal systems c) 3 crystal systems d) 14 crystal systems

379) 10A = __________ m

a) 10-10 b) 10-11 c) 10-12 d) 10-13

380) Number of moles in 100g of KClO3 .

a) 0.76 b) 0.56 c) 0.014 d) 0.816

381) Covalent bonds are

a) Rigid and directional b) Rigid and non c) Non Rigid and d) Non Rigid and non
directional directional directional

382) Bromine has Isotopes.

a) 8 b) 6 c) 4 d) 2

383) In stoichiometric calculate all the reactants must converted into

a) Products b) Reactants c) Both A & B d) Molar mass

a) Appearance of new d) Appearance of new

phase phase and solubility of
substance

385) The highest temperature above which a gas cannot be liquefied , no matter how much the pressure is applied is known as
a) Boiling temperature b) Absolute zero c) Consulate temeprature d) Critical temperature

386) Who proposed the quantum theory

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a) J.J. Thomson b) Max planck c) Rutherford d) Bohar

387) All radioactive disintegration nuclear reactions are of

a) First order b) 2nd order c) 3rd order d) Zero order

388) In zero order reaction , the rate is independent of

a) Temperature of reaction b) Concentration of products d) Pressure of reaction

389) Hydrogen bonding is extensively present in proteins between

a) Nitrogen and hydrogen b) Carbon and hydrogen c) Oxygen and hydrogen
atoms atoms atoms

390) Feeling uncomfortable breathing in un-pressurized cabins is due to.

a) High pressure of CO2 b) Fatigue c) Low Pressure of O2 d) Low Pressure of CO2

391) Quantum number value for 2p orbitals are

a) n = 2 , l = 1 b) n = 1 , l = 0 c) n = 0, l = 2 d) n = 2, l = 0

392) Which of the following relationships is incorrect ?

a) K = C0 + 273 b) c) d)

a) The atom did not have a b) It did not account for the c) It did not account for d) There is actually no
nucleus and electron attraction between proton the stability of the atom space between the nucleus
and neutrons and the electrons

394) Which of the following has the highest boiling point?

a) 5.85% solution of b) 18.0% solution of glucose c) 6.0% solution of urea d) All have the same
sodium chloride boiling point

395) The average distance of an electron from the nucleus of an atom is

a) 10-20 cm b) 10-12 cm c) 10-8 cm d) 10-4 cm

396) Which is correct relation ?

a) b) c) d)

397) Molecule in which the distance between two carbon atoms in the largest is.
a) C2H6 b) C2H4 c) C2H2 d) C6H6

398) Select the most suitable answer from the given ones in each question.
a) Isotopes with even b) Isotopes with odd atomic c) Isotopes with even d) Isotopes with even
atomic masses are masses are comparatively atomic masses and even atomic masses and odd
comparatively abundant. abundant. atomic numbers are atomic numbers are
comparatively abundant. comparatively abundant.

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399) The gas law giving relationship between volume and temperature of gas is
a) Dalton's law b) Charl's law c) Graham's law d) Boyle's law

400) For a given reaction which description is correct ?

CH4 + 2O2 CO2 + 2H2O
a) Heat of oxidation b) Heat of combustion of c) Endothermic reaction d) Heat of Atomization
CH4

401) In the presence of common ion, the ionization of an electrolyte will.

a) Increase b) Decrease c) No effect d) Moderate change

402) When a reaction proceeds in more then one steps the overall rate is determined by
a) Fastest step b) Rate cannot be determined c) Slowest step d) Any step can be used

403) Charge on an electron is

a) 1.602 × 10-19C b) 9.1 × 10-34C c) 1.7588 × 1011C d) 6.625 × 10-34C

404) Diamond is bad conductor because.

a) It has a tight structure b) It has a high density c) It is transparent to light d) There are no free
electrons present in the
crystal of diamond to
conduct electricity
405) The Chemical reactions in which reactants requite high amount of activation energy are generally
a) Slow b) Fast c) Instantaneous d) Spontaneous

406) Plastics are amorphous solids and

a) Have sharp melting b) Undergo clean cleavage c) Do not undergo clean d) Possess orderly
point when cut with knife cleavage arrangement over long
distances

407) After 2 half lives of a chemical reaction , the % fraction of the amount left is
a) 6.25 b) 75 c) 12.5 d) 50

408) Body temperature of a normal person is

a) 97.60F b) 96.80F c) 98.40F d) 98.60F

409) The number of Cl- ions per unit cell of NaCl are
a) 6 b) 4 c) 2 d) 8

a) Common Ion effect b) Le-Charterlier c) Law of mass action d) Bronsted Acid-Base
Theory

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a) Is taken is lesser b) Is taken is lesser c) Gives the maximum d) Gives the minimum
quantity to the amount in quantity in volume as per amount of the product amount of the required
gram required its required required product

a) Light b) Heat c) Both A & B d) None of these

413) 4 gm of H2 gas at STP occupies volume of

a) 60 lit b) 44.8 lit c) 35.5 lit d) 22.4 lit

414) Which of the following is correct for energy when we go from lower to higher orbits in case of Bohr's atomic model
a) E2 - E1 < E3 - E2 > E3 - b) E3 - E2 < E2 - E1 > E4 - c) E2 - E1 < E3 - E2 > E4 d) E3 - E4 < E3 - E2 > E4 -
E4 > .............. E3 > ............. - E3 > ............................ E3 > .............

415) Orbitals having same energy are called.

a) Hybrid orbitals b) Degenerate orbitals c) Valence orbitals d) d-orbitals

416) A certain mass of a gas occupies a volume of 2 dm3 at STP . Keeping the pressure constant , at what temperature would
the gas occupies a volume of 4 dm3 ?
a) 3000C b) 546 K c) 500K d) 1000C

417) NaCl has face centered cubic structure . The Na + ion at the faces of the unit cell is shared by
a) 2 unit cells b) 4 unit cells c) 8 unit cells d) Only one unit cell

418) The net heat change in a chemical reaction is same whether it is brought about in two or more different ways in one or
several steps. It is known as.
a) Henry's law b) Hess's law c) Joule's principle d) Law of conservation of
energy

419) Feeling uncomfortable breathing in un-pressurized cabin is due to

a) High pressure of CO2 b) Low pressure of O2 c) Low pressure of CO2 d) High pressure of O2

420) The mass of one mole of electron is

a) 1.008 mg b) 0.55 mg c) 0.184 mg d) 1.673 mg

421) The suppression of ionization of weak electrolyte by adding a _____ from outside is called common ion effect.
a) Acid b) Base c) None of these d) Common ion

422) Cu metal can be purified in electrolytic cell by making the impure Cu are
a) Anode b) By making its CuSO4 c) Cathode d) SHE
solution

423) The standard electrode potential ( in volt ) of SHE is taken as

a) 0.00 b) 1.00 c) 10.0 d) 100

424) Which of the following has linear structure ?

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a) CO2 b) NH3 c) CH4 d) H2O

425) Solvent extraction is an equilibrium process and it is controlled by.

a) Law of mass action b) Distribution law c) The amount of solute d) The amount of solvent
used

426) Orbital having same energy are called

d) d-orbital

427) Catalyst used in preparation of NH3 from N2 and H2 is

a) Fe b) Ni c) Pt d) V2O5

428) Acetone and chloroform are soluble in each other due to

a) Intermolecular hydrogen b) Instantaneous dipoles c) Dipole-dipole d) Ion dipole forces
bonding interaction

429) The process of synthesis of Ammonia was first used in

a) 1934 b) 1933 c) 1935 d) 1932

430) The isotherm of CO2 changes the position in the graph by changing the temperature in such a way that
a) The curve comes b) The curve goes from c) The curve are converted d) The curve becomes
closer to the axis by the axis by increasing the into straight line at high discontinuous at 31.50C
increasing pressure temperature temperature

a) Enthalpy change b) Bond energy c) Heat of sublimation d) Internal energy change

a) Benzene - toluene b) Ethanol - water c) Benzene - ether d) None of these

a) Pressure b) Volume c) Temperature d) Heat

a) b) c) d) All of these

435) Which of the following species has unpaired electrons in antibonding molecular orbitals.
a) 02 2+ b) N2 2- c) B2 d) F2

436) The structure of NaCl crystal is

a) Body centered cubic b) Square planar c) Face centered cubic d) Octahedral
lattice lattice

437) De-Broglie equation is represented by

a) b) c) d)

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438) One mole of water contains .

a) 81 g water b) 6.02 × 1023 atoms c) 6.02 × 1023 inons d) 6.02 × 1023 molecules

439) Which of the following solutions have highest pH ?

a) 0.1M H2SO4 b) 0.02 M CH3COONa c) 0.01 M NaOH d) 0.01 M NaHCO3

440) The drying agent used in a desiccator.

a) AgCI b) NH4CI c) P2O5 d) AICI3

441) The boiling point of pure water at 1 atm pressure is.

a) 1000C b) 980C c) 690C d) 1200C

442) The unit of the rate constant is same us that of the rate of reaction in
a) First order reaction b) Zero order reaction c) Second order reaction d) Third order reaction

443) A limiting reactant is the one which

a) Is taken in lesser b) Is taken in lesser c) Gives the maximum d) Gives the minimum
quantity in grams as quantity in volume as amount of the product amount of the product under
compared to other compared to the other which is required. consideration.
reactants. reactants.

444) Variation of a physical property in a crystal in different directions is called

a) Absence of symmetry b) Anisotropy c) Isomorphism d) Polymorphism

445) The reduction potential of Zn is

a) + 0.76V b) - 0.34V c) + 0.34V d) - 0.76V

446) The solubility of Ce ( SO4 )3

a) Is independent of b) Decreases with the c) Decrease with the d) Increases with the
temperature increase in temperature decrease in temperature increases in temperature

447) Acetone and chloroform are soluble in each other due to

a) Intermolecular hydrogen b) Instantaneous dipole c) Ion-dipole interaction d) All of the above
bonding

448) The molar volume of CO2 is maximum at

a) STP ( 00C and 1 atm ) b) 00C and 1 atm c) 1270C and 1 atm d) 2730C and 2 atm

449) The nature of residual gas

a) Independent of its b) Depends on its c) Equal to its square of its d) Depends on its source
wavelength wavelength magnitude

450) Gas equation is derived by combining .

a) Avogadro's and Charls' b) Avogadro's and Boyle's c) Avogadro's , Charls' d) Charls' law and
law law and Boyle's law Boyle's law

451) The comparative rates at which the solutes move in paper chromatography, depend on:

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a) The size of paper b) Temperature of the c) R values Of d) Size of the chromatographic
experiment solutes tank used

452) The rate of reaction .

a) Increase as the reaction b) Decreases as the c) Remains the same as the d) May decrease or
proceeds reaction proceeds reactions proceeds increase as the reaction
proceeds

453) Concept of Elliptical orbits in an atom was proposed by

a) Bohr b) Heisenberg c) Schrodinger d) Sommerfeld

454) The electrolysis of aqueous solution of NaCl is employed to prepare caustic soda on commercial scale . The reaction at
the cathode is
a) Formation of water b) Oxidation of Cl ions c) Reduction of H ions d) Reduction of Na ions
molecule

455) Colligative properties are the properties of

a) Dilution solutions b) Concentrated solutions which c) Both A & B d) Neither ( a ) nor ( b)
which behave as nearly behave as nearly non-ideal
ideal solutions solutions

456) The sum of pH and pOH at 250C always equal to

a) 7 b) Zero c) 14 d) 10-14

457) Silver has ________ natural isotopes.

a) Nine b) Two c) Eleven d) Sixteen

458) Neutron was discovered by

a) Rutherford b) Bohr c) Goldstein d) James Chadwick

459) Which equation correctly presents the Heisenberg's uncertainty principle.

a) b) c) d)

460) In chromatography liquid crystal are used as_______

a) Solute b) Solvent c) Substrate d) None of these

461) Solvent extraction is an equilibrium process and it is controlled by

b) Distribution law c) The amount of solvent d) The amount of solute
used

462) The voltage of Nickel Cadmium cell is.

a) 1 V b) 1.2 V c) 1.4 V d) 1.6 V

463) What is the maximum mass of chromium that can be extracted from 76g of Cr2O3 ?
a) 48g b) 52g c) 104g d) 152g

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464) Van-der Waal's forces are weak intermolecular forces , they include
a) Dipole-Dipole forces b) Ion-Dipole forces only c) Dipole-induced dipole d) All of the above
only forces only

465) London dispersion forces are the only forces present among the
a) Molecules of water in b) Atoms of helium in c) Molecules of solid d) Molecules of hydrogen
liquid state gaseous state at high iodine. chloride gas.
temperature

466) For which system does the equilibrium constant Kc has units of ( concentration ) ?
a) N2 + 3H2 2NH3 b) 2NO2 N2O4 c) H2 + I2 2HI d) 2HF H 2 + F2

467) The formula for density of a gas at a given temperature and pressure is
a) b) c) d)

468) The sub-shell which has highest energy is

a) 4d b) 5d c) 6s d) 6p

469) The structure of Ammonia is

a) Linear b) Bipyramidal c) Tetragonal d) Triangular pyramidal

470) Oxidation number of Cr in K2CrO4 is

a) +2 b) +4 c) +6 d) +8

471) The molar boiling point constant is the ratio of the elevation in boiling point to
a) Molarity b) Molality d) Mole fraction of solute

472) n + I value of 6d orbital is.

a) 08 b) 09 c) 10 d) 11

473) A basic buffer solution can be prepared by mixing

a) Weak acid and its salt b) Strong acid and its salt c) Strong base and its salt d) Weak base and its salt
with strong base with weak base with weak acid with strong acid

474) Which orbital lies upon the axis?

a) dz2 b) dxy c) dyz d) dxz

a) 5.85% solution of b) 18% solution of glucose c) 6% solution of urea d) All have the same
NaCl boiling point

a) Potential difference b) Potential failure c) Both A & B d) None of these

a b

a) 7 b) 1 c) 14

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478) Which one of the following is not an example of voltaic cell

a) Ni - Cd cell b) Fuel cell c) Down's cell d) Silver oxide battery

479) Glucose can be converted into ethanol by an enxyme.

a) Lipase b) Zymase c) Sucrose d) Urease

480) For a given process, the heat changes at constant pressure (qp) and at constant volume (qv ) are related to each other as
a) qp = qv b) qp < qv c) qp > qv d) qp =qv / 2

481) Stoichiometry tells us the ______ relationship between reactants and products .
a) Qualitative b) Quantitative c) Both A & B d) None of these

482) The boiling point of water at Murree Hills.

a) 900C b) 980C c) 1000C d) 1200C

483) The solid which has no definite crystalline shape

a) Sugar b) Salt c) Glass d) Dry ice

484) The number of water molecules in CuSO4 attacked with Cu2+ ion
a) One b) Two c) Three d) Five

485) According to common Ion effect ______ soluble salt is precipitated out first .
a) More b) Less c) Unreactive d) Insoluble

486) The number of f-orbitals associated with n = 5

a) 5 b) 6 c) 7 d) 8

487) Which of the following has bond angle of 1200 ?

a) BF3 b) NH3 c) CH4 d) BeCl3

488) The measurement of enthalpy change at standard condition means that we should manage the measurement at.
a) 240C at 1 atm b) 250C at 1 atm c) 00C at 1 atm d) 1000C at 1 atm

489) If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of the surrounding air.
a) Remains constant b) Decreases c) Increases d) Remain unchanged

490) Rutherford's experiment of scattering particles showed for 1st time that an atom has
a) Electron b) Proton c) Nucleus d) Neutrons

491) Tin has Isotopes.

a) 9 b) 10 c) 11 d) 12

492) The type of hydridization in BeCl2

a) sp3 b) sp2 c) sp d) dsp2

493) The value of the general gas constant R in SI units is

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a) 8.3143 kj.K-1 .mol-1 b) 0.0821 dm3 .torr.K-1 c) 62.4 dm3 .torr.K-1 .mol-1 d) 8.3143 Nm.K-1 .mol-
.mol-1 1

494) If a solution has zero pH . The hydrogen ion concentration will be

a) 10-4 b) 10-3 c) 10-7 d) 1

495) Wave number has the unit

a) m b) cm c) m-1 d) No unit

496) The unit of rate constant depends on

a) Number of reactants b) Order of reaction c) Concentration terms d) Molecularity of reaction

497) What is molecular geometry of SO4 -2 ion ?

a) Tetrahedral b) Trigonal planer c) Trigonal pyramidal d) Linear

498) Gooch crucible is made of .

a) Glass b) Paper c) Teflon d) Procelain

499) The order of the rate of diffusion of gases NH3, SO2, Cl2, an CO2 is:
a) NH3 > SO2 > Cl2 > CO2 3 2 2 c) Cl2 > SO2 > CO2 > NH3 d) NH3 > CO2 > Cl2 > SO2
2

500) Both Ebullioscopic and cryoscopic constants depend upon

a) Nature of solvent b) Nature of solvent and c) Nature of solute d) None of the above
solute

501) If the salt bridge is not used between two half cells , then the voltage .
a) Decreases repidly b) Decreases slowly c) Does not change d) Drops to zero

502) Standard enthalpies are measured at

a) 2730C b) 3730C c) 00C d) 298K

503) Splitting of specteal line of hydrogen atom under the influence of magnetic field is called
a) Photoelectric effect b) Zeeman effect c) Compton effect d) Stark effect

504) Buffers are not used in

a) Clinical Analysis b) Cell Biology c) Analytical Chemistry d) Salt Analysis

505) Which of the hydrogen halides has the highest percentage of ionic character ?
a) HCl b) HBr c) HF d) Hl

506) When a reaction proceeds in more than one steps the overall rate is determined by
a) Fastest step b) Rate cannot be determined c) Slowest step d) Any step can be used

507) The probability of finding the electron outside the nucleus is at a distance of
a) 0.83 m b) 0.053 m c) 0.053 nm d) 0.083 m

508) Spectrum of lines of pfund series of H-atom are produced when electron jumps down to

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a) Fifth orbit b) Third orbit c) Second orbit d) First orbit

509) The carbon atom is C2H4 is.

a) sp3 - hybridized b) sp - hybridized c) sG2 - hybridized d) dsG2 - hybridized

510) According to Kinetic Molecular Theory , Kinetic energy of molecules increase when they are
a) Mixed with other melecules b) Frozen to solid c) Melted from solid to d) Condensed to liquid
at low temperature liquid

511) In endothermic reactions, the heat content of the

a) Products is more than b) Reactants is more than c) Both (a) and (b) d) Reactants and products
that of reactants that of products are equal

512) Which molecule has sG2 - hybridization.

a) CH4 b) C2H4 c) C2H2 d) C2H6

513) Under a given set of experimental conditions , with increase of concentration of the reactants , the rate of a chemical
reaction .
a) Always decrease b) First decreases , than c) Always increases d) Remains same
increases

514) What is the value of ( n + l ) for the 3d sub-shell ?

a) 2 b) 1 c) 5 d) 3

515) The excess of aqueous silver nitrate is added to aqueous. Barium chloride and precipitate is removed by filtration .What
are the main ions in the filtrate .
+ -
b) Ag+ and Ba2+ and c) Ba2+ and NO3- d) None of these
3-
NO

516) The bond formation energy of a compound is

a) Less than bond b) Equal to bond c) Greater than bond d) Inversely proportional
dissociation energy dissociation energy dissociation energy to bond dissociation energy

517) Which of the following statements is correct about Galvanic cell ?

a) Anode is negatively b) Cathode is positively c) Reduction occurs at d) Oxidation occurs at
charged charged anode cathode

518) The mass of neutron is greater than electron by

a) 2000 times b) 300 times c) 1840 times d) 1580 times

519) London dispersion forces are the only forces present among the
a) Molecules of water in b) Atoms of helium in c) Molecules of solid d) Molecules of hydrogen
liquid state gaseous state at high iodine chloride gas
temperature

520) Which of the following is solution in which solvent and solute both are solids ?

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a) Butter b) Mercury in silver c) Smoke d) Steel

521) The units of Kc for the reaction of ammonia synthesis are

a) mol-2dm6 b) mol-1dm6 c) mol-2dm3 d) mol-2dm2

522) The number of isotopes of calcium is

a) Six b) Seven c) Five d) Nine

523) Which of the following statements is contrary to the first law of thermodynamics?
a) Energy can neither be b) One form of energy can c) In an adiabatic process, d) Continuous
created nor destroyed. be transferred into an the work done is production of mechanical
equivalent amount of other independent of its path. work without supplying an
kinds of energy. equivalent amount of heat is
possible.

524) The rate of reaction

a) Increases as the reaction b) Increase in activation c) Increases in number of d) Decreases as the
proceeds energy of reactans effective collisions reaction proceeds

525) The mass of one mole of electron is.

a) 1.008 mg b) 0.55 mg c) 0.184 mg d) 1.673 mg

526) The minimum energy more than the average energy required for the molecules to undergo reaction is
a) Internal energy b) Free energy c) Activation energy d) Kinetic energy

527) Amorphous solids

a) Have sharp points b) Undergo clean cleavage c) Have perfect arrangement d) Can possess small
when cut with knife of atoms regions of orderly
arrangement of atoms

528) The half life period for the decomposition of N2O5 is

a) 48 minutes b) 24 minutes c) 48 minutes d) 50 minutes

529) The correct expression derived for the energy of an electron in the nth energy level is

a) b) c) d)

530) Stoichiometry is a branch of ______

a) Physics b) Chemistry c) Biology d) English

531) Tendency of an atom to attract the shared pair of electrons is called

a) Ionization Energy b) Electronegativity c) Electron Affinity d) Electropositivity

532) For the reaction: NaOH+HCl NaCl+H2 O the change in enthalpy is called
a) Heat of reaction b) Heat of neutralization c) Heat of formation d) Heat of combustion

533) When - particles is bombarded over beryllium _______ is produced.

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a) Positron b) Proton c) Electron d) Neutron

534) Direct conversion of solid into its vapour is called

a) Crystallization b) Sublimation c) Vapourization d) Distribution

535) When 5d orbital is completed then entering electron goes into.

a) 6s b) 6p c) 6d d) 6f

536) The boiling point of glycerin at one atm is.

a) 2800C b) 2900C c) 1000C d) 1100C

537) Vapour pressure of a solution when non-volatile solute is added to a solvent is always
a) Abovethe vapour c) Less than the vapour d) Equal to atmospheric
pressure of the pure solvent pressure of the pure pressure
solvent

538) For an ideal gas at a constant T at which pressure its volume doubles , when the initial pressure is 2 atm.
a) 4 atm b) 101325 Nm-2 c) 1 torr d) 101325 torr

539) Which of the following statements is not correct about Galvanic cell ?
a) Anode is negatively b) Cathode is positively c) Reduction occurs at d) Reduction occurs at
charged charged anode cathode

540) The molal boiling point constant is the ration of the elevation in boiling point to
a) Molarity b) Mole c) Mole fraction of solvent d) Mole fraction of solute

541) The volume occupied by 1.4 g of N2 at S.T.P is.

a) 2.24 dm3 b) 22.4 dm3 c) 1.12 dm3 d) 112 dm3

542) Dipole moment of H2O is.

a) 1.61 D b) 1.85 D c) 0.95 D d) 1.49 D

543) Percentage ionic character of HF is.

a) 100% b) 80% c) 43% d) 57%

544) The amount of products obtained in a chemical reaction is called _______ yield of that reaction .
a) Required b) Low c) High d) Actual

545) Which of the following pairs can be separated by sublimation?

a) Sand and NaCl b) Sand and broken pieces c) Sand and naphthalene d) NaCl and KCl
of glass

546) The order of the reactions is 2NO + 2H2 2H2O + N2

a) Zero b) One c) Two d) Three

547) If an endothermic reaction is allowed to take place very rapidly in the air, the temperature of the surrounding air
a) Remains constant b) Decreases c) Increases d) Remains unchanged

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548) The cathodic reaction in the electrolysis of dilute H2SO4 with Pt electrodes is
a) Reduction c) Both Oxidation and d) Neither oxidation not
Reduction reduction

a) Henderson b) Sorenson c) Goldstein d) Thomson

550) The element nickel has isotopes.

a) 5 b) 2 c) 7 d) 3

551) Depression of freezing point of equimolal aqueous solutions will be maximum for
a) Sucrose b) Glucose c) NaCl d) Urea

552) Which of the following process always involve the decrease in oxidation number ?
a) Hydrolysis b) Decomposition c) Reduction d) Oxidation

553) Pressure remaining constant at which temperature the volume of a gas will become twice of what it is at 00C.
a) 5460C b) 2000C c) 5460K d) 273 K

554) A graph is plotted between two variable that is pressure and volume at constant temperature and fixed number of moles
of the gas, the graph is called
a) Isotherm b) Isobar c) Isochor d) Adiabat

555) The number of bonds in nitrogen molecule is

a) one ó and one b) one ó and two c) three sigma only d) two ó and one

556) The electrochemical cell stopts working after sometime because

a) The reaction reverse its b) Electrode potentials of c) Electrode potentials of d) One of electrode
direction both the electrodes equalize both the electrodes completely vanishes
becomes zero

557) Velocity of proton is

a) Dependent on its b) Dependent on its source c) Independent of its d) Equal to square of
wavelength wavelength amplitude

558) For a given process, the heat changes at constant pressure (qp) and at constant volume (qv) are related to each other as.
a) qp = qv b) qp < qv c) qp > qv d)

559) The number of natural Isotopes is

a) 280 b) 150 c) 300 d) 400

560) The energy of an electron at infinite orbital is

a) Positive b) Zero c) Negative d) Very high

561) During Combustion analysis, CO2 Produced is absorbed in

a) Mg(CIO4)2 b) 50% KOH c) CaCI2 d) P2O5

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562) Formula for calculating the number of electrons in a sub-shell is

a) 2n2 b) 2 ( 2l + 1 ) c) 2n2+1 d) 2 ( 2l + 2 )

563) Which of the following liquid has highest boiling point.

a) HCl b) HBr c) H2O d) Br2

564) The reactant which consumes earlier and gives least quantity of product is called.
a) Reactant c) Stoichiometryd d) Stoichiometric amount

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