Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II
SAFETY DATA SHEET
Jotamastic 87 Standard Comp B
1. Identification of the preparation and of the company
Product name and/or code : Jotamastic 87 Standard Comp B
Label No. : 527
Supplier/Manufacturer : Jotun India Pvt Ltd
Plot No. D-280, Ranjangaon MIDC
Taluka Shirur
District Pune -412210
Maharashtra State
India
[email protected]
Emergency telephone : Jotun India Pvt Ltd +91 2138 671300
number
Product use : Coatings: Hardener.
1,2 527
VValidationDate). 1
2. Hazards identification
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Harmful if swallowed. Causes burns. May cause sensitisation
by skin contact.
Corrosive
Additional hazards : None known.
3. Composition/information on ingredients
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Classification
Product/ingredient CAS no. % 67/548/EEC Regulation (EC) No. Type Notes
name 1272/2008 [CLP]
benzyl alcohol 100-51-6 >=7, Xn; R20/22 Acute Tox. 4, H302 [1] -
<25 Acute Tox. 4, H332
3-aminomethyl-3,5, 2855-13-2 >=10, Xn; R21/22 Acute Tox. 4, H302 [1] -
5-trimethylcyclohexylamine <20 C; R34 Acute Tox. 4, H312
R43 Skin Corr. 1B, H314
R52/53 Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Chronic 3,
H412
2,2,4(or 2,4,4)- 25513-64-8 >=7, Xn; R22 Acute Tox. 4, H302 [1] -
trimethylhexane-1, <10 C; R35 Skin Corr. 1A, H314
6-diamine R43 Eye Dam. 1, H318
R52/53 Skin Sens. 1, H317
Aquatic Chronic 3,
H412
See Section 16 for See Section 16 for
the full text of the R- the full text of the H
phrases declared statements
above. declared above.
Type
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Jotamastic 87 Standard Comp B
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.
4. First-aid measures
First-aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and seek medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running
water for at least 15 minutes, keeping eyelids open. Seek immediate medical
attention.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do NOT induce vomiting.
5. Fire-fighting measures
Extinguishing media : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
Extinguishing media not to : Do not use water jet.
be used
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required.
Cool closed containers exposed to fire with water. Do not release runoff from fire to
drains or watercourses.
6. Accidental release measures
Personal precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
Spill : Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see Section 13). Preferably clean with a detergent.
Avoid using solvents.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.
7. Handling and storage
Handling : Due to the organic solvents content of the mixture:
Prevent the creation of flammable or explosive concentrations of vapours in air and
avoid vapour concentrations higher than the occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this mixture. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Put on appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one.
Comply with the health and safety at work laws.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air.
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Jotamastic 87 Standard Comp B
When operators, whether spraying or not, have to work inside the spray booth,
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.
Storage : Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away
from heat and direct sunlight.
Keep container tightly closed.
Keep away from sources of ignition. No smoking. Prevent unauthorised access.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage.
8. Exposure controls/personal protection
Engineering measures : Provide adequate ventilation. Where reasonably practicable, this should be
achieved by the use of local exhaust ventilation and good general extraction. If
these are not sufficient to maintain concentrations of particulates and solvent
vapours below the OEL, suitable respiratory protection must be worn.
Occupational exposure limits
Personal protective equipment
Respiratory system : If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Skin and body : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Hands : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use,
storage, maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.
Always ensure that gloves are free from defects and that they are stored and used
correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical
damage and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Eyes : Use safety eyewear designed to protect against splash of liquids.
9. Physical and chemical properties
Physical state : Liquid.
Odour : Characteristic.
Colour : Various colours.
Flash point : Closed cup: 99°C (210,2°F)
Density : 1.03 g/cm³
Explosion limits : 1.2 - 13%
Solubility : Insoluble in the following materials: cold water and hot water.
Boiling point : Lowest known value: 205°C (401°F) (benzyl alcohol). Weighted average: 222.79°C
(433°F)
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Jotamastic 87 Standard Comp B
10. Stability and reactivity
Stable under recommended storage and handling conditions (see Section 7).
Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.
Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong
acids.
11. Toxicological information
There are no data available on the mixture itself. The mixture has been assessed following the conventional method of
the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See Sections 2
and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness,
drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by
absorption through the skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the
skin, resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may
cause irritation and reversible damage. Swallowing may cause nausea, diarrhoea and vomiting.
Contains 3-aminomethyl-3,5,5-trimethylcyclohexylamine, 2,2,4(or 2,4,4)-trimethylhexane-1,6-diamine. May produce an
allergic reaction.
Corrosive to eyes and skin.Vapour may be irritating to eyes and respiratory system.Harmful if ingested.Material is
corrosive to the mucous membranes.
12. Ecological information
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.
The mixture has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is not classified as dangerous for the environment but contains a substance or substances dangerous
for the environment. See section 3 for details.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
3-aminomethyl-3,5, Intoxication Acute EC50 17,4 to 21,5 Daphnia - 48 hours
5-trimethylcyclohexylamine mg/l Fresh water Water flea -
Daphnia
magna - <24
hours
- Acute IC50 37 mg/l Algae 72 hours
trimethylhexamethylenediamine - Acute EC50 31,5 mg/l Daphnia - 24 hours
Daphnia
magna
- Acute EC50 29,5 mg/l Algae - 72 hours
Scenedesmus
subspicatus
- Acute LC50 150 mg/l Fish - 48 hours
Leuciscus
idus
melanotus
Ecological information
Biodegradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
benzyl alcohol - - Readily
3-aminomethyl-3,5, - - Not readily
5-trimethylcyclohexylamine
trimethylhexamethylenediamine - - Not readily
Bioaccumulative potential
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Jotamastic 87 Standard Comp B
Product/ingredient name LogKow BCF Potential
benzyl alcohol 1,1 <100 low
3-aminomethyl-3,5, 0,99 - low
5-trimethylcyclohexylamine
trimethylhexamethylenediamine -0,3 - low
13. Disposal considerations
Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
European waste catalogue : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous
(EWC) substances. If this product is mixed with other wastes, this code may no longer apply.
If mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.
14. Transport information
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name : Polyamines, liquid, corrosive, n.o.s. (3-aminomethyl-3,5,5-trimethylcyclohexylamine)
UN Number : 2735
Class : 8
Packing group : III
Label :
Additional information
ADR / RID : Tunnel restriction code: (E)
Hazard identification number: 80
IMDG : Emergency schedules (EmS): F-A, S-B
Marine pollutant: No.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
15. Regulatory information
EU regulations : The product is classified and labelled for supply in accordance with the Directive
1999/45/EC as follows:
Hazard symbol or symbols :
Corrosive
Risk phrases : R22- Harmful if swallowed.
R34- Causes burns.
R43- May cause sensitisation by skin contact.
Safety phrases : S23- Do not breathe vapour / spray.
S26- In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S51- Use only in well-ventilated areas.
Contains : benzyl alcohol
3-aminomethyl-3,5,5-trimethylcyclohexylamine
trimethylhexamethylenediamine
Industrial use : The information contained in this safety data sheet does not constitute the user’s
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.
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Jotamastic 87 Standard Comp B
16. Other information
CEPE Classification : 2
Full text of abbreviated H : H302 Harmful if swallowed.
statements H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
H412 Harmful to aquatic life with long lasting effects.
Full text of abbreviated R : R22- Harmful if swallowed.
phrases R20/22- Harmful by inhalation and if swallowed.
R21/22- Harmful in contact with skin and if swallowed.
R34- Causes burns.
R35- Causes severe burns.
R43- May cause sensitisation by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006.
Date of issue : 09.04.2014.
Notice to reader
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.
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