School of Chemical Engineering CHE553 Chemical Engineering Thermodynamics
TUTORIAL 7
1. Determine good estimates of the fugacity and GR/RT for SO2 at 600K and 300 bar by using Lee-
Kesler correlation.
( )( )
φ = φ o φ1
ω
2. Estimate the fugacity of isobutylene as a gas at 280oC (553.15 K) and 20 bar by using the following
equation:
P
(
φ = exp r B o + ωB1
)
Tr
0.422 0.172
B o = 0.083 − B1 = 0.139 −
Tr1.6 Tr4.2
3. Determine the fugacity and fugacity coefficient for isobutane at 40oC (313.15 K) and pressure of
2 bar, 5.28 bar and 8 bar by using the given equations. The vapor pressure of isobutane at 40oC
(313.15 K) is 5.28 bar.
Fugacity coefficient for vapor phase:
P
(
φ = exp r B o + ωB1 )
Tr
0.422 0.172
B o = 0.083 − B1 = 0.139 −
Tr1.6 Tr4.2
Fugacity for liquid phase:
f i = φisat Pi sat exp
(
V sat P − Pi sat )
RT
2
V sat = Vc Z c(1−Tr )
7
4. For the system ethylene(1)/propylene(2) as a gas, estimate fˆ1 , fˆ2 , φˆ1 , and φˆ2 at T = 423.15 K,
P = 30 bar and y1 = 0.35
(a) Through application of equation:
P
( )
^
ln φ1 = B11 + y 22δ 12
RT
P
( )
^
ln φ 2 = B22 + y12δ 12
RT
(b) Assuming that the mixture is an ideal solution
Semester 20232
