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SAFETY DATA SHEET

Love Beauty and Planet Shampoo Coconut Oil + Butterfly Pea + Vegan
Collagen

Section 1. Identification
Product name : Love Beauty and Planet Shampoo Coconut Oil + Butterfly Pea +
Vegan Collagen
Product description : Hair shampoo
Product code : 200000264848
Product code : 69576824_C, 69560363

Relevant identified uses of the substance or mixture and uses advised against

Identified uses
Consumer uses

Supplier's details : UNILEVER

700 Sylvan Avenue

Englewood Cliffs NJ 07632
USA

Emergency telephone number : Phone #: 800-761-3683 Monday thru Friday (8:30 AM – 5:00 PM
(with hours of operation) EST)
Emergency #: 800-745-9269 (24 hours)
Poison Control #: 800-949-7866 (24 hours)
CHEMTREC #: 800-424-9300(24 hours, Transportation
Emergencies)

Consumer Information:

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For information regarding the use of this product by a consumer, please refer directly to the product label. This
industrial MSDS is provided for workplace employees, per US OSHA regulations. It contains recommendations
for handling of this product in an occupational, or workplace, setting.

Any first aid or warnings that are applicable to consumer use are stated directly on the product label, in
accordance with all applicable government regulations.

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard
Communication Standard (29 CFR 1910.1200).

Classification of the substance or : EYE IRRITATION - Category 2A

mixture

GHS label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : Causes serious eye irritation.

Precautionary statements

General : Not applicable.

Prevention : Wear eye or face protection. Wash thoroughly after handling.
Response : IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice or attention.

Storage : Not applicable.

Disposal : Not applicable.
Supplemental label elements : None known.
Hazards not otherwise classified : None known.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

CAS number/other identifiers

Ingredient name % CAS number

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Cocamidopropyl Betaine 0 - 10 61789-40-0

Sodium Lauroyl Isethionate 0-3 7381-01-3

Sodium Methyl Lauroyl Taurate 0-3 4337-75-1

Sodium benzoate 0-3 532-32-1

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in
the concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. If material has
been swallowed and the exposed person is conscious, give small
quantities of water to drink. Stop if the exposed person feels sick as
vomiting may be dangerous. Do not induce vomiting unless directed
to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give
anything by mouth to an unconscious person. If unconscious, place
in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband.

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Most important symptoms/effects, acute and delayed

Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following:

pain or irritation
watering
redness
Inhalation : None known.
Skin contact : No specific data.
Ingestion : None known.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist

immediately if large quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media : None known.
NFPA 30B Classification : Not available.

Specific hazards arising from the : In a fire or if heated, a pressure increase will occur and the container
chemical may burst.
Hazardous thermal : No specific data.
decomposition products

Special protective actions for fire- : Promptly isolate the scene by removing all persons from the vicinity
fighters of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training.
Special protective equipment for : Fire-fighters should wear appropriate protective equipment and self-
fire-fighters contained breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.
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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilled material. Avoid breathing vapor or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note
of any information in Section 8 on suitable and unsuitable materials.
See also the information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble. Alternatively, or if water-
insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach
release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage
with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilled product. Note: see Section 1
for emergency contact information and Section 13 for waste
disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8).
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid
breathing vapor or mist. Keep in the original container or an
approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container.

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Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where
hygiene this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering
eating areas. See also Section 8 for additional information on
hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original
including any incompatibilities container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10)
and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible
materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits

Appropriate engineering controls : Good general ventilation should be sufficient to control worker
exposure to airborne contaminants.
Environmental exposure controls : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume scrubbers,
filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: chemical splash
goggles.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved

standard should be worn at all times when handling chemical
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products if a risk assessment indicates this is necessary. Considering

the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of
mixtures, consisting of several substances, the protection time of the
gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator
that meets the appropriate standard or certification. Respirators must
be used according to a respiratory protection program to ensure
proper fitting, training, and other important aspects of use.

Section 9. Physical and chemical properties

Appearance

Physical state : liquid

Color : Off-white.
Odor : Characteristic.
Odor threshold : Not available.
pH : 5.8 [Conc. (% w/w): 1,000 g/l ]
Melting point : Not applicable
Under normal conditions, melting point/freezing point will not be
observed
Boiling point : Not available.
Flash point : Non-flammable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: Not available.
(flammable) limits Upper: Not available.
Vapor density : Not available.
Relative density : Not available.
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic: Not available.
Kinematic: Not available.

Section 10. Stability and reactivity

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Reactivity : No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition : Under normal conditions of storage and use, hazardous
products decomposition products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Conclusion/Summary : Based on available data, the classification criteria are not met.

Irritation/Corrosion

Conclusion/Summary
Skin : Non-irritant to skin.
Eyes : Causes serious eye irritation.
Respiratory : Non-irritating to the respiratory system.

Sensitization

Conclusion/Summary
Skin : Not sensitizing
Respiratory : Not sensitizing

Mutagenicity

Conclusion/Summary : Based on available data, the classification criteria are not met.

Carcinogenicity

Conclusion/Summary : Not classified or listed by IARC, NTP, OSHA, EU and ACGIH.

Reproductive toxicity

Conclusion/Summary : Based on available data, the classification criteria are not met.

Teratogenicity

Conclusion/Summary : Based on available data, the classification criteria are not met.

Specific target organ toxicity (single exposure)

Not available.

Specific target organ toxicity (repeated exposure)

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Not available.

Aspiration hazard
Not available.

Information on the likely routes : Not available.

of exposure

Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:

pain or irritation
watering
redness
Inhalation : None known.
Skin contact : No specific data.
Ingestion : None known.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects : No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Long term exposure

Potential immediate effects : No known significant effects or critical hazards.

Potential delayed effects : No known significant effects or critical hazards.

Potential chronic health effects

Conclusion/Summary : Based on available data, the classification criteria are not met.

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
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Numerical measures of toxicity

Acute toxicity estimates

Route ATE value

Oral >5,000 mg/kg

Section 12. Ecological information

Toxicity

Conclusion/Summary : No known significant effects or critical hazards.

Persistence and degradability

Conclusion/Summary : No known significant effects or critical hazards.

Conclusion/Summary : No known significant effects or critical hazards.

Mobility in soil

Soil/water partition coefficient : Not available.

(KOC)
Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever
possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not
be disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be
considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
RCRA classification : No known significant effects or critical hazards.

United States - RCRA Acute hazardous waste "P" List: Not listed

United States - RCRA Toxic hazardous waste "U" List: Not listed
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Section 14. Transport information

FOR SHIPMENT IN
CONSUMER GROUND WATER AIR
PACKAGING
PROPER SHIPPING
Not regulated Not regulated Not regulated
NAME:
HAZARD CLASS: Not regulated Not regulated Not regulated
UN/ID #: None None None
PACKING GROUP: None None None
REQUIRED MARKINGS
None None None
and/or LABELS:
MARKINGS and/or LABEL
None None None
TYPES:
ADDITIONAL
Not regulated Not regulated Not regulated
INFORMATION:

Special precautions for user : Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product know what to do in the event of an accident
or spillage.

Transport in bulk according to IMO instruments

Not available.

Section 15. Regulatory information

U.S. Federal regulations : United States - TSCA 12(b) - Chemical export notification:
None of the components are listed.
United States - TSCA 4(a) - Final Test Rules: Not listed
United States - TSCA 4(a) - ITC Priority list: Not listed
United States - TSCA 4(a) - Proposed test rules: Not listed
United States - TSCA 4(f) - Priority risk review: Not listed
United States - TSCA 5(a)2 - Final significant new use rules:
Not listed
United States - TSCA 5(a)2 - Proposed significant new use rules:
Not listed
United States - TSCA 5(e) - Substances consent order: Not listed
United States - TSCA 6 - Final risk management: Not listed
United States - TSCA 6 - Proposed risk management: Not listed
United States - TSCA 8(a) - Chemical risk rules: Not listed
United States - TSCA 8(a) - Dioxin/Furane precusor: Not listed
United States - TSCA 8(a) - Chemical Data Reporting (CDR):
Not determined

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United States - TSCA 8(a) - Preliminary assessment report

(PAIR): Not listed
United States - TSCA 8(c) - Significant adverse reaction (SAR):
Not listed
United States - TSCA 8(d) - Health and safety studies: Not listed

United States - EPA Clean water act (CWA) section 307 -

Priority pollutants: Not listed

United States - EPA Clean water act (CWA) section 311 -

Hazardous substances: Not listed
United States - EPA Clean air act (CAA) section 112 -
Accidental release prevention - Flammable substances: Not
listed
United States - EPA Clean air act (CAA) section 112 -
Accidental release prevention - Toxic substances: Not listed
United States - Department of commerce - Precursor chemical:
Not listed

Clean Air Act Section 112(b) : Not listed

Hazardous Air Pollutants (HAPs)
Clean Air Act Section 602 Class I : Not listed
Substances
Clean Air Act Section 602 Class : Not listed
II Substances
DEA List I Chemicals (Precursor : Not listed
Chemicals)
DEA List II Chemicals (Essential : Not listed
Chemicals)

SARA 302/304 : Not applicable.

SARA 304 RQ : Not applicable.

SARA 311/312

Classification : EYE IRRITATION

Category 2A

Composition/information on ingredients

Name % Classification
Cocamidopropyl Betaine 0 - 10 Eye Dam., 1

Sodium Lauroyl Isethionate 0-3 Eye Irrit., 2A

Sodium Methyl Lauroyl Taurate 0-3 Eye Irrit., 2A

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Sodium benzoate 0-3 Eye Irrit., 2A

SARA 313
None of the components are listed.

State regulations
Massachusetts : None of the components are listed.
New York : None of the components are listed.
New Jersey : None of the components are listed.
Pennsylvania : None of the components are listed.

US California 22CCR Appendix X Substances

Not Listed

United States inventory (TSCA : Not determined.

8b)

Canada inventory : Not determined.

International regulations

International lists : China inventory (IECSC): Not determined.

Korea inventory: Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.

Chemical Weapons Convention : Not listed

List Schedule I Chemicals
Chemical Weapons Convention : Not listed
List Schedule II Chemicals
Chemical Weapons Convention : Not listed
List Schedule III Chemicals

Section 16. Other information

History
Date of printing : 05.02.2022
Date of issue/Date of revision : 05.02.2022
Date of previous issue : 00.00.0000
Version : 1.0
Prepared by : Global Product Compliance
Unilever Regulatory Affairs
40 Merritt Blvd
Trumbull, CT 06611
USA

Key to abbreviations : ATE = Acute Toxicity Estimate

ACGIH = American Conference of Governmental & Industrial Hygienists
AH = Acute Hazard
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BCF = Bioconcentration Factor

CAA = Clean Air Act
CARB = California Air Resources Board
CCR = California Code of Regulations
CERCLA = Comprehensive Environmental Response, Compensation &
Liability Act
CFR = Code of Federal Regulations
CH = Chronic Hazard
CWA = Clean Water Act
DEA = Drug Enforcement Administration
DOT = Department of Transportation
EC = European Commission
EPCRA = Emergency Planning and Community Right‑To‑Know Act
EST = Eastern Standard Time
F = Fire
HAPS = Hazardous Air Pollutants
HCS = Hazard Communication Standard
HMIS = Hazardous Materials Information System
HVOC = High Volatile Organic Compound
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IARC = International Agency for the Research of Cancer
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
IMO = International Maritime Organization
ITC = Interagency Testing Committee (TSCA)
KOC = Organic Carbon/Water Partition Constant
LogPow = logarithm of the octanol/water partition coefficient
LVOC = Low Volatile Organic Compound
MARPOL = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine
pollution)
MPPCF = Million Particles Per Cubic Foot
N/A = Not Applicable
NFPA = National Fire Protection Association
NOEC = No Observable Effect Concentration
NTP = National Toxicology Program
OSHA = Occupation Safety & Health Administration
PEL = Permissible Exposure Limit
RCRA = Resource Conservation & Recovery Act
RQ = Reportable Quantity
RTK = Right-To-Know
SARA = Superfund Amendments & Reauthorization Act
STEL = Short-Term Exposure Limit
TBD = To Be Determined
TCC = Tagliabue Closed Cup
TCLP = Toxicity Characteristic Leaching Procedure
TDG = Transport of Dangerous Goods
TLV = Threshold Limit Value
TSCA = Toxic Substances Control Act
TWA = Time Weighted Average
UN = United Nations
References : Evaluation method used for mixture classification: Calculation
method.

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Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.

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